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Tim Rivard MBa
Fuel Right (Canada) Limited
www.fuelright.ca
RUN CLEANER. RUN SMARTER.
A clean diesel program designed to
delivery higher quality fuel to exceed
the demands of new engine technology.
ABOUT US
Established mid 90’s
20 years R&D
Proprietary technology
Applications
Diesel fuel
Heating oil
Unleaded fuel
MGO
IFO Marine Fuels
Hydraulic Oils
3
OUR FOUNDER
35 years with DuPont
Materials Research Engineer
Expertise in Bacterial Growth & MIC
Numerous Publications
NACE
“Microbiologically Influenced Corrosion
– Corrosion Fundamentals”
“Identification of MIC”
Crevice Corrosion of Stainless Steel in
Recirculating Cooling Water”
Many others….
4
REGULATORY
Proprietary Blend
EU REACH Registered
US EPA Registered
UN GHS Compliant
Health Canada (GHS)
5
INTERNATIONAL DISTRIBUTION
Distributed in more than 32 Countries
6
OUR MISSION
Market innovative technology that enhances fuel quality
to a cleanliness standard exceeding ISO 4406 18/16/13,
eliminates microbial contamination in middle distillates,
prevents sludge recurrence, stops MIC corrosion and
optimizes storage tank, fuel filter and engine
performance.
7
IMPORTANT FACTORS TODAY
Particulate control
ISO 4406 18/16/13
Contamination
Water
Microbial
Corrosion
Filtration
ENGINE TECHNOLOGY
Common Rail Design
Injector pressures 120 – 150
MPa
5 injector strokes per piston
stroke
3000 rpm equates to 15,000
strokes per minute
Low tolerance to contaminated fuels
Requires enhanced fuel lubricity
Tighter filter tolerance
2 micron filtration
9
HPCR INJECTORS
Maximum particulate size
<2µ
Target - ISO 12/9/7
Water
<200 ppm
Lubricity
Injector Cooling
A typical HPCR injector does 5 TO 7 strokes per
engine rotation – an engine running at 2500 rpm
requires an injector to make 12500 strokes per
minute
INJECTOR FAILURES
Injector deposits
Salts (Na,Ca,S,Cl)
React with corrosion inhibitors forming carboxylic salt
deposits in injectors
Water
Catastrophic failure (seizure)
Wear
Excess fuel particulates
PREVENTATIVE MEASURES
FUEL HYGIENE
Water
Corrosion
microbes
FILTRATION
Water absorbing
Proper sizing
VALUE PROPOSITION
13
Holistic fuel quality management
Clean Fuel - free of microbial contamination, corrosion by-products
and water from the source of supply enhances the performance of the
overall system by reducing maintenance and eliminating factors
affecting engine performance.
Fuel Storage
Biofilms, Biocides, Water Emulsifiers
DIESEL STORAGE FACTS
3% of tank volume never gets
exchanged
1500 litres in a 50,000 litre tank
Diesel can carry 0.01% by weight of
water
IE. 50,000 litre tank
Exchanged 4x per month
150 litres water/month
Microbial Count (tank bottoms)
2.5B organisms per litre not uncommon
15
Reference:
National Petroleum News 91(7), p 20-22, July 1999
F.J. Passman, Ph.D., President, BCA, Inc.
DIESEL FUEL “ECOSYSTEM”
Hydro-
peroxides
Bacteria
Water
Corrosion
Oxidation
Catalysts
Cu, V, Fe
All factors affect fuel quality,
stability and performance
Interactive relationship
These factors are the Root
Causes of diesel fuel quality
Issues
16
BACTERIAL SLUDGE
FUEL AND WATER?
FUEL RIGHT AND WATER?
Amines establish Micelles
Attract water – polar bond
Create layering – pushing
excess water out of the fuel
to the bottom of the tank
FUEL RIGHT RESULTS – BEFORE/AFTER
Water
Clean Fuel
FUEL RIGHT RESULTS
Before/After
Gasolina
limpia
Bacteria – Biofilms?
IMPLICATIONS OF BACTERIAL PRESENCE
Higher rates of microbial
influenced corrosion
Tanks, strainers, risers, filters,
submersible pumps
Premature tank failures
6 months to 5 years
Environmental spills result
Excessively acidic deposits
pH 3-5
Breaks down composite tanks
Increasing maintenance
costs
22
HOW BIOFILMS AFFECT FUEL QUALITY
Reduces corrosion inhibitor
effectiveness
Reduces Anti-oxidant effectiveness
Reduces lubricity
Reduces Oxidative stability
Increases Peroxide number
Increases TAN (total acid number)
Increases Corrosion
CONVENTIONAL ADDITIVES
Do not displace bio-films
Do not dissolve sloughing
What does that mean?
Acute affects of additives
Reduced effectiveness
Not (dis)solving the key
source of the problem
FUEL RIGHT REMOVES BIOFILM
Fuel Right dissolves and
removes biofilms
Implications?
Releases trapped particulates
Removes corrosion influence
Removes acid producer
Eliminate Sloughing deposits
Hinder Potential bacteria
“blooms”
Fuel Right slowing dissolving bio-film
deposits and severely degraded fuel
deposits inside a diesel truck tank
TANK INTERIORS
Inspected after 1 year of continuous use with Fuel Right
Image credit: Fuel 360 New Zealand
FUEL RIGHT RESULTS
27
FUEL RIGHT® RESTORES FUEL QUALITY
28
Original Fuel
Sample
Treated with
Competitor
Treated with
Fuel Right®
DOES CLEAR FUEL = CLEAN FUEL?
1. 2. 3.
1. Tank Bottom sample
2. Above bottom layer
3. Top of the tank
Tank bottom sample shows strong evidence of MIC corrosion.
Despite being clear and bright, this fuel is unlikely to meet ISO 4406 Particulate
standard or SAE 4059
WORLDWIDE FUEL CHARTER
ISO 4406
Associate members
Asociación de Fábricas de Automotores de Argentina (ADEFA)
Associacion Mexicana de la Industria Automotriz, A.C. (AMIA)
Brazilian Association of motor vehicle and motorised agricultural
machinery manufacturers (ANFAVEA)
Canadian Vehicle Manufacturers’ Association (CVMA)
Chamber of Automotive Manufacturers of the Philippines, Inc.
