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Climate Change
and the
Greenhouse Gases
Introduction to
Environmental Science
WEATHER
 state of the atmosphere at a particular time and
place
 elements: temperature, humidity, cloudiness,
precipitation, wind, and pressure
 elements are organized into various weather
systems: monsoons, areas of high and low
pressure, thunderstorms, and tornadoes
monsoons 
(Arabic
mauism,
“season”),
wind that
changes
direction
with the
change of
seasons
LPA HPA
Tropical cyclone occurrence/passage
within the Philippine Area of
Responsibility during the 1948-2010
period.
Decadal changes in intense tropical cyclone occurrence in the three main islands in
the Philippines(1951-2000).
thunderstorms
 rain cloud or clouds that
produce thunder and lightning
 Formation:
 warm/humid ground air rises
 becomes cooler
 water vapor in air
condenses
if warmer than surrounding 
conditions, continue to rise
 lightning = large charge difference
exists between the bottom of the
cloud and the ground
tornadoes
Climate (from Greek klimat, inclination or latitude)
 long-term effect of the sun's radiation on earth's surface
and atmosphere
 influenced by the atmosphere; by the ways in which it
and the ocean transport heat
 for any given area on earth, not only the latitude must be
considered but also: elevation, terrain, distance from the
ocean, relation to mountain systems and lakes, and other
such influences
CLIMATICCATASTROPHES
• long-term change in the statistical distribution of weather
patterns over periods of time (decades-millions of years)
• may be limited to a specific region, or may occur across the
whole Earth
• global climate change: global warming or global cooling
• affects the limiting capacity of species: shown in the great
die-off 65 million years ago(late Cretaceous period) where
dinosaurs, large numbers of animals and plant species became
extinct due to sudden cooling
DRIVING FORCES AND PATTERNS IN CLIMATIC CHANGES
 MILANKOVITCH ASTRONOMICAL THEORY
 Serbian scientist Milutin Milankovitch
 regular climatic fluctuations based on three variations:
1. Earth’s elliptical orbit (100,000-year cycle)
2. axis of rotation (40,000-year cycle)
3. axis wobbles (26,000-year period)
 variability in sunlight distribution
 Arctic Circle low amounts of summer radiation about once every
100,000 years  glaciation
 responsible for glaciers and ice sheets during the Pleistocene Epoch (1.8
million to 11,500 years before present) glacial and interglacial period
 historical precedent : “little ice age”, Europe, 1440s = temperature
drops, fishes migrated away and settlers died in some settlements
SOLAR ACTIVITY ATTRIBUTED TO SUNSPOTS
Sunspots - huge magnetic storms in darker regions on the
sun’s surface ; 11-year cycles
 maximum sunspots: sun emits more energy
 sunspot cycles indicator of overall brightness of the
sun; changes on cycles of a century ; have an influence
on climate
 10% of the total effect that increasing levels of that
greenhouse gases have had on warming the atmosphere
to date
 evidence : scientists pointed to periods in the 17th
century when hardly any sunspots had been observed
presumably reflecting spells of drought
 sunspots reflected some kind of storminess on the Sun's
surface — violent activity that strongly affected the
Earth's magnetic field
 might explain the ice ages
 correlations between the sunspot cycle and rings in trees
 showed the extreme sensitivity of the climate system to
small perturbations
• 1610 till around 1900 – 1950 , ave. terrestrial ground temps.
