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TALAT Lecture 3501



                      Alloys and Properties
                                  8 pages, 6 figures

                                     Basic Level

prepared by Klaus Siegert and Manfred Kammerer, Institut für Umformtechnik,
                             Universität Stuttgart




Objectives:

− To provide a background on aluminium alloys suitable for impact extrusion
− To draw attention to raw material parameters which may affect the properties of
  impact extruded parts


Prerequisites:

− Basic knowledge about the formability of metals
− Background in mechanical engineering




Date of Issue: 1994
   EAA- Euro p ean Aluminium Asso ciatio n
3501               Alloys and Properties

Table of Contents:

3501     Alloys and Properties ..................................................................................2
  3501.01 General Information on Alloys and Raw Materials ................................ 2
     Aluminium Alloys for Impact Extrusion .................................................................2
     Reference Values for the Strength of Aluminium Alloy Impacts............................3
     Flow Curves and Fow Stresses ................................................................................4
     Raw Materials, Blanks and Slugs ............................................................................5
     Lubricants ................................................................................................................5
     Tool Life as a Function of Amounts of Lubricant ...................................................6
  3501.02 Literature: ................................................................................................... 8
  3501.03 List of figures............................................................................................... 8




3501.01 General Information on Alloys and Raw Materials



Aluminium Alloys for Impact Extrusion

Figure 3501.01.01 lists the different types of aluminium alloys used for impact
extrusion together with an evaluation considering different aspects. All aluminium
alloys of the non-heat-treatable and heat-treatable types can be impact extruded,
especially when in their soft annealed state. (See also DIN 1712, part 3 and DIN 1725,
part 1).




TALAT 3501                                                     2
Aluminium                                     Designation           Relative merit values1) under various aspects
                                                  according to    Impact       Decorative   Joining   Remarks
    Alloys                                        DIN 1712, p.3   extrud-      anodising    process3)
                                                  and             ability 2)
    for Impact                                    DIN 1725, p.1
                                                                                            S    L


    Extrusion                                     Pure and high purity aluminium (DIN 1712, part3)
    Aluminium alloys
                                                  Al99.5                1          2        2    1   Main material for impacts
    for impact
                                                  Al99.7                1          2        2    1
    extrusion
    1)
                                                  Al99.8                1          1        2    1
       Merit values,
       falling from 1 to 4;                       Al99.9                1          1        2    1   Chemical brightening possible
       "-" = not suitable                         Non-heat-treatable alloys (DIN 1725, part 1)
    2)
       Valuation is valid
       for the original soft                      AlMn                  2          -        2    1
       annealed state                             AlRMg0.5              2          1        2    2   Chemical brightening possible
    3)
       S = weldability;                           AlMg1                 2          2        2    2
       L = suitability for                        AlMg3                 4          2        1    -
       brazing.
                                                  AlMg2Mn0.3            3          3        1    -
       Strength loss due
       to welding and                             Heat-treatable alloys (DIN 1725, part 1)
       soldering must be                          AlMgSi0.5             2          1        2    3
       considered!                                AlMgSi1               3          2        2    3
                                                  AlZn4.5Mg1            3          -        2    -   Used only in artificially aged state
    Source: Aluminium                             AlCuMg1               4          -        -    -   Only for parts with heavy wall thickness
    -Zentrale e.V.                                AlZnMgCu0.5           4          -        -    -   which are used only in an aged state

                                            alu

     Training in Aluminium Application Technologies
                                                           Aluminium Alloys for Impact Extrusion                             3501.01.01


In order to obtain high quality impacts, it is important to use materials which exhibit a
homogeneous fibre structure or a uniform fine-grained structure. A non-homogeneous
structure affects not only the chemical and physical properties of the impacts but also
their form. An unsymmetrical grain structure can have a large effect on flow stress
which in turn might lead to excentricity of the part, warpage or uneven distribution of
wall thicknesses.


Reference Values for the Strength of Aluminium Alloy Impacts

Figure 3501.01.02 tables reference values for the strength of aluminium alloy impacts.
The aluminium alloys Al99,9, Al99,8. Al99,7 and Al99,5 are mainly used for
manufacturing tubes and cans. The alloys AlMgSi0,5 and AlMgSi1 can be considered to
be standard materials for impact extrusion. Care must be taken during the machining of
the alloys AlZn4,5Mg1 and AlZnMgCu0,5, since the emulsions used can lead to
corrosion.