(CAMPI)
China Association of Automobile Manufacturers (CAAM)
Global Automakers ›
Global Automakers of Canada (GAC)
Indonesia Automotive Federation (IAF)
Korean Automobile Manufacturers Association (KAMA)
National Association of Automobile Manufacturers of South Africa
(NAAMSA)
Malaysian Automotive Association (MAA)
Society of Indian Automobile Manufacturers (SIAM)
Thai Automotive Industry Association (TAIA)
Vietnam Automobile Manufacturers Association (VAMA)
ISO CLEANLINESS?
World Wide Fuel Charter
Two Key Metrics
Water content <200ppm
ISO code 18/16/13 particulate
standard
Fuel Right exceeds ISO fuel standard
Water content ~100 ppm
13/9/7 –measured with laser
particulate counter
Testing in Canada using Filtertechnik
PC 9001 Laser Particulate Counter.
31
ISO CODE 18/16/13
ISO 4406 Chart
Range Code
Particles per milliliter of fuel
Particle size and up
More than Up to/including
18 1,300 2,500 4µ
16 320 640 6µ
13 40 80 14µ
Note: High pressure common rail engines require fuel to minimize particulate count
from 3 and up. Previous generations of engines were able to tolerate up to 7
particles in size. The demand for cleaner fuel to avoid injector damage is much
higher than the worldwide fuel charter ISO4406 18/16/13 standard.
Why is particle count important?
How do injectors fail?
INTERNAL INJECTOR DEPOSITS
Images borrowed from CRC Report No. 665
(CRC Project No. DP-04-13a)
Carboxylate soap deposits Lacquer type deposits
New HPCR injectors are less tolerant of deposits and require much
cleaner fuel standards than ISO 4406 18/16/13
CARBOXYLATE DEPOSITS
Na/Ca salts
React with DDSA/HDSA
Used as a corrosion
control additive in the
pipeline industry
DDSA – dodecenyl succinic acid
HDSA – hexadecenyl succinic acid
SPILL CONTROL VALVE
Operate on a clearance
of 1.5 – 3 microns
(human hair is 40
microns)
Prone to particulate
damage
Biofilms deposit sugars
Reference: D.G. Quirk - BP
BIOFUEL BLENDS
“Some correlation between the introduction of
ULSD and/or use of biodiesel and the incidence
of IDID” – CRC Report No. 665, Oct 2013
Image depicts the degradation of
biofuel into a “black honey” substance
with low solubility
INJECTOR FAILURE
Loss of power
Over fuelling
Overheating
Piston failure
No-start condition
Emission control
ISO CODE 12/9/7 (Target for HPCR)
ISO 4406 Chart
Range Code
Particles per milliliter of fuel
Particle size and up
More than Up to/including
12 20 40 4µ
9 2.5 5 6µ
7 .64 1.3 14µ
Note: High pressure common rail engines require fuel to minimize particulate count
from 3µ and up. Previous generations of engines were able to tolerate up to 7µ
particles in size. The demand for cleaner fuel to avoid injector damage is much
higher than the worldwide fuel charter ISO4406 18/16/13 standard.
FUEL RIGHT FIELD RESULTS
(December 20, 2015 – 6 months of treatment)
UG Tank # Volume Count/ 18 Count/ 16 Count/ 13 Water ppm
allowable 1300-2500 320-640 40-80 200ppm
3 50,000 244* / 15** 146* / 14** 21* / 12** 87
4 75,000 89* / 14** 29* / 12** 3* / 9** 79
5 50,000 1475* / 18** 337* / 16** 15* / 11** 92
6 75,000 309 */ 15** 108 */ 14** 11* / 11** 85
7 50,000 470 */ 16** 170 */ 15** 11* / 11** 81
8 50,000 138 */ 14** 46* / 13** 4* / 9** 75
9 90,000 106 */ 14** 28* / 12** 2* / 8** 75
Tanks were installed in the mid 1980’s are located underground and were not cleaned prior to testing.
Laser Particulate Tests performed by Prime Fuel Polish, Sarnia, ON
December 20, 2015
Client: Hensall Coop, Hensall, ON
*First number represents actual particulate count
**Second number represents ISO Code Number
FUEL RIGHT FIELD RESULTS
(March 10, 2017 – 20 months of treatment)
UG Tank # Volume Count/ 18 Count/ 16 Count/ 13 Water ppm
allowable 1300-2500 320-640 40-80 200ppm
3 50,000 110* / 14** 10* / 11** 2* / 8** 86
4 75,000 42* / 13** 4* / 9** 1* / 7** 120
5 50,000 106* / 14** 11* / 11** 1* / 7** 88
6 75,000 88 */ 14** 13 */ 11** 3* / 9** 85
7 50,000 60 */ 13** 8 */ 10** 1* / 7** 90
8 50,000 154 */ 14** 32* / 12** 4* / 10** 127
9 90,000 50 */ 13** 7* / 10** 1* / 7** 110
Tanks were installed in the mid 1980’s are located underground and were not cleaned prior to testing.
Laser Particulate Tests performed by Prime Fuel Polish, Sarnia, ON
March 10, 2017
Client: Hensall Coop, Hensall, ON
*First number represents actual particulate count
**Second number represents ISO Code Number
FUEL RIGHT FIELD RESULTS
ISO 4406 Worldwide Fuel Charter
UG Tank # Volume 18 16 13 Water ppm
allowable 1300-2500 320-640 40-80 200ppm
1 unknown 73 */ 13** 14 */ 11** 1 */ 7** 120
Client has consistently treated fuel for more than 24 months
Tank was installed in the mid 1980’s are located underground and were not cleaned prior to testing.