depend solely on solar magnetic field variations
• sun’s polar magnetic fields fluctuates = opposite polarity (known
as “heliosphere” extends billions of kms.beyond Pluto)
• solar field reversals referred to “current sheet” sprawling
surface jutting outward from the sun’s equator where the sun’s
slowly-rotating magnetic field induces an electrical current (small
but lots of it): the amperage flows through a region 10,000 km
thick and billions of kilometers wide
• entire heliosphere organized around this enormous sheet:
current sheet becomes very wavy; Earth dip in and out of the
current sheet=transitions from one side to another can stir up
stormy space weather around our planet
• increased ultraviolet radiation during higher solar activity might
affect climate by altering stratospheric ozone
Solar Magnetic Cycles
• Moon moves 70% of the matter on the Earth’s
surface every day  suggest that maybe, it affects
air, wind, and causes atmospheric tides
• climate models assume the effect is zero or close
to it
• atmospheric tides swirl around Earth  standing
waves of abnormal air-pressure that slowly circle
the planet, once every 18 years
• if proven then key to understand the mysterious
Pacific ENSO pattern affecting the global climate
 Shifting Angles of Moon Orbits
• eject dust, aerosols and gas into the atmosphere
= cool climate; the larger the volcano means
greater effects
• volcanic gas: sulfur dioxide = global cooling;
volcanic carbon dioxide = global warming
• Mt. Pinatubo eruption in 1991 cooled the climate
by at least 1°C
 Volcanic Eruptions (tectonic climate change)
EL NIÑO SOUTHERN OSCILLATIONS ( ENSO)
EL NIÑO
•Spanish for “the child,” refers to the infant Jesus Christ; current
usually begins during the Christmas season
•increased of drier conditions
•climate disturbances:
sea surface temperatures in the southeastern tropical Pacific are high :low
pressure in warmer waters, rising moisture
in the eastern Pacific, water is cold and air pressure is high : creating arid
conditions along coastal South America, but
 trade winds blow from east to west, pushing sun-warmed waters westward
and exposing cold water in the east
droughts to the east, heavy rains to the west
• counterpart is La NiÑa = The Little Girl, sometimes El Viejo= anti-El NiÑo
 When a high
pressure cell in the
standing wave lies
over the high
pressure summer
semi-stationary high,
the anticlockwise
circulation is
strengthened. This
increases the
prevailing trade
winds (which run
East to West across
that part of the
Pacific). This sets up
La Nina type
conditions.
Fact : Without natural
greenhouse effect, Earth’s
climate is about 33°C
cooler—too cold for most
living organisms to survive.
THE GREENHOUSE
EFFECT
 certain gases in atmosphere
trap heat emitted from Earth’s
surface = insulating and
warming the planet
 warmed Earth for over 4
billion years
 Industrial Revolution:1700s
 humans burn fossil fuels
(coal, oil, and natural gas),
clearing land for agriculture /
settlements,  releases same
gases that trap heat in the
atmosphere: carbon dioxide,
methane, and nitrous oxide
(risen higher than at any time
in at least the last 650,000
year)
0.74 °C increase in
global mean
temperature during
the last 150 years
- IPCC REPORT, 2011
 prolonged drought / increased
flooding in some world’s leading
agricultural regions
 affect weather patterns
 global warming( an increase in Earth’s
surface temperature of about
0.6°C over the last 100 years)
 Earth’s climate warmer than it would naturally
 trap more heat near Earth’s surface
gases build up
Observed mean annual minimum
temperature anomalies in the Philippines
during the 1951-2010 period (compared
with 1971-2000 mean values).
 interaction between
sunlight and the layer of
greenhouse gases in the
atmosphere
 sunlight includes visible
light, infrared light, gamma
rays, X rays, and ultraviolet
light
 some 25 % of the radiant
energy is reflected back
into space by clouds and
other atmospheric particles
 about 20 % absorbed in the
atmosphere: Sun’s
ultraviolet radiation is
Greenhouse Gases
 refers to gases that contribute to the greenhouse effect
by absorbing infrared radiation (heat)
 occur naturally or manufactured
 most abundant naturally occurring is water vapor
carbon dioxide  methane nitrous oxide
 human-made chemicals as greenhouse gases :
chlorofluorocarbons (CFCs), hydrochlorofluorocarbons
(HCFCs), hydrofluorocarbons (HFCs), and
perfluorocarbons (PFCs)
 1700s: human activities have increased the levels of
greenhouse gases in the atmosphere
WATER VAPOR
most common greenhouse gas in the
atmosphere
60-70 % of natural greenhouse effect
human activities increase greenhouse
gases: evaporation of oceans, lakes, and
rivers, evapotranspiration  increase
and raise the amount of water vapor in
the atmosphere
CARBON DIOXIDE
circulates in environment thru natural processes: carbon cycle
volcanic eruptions ,decay of plant/animal matter release CO2
into the atmosphere.