TALAT 3501                                                                        3
Reference
                                                                     Designation        State                                     Strength in N/mm²            Elongation
          Values for                                                                                                             Rm (σB)       Rp0.2 (σ0.2)      A5 (%)
          the Strength                                               Al99.5/            annealed                                    70               25               40
                                                                     Al99               impact extruded                            130              110                6
          of Impacts                                                 Al99.7/            annealed                                    60               18               40
                                                                     Al99.8             impact extruded                            120              100                4
     Attainable                                                                                                                                                       40
                                                                     Al99.9             annealed                                    40               15
     mechanical properties,                                                             impact extruded                            100               80                4
     not minimum values                                              AlMn               annealed                                    90               35               24
                                                                                        impact extruded                            170              145                4
     1)
          By impact extruding                                        AlRMg0.5           annealed                                    80               25               23
          directly after solution                                                       impact extruded                            140              110                4
                                                                     AlMg1              annealed                                   105               35               24
          treatment and quenching
                                                                                        impact extruded                            165              145                4
          ("freshly quenched" state)
                                                                     AlMg3              annealed                                   190               80               20
          and then aging, 90% of                                                        impact extruded                            265              215                4
          the strength of the                                        AlMg2Mn0.3         annealed                                   155               60               20
          state "artificially                                                           impact extruded                            230              200                4
          aged" can be attained.                                     AlMgSi0.5          annealed, imp. extr.                       165              145                4
                                                                     1)                 artificially aged                          245              195               10
                                                                     AlMgSi1            annealed, imp. extr.                       190              170                4
                                                                     1)                 artificially aged                          310              260               10
                                                                     AlZn4.5Mg1         artificially aged                          350              290               10
                                                                     AlCuMg1            naturally aged                             400              350               10
                                                                     AlZnMgCu0.5        artificially aged                          500              450                7
    Source: Aluminium-Zentrale e.V.

                                                  alu

    Training in Aluminium Application Technologies
                                                                     Reference Values for the Strength of Impacts                                             3501.01.02




Flow Curves and Fow Stresses

Figure 3501.01.03 shows flow curves and flow stresses of some aluminium alloys (at
left) and the effect of state of heat treatment of AlMgSi1-slugs on the flow behaviour (at
right). Flow curves are needed for the calculation of forces for the impact extrusion
process. For further flow curves, refer to the VDI guideline 3500.


                                                                 Flow Curves and Flow Stresses
                            Flow curves for various annealed                                                         Flow stress as a function of
                          aluminium alloys at room temperature                                                      heat treatment state of the slug

                                            600         State: annealed                                             600                         Artificially aged
                                                        ϕ = 5 x 10 s
                                                                  -4 -1

                          N/mm²                                                                   N/mm²                                              Naturally aged
                                                                        AlMg3
                          Flow stress, kf




                                                                                                  Flow stress, kf




                                            400                                                                     400
                                                                        AlCuMg
                                                                                                                                                      Hot worked
                                                                        AlMgSi(Mn)
                                            200                                                                     200                              Soft
                                                                        Al99.5
                                                                                                                                                    AlMgSi1
                                                                                                                                                    RT
                                              0                                                                       0
                                                  0          1         2          3                                       0         1         2           3
                                                           True strain ϕ                                                            True strain ϕ
                                                  Source: J.Hardt                                                         Source: H.G.Roczyn




                                                           alu
                                                                               Flow Curves and Flow Stresses                                           3501.01.03
                    Training in Aluminium Application Technologies




TALAT 3501                                                                                   4
Raw Materials, Blanks and Slugs

Figure 3501.01.04 gives information regarding the manufacturing of slugs and blanks,
their required surface condition and their properties. Cold rolled sheets and rods or tubes
from which blanks and slugs are obtained by blanking or sawing, respectively, are
standardised in DIN 1745, part 1 and DIN 59604. Round rods of pure aluminium or
aluminium alloys are extruded with so-called multiple extrusion dies, i.e. three or four
die openings are arranged around the centre of the die. In a final step these rods are cold
drawn to size and final dimensions. Since the material is pressed through the multiple
die not only from the centre portion of the billet but also from its outer areas, such round
rods may exhibit different grain sizes in any one cross-section. As a result, impact
extruded parts can warp in unexpected amounts and wall thicknesses may vary.
Therefore, care should be exercised, that only single-strand extruded rods are taken as
base material for slugs and blanks.


