Test to identify carbonyl group

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Carbonyl compounds can be identify by different chemical tests which will help to differentiate between aldehyde and ketone.

Education

Test to identify carbonyl
group
Aldehyde and Ketone

Silver nitrate
&
NaOH
Ammonium hydroxide
Silver oxide

Ppt get disolve
Organic compound
Tollen’s reagent

Silver Mirror Test
Heating the mixture in
water bath
Formation of ppt

Organic compound is added in Fehling’s
solution and heated in water bath

Iodoform Test
• This test is given by all those carbonyl compounds, which contain
terminal methyl group.
CH3 ----- C O
R
In this reaction, carbonyl compound react with NaOH + I2, and gives
yellow ppt of iodoform.
Terminal
methyl group
Carbonyl group

Now NaOH is added until brown colour just
disappears

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