in respiration: animals digest to release the energy required to
build and maintain cellular activity
byproduct of respiration: formation ofCO2
oceans, lakes, rivers absorb CO2 from atmosphere
photosynthesis: plants collect CO2 use it to make their own
food incorporating carbon into new plant tissue releasing
oxygen to the environment as a byproduct
METHANE
natural processes produce methane:
natural gas
released thru:
 decomposition of carbon-containing
substances found in oxygen-free
environments, such as wastes in
landfills
 ruminating animals: cattle , sheep
belch methane as a byproduct of
digestion
 microorganisms in damp soils: rice
fields, break down organic matter
 emitted: coal mining,
production/transport of other fossil
fuels
 others: wetlands, termites, oceans
NITROUS OXIDE
released by burning of fossil fuels,
automobile exhaust
farmers use nitrogen-containing fertilizers to
provide nutrients to their crops
when these fertilizers break down in the soil,
they emit nitrous oxide into the air
plowing fields also releases nitrous oxide
OZONE
 natural and human-made
 ozone in upper atmosphere :ozone
layer shields life on Earth from
the harmful ultraviolet radiation
 ozone in lower atmosphere : smog
severe type of air pollution
 ozone in the lower atmosphere
tends to be limited to industrialized
regions
FLUORINATED COMPOUNDS
most potent GHGs emitted produced by human activities
main categories: CFCs, HCFCs, HFCs, PFCs, SF6
used in a variety of manufacturing processes
one molecule =thousand times effective trapping heat than a
single molecule CO2
long atmospheric lifetime, high global warming potential,
depletes O3
affect the climate for many decades or centuries
UVB radiation can cause skin cancer, linked to cataracts of
the eye, suppression of immune system
at risk from UVB : shellfishes, fishes, amphibians,
phytoplankton, microscopic organisms (foundation of aquatic
food webs)
drift up to the stratosphere
 break down by ultraviolet radiation
 release components
 depletes ozone layer
 ozone layer thins
 more UVB reaches Earth’s
surface
CHLOROFLUOROCARBONS (CFCs)
 stable, nonflammable, noncorrosive, nontoxic, inexpensive
 developed in 1920s
 refrigerants: refrigerators, freezers, air conditioners, heat pumps,
 propellants: aerosols and medical inhalers
 insulating foams: packaging materials, furniture, bedding, and car seats
 cleaning agents: electronic circuit boards, metal parts, and dry cleaning
processes
 1 Cl atom destroy 100,000 ozone molecules
Since 1992, there has been a steady decline in the total consumption of
ODS. Serious efforts have led to the total phaseout of CFC 113, 114 and 115
as of 1999. The POD, through the NCPP Project, has aimed to phase out the
remaining consumption of CFCs available locally. Importation of CFC-11 has
been banned in 2005. The importation of CFC-12 is likewise set to be totally
phasedout by 2010 (zero importation of CFCs).
HYDROFLUOROCARBONS (HFCs)
 alternative to ozone damaging CFCs in
refrigeration systems
 three main HFCs are HFC-23, HFC-134a
and HFC152a, with HFC-134a being the
most widely used refrigerant.
 HFC-134a have risen massively; an
atmospheric lifetime of about 14 years
HYDROCHLOROFLUOROCARBON
s (HCFCs)
 close to CFCs, but including 1 or more H atoms
 gases/liquids, very volatile, fairly stable,
unreactive, nonpolar liquids
 similar properties to HBFCs, Halons HCFCs
 volatile organic compounds (VOCs)
 replaced CFCs, now used in refrigerators, freezers and
air conditioning systems, insulative foams
 phased out in developed countries
 amounts emitted relatively small but powerful warming
effect
Volatile Organic Compounds (VOCs) – “Hydrocarbon compounds that
have low boiling points, usually less than 100ºC, and therefore evaporate
readily. Some are gases at room temperature. Propane, benzene, and
other components of gasoline are all volatile organic compounds.” - Art,
1993
PERFLUORINATED COMPOUNDS (PFCs)
 make products stain, grease, and water resistant, non-stick , stain-
repellant
 uses: paper food containers like microwave popcorn bags, fast food
wrappers
 considered persistent organic pollutants (POPs)
 resist chemical, biological, and photolytic degradation in the environment
 biomagnify in the food chain; bioaccumulate in animal and human
tissues
 linked to: Thyroid dysfunction, Preeclampsia, Risk of high cholesterol,
Risk of cancer, Liver dysfunction, Immunotoxicity, Endocrine disruption,
Developmental delays, Fertility issues
 present in: Teflon, Scotchguard, carpets, clothing, car interiors,
furnitures, drinking water thru leaching
SULFUR HEXAFLUORIDE (SF6)
 24,000 times the warming effect as an equal amount of