Laser Particulate Tests performed by Prime Fuel Polish, Sarnia, ON - February 28, 2017
Client: Elgie Bus Lines, London, Ontario
*First number represents actual particulate count
**Second number represents ISO Code Number
FUEL RIGHT LAB RESULTS – 48 Hours
ISO 4406 Worldwide Fuel Charter
Count/ 18 Count/ 16 Count/ 13 Water ppm
allowable 1300-2500 320-640 40-80 200ppm
B2 Untreated 5056*/20** 1864*/18** 924*/14** 90.6
B2 (48 hours) Treated 48 hours 1437*/18** 281*/15** 35*/12**
B9 Untreated 3929*/19** 1130*/17** 34*/12** 66.7 ppm
B9 (48 hours) Treated 48 hours 546*/16** 118*/14** 22*/12**
B40 Untreated 17561*/21** 7891*/20** 617*/16** 102 ppm
B40 (48 hours) Treated 48 hours 11768*/21** 4113*/19** 134*/14**
Samples were provided by Terpel at their fuel terminal in Factactac Sept 20, 2017
Biofuel blend is Palm Oil
*First number represents actual particulate count
**Second number represents ISO Code Number
BATELLE FIELD STUDY
“Corrosion in Systems Storing and Dispensing Ultra Low Sulfur Diesel
(ULSD), Hypothesis Investigation” by Battelle Memorial Institute,
Columbus Ohio (published 13 August 2011)
Report analyses six diesel fuel tank systems in California, New York State,
and North Carolina to determine reasons for sludge and underlying
corrosion on various metal parts
Treated Tank NC-1 with Fuel Right 15K December 2011
Inspection Feb 8, 2012
Fiberglass double wall tank
Bacteria DNA count – too low to measure
Total Acid Number 0.01 KOH/L – ISO Standard 0.12 Maximum
Water 39 ppm (diesel can “hold” 100 ppm) – ISO Standard 200ppm Maximum
Tank NC-1 ONLY tank with minimal/no sludge formation
44
How does Fuel Right impact
injector life?
IMPLICATIONS OF FUEL RIGHT RESULTS
WWFC ISO 4406 18/16/13
Equates to 2500 particles per mL
of fuel
Fuel Right Results
Exceeds WWFC up to 60x
Reduction of particulate
Extends fuel system component life –
reduced injector wear Injector Needle – 3280 hours with 15K
3280 Hours JD7830
Corrosion – MIC?
WHAT IS MIC?
Microbially Influenced Corrosion
Electrolyte
Acceptor Site
Donor Site
MIC - Microbially Influenced Corrosion
Pitting Corrosion
Accelerated due to
presence of biofilms
Leads to tank failure
MIC
MIC EVIDENCE
“Coffee grounds” indicate severe corrosion present
STEEL TANK FAILURES
52
MIC – CORROSION EXAMPLES
53
FUEL RIGHT CORROSION PREVENTION
Strips biofilm from tank walls
Dissolves the bacterial colonies
Interrupts development of
acidic sludge
Hinders biofilm development
54
MICROSCOPIC CORROSION COATING
TREATMENT RESULTS
Late 90’s tank inspected after 1 year of Fuel Right 15K treatment. Tank is exceptionally cleaned
– showing evidence of minor MIC and vapour space corrosion after 20 years of service.
COMPOSITE TANKS NOT IMMUNE
Fiberglass Tanks
Water accumulation
Bacteria
pH 3-3.5
Extremely acidic
Breaks down binding resins
57
COMPOSITE TANK INTERIOR
58
WHAT ABOUT USING BIOCIDES?
Should only be used “after” you
have cleaned the fuel
Specific to bacteria type
Ineffective against well
established bacterial infections
May become a food source for
bacteria
Biocides can be corrosive
HOW DO BIOCIDES COMPARE?
Kill planktonic bacteria only
Bacteria develop resistant
strains
Not all species are vulnerable
Biofilms remain behind
Biocides are consumable
Potential food supply
FUEL RIGHT vs BIOCIDES
61
Actual Lab results at the end of an 18 month jar test. Fuel Right out performs
competitive products in its ability to dissolve and prevent bacterial growth and
protect from corrosion.
FUEL RIGHT vs FUEL ADDITIVES
62
Conventional additives are ineffective treatments against microbial sludge
TANK STORAGE SUMMARY
Clean Tank, free of bacteria, biofilms and water and
other contaminants is the most important factor in any
fuel system
Reduces potential fuel related failures
Enhances asset life – protection from corrosion and tank
failure
Enhances engine performance and engine component life
cycle
RUN CLEANER. RUN SMARTER.
Fuel Filtering & Delivery
Biofilms, Lubricity, Particulate
FILTRATION
Older series diesel engine Modern HPCR diesel engines
Refinery Fuels 0X 16X
Typical Fuel 4-8X 64-128X
Poor Fuel 16-32X 256-512X
Bad Fuel 64X 1024X +
Based on new engine technology, injectors are less tolerant to particulate
contamination. Dual stage filtration 10 um to < 2/4um required for new HPCR
engines. This chart shows how much cleaner fuel must be to meet modern injector
technology specifications when comparing to older series engines.
FILTER PLUGGING
High efficiency filtration (4
um)
Cold flow modifiers
Biofuel – glycerine forming
solids
Metal carboxylates
BIOFILMS & FILTERS
Biofilms are transparent
Biofilms block filters
Vacuum pressure affects
fuel flow
Fuel pump cavitation &
premature wear
These filters demonstrate consecutive reduced plugging
over 90 days of treatment. Despite appearing similar in
colour, the filter on the far left is restricted by opaque
biofilm. The filter on the right is clean as a result of a 90
day Fuel Right continuous treatment program.
FILTERING PARTICULATE
Common filter size
10-30µ
Implications
Smaller particulate still
passing through
Potential fuel pump or
injector failure
Common rail OEM’s
recommending 4µ
www.nikede.com.br (13) 33535830
December/2013 to March/2014 → 29 changings of element Racor
December/2014 to March/2015 → 16 changings of element Racor
Figure 4 : Racor filter prior tests
Gain of 45% reduction in the consumption of
filter elements, emphasizing that this result is
extremely conservative, given that, because
there can be no parade of ferries for failure in
the power circuit, changings were made in
preventive character
DERSA Ferry Corp, Brazil
REDUCES FILTER CONSUMPTION
IDO MARINE - Turkey
Filter changes reduced from once every 24 hours to engine recommended hours of service.
Images depict severity of contamination in filtration system prior to Fuel Right Program.