                                                       Raw Materials; Blanks and Slugs
                           Manufacturing raw materials
                           The raw material consists almost exclusively of stamped or sawed blanks
                           and slugs available from extruders or stockists


                           Surface condition of raw material
                           Blank, ground, tumbled, blasted

                           Requirements of raw material
                           !        The weight of blanks or slugs is allowed to vary only within a narrow
                                    tolerance range
                           !        Minimum clearance between slugs and die: 0.3 to 0.4mm
                           !        Maximum tolerance for round slugs and blanks is h11 (larger deviations in
                                    diameter lead to positioning errors)
                           !        A uniform grain size. Varying grain size can lead to variations in dimensions

             Source: Schlosser; Brix

                                                    alu

             Training in Aluminium Application Technologies
                                                              Raw Materials; Blanks and Slugs            3501.01.04




Lubricants

Figure 3501.01.05 lists the different lubricants used and the methods of applying them.
Because of environmental considerations, water-soluble lubricants like alkalinen soaps
and liquid lubricants based on oil are being increasingly used. Zinc stearate and zinc
behenate have nowadays to compete with
   − Lubrimet GTT (Sapilub Ltd. Co. Wangen, Zurich) based on paraffin without
     chlorinated solvents and heavy metal soaps with optimal solubility in water,
   − Glisapal SM-155 (Nußbaum Co., Matzingen), a water-soluble, solvent-free,
     powdery lubricant based on alkaline soaps, not suitable for anneal degreasing and
     solvent cleaning,



TALAT 3501                                                                   5
− and liquid lubricants based on oil, like Bonderlube VP 4404/5 (Chemetall Co.,
     Frankfurt), with sulphur compounds, but free from chloroparaffins and metal
     organic compounds or
   − Multipress 9391 (Zeller and Gmelin Co., Eislingen), a fully synthetic oil.

In individual cases, coating layers serving as carriers for lubricants (aluminium,
phosphate) are used.


                                                                           Lubricants
                                                            Lubricants used

                                                            ! Zinc stearate and zinc behenate (insoluble in water)
                                                            ! Alkaline soaps (water soluble)
                                                            ! Liquid lubricants based on oil (water soluble)


                                                            Methods of applying lubricants

                                                            !   Spraying
                                                            !   Coating
                                                            !   Sprinkling, powdering
                                                            !   Dipping
                                                            !   Tumbling

           Source: D.Schlosser

                                                  alu

           Training in Aluminium Application Technologies
                                                                               Lubricants                      3501.01.05




Tool Life as a Function of Amounts of Lubricant

Figure 3501.01.06 illustrates the influence of amount of lubricant used (g/m²) on tool
life. As can be clearly seen, too little or too much lubrication reduces the tool life. If the
lubricant used is insufficient, cold welding can occur between tool and work-piece. If
too much lubricant is used, then the lubricant accumulation leads to defects in contour
replication and to lubricant indentations in the tool. In these cases, the tool has to be
cleaned very often. The surface roughness of slugs and blanks has an effect on the tool
life. Experiments have shown that smooth slugs reduce the life of tools because the
smooth slug surface offers hardly any cavities and pits in which the lubricant can be
anchored.




TALAT 3501                                                                         6
Tool Life as a Function of Amounts of Lubricant

                                                                    Cold                 Contour
                                                                   welding               defects
                                                                    failure   optimum    failure



                                                       Tool life




                                                                     Relative lubricant amount in g/ m²
      Source: D.Schlosser

                                             alu

      Training in Aluminium Application Technologies
                                                                    Tool Life and Lubricant Amounts       3501.01.06




TALAT 3501                                                                         7
3501.02 Literature:

1) F.Ostermann: Technische Kaltfließpreßteile aus Aluminium. In seminar volume
   "Gestalten und Fertigen von technischen Fließpreßteilen aus Aluminium", Institut
   für Umformtechnik, Universität Stuttgart, 15.-16. June, 1992

2) D.Schlosser: Einflußgrößen auf das Fließpressen von Aluminium und
   Aluminiumlegierungen und ihre Auswirkung auf die Weiter- und
   Fertigbearbeitung der fließgepreßten Rohteile. In seminar volume "Gestalten und
   Fertigen von technischen Fließpreßteilen aus Aluminium", Institut für
   Umformtechnik, Universität Stuttgart, 15.-16. June, 1992