carbon dioxide
 inorganic, colorless, odorless, non-flammable gas
 use : electrical industry as a gaseous dielectric medium
for various voltage circuit breakers, switchgear and
other electrical equipment, often replacing oil filled
circuit breakers (OCBs) that can contain harmful PCBs
 Other factors in Greenhouse Effect
Aerosols
 airborne particles,absorb, scatter, reflect radiation back
into space
 examples: clouds, windblown dust, and particles traced
to erupting volcanoes
 not considered heat-trapping GHGs but affect heat
transfer radiated from Earth to space
 light-colored aerosols = cooling effect, dark aerosols =
soot contribute to warming
INDICATORS OF CLIMATE CHANGE
Increase in:
 Tropospheric temperature
 Humidity
 Temperature over oceans
 Sea surface temperature
 Sea level
 Ocean heat content
 Temperature over land
Decrease in:
 Sea ice
 Glaciers
 Snow cover
CONCENTRATIONS AND TRENDS
ARMM- temperature = (27.6 °C +1.0 °C) = 28.6 °C;
rainfall = (225.3+14.2)mm or 239.5mm;
number of days with Tmax > 35 °C 2006-2035 period (centered at 2020) = 3,382;
number of dry days in Cotabato City during the 2006-2035 period (centered at 2020)
= 5,471
 increase in annual mean temperature by 0.57 °C;
 trends of tropical cyclone occurrence/passage within the so-
called Philippine Area of Responsibility (PAR) show that an
average of 20 tropical cyclones form and/or cross the PAR
per year with strong multi-decadal variability
 trends of extreme daily temperatures and extreme daily
rainfall indicate increase in number of hot days but decrease
of cool nights, and those of rainfall are not clear, both in
magnitude and direction with very little spatial coherence
Current and projected
number of dry days in
the Philippines in 2020
and 2050 under mid-
range scenario.
Current and projected
extreme rainfall in the
Philippines in 2020 and 2050
under mid-range scenario.
 www.bom.au.gov(elnino.htm)
 www.ensaa.eu.htm
 www.volcanoes.usgs.gov.htm
 www.aradical‘snut.htm
 www.wyi.htm
 www.ecochild'splay.htm

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Climate Change and the Greenhouse Gases

  • 1. Climate Change and the Greenhouse Gases Introduction to Environmental Science
  • 2. WEATHER  state of the atmosphere at a particular time and place  elements: temperature, humidity, cloudiness, precipitation, wind, and pressure  elements are organized into various weather systems: monsoons, areas of high and low pressure, thunderstorms, and tornadoes
  • 4. LPA HPA Tropical cyclone occurrence/passage within the Philippine Area of Responsibility during the 1948-2010 period. Decadal changes in intense tropical cyclone occurrence in the three main islands in the Philippines(1951-2000).
  • 5. thunderstorms  rain cloud or clouds that produce thunder and lightning  Formation:  warm/humid ground air rises  becomes cooler  water vapor in air condenses if warmer than surrounding  conditions, continue to rise  lightning = large charge difference exists between the bottom of the cloud and the ground
  • 7. Climate (from Greek klimat, inclination or latitude)  long-term effect of the sun's radiation on earth's surface and atmosphere  influenced by the atmosphere; by the ways in which it and the ocean transport heat  for any given area on earth, not only the latitude must be considered but also: elevation, terrain, distance from the ocean, relation to mountain systems and lakes, and other such influences
  • 9. • long-term change in the statistical distribution of weather patterns over periods of time (decades-millions of years) • may be limited to a specific region, or may occur across the whole Earth • global climate change: global warming or global cooling • affects the limiting capacity of species: shown in the great die-off 65 million years ago(late Cretaceous period) where dinosaurs, large numbers of animals and plant species became extinct due to sudden cooling
  • 10. DRIVING FORCES AND PATTERNS IN CLIMATIC CHANGES  MILANKOVITCH ASTRONOMICAL THEORY  Serbian scientist Milutin Milankovitch  regular climatic fluctuations based on three variations: 1. Earth’s elliptical orbit (100,000-year cycle) 2. axis of rotation (40,000-year cycle) 3. axis wobbles (26,000-year period)  variability in sunlight distribution  Arctic Circle low amounts of summer radiation about once every 100,000 years  glaciation  responsible for glaciers and ice sheets during the Pleistocene Epoch (1.8 million to 11,500 years before present) glacial and interglacial period  historical precedent : “little ice age”, Europe, 1440s = temperature drops, fishes migrated away and settlers died in some settlements
  • 11.