IFO 180 – FUEL FILTERING
ELIN Ship – ATHENS, GREECE
1. Although filter cleaning intervals have been kept the same, filters present a somewhat
"cleaner" picture.
2. IFO Purifier cleaning intervals have been significantly extended. From less than one
month to approximately two months.
3. There is no sign of microbial infection whatsoever.
Engine Performance
Detergency, Cetane, Lubricity
DEPOSIT CONTROL
Purpose
Improve fuel flow
Improve atomization
Fuel Right Cleans Injectors
Improves atomization
(combustion)
Tip shows no sign of
coking (carbon build-up)
indicating excellent
combustion
Plunger is exceptionally
clean and shows no sign of
premature wear.
*2 years operating on Fuel Right 15K
FUEL RIGHT ENHANCES LUBRICITY
Fuel
Sample
1st
Measurement
2nd
Measurement
Average
Value
D1 526 524 525
D1 +
15K
461 457 459
D2 445 444 445
D2 +
15K
442 433 438
74
Fuel Right Fuel Right
Testing based on using a High Frequency Reciprocating Rig (HFRR) as per following standards:
CEC F-06-A-96: Measurement of Diesel Fuel Lubricity
ASTM D6079: Standard Test Method for evaluating Lubricity of Diesel Fuels
ISO 450: Diesel Fuel-Assessment of lubricity using the High Frequency reciprocating test rig
ISO 12156-1:Diesel Fuel-Assessment of lubricity using the High Frequency reciprocating test rig
EN 590: 1999 Fuels – Diesel requirements & test procedures
COMBUSTION
Fuel Right
Improves atomization
Improves cold weather
starting
Reduces emissions
JOHN DEERE 7830 INJECTOR
ISTANBUL TECHNICAL UNIVERSITY
(g/kWh) (g/kWh) % Change
NOx 11.909 11.672 -1.99
SO2 0.103 0.051 -50.93
CO 0.666 0.623 -6.54
CO2 611.140 631.683 3.36
O2 1350.104 1431.703 6.04
HC 0.623 0.247 -60.28
PM 2.5> 0.056 0.033 -40.68
PM 2.5-PM10 0.010 0.007 -21.92
PM<10 0.012 0.007 -38.85
PM Total 0.079 0.049 -38.17
Testing performed independently by Istanbul Technical University
Test performed on a large marine diesel engine in situ on an operating ferry.
Publication is available upon request.
REDUCED EMISSIONS
0
2
4
6
8
10
12
14
1 4 7 1013161922252831343740434649525558
Pre Additive
Initial Additive
Post-Drive-Additive
78
Pre Additive RESULTS Initial Additive RESULTS Post-Drive-Additive RESULTS
Mass Average
[mg/m3] 0.779 Mass Average [mg/m3] 0.687 Mass Average [mg/m3] 0.621
Mass Minimum
[mg/m3] 0.024 Mass Minimum [mg/m3] 0.036 Mass Minimum [mg/m3] 0.031
Mass Maximum
[mg/m3] 12.6 Mass Maximum [mg/m3] 11.2 Mass Maximum [mg/m3] 9.23
20% reduction in
emissions with Fuel Right
Test Performed by Mammoth
Filters, Australia
Testing in accordance with
Australian ADR80/03; alternate
USA EPA 2007 and Japan JE05.
CASE STUDY: 2007 Isuzu Sportiva
Summary:
Date Activity
Odometer
reading (Km)
KM
run
Fuel Used
(EURO 4 diesel)
Exhaust Opacity : Light
Absorption Coeff.
(2.2max)
27th Jan 2016 Change Oil Shell V-Power
15th Feb 2016 1st Emission test 115,530 Shell V-Power 1.81
15th Mar 2016 2nd Emission test 116,500 970 Fuel Right 0.83
Result: 55% reduction in emission reading
EMISSION DATA– Student Buses
Unit Model Year Result % Limit % Pass/Fail
1 International 3800 2003 5 30 PASS
2 IC Corporation 2007 7.8 30 PASS
3 Ford E450 Super Duty 2007 4.7 30 PASS
4 IC Corporation 2009 1.1 30 PASS
5 IC Corporation 2009 0.7 30 PASS
6 Chevrolet Express 2009 0.4 30 PASS
7 International 3800 2003 6.4 30 PASS
8 IC Corporation 2010 0.3 30 PASS
9 IC Corporation 2010 0.7 30 PASS
10 IC Corporation 2010 3.5 30 PASS
11 IC Corporation 2010 0.9 30 PASS
12 IC Corporation 2010 0.5 30 PASS
13 International 3800 2003 3.4 30 PASS
14 International 3800 2003 5.8 30 PASS
COLD WEATHER STARTING
Fuels formulated to
seasonal temps
Water is a key issue
Fuel Right pushes water out
of the fuel
Improves cold weather
starting
Fuel Economy
Fuel Right Optimizes Fuel Economy
ElinOIL – FUEL ECONOMY
Testing conducted and Recorded by ELINOIL Hellenic Petroleum Company, S.A.
Km/litre
Without Fuel Right With Fuel Right
ΥΧΒ 6534 SCANIA 141 440 HP, 12.800cc 2,04 2,28 12%
IEE 2501 MITSUBISHI CANTER 140 HP, 3.908cc, EURO 3 5,16 5,70 10%
ΙΕΕ 2669 ΜΑΝ L82 15.250, 6.871cc, EURO 3 3,81 4,67 23%
ΙΕΕ 2823 ΜΑΝ L82 15.250, 6.871cc, EURO 3 3,88 3,78 -2%
ΙΕΕ 2971 ΜΑΝ L82 15.250, 6.871cc, EURO 3 3,57 4,18 17%
ΙΕΒ 8986 MAN TGA ΗΟ9 480 HP, 12.816cc, EURO 3 2,82 2,77 -2%
ΙΒΝ 2129 MAN TGA ΗΟ9 480 HP, 12.816cc, EURO 3 3,10 3,40 9%
Average Fuel Economy Improvement 9.59%
STUDENT TRANSPORT CANADA
Fuel economy testing and documentation by STC in trial of 240 busses
Km/litre
Without Fuel Right With Fuel Right
Unit 1 2.90 3.08 +6.02%
Unit 2 2.67 3.18 +17.43%
Unit 3 2.64 3.06 +14.73%
Unit 4 2.71 3.13 +14.38%
Unit 5 2.72 3.18 +15.59%
Unit 6 2.97 3.10 +4.28%
Unit 7 2.83 3.14 +10.38%
Unit 8 2.86 2.86 0%
Average Fuel Economy Improvement 10.35%
QUESTIONS?
