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CALUMEX UPC WHITE White Calcium Aluminate Cement
Hunter whiteness
0
2
4
6
8
10
12
14
16
setting time UPC White
initial set final set
10 min
14 min
minutes
Vicat
0
10
20
30
40
50
60
70
6 hours 24 hours 2 days 7 days
compressive strength UPC White
compressive
strength
MPa
tested EN196-1 prisms 16x4x4 cm
0
10
20
30
40
50
60
70
80
6 hours 24 hours 2 days 7 days 14 days 28 days
progressive strength development UPC White
compressive
strength
MPa
tested EN196-1 prisms 16x4x4 cm
0
5
10
15
20
25
5 10 15 20 25 30
bound water
time hours
bound
water
%
differential thermal analysis (DTA) / thermogravimetric analysis (TG)
0
5
10
15
20
25
30
35
40
45
0 5 10 15 20 25 30
porosity / bound water
bound water %
porosity
%
relation porosity / bound water
-0,03
-0,02
-0,01
0,00
0,01
0,02
0,03
0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300
shrinkage
time / minutes
shrinkage
mm/m
used as binder
White
Portlandcement
mixed with
r-1:0 r-3:1 r-2:1 r-1:1 r-1:2 r-1:3 r-0:1
WHITE
PORTLANDCEMENT
CEM I 52,5 N
300 225 200 150 100 75
75 100 150 200 225 300
Total 300 300 300 300 300 300 300
mixratio White OPC : UPC WHITE
3:00:00
0:50:00
0:30:00
0:20:00 0:18:00
0:15:00
0:10:00
4:00:00
1:10:00
0:40:00
0:25:00 0:24:00
0:21:00
0:14:00
r-1:0 r-3:1 r-2:1 r-1:1 r-1:2 r-1:3 r-0:1
Initial set Final set
Setting times
4:30
4:00
3:30
3:00
2:30
2:00
1:30
1:00
0:30
0:00
time
hrs:min:sec
0,00
2,04
4,29
8,19
14,35
15,69
24,35
16,20
28,56
37,57
39,48
38,23
39,28
46,10
30,38
34,86
43,01
46,14
45,17 45,63
50,98
42,56
43,77
46,94
52,99 52,42 51,40
59,39
45,535
46,215
47,4
54,85 53,35
56,735
64,365
53,17
52,175 52,61
58,51 58,595 59,44
67,315
0,00
10,00
20,00
30,00
40,00
50,00
60,00
70,00
80,00
OPC 1:0 UPC OPC 3:1 UPC OPC 2:1 UPC OPC 1:1 UPC OPC 1:2 UPC OPC 1:3 UPC OPC 0:1 UPC
6 hours 24 hours 2 days 7 days 14 days 28 days
compressive
strength
(Mpa)
compressive strength
based on the chemical reaction on hydration
by fast release of alumina ions from its main
phase 12CaO 7Al2O3
(C12A7 ”mayenite”)
reacting quickly with available
calcium and sulphate ions forming high
amounts of so called “ettringite” crystals
(Aft also KLEIN’s compound)
tri-sulpho-aluminate salt;
ettringite crystals
needle, ladth or rod like crystals (morphology can vary)
formed at early stage of hydration
• fine needles, hexagonal shaped crystals
• on average 1 ~ 7 μ in size
• volume increase on hydration
• binds excess water (32 water molecules)
• improve the density filling the pore structure
ettringite crystal
0,007 mm 7 μ
0.0003 inch
human hair
0,070 mm
70 μ
0.0035 inch
combines all features of Calcium Sulpho Aluminate Cement
with a white consistent colour;
ü rapid hardening
ü high early strength
ü excess water bound on hydration
ü progressive strength development
ü compensated shrinkage
ü improved bond strength
ü reduced alkali
ü accelerated autogenous drying
ü closed pore structure
ü low porosity
European Standard for tile adhesives and –grouts
modern unglazed tiles called “ultragres” or “porcelanosa” and getting
bigger and thinner
thickness between 3 and 6 mm.(0,12”~0,24”) is becoming the standard.
water absorbency is <0.05% on the surface and water absorbency on
the bottom < 0.3% (EN-ISO 10545-3)
use of class C2 is advised to garantee sufficient bond strength
EUF (European Tile Setters
Federation ) divides large sized
tiles in;
XL (surface area of 1 square meter
or 10 square feet)
XXL (surface area of at least 3m or
32 squarefeet)
how to obtain sufficient contact surface when
installing these type of large “gres” tiles
assuring sufficient bond strength to comply to
standard C2 FTE S2 ?