  • 12. SOLAR ACTIVITY ATTRIBUTED TO SUNSPOTS Sunspots - huge magnetic storms in darker regions on the sun’s surface ; 11-year cycles  maximum sunspots: sun emits more energy  sunspot cycles indicator of overall brightness of the sun; changes on cycles of a century ; have an influence on climate  10% of the total effect that increasing levels of that greenhouse gases have had on warming the atmosphere to date  evidence : scientists pointed to periods in the 17th century when hardly any sunspots had been observed presumably reflecting spells of drought  sunspots reflected some kind of storminess on the Sun's surface — violent activity that strongly affected the Earth's magnetic field  might explain the ice ages  correlations between the sunspot cycle and rings in trees  showed the extreme sensitivity of the climate system to small perturbations
  • 13. • 1610 till around 1900 – 1950 , ave. terrestrial ground temps. depend solely on solar magnetic field variations • sun’s polar magnetic fields fluctuates = opposite polarity (known as “heliosphere” extends billions of kms.beyond Pluto) • solar field reversals referred to “current sheet” sprawling surface jutting outward from the sun’s equator where the sun’s slowly-rotating magnetic field induces an electrical current (small but lots of it): the amperage flows through a region 10,000 km thick and billions of kilometers wide • entire heliosphere organized around this enormous sheet: current sheet becomes very wavy; Earth dip in and out of the current sheet=transitions from one side to another can stir up stormy space weather around our planet • increased ultraviolet radiation during higher solar activity might affect climate by altering stratospheric ozone Solar Magnetic Cycles
  • 14.
  • 15. • Moon moves 70% of the matter on the Earth’s surface every day  suggest that maybe, it affects air, wind, and causes atmospheric tides • climate models assume the effect is zero or close to it • atmospheric tides swirl around Earth  standing waves of abnormal air-pressure that slowly circle the planet, once every 18 years • if proven then key to understand the mysterious Pacific ENSO pattern affecting the global climate  Shifting Angles of Moon Orbits
  • 16. • eject dust, aerosols and gas into the atmosphere = cool climate; the larger the volcano means greater effects • volcanic gas: sulfur dioxide = global cooling; volcanic carbon dioxide = global warming • Mt. Pinatubo eruption in 1991 cooled the climate by at least 1°C  Volcanic Eruptions (tectonic climate change)
  • 17.
  • 18. EL NIÑO SOUTHERN OSCILLATIONS ( ENSO) EL NIÑO •Spanish for “the child,” refers to the infant Jesus Christ; current usually begins during the Christmas season •increased of drier conditions •climate disturbances: sea surface temperatures in the southeastern tropical Pacific are high :low pressure in warmer waters, rising moisture in the eastern Pacific, water is cold and air pressure is high : creating arid conditions along coastal South America, but  trade winds blow from east to west, pushing sun-warmed waters westward and exposing cold water in the east droughts to the east, heavy rains to the west • counterpart is La NiÑa = The Little Girl, sometimes El Viejo= anti-El NiÑo
  • 19.  When a high pressure cell in the standing wave lies over the high pressure summer semi-stationary high, the anticlockwise circulation is strengthened. This increases the prevailing trade winds (which run East to West across that part of the Pacific). This sets up La Nina type conditions.