85
XIE XIE!

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Fuel right sdp eng 2020 rev 1

  • 1. Tim Rivard MBa Fuel Right (Canada) Limited www.fuelright.ca
  • 2. RUN CLEANER. RUN SMARTER. A clean diesel program designed to delivery higher quality fuel to exceed the demands of new engine technology.
  • 3. ABOUT US Established mid 90’s 20 years R&D Proprietary technology Applications Diesel fuel Heating oil Unleaded fuel MGO IFO Marine Fuels Hydraulic Oils 3
  • 4. OUR FOUNDER 35 years with DuPont Materials Research Engineer Expertise in Bacterial Growth & MIC Numerous Publications NACE “Microbiologically Influenced Corrosion – Corrosion Fundamentals” “Identification of MIC” Crevice Corrosion of Stainless Steel in Recirculating Cooling Water” Many others…. 4
  • 5. REGULATORY Proprietary Blend EU REACH Registered US EPA Registered UN GHS Compliant Health Canada (GHS) 5
  • 6. INTERNATIONAL DISTRIBUTION Distributed in more than 32 Countries 6
  • 7. OUR MISSION Market innovative technology that enhances fuel quality to a cleanliness standard exceeding ISO 4406 18/16/13, eliminates microbial contamination in middle distillates, prevents sludge recurrence, stops MIC corrosion and optimizes storage tank, fuel filter and engine performance. 7
  • 8. IMPORTANT FACTORS TODAY Particulate control ISO 4406 18/16/13 Contamination Water Microbial Corrosion Filtration
  • 9. ENGINE TECHNOLOGY Common Rail Design Injector pressures 120 – 150 MPa 5 injector strokes per piston stroke 3000 rpm equates to 15,000 strokes per minute Low tolerance to contaminated fuels Requires enhanced fuel lubricity Tighter filter tolerance 2 micron filtration 9
  • 10. HPCR INJECTORS Maximum particulate size <2µ Target - ISO 12/9/7 Water <200 ppm Lubricity Injector Cooling A typical HPCR injector does 5 TO 7 strokes per engine rotation – an engine running at 2500 rpm requires an injector to make 12500 strokes per minute
  • 11. INJECTOR FAILURES Injector deposits Salts (Na,Ca,S,Cl) React with corrosion inhibitors forming carboxylic salt deposits in injectors Water Catastrophic failure (seizure) Wear Excess fuel particulates
  • 13. VALUE PROPOSITION 13 Holistic fuel quality management Clean Fuel - free of microbial contamination, corrosion by-products and water from the source of supply enhances the performance of the overall system by reducing maintenance and eliminating factors affecting engine performance.
  • 14. Fuel Storage Biofilms, Biocides, Water Emulsifiers
  • 15. DIESEL STORAGE FACTS 3% of tank volume never gets exchanged 1500 litres in a 50,000 litre tank Diesel can carry 0.01% by weight of water IE. 50,000 litre tank Exchanged 4x per month 150 litres water/month Microbial Count (tank bottoms) 2.5B organisms per litre not uncommon 15 Reference: National Petroleum News 91(7), p 20-22, July 1999 F.J. Passman, Ph.D., President, BCA, Inc.
  • 16. DIESEL FUEL “ECOSYSTEM” Hydro- peroxides Bacteria Water Corrosion Oxidation Catalysts Cu, V, Fe All factors affect fuel quality, stability and performance Interactive relationship These factors are the Root Causes of diesel fuel quality Issues 16 BACTERIAL SLUDGE
  • 18. FUEL RIGHT AND WATER? Amines establish Micelles Attract water – polar bond Create layering – pushing excess water out of the fuel to the bottom of the tank
  • 19. FUEL RIGHT RESULTS – BEFORE/AFTER Water Clean Fuel
  • 22. IMPLICATIONS OF BACTERIAL PRESENCE Higher rates of microbial influenced corrosion Tanks, strainers, risers, filters, submersible pumps Premature tank failures 6 months to 5 years Environmental spills result Excessively acidic deposits pH 3-5 Breaks down composite tanks Increasing maintenance costs 22
  • 23. HOW BIOFILMS AFFECT FUEL QUALITY Reduces corrosion inhibitor effectiveness Reduces Anti-oxidant effectiveness Reduces lubricity Reduces Oxidative stability Increases Peroxide number Increases TAN (total acid number) Increases Corrosion
  • 24. CONVENTIONAL ADDITIVES Do not displace bio-films Do not dissolve sloughing What does that mean? Acute affects of additives Reduced effectiveness Not (dis)solving the key source of the problem
  • 25. FUEL RIGHT REMOVES BIOFILM Fuel Right dissolves and removes biofilms Implications? Releases trapped particulates Removes corrosion influence Removes acid producer Eliminate Sloughing deposits Hinder Potential bacteria “blooms” Fuel Right slowing dissolving bio-film deposits and severely degraded fuel deposits inside a diesel truck tank
  • 26. TANK INTERIORS Inspected after 1 year of continuous use with Fuel Right Image credit: Fuel 360 New Zealand
  • 28. FUEL RIGHT® RESTORES FUEL QUALITY 28 Original Fuel Sample Treated with Competitor Treated with Fuel Right®
  • 29. DOES CLEAR FUEL = CLEAN FUEL? 1. 2. 3. 1. Tank Bottom sample 2. Above bottom layer 3. Top of the tank Tank bottom sample shows strong evidence of MIC corrosion. Despite being clear and bright, this fuel is unlikely to meet ISO 4406 Particulate standard or SAE 4059
  • 30. WORLDWIDE FUEL CHARTER ISO 4406 Associate members Asociación de Fábricas de Automotores de Argentina (ADEFA) Associacion Mexicana de la Industria Automotriz, A.C. (AMIA) Brazilian Association of motor vehicle and motorised agricultural machinery manufacturers (ANFAVEA) Canadian Vehicle Manufacturers’ Association (CVMA) Chamber of Automotive Manufacturers of the Philippines, Inc. (CAMPI) China Association of Automobile Manufacturers (CAAM) Global Automakers › Global Automakers of Canada (GAC) Indonesia Automotive Federation (IAF) Korean Automobile Manufacturers Association (KAMA) National Association of Automobile Manufacturers of South Africa (NAAMSA) Malaysian Automotive Association (MAA) Society of Indian Automobile Manufacturers (SIAM) Thai Automotive Industry Association (TAIA) Vietnam Automobile Manufacturers Association (VAMA)
  • 31. ISO CLEANLINESS? World Wide Fuel Charter Two Key Metrics Water content <200ppm ISO code 18/16/13 particulate standard Fuel Right exceeds ISO fuel standard Water content ~100 ppm 13/9/7 –measured with laser particulate counter Testing in Canada using Filtertechnik PC 9001 Laser Particulate Counter. 31
  • 32. ISO CODE 18/16/13 ISO 4406 Chart Range Code Particles per milliliter of fuel Particle size and up More than Up to/including 18 1,300 2,500 4µ 16 320 640 6µ 13 40 80 14µ Note: High pressure common rail engines require fuel to minimize particulate count from 3 and up. Previous generations of engines were able to tolerate up to 7 particles in size. The demand for cleaner fuel to avoid injector damage is much higher than the worldwide fuel charter ISO4406 18/16/13 standard.