• C2 : improved adhesive
• F :Fast Setting
• T :Thixotropic
• E : Extended Working Time
• S2 : Highly Deformable
large size tiles are inserted on a flat surface with a back and forth movement,
crosswise to the adhesive grooves
pressed firmly from the center towards the edges in order to flatten the adhesive
grooves, minimizing the amount of air inclusions
a maximum contact surface and an optimal adhesive distribution gives the optimum
bond
cellulose ethers and higher dosage of redispersible polymer powder (RDP dosage
advised S2 is more than 5%) delay cement hydration, impact rheology and cause air
entrapment allowing a possible further reduction of the bond strength
UPC WHITE as binder / addition to Portlandcement;
• accelerated set
• rheology modification
• low porosity, high density
• improved bond strength
• excess water bound, autogenous drying
• positive volume change, less stress
• rapid and complete drying of interfacial surface
• low alkali cement
placing natural stone the risk of stains forming on the
surface is minimized
controlled formation of ettringite crystals play an important role in cement tile grouts
in order to fill the thin, fine joints used in the application of large size tiles the grout
contains a lot of water impacting shrinkage, porosity, efflorescence and wear resistance
CALUMEX UPC WHITE as binder
• quick hardening and drying
• closed fine matrix
• high density
• leaving less pores
• high wear resistance
• compensating shrinkage ensuring a durable and stable joint
• low alkali content prevents discoloration
• no lime bloom
®
for making ‘’ fast set terrazzo’’
ü high reflection value
ü quick de-molding
ü compatible with various aggregates
ü recycled glass
ü reduced risk efflorescence
ü fast polishing
self leveling easy handling
rapid hardening fast polishable
• decorative concrete
• countertops
• glass fiber reinforced concrete (GRC)
• architectural precast
• dry-mixed mortars
• self levelling topping mortar
UPC_WHITE_fast_set_WHITE_CEMENT
UPC_WHITE_fast_set_WHITE_CEMENT
UPC_WHITE_fast_set_WHITE_CEMENT
UPC_WHITE_fast_set_WHITE_CEMENT

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UPC_WHITE_fast_set_WHITE_CEMENT

  • 1.
  • 2.
  • 3.
  • 4. 89 92 CALUMEX UPC WHITE White Calcium Aluminate Cement Hunter whiteness
  • 5. 0 2 4 6 8 10 12 14 16 setting time UPC White initial set final set 10 min 14 min minutes Vicat
  • 6. 0 10 20 30 40 50 60 70 6 hours 24 hours 2 days 7 days compressive strength UPC White compressive strength MPa tested EN196-1 prisms 16x4x4 cm
  • 7. 0 10 20 30 40 50 60 70 80 6 hours 24 hours 2 days 7 days 14 days 28 days progressive strength development UPC White compressive strength MPa tested EN196-1 prisms 16x4x4 cm
  • 8. 0 5 10 15 20 25 5 10 15 20 25 30 bound water time hours bound water % differential thermal analysis (DTA) / thermogravimetric analysis (TG)
  • 9. 0 5 10 15 20 25 30 35 40 45 0 5 10 15 20 25 30 porosity / bound water bound water % porosity % relation porosity / bound water
  • 10. -0,03 -0,02 -0,01 0,00 0,01 0,02 0,03 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300 shrinkage time / minutes shrinkage mm/m
  • 12. r-1:0 r-3:1 r-2:1 r-1:1 r-1:2 r-1:3 r-0:1 WHITE PORTLANDCEMENT CEM I 52,5 N 300 225 200 150 100 75 75 100 150 200 225 300 Total 300 300 300 300 300 300 300 mixratio White OPC : UPC WHITE
  • 13. 3:00:00 0:50:00 0:30:00 0:20:00 0:18:00 0:15:00 0:10:00 4:00:00 1:10:00 0:40:00 0:25:00 0:24:00 0:21:00 0:14:00 r-1:0 r-3:1 r-2:1 r-1:1 r-1:2 r-1:3 r-0:1 Initial set Final set Setting times 4:30 4:00 3:30 3:00 2:30 2:00 1:30 1:00 0:30 0:00 time hrs:min:sec
  • 14. 0,00 2,04 4,29 8,19 14,35 15,69 24,35 16,20 28,56 37,57 39,48 38,23 39,28 46,10 30,38 34,86 43,01 46,14 45,17 45,63 50,98 42,56 43,77 46,94 52,99 52,42 51,40 59,39 45,535 46,215 47,4 54,85 53,35 56,735 64,365 53,17 52,175 52,61 58,51 58,595 59,44 67,315 0,00 10,00 20,00 30,00 40,00 50,00 60,00 70,00 80,00 OPC 1:0 UPC OPC 3:1 UPC OPC 2:1 UPC OPC 1:1 UPC OPC 1:2 UPC OPC 1:3 