  • 20. Fact : Without natural greenhouse effect, Earth’s climate is about 33°C cooler—too cold for most living organisms to survive. THE GREENHOUSE EFFECT  certain gases in atmosphere trap heat emitted from Earth’s surface = insulating and warming the planet  warmed Earth for over 4 billion years  Industrial Revolution:1700s  humans burn fossil fuels (coal, oil, and natural gas), clearing land for agriculture / settlements,  releases same gases that trap heat in the atmosphere: carbon dioxide, methane, and nitrous oxide (risen higher than at any time in at least the last 650,000 year) 0.74 °C increase in global mean temperature during the last 150 years - IPCC REPORT, 2011
  • 21.  prolonged drought / increased flooding in some world’s leading agricultural regions  affect weather patterns  global warming( an increase in Earth’s surface temperature of about 0.6°C over the last 100 years)  Earth’s climate warmer than it would naturally  trap more heat near Earth’s surface gases build up Observed mean annual minimum temperature anomalies in the Philippines during the 1951-2010 period (compared with 1971-2000 mean values).
  • 22.  interaction between sunlight and the layer of greenhouse gases in the atmosphere  sunlight includes visible light, infrared light, gamma rays, X rays, and ultraviolet light  some 25 % of the radiant energy is reflected back into space by clouds and other atmospheric particles  about 20 % absorbed in the atmosphere: Sun’s ultraviolet radiation is
  • 23. Greenhouse Gases  refers to gases that contribute to the greenhouse effect by absorbing infrared radiation (heat)  occur naturally or manufactured  most abundant naturally occurring is water vapor carbon dioxide  methane nitrous oxide  human-made chemicals as greenhouse gases : chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), hydrofluorocarbons (HFCs), and perfluorocarbons (PFCs)  1700s: human activities have increased the levels of greenhouse gases in the atmosphere
  • 24. WATER VAPOR most common greenhouse gas in the atmosphere 60-70 % of natural greenhouse effect human activities increase greenhouse gases: evaporation of oceans, lakes, and rivers, evapotranspiration  increase and raise the amount of water vapor in the atmosphere
  • 25. CARBON DIOXIDE circulates in environment thru natural processes: carbon cycle volcanic eruptions ,decay of plant/animal matter release CO2 into the atmosphere. in respiration: animals digest to release the energy required to build and maintain cellular activity byproduct of respiration: formation ofCO2 oceans, lakes, rivers absorb CO2 from atmosphere photosynthesis: plants collect CO2 use it to make their own food incorporating carbon into new plant tissue releasing oxygen to the environment as a byproduct
  • 26. METHANE natural processes produce methane: natural gas released thru:  decomposition of carbon-containing substances found in oxygen-free environments, such as wastes in landfills  ruminating animals: cattle , sheep belch methane as a byproduct of digestion  microorganisms in damp soils: rice fields, break down organic matter  emitted: coal mining, production/transport of other fossil fuels  others: wetlands, termites, oceans
  • 27. NITROUS OXIDE released by burning of fossil fuels, automobile exhaust farmers use nitrogen-containing fertilizers to provide nutrients to their crops when these fertilizers break down in the soil, they emit nitrous oxide into the air plowing fields also releases nitrous oxide
  • 28. OZONE  natural and human-made  ozone in upper atmosphere :ozone layer shields life on Earth from the harmful ultraviolet radiation  ozone in lower atmosphere : smog severe type of air pollution  ozone in the lower atmosphere tends to be limited to industrialized regions
  • 29. FLUORINATED COMPOUNDS most potent GHGs emitted produced by human activities main categories: CFCs, HCFCs, HFCs, PFCs, SF6 used in a variety of manufacturing processes one molecule =thousand times effective trapping heat than a single molecule CO2 long atmospheric lifetime, high global warming potential, depletes O3 affect the climate for many decades or centuries UVB radiation can cause skin cancer, linked to cataracts of the eye, suppression of immune system at risk from UVB : shellfishes, fishes, amphibians, phytoplankton, microscopic organisms (foundation of aquatic food webs)
  • 30. drift up to the stratosphere  break down by ultraviolet radiation  release components  depletes ozone layer  ozone layer thins  more UVB reaches Earth’s surface
  • 31. CHLOROFLUOROCARBONS (CFCs)  stable, nonflammable, noncorrosive, nontoxic, inexpensive  developed in 1920s  refrigerants: refrigerators, freezers, air conditioners, heat pumps,  propellants: aerosols and medical inhalers  insulating foams: packaging materials, furniture, bedding, and car seats  cleaning agents: electronic circuit boards, metal parts, and dry cleaning processes  1 Cl atom destroy 100,000 ozone molecules Since 1992, there has been a steady decline in the total consumption of ODS. Serious efforts have led to the total phaseout of CFC 113, 114 and 115 as of 1999. The POD, through the NCPP Project, has aimed to phase out the remaining consumption of CFCs available locally. Importation of CFC-11 has been banned in 2005. The importation of CFC-12 is likewise set to be totally phasedout by 2010 (zero importation of CFCs).