  • 33. Why is particle count important? How do injectors fail?
  • 34. INTERNAL INJECTOR DEPOSITS Images borrowed from CRC Report No. 665 (CRC Project No. DP-04-13a) Carboxylate soap deposits Lacquer type deposits New HPCR injectors are less tolerant of deposits and require much cleaner fuel standards than ISO 4406 18/16/13
  • 35. CARBOXYLATE DEPOSITS Na/Ca salts React with DDSA/HDSA Used as a corrosion control additive in the pipeline industry DDSA – dodecenyl succinic acid HDSA – hexadecenyl succinic acid
  • 36. SPILL CONTROL VALVE Operate on a clearance of 1.5 – 3 microns (human hair is 40 microns) Prone to particulate damage Biofilms deposit sugars Reference: D.G. Quirk - BP
  • 37. BIOFUEL BLENDS “Some correlation between the introduction of ULSD and/or use of biodiesel and the incidence of IDID” – CRC Report No. 665, Oct 2013 Image depicts the degradation of biofuel into a “black honey” substance with low solubility
  • 38. INJECTOR FAILURE Loss of power Over fuelling Overheating Piston failure No-start condition Emission control
  • 39. ISO CODE 12/9/7 (Target for HPCR) ISO 4406 Chart Range Code Particles per milliliter of fuel Particle size and up More than Up to/including 12 20 40 4µ 9 2.5 5 6µ 7 .64 1.3 14µ Note: High pressure common rail engines require fuel to minimize particulate count from 3µ and up. Previous generations of engines were able to tolerate up to 7µ particles in size. The demand for cleaner fuel to avoid injector damage is much higher than the worldwide fuel charter ISO4406 18/16/13 standard.
  • 40. FUEL RIGHT FIELD RESULTS (December 20, 2015 – 6 months of treatment) UG Tank # Volume Count/ 18 Count/ 16 Count/ 13 Water ppm allowable 1300-2500 320-640 40-80 200ppm 3 50,000 244* / 15** 146* / 14** 21* / 12** 87 4 75,000 89* / 14** 29* / 12** 3* / 9** 79 5 50,000 1475* / 18** 337* / 16** 15* / 11** 92 6 75,000 309 */ 15** 108 */ 14** 11* / 11** 85 7 50,000 470 */ 16** 170 */ 15** 11* / 11** 81 8 50,000 138 */ 14** 46* / 13** 4* / 9** 75 9 90,000 106 */ 14** 28* / 12** 2* / 8** 75 Tanks were installed in the mid 1980’s are located underground and were not cleaned prior to testing. Laser Particulate Tests performed by Prime Fuel Polish, Sarnia, ON December 20, 2015 Client: Hensall Coop, Hensall, ON *First number represents actual particulate count **Second number represents ISO Code Number
  • 41. FUEL RIGHT FIELD RESULTS (March 10, 2017 – 20 months of treatment) UG Tank # Volume Count/ 18 Count/ 16 Count/ 13 Water ppm allowable 1300-2500 320-640 40-80 200ppm 3 50,000 110* / 14** 10* / 11** 2* / 8** 86 4 75,000 42* / 13** 4* / 9** 1* / 7** 120 5 50,000 106* / 14** 11* / 11** 1* / 7** 88 6 75,000 88 */ 14** 13 */ 11** 3* / 9** 85 7 50,000 60 */ 13** 8 */ 10** 1* / 7** 90 8 50,000 154 */ 14** 32* / 12** 4* / 10** 127 9 90,000 50 */ 13** 7* / 10** 1* / 7** 110 Tanks were installed in the mid 1980’s are located underground and were not cleaned prior to testing. Laser Particulate Tests performed by Prime Fuel Polish, Sarnia, ON March 10, 2017 Client: Hensall Coop, Hensall, ON *First number represents actual particulate count **Second number represents ISO Code Number
  • 42. FUEL RIGHT FIELD RESULTS ISO 4406 Worldwide Fuel Charter UG Tank # Volume 18 16 13 Water ppm allowable 1300-2500 320-640 40-80 200ppm 1 unknown 73 */ 13** 14 */ 11** 1 */ 7** 120 Client has consistently treated fuel for more than 24 months Tank was installed in the mid 1980’s are located underground and were not cleaned prior to testing. Laser Particulate Tests performed by Prime Fuel Polish, Sarnia, ON - February 28, 2017 Client: Elgie Bus Lines, London, Ontario *First number represents actual particulate count **Second number represents ISO Code Number
  • 43. FUEL RIGHT LAB RESULTS – 48 Hours ISO 4406 Worldwide Fuel Charter Count/ 18 Count/ 16 Count/ 13 Water ppm allowable 1300-2500 320-640 40-80 200ppm B2 Untreated 5056*/20** 1864*/18** 924*/14** 90.6 B2 (48 hours) Treated 48 hours 1437*/18** 281*/15** 35*/12** B9 Untreated 3929*/19** 1130*/17** 34*/12** 66.7 ppm B9 (48 hours) Treated 48 hours 546*/16** 118*/14** 22*/12** B40 Untreated 17561*/21** 7891*/20** 617*/16** 102 ppm B40 (48 hours) Treated 48 hours 11768*/21** 4113*/19** 134*/14** Samples were provided by Terpel at their fuel terminal in Factactac Sept 20, 2017 Biofuel blend is Palm Oil *First number represents actual particulate count **Second number represents ISO Code Number
  • 44. BATELLE FIELD STUDY “Corrosion in Systems Storing and Dispensing Ultra Low Sulfur Diesel (ULSD), Hypothesis Investigation” by Battelle Memorial Institute, Columbus Ohio (published 13 August 2011) Report analyses six diesel fuel tank systems in California, New York State, and North Carolina to determine reasons for sludge and underlying corrosion on various metal parts Treated Tank NC-1 with Fuel Right 15K December 2011 Inspection Feb 8, 2012 Fiberglass double wall tank Bacteria DNA count – too low to measure Total Acid Number 0.01 KOH/L – ISO Standard 0.12 Maximum Water 39 ppm (diesel can “hold” 100 ppm) – ISO Standard 200ppm Maximum Tank NC-1 ONLY tank with minimal/no sludge formation 44
  • 45. How does Fuel Right impact injector life?