3) D.Brix: Kaltfließpressen von Leichtmetall - Qualität und Wirtschaftlichkeit. Draht
   1975/5, p. 216-219

4) VDI-Richtlinie 3138: Kaltfließpressen von Stählen und Nichteisenmetallen,
   Grundlagen, part 1. Beuth-Verlag, Berlin, 1970

5) Aluminium-Zentrale e.V., Report No. 29 "Aluminium für technische
   Fließpreßteile", Düsseldorf, 1982




3501.03 List of figures


Figure No.   Figure Title (Overhead)
3501.01.01   Aluminium Alloys for Impact Extrusion
3501.01.02   Reference Values for the Strength of Impacts
3501.01.03   Flow Curves and Flow Stresses
3501.01.04   Raw Materials; Blanks and Slugs
3501.01.05   Lubricants
3501.01.06   Tool Life and Lubricant Amounts




TALAT 3501                                 8

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TALAT Lecture 3501: Alloys and Properties

  • 1. TALAT Lecture 3501 Alloys and Properties 8 pages, 6 figures Basic Level prepared by Klaus Siegert and Manfred Kammerer, Institut für Umformtechnik, Universität Stuttgart Objectives: − To provide a background on aluminium alloys suitable for impact extrusion − To draw attention to raw material parameters which may affect the properties of impact extruded parts Prerequisites: − Basic knowledge about the formability of metals − Background in mechanical engineering Date of Issue: 1994  EAA- Euro p ean Aluminium Asso ciatio n
  • 2. 3501 Alloys and Properties Table of Contents: 3501 Alloys and Properties ..................................................................................2 3501.01 General Information on Alloys and Raw Materials ................................ 2 Aluminium Alloys for Impact Extrusion .................................................................2 Reference Values for the Strength of Aluminium Alloy Impacts............................3 Flow Curves and Fow Stresses ................................................................................4 Raw Materials, Blanks and Slugs ............................................................................5 Lubricants ................................................................................................................5 Tool Life as a Function of Amounts of Lubricant ...................................................6 3501.02 Literature: ................................................................................................... 8 3501.03 List of figures............................................................................................... 8 3501.01 General Information on Alloys and Raw Materials Aluminium Alloys for Impact Extrusion Figure 3501.01.01 lists the different types of aluminium alloys used for impact extrusion together with an evaluation considering different aspects. All aluminium alloys of the non-heat-treatable and heat-treatable types can be impact extruded, especially when in their soft annealed state. (See also DIN 1712, part 3 and DIN 1725, part 1). TALAT 3501 2
  • 3. Aluminium Designation Relative merit values1) under various aspects according to Impact Decorative Joining Remarks Alloys DIN 1712, p.3 extrud- anodising process3) and ability 2) for Impact DIN 1725, p.1 S L Extrusion Pure and high purity aluminium (DIN 1712, part3) Aluminium alloys Al99.5 1 2 2 1 Main material for impacts for impact Al99.7 1 2 2 1 extrusion 1) Al99.8 1 1 2 1 Merit values, falling from 1 to 4; Al99.9 1 1 2 1 Chemical brightening possible "-" = not suitable Non-heat-treatable alloys (DIN 1725, part 1) 2) Valuation is valid for the original soft AlMn 2 - 2 1 annealed state AlRMg0.5 2 1 2 2 Chemical brightening possible 3) S = weldability; AlMg1 2 2 2 2 L = suitability for AlMg3 4 2 1 - brazing. AlMg2Mn0.3 3 3 1 - Strength loss due to welding and Heat-treatable alloys (DIN 1725, part 1) soldering must be AlMgSi0.5 2 1 2 3 considered! AlMgSi1 3 2 2 3 AlZn4.5Mg1 3 - 2 - Used only in artificially aged state Source: Aluminium AlCuMg1 4 - - - Only for parts with heavy wall thickness -Zentrale e.V. AlZnMgCu0.5 4 - - - which are used only in an aged state alu Training in Aluminium Application Technologies Aluminium Alloys for Impact Extrusion 3501.01.01 In order to obtain high quality impacts, it is important to use