  • 32. HYDROFLUOROCARBONS (HFCs)  alternative to ozone damaging CFCs in refrigeration systems  three main HFCs are HFC-23, HFC-134a and HFC152a, with HFC-134a being the most widely used refrigerant.  HFC-134a have risen massively; an atmospheric lifetime of about 14 years
  • 33. HYDROCHLOROFLUOROCARBON s (HCFCs)  close to CFCs, but including 1 or more H atoms  gases/liquids, very volatile, fairly stable, unreactive, nonpolar liquids  similar properties to HBFCs, Halons HCFCs  volatile organic compounds (VOCs)  replaced CFCs, now used in refrigerators, freezers and air conditioning systems, insulative foams  phased out in developed countries  amounts emitted relatively small but powerful warming effect Volatile Organic Compounds (VOCs) – “Hydrocarbon compounds that have low boiling points, usually less than 100ºC, and therefore evaporate readily. Some are gases at room temperature. Propane, benzene, and other components of gasoline are all volatile organic compounds.” - Art, 1993
  • 34. PERFLUORINATED COMPOUNDS (PFCs)  make products stain, grease, and water resistant, non-stick , stain- repellant  uses: paper food containers like microwave popcorn bags, fast food wrappers  considered persistent organic pollutants (POPs)  resist chemical, biological, and photolytic degradation in the environment  biomagnify in the food chain; bioaccumulate in animal and human tissues  linked to: Thyroid dysfunction, Preeclampsia, Risk of high cholesterol, Risk of cancer, Liver dysfunction, Immunotoxicity, Endocrine disruption, Developmental delays, Fertility issues  present in: Teflon, Scotchguard, carpets, clothing, car interiors, furnitures, drinking water thru leaching
  • 35. SULFUR HEXAFLUORIDE (SF6)  24,000 times the warming effect as an equal amount of carbon dioxide  inorganic, colorless, odorless, non-flammable gas  use : electrical industry as a gaseous dielectric medium for various voltage circuit breakers, switchgear and other electrical equipment, often replacing oil filled circuit breakers (OCBs) that can contain harmful PCBs
  • 36.  Other factors in Greenhouse Effect Aerosols  airborne particles,absorb, scatter, reflect radiation back into space  examples: clouds, windblown dust, and particles traced to erupting volcanoes  not considered heat-trapping GHGs but affect heat transfer radiated from Earth to space  light-colored aerosols = cooling effect, dark aerosols = soot contribute to warming
  • 37. INDICATORS OF CLIMATE CHANGE Increase in:  Tropospheric temperature  Humidity  Temperature over oceans  Sea surface temperature  Sea level  Ocean heat content  Temperature over land Decrease in:  Sea ice  Glaciers  Snow cover
  • 39. ARMM- temperature = (27.6 °C +1.0 °C) = 28.6 °C; rainfall = (225.3+14.2)mm or 239.5mm; number of days with Tmax > 35 °C 2006-2035 period (centered at 2020) = 3,382; number of dry days in Cotabato City during the 2006-2035 period (centered at 2020) = 5,471  increase in annual mean temperature by 0.57 °C;  trends of tropical cyclone occurrence/passage within the so- called Philippine Area of Responsibility (PAR) show that an average of 20 tropical cyclones form and/or cross the PAR per year with strong multi-decadal variability  trends of extreme daily temperatures and extreme daily rainfall indicate increase in number of hot days but decrease of cool nights, and those of rainfall are not clear, both in magnitude and direction with very little spatial coherence
  • 40. Current and projected number of dry days in the Philippines in 2020 and 2050 under mid- range scenario. Current and projected extreme rainfall in the Philippines in 2020 and 2050 under mid-range scenario.
  • 41.  www.bom.au.gov(elnino.htm)  www.ensaa.eu.htm  www.volcanoes.usgs.gov.htm  www.aradical‘snut.htm  www.wyi.htm  www.ecochild'splay.htm