  • 46. IMPLICATIONS OF FUEL RIGHT RESULTS WWFC ISO 4406 18/16/13 Equates to 2500 particles per mL of fuel Fuel Right Results Exceeds WWFC up to 60x Reduction of particulate Extends fuel system component life – reduced injector wear Injector Needle – 3280 hours with 15K
  • 49. WHAT IS MIC? Microbially Influenced Corrosion Electrolyte Acceptor Site Donor Site
  • 50. MIC - Microbially Influenced Corrosion Pitting Corrosion Accelerated due to presence of biofilms Leads to tank failure MIC
  • 51. MIC EVIDENCE “Coffee grounds” indicate severe corrosion present
  • 53. MIC – CORROSION EXAMPLES 53
  • 54. FUEL RIGHT CORROSION PREVENTION Strips biofilm from tank walls Dissolves the bacterial colonies Interrupts development of acidic sludge Hinders biofilm development 54
  • 56. TREATMENT RESULTS Late 90’s tank inspected after 1 year of Fuel Right 15K treatment. Tank is exceptionally cleaned – showing evidence of minor MIC and vapour space corrosion after 20 years of service.
  • 57. COMPOSITE TANKS NOT IMMUNE Fiberglass Tanks Water accumulation Bacteria pH 3-3.5 Extremely acidic Breaks down binding resins 57
  • 59. WHAT ABOUT USING BIOCIDES? Should only be used “after” you have cleaned the fuel Specific to bacteria type Ineffective against well established bacterial infections May become a food source for bacteria Biocides can be corrosive
  • 60. HOW DO BIOCIDES COMPARE? Kill planktonic bacteria only Bacteria develop resistant strains Not all species are vulnerable Biofilms remain behind Biocides are consumable Potential food supply
  • 61. FUEL RIGHT vs BIOCIDES 61 Actual Lab results at the end of an 18 month jar test. Fuel Right out performs competitive products in its ability to dissolve and prevent bacterial growth and protect from corrosion.
  • 62. FUEL RIGHT vs FUEL ADDITIVES 62 Conventional additives are ineffective treatments against microbial sludge
  • 63. TANK STORAGE SUMMARY Clean Tank, free of bacteria, biofilms and water and other contaminants is the most important factor in any fuel system Reduces potential fuel related failures Enhances asset life – protection from corrosion and tank failure Enhances engine performance and engine component life cycle RUN CLEANER. RUN SMARTER.
  • 64. Fuel Filtering & Delivery Biofilms, Lubricity, Particulate
  • 65. FILTRATION Older series diesel engine Modern HPCR diesel engines Refinery Fuels 0X 16X Typical Fuel 4-8X 64-128X Poor Fuel 16-32X 256-512X Bad Fuel 64X 1024X + Based on new engine technology, injectors are less tolerant to particulate contamination. Dual stage filtration 10 um to < 2/4um required for new HPCR engines. This chart shows how much cleaner fuel must be to meet modern injector technology specifications when comparing to older series engines.
  • 66. FILTER PLUGGING High efficiency filtration (4 um) Cold flow modifiers Biofuel – glycerine forming solids Metal carboxylates
  • 67. BIOFILMS & FILTERS Biofilms are transparent Biofilms block filters Vacuum pressure affects fuel flow Fuel pump cavitation & premature wear These filters demonstrate consecutive reduced plugging over 90 days of treatment. Despite appearing similar in colour, the filter on the far left is restricted by opaque biofilm. The filter on the right is clean as a result of a 90 day Fuel Right continuous treatment program.
  • 68. FILTERING PARTICULATE Common filter size 10-30µ Implications Smaller particulate still passing through Potential fuel pump or injector failure Common rail OEM’s recommending 4µ
  • 69. www.nikede.com.br (13) 33535830 December/2013 to March/2014 → 29 changings of element Racor December/2014 to March/2015 → 16 changings of element Racor Figure 4 : Racor filter prior tests Gain of 45% reduction in the consumption of filter elements, emphasizing that this result is extremely conservative, given that, because there can be no parade of ferries for failure in the power circuit, changings were made in preventive character DERSA Ferry Corp, Brazil REDUCES FILTER CONSUMPTION
  • 70. IDO MARINE - Turkey Filter changes reduced from once every 24 hours to engine recommended hours of service. Images depict severity of contamination in filtration system prior to Fuel Right Program.
  • 71. IFO 180 – FUEL FILTERING ELIN Ship – ATHENS, GREECE 1. Although filter cleaning intervals have been kept the same, filters present a somewhat "cleaner" picture. 2. IFO Purifier cleaning intervals have been significantly extended. From less than one month to approximately two months. 3. There is no sign of microbial infection whatsoever.