materials which exhibit a homogeneous fibre structure or a uniform fine-grained structure. A non-homogeneous structure affects not only the chemical and physical properties of the impacts but also their form. An unsymmetrical grain structure can have a large effect on flow stress which in turn might lead to excentricity of the part, warpage or uneven distribution of wall thicknesses. Reference Values for the Strength of Aluminium Alloy Impacts Figure 3501.01.02 tables reference values for the strength of aluminium alloy impacts. The aluminium alloys Al99,9, Al99,8. Al99,7 and Al99,5 are mainly used for manufacturing tubes and cans. The alloys AlMgSi0,5 and AlMgSi1 can be considered to be standard materials for impact extrusion. Care must be taken during the machining of the alloys AlZn4,5Mg1 and AlZnMgCu0,5, since the emulsions used can lead to corrosion. TALAT 3501 3
  • 4. Reference Designation State Strength in N/mm² Elongation Values for Rm (σB) Rp0.2 (σ0.2) A5 (%) the Strength Al99.5/ annealed 70 25 40 Al99 impact extruded 130 110 6 of Impacts Al99.7/ annealed 60 18 40 Al99.8 impact extruded 120 100 4 Attainable 40 Al99.9 annealed 40 15 mechanical properties, impact extruded 100 80 4 not minimum values AlMn annealed 90 35 24 impact extruded 170 145 4 1) By impact extruding AlRMg0.5 annealed 80 25 23 directly after solution impact extruded 140 110 4 AlMg1 annealed 105 35 24 treatment and quenching impact extruded 165 145 4 ("freshly quenched" state) AlMg3 annealed 190 80 20 and then aging, 90% of impact extruded 265 215 4 the strength of the AlMg2Mn0.3 annealed 155 60 20 state "artificially impact extruded 230 200 4 aged" can be attained. AlMgSi0.5 annealed, imp. extr. 165 145 4 1) artificially aged 245 195 10 AlMgSi1 annealed, imp. extr. 190 170 4 1) artificially aged 310 260 10 AlZn4.5Mg1 artificially aged 350 290 10 AlCuMg1 naturally aged 400 350 10 AlZnMgCu0.5 artificially aged 500 450 7 Source: Aluminium-Zentrale e.V. alu Training in Aluminium Application Technologies Reference Values for the Strength of Impacts 3501.01.02 Flow Curves and Fow Stresses Figure 3501.01.03 shows flow curves and flow stresses of some aluminium alloys (at left) and the effect of state of heat treatment of AlMgSi1-slugs on the flow behaviour (at right). Flow curves are needed for the calculation of forces for the impact extrusion process. For further flow curves, refer to the VDI guideline 3500. Flow Curves and Flow Stresses Flow curves for various annealed Flow stress as a function of aluminium alloys at room temperature heat treatment state of the slug 600 State: annealed 600 Artificially aged ϕ = 5 x 10 s -4 -1 N/mm² N/mm² Naturally aged AlMg3 Flow stress, kf Flow stress, kf 400 400 AlCuMg Hot worked AlMgSi(Mn) 200 200 Soft Al99.5 AlMgSi1 RT 0 0 0 1 2 3 0 1 2 3 True strain ϕ True strain ϕ Source: J.Hardt Source: H.G.Roczyn alu Flow Curves and Flow Stresses 3501.01.03 Training in Aluminium Application Technologies TALAT 3501 4
  • 5. Raw Materials, Blanks and Slugs Figure 3501.01.04 gives information regarding the manufacturing of slugs and blanks, their required surface condition and their properties. Cold rolled sheets and rods or tubes from which blanks and slugs are obtained by blanking or sawing, respectively, are standardised in DIN 1745, part 1 and DIN 59604. Round rods of pure aluminium or aluminium alloys are extruded with so-called multiple extrusion dies, i.e. three or four die openings are arranged around the centre of the die. In a final step these rods are cold drawn to size and final dimensions. Since the material is pressed through the multiple die not only from the centre portion of the billet but also from its outer areas, such round rods may exhibit different grain sizes in any one cross-section. As a result, impact extruded parts can warp in unexpected amounts and wall thicknesses may vary. Therefore, care should be exercised, that only single-strand extruded rods are taken as base material for slugs and blanks. Raw Materials; Blanks and Slugs Manufacturing raw materials The raw material consists almost exclusively of stamped or sawed blanks and slugs available from extruders or stockists Surface condition of raw material Blank, ground, tumbled, blasted Requirements of raw material ! The weight of blanks or slugs is allowed to vary only within a narrow tolerance range ! Minimum clearance between slugs and die: 0.3 to 0.4mm ! Maximum tolerance for round slugs and blanks is h11 (larger deviations in diameter lead to positioning errors) ! A uniform grain size. Varying grain size can lead to variations in dimensions Source: Schlosser; Brix alu Training in Aluminium Application Technologies Raw Materials; Blanks and Slugs 3501.01.04 Lubricants Figure 3501.01.05 lists the different lubricants used and the methods of applying them. Because of environmental considerations, water-soluble lubricants like alkalinen soaps and liquid lubricants based on oil are being increasingly used. Zinc stearate and zinc behenate have nowadays to compete with − Lubrimet GTT (Sapilub Ltd. Co. Wangen, Zurich) based on paraffin without chlorinated solvents and heavy metal soaps with optimal solubility in water, − Glisapal SM-155 (Nußbaum Co., Matzingen), a water-soluble, solvent-free, powdery lubricant based on alkaline soaps, not suitable for anneal degreasing and solvent cleaning, TALAT 3501 5
  • 6. − and liquid lubricants based on oil, like Bonderlube VP 4404/5 (Chemetall Co., Frankfurt), with sulphur compounds, but free from chloroparaffins and metal organic compounds or − Multipress 9391 (Zeller and Gmelin Co., Eislingen), a fully synthetic oil. In individual cases, coating layers serving as carriers for lubricants (aluminium, phosphate) are used. Lubricants Lubricants used ! Zinc stearate and zinc behenate (insoluble in water) ! Alkaline soaps (water soluble) ! Liquid lubricants based on oil (water soluble) Methods of applying lubricants ! Spraying ! Coating ! Sprinkling, powdering ! Dipping ! Tumbling Source: D.Schlosser alu Training in Aluminium Application Technologies Lubricants 3501.01.05 Tool Life as a Function of Amounts of Lubricant Figure 3501.01.06 illustrates the influence of amount of lubricant used (g/m²) on tool life. As can be clearly seen, too little or too much lubrication reduces the tool life. If the lubricant used is insufficient, cold welding can occur between tool and work-piece. If too much lubricant is used, then the lubricant accumulation leads to defects in contour replication and to lubricant indentations in the tool. In these cases, the tool has to be cleaned very often. The surface roughness of slugs and blanks has an effect on the tool life. Experiments have shown that smooth slugs reduce the life of tools because the smooth slug surface offers hardly any cavities and pits in which the lubricant can be anchored. TALAT 3501 6
  • 7. Tool Life as a Function of Amounts of Lubricant Cold Contour welding defects failure optimum failure Tool life Relative lubricant amount in g/ m² Source: D.Schlosser alu Training in Aluminium Application Technologies Tool Life and Lubricant Amounts 3501.01.06 TALAT 3501 7
  • 8. 3501.02 Literature: 1) F.Ostermann: Technische Kaltfließpreßteile aus Aluminium. In seminar volume "Gestalten und Fertigen von technischen Fließpreßteilen aus Aluminium", Institut für Umformtechnik, Universität Stuttgart, 15.-16. June, 1992 2) D.Schlosser: Einflußgrößen auf das Fließpressen von Aluminium und Aluminiumlegierungen und ihre Auswirkung auf die Weiter- und Fertigbearbeitung der fließgepreßten Rohteile. In seminar volume "Gestalten und Fertigen von technischen Fließpreßteilen aus Aluminium", Institut für Umformtechnik, Universität Stuttgart, 15.-16. June, 1992 3) D.Brix: Kaltfließpressen von Leichtmetall - Qualität und Wirtschaftlichkeit. Draht 1975/5, p. 216-219 4) VDI-Richtlinie 3138: Kaltfließpressen von Stählen und Nichteisenmetallen, Grundlagen, part 1. Beuth-Verlag, Berlin, 1970 5) Aluminium-Zentrale e.V., Report No. 29 "Aluminium für technische Fließpreßteile", Düsseldorf, 1982 3501.03 List of figures Figure No. Figure Title (Overhead) 3501.01.01 Aluminium Alloys for Impact Extrusion 3501.01.02 Reference Values for the Strength of Impacts 3501.01.03 Flow Curves and Flow Stresses 3501.01.04 Raw Materials; Blanks and Slugs 3501.01.05 Lubricants 3501.01.06 Tool Life and Lubricant Amounts TALAT 3501 8