  • 73. DEPOSIT CONTROL Purpose Improve fuel flow Improve atomization Fuel Right Cleans Injectors Improves atomization (combustion) Tip shows no sign of coking (carbon build-up) indicating excellent combustion Plunger is exceptionally clean and shows no sign of premature wear. *2 years operating on Fuel Right 15K
  • 74. FUEL RIGHT ENHANCES LUBRICITY Fuel Sample 1st Measurement 2nd Measurement Average Value D1 526 524 525 D1 + 15K 461 457 459 D2 445 444 445 D2 + 15K 442 433 438 74 Fuel Right Fuel Right Testing based on using a High Frequency Reciprocating Rig (HFRR) as per following standards: CEC F-06-A-96: Measurement of Diesel Fuel Lubricity ASTM D6079: Standard Test Method for evaluating Lubricity of Diesel Fuels ISO 450: Diesel Fuel-Assessment of lubricity using the High Frequency reciprocating test rig ISO 12156-1:Diesel Fuel-Assessment of lubricity using the High Frequency reciprocating test rig EN 590: 1999 Fuels – Diesel requirements & test procedures
  • 75. COMBUSTION Fuel Right Improves atomization Improves cold weather starting Reduces emissions
  • 76. JOHN DEERE 7830 INJECTOR
  • 77. ISTANBUL TECHNICAL UNIVERSITY (g/kWh) (g/kWh) % Change NOx 11.909 11.672 -1.99 SO2 0.103 0.051 -50.93 CO 0.666 0.623 -6.54 CO2 611.140 631.683 3.36 O2 1350.104 1431.703 6.04 HC 0.623 0.247 -60.28 PM 2.5> 0.056 0.033 -40.68 PM 2.5-PM10 0.010 0.007 -21.92 PM<10 0.012 0.007 -38.85 PM Total 0.079 0.049 -38.17 Testing performed independently by Istanbul Technical University Test performed on a large marine diesel engine in situ on an operating ferry. Publication is available upon request.
  • 78. REDUCED EMISSIONS 0 2 4 6 8 10 12 14 1 4 7 1013161922252831343740434649525558 Pre Additive Initial Additive Post-Drive-Additive 78 Pre Additive RESULTS Initial Additive RESULTS Post-Drive-Additive RESULTS Mass Average [mg/m3] 0.779 Mass Average [mg/m3] 0.687 Mass Average [mg/m3] 0.621 Mass Minimum [mg/m3] 0.024 Mass Minimum [mg/m3] 0.036 Mass Minimum [mg/m3] 0.031 Mass Maximum [mg/m3] 12.6 Mass Maximum [mg/m3] 11.2 Mass Maximum [mg/m3] 9.23 20% reduction in emissions with Fuel Right Test Performed by Mammoth Filters, Australia Testing in accordance with Australian ADR80/03; alternate USA EPA 2007 and Japan JE05.
  • 79. CASE STUDY: 2007 Isuzu Sportiva Summary: Date Activity Odometer reading (Km) KM run Fuel Used (EURO 4 diesel) Exhaust Opacity : Light Absorption Coeff. (2.2max) 27th Jan 2016 Change Oil Shell V-Power 15th Feb 2016 1st Emission test 115,530 Shell V-Power 1.81 15th Mar 2016 2nd Emission test 116,500 970 Fuel Right 0.83 Result: 55% reduction in emission reading
  • 80. EMISSION DATA– Student Buses Unit Model Year Result % Limit % Pass/Fail 1 International 3800 2003 5 30 PASS 2 IC Corporation 2007 7.8 30 PASS 3 Ford E450 Super Duty 2007 4.7 30 PASS 4 IC Corporation 2009 1.1 30 PASS 5 IC Corporation 2009 0.7 30 PASS 6 Chevrolet Express 2009 0.4 30 PASS 7 International 3800 2003 6.4 30 PASS 8 IC Corporation 2010 0.3 30 PASS 9 IC Corporation 2010 0.7 30 PASS 10 IC Corporation 2010 3.5 30 PASS 11 IC Corporation 2010 0.9 30 PASS 12 IC Corporation 2010 0.5 30 PASS 13 International 3800 2003 3.4 30 PASS 14 International 3800 2003 5.8 30 PASS
  • 81. COLD WEATHER STARTING Fuels formulated to seasonal temps Water is a key issue Fuel Right pushes water out of the fuel Improves cold weather starting
  • 82. Fuel Economy Fuel Right Optimizes Fuel Economy
  • 83. ElinOIL – FUEL ECONOMY Testing conducted and Recorded by ELINOIL Hellenic Petroleum Company, S.A. Km/litre Without Fuel Right With Fuel Right ΥΧΒ 6534 SCANIA 141 440 HP, 12.800cc 2,04 2,28 12% IEE 2501 MITSUBISHI CANTER 140 HP, 3.908cc, EURO 3 5,16 5,70 10% ΙΕΕ 2669 ΜΑΝ L82 15.250, 6.871cc, EURO 3 3,81 4,67 23% ΙΕΕ 2823 ΜΑΝ L82 15.250, 6.871cc, EURO 3 3,88 3,78 -2% ΙΕΕ 2971 ΜΑΝ L82 15.250, 6.871cc, EURO 3 3,57 4,18 17% ΙΕΒ 8986 MAN TGA ΗΟ9 480 HP, 12.816cc, EURO 3 2,82 2,77 -2% ΙΒΝ 2129 MAN TGA ΗΟ9 480 HP, 12.816cc, EURO 3 3,10 3,40 9% Average Fuel Economy Improvement 9.59%
  • 84. STUDENT TRANSPORT CANADA Fuel economy testing and documentation by STC in trial of 240 busses Km/litre Without Fuel Right With Fuel Right Unit 1 2.90 3.08 +6.02% Unit 2 2.67 3.18 +17.43% Unit 3 2.64 3.06 +14.73% Unit 4 2.71 3.13 +14.38% Unit 5 2.72 3.18 +15.59% Unit 6 2.97 3.10 +4.28% Unit 7 2.83 3.14 +10.38% Unit 8 2.86 2.86 0% Average Fuel Economy Improvement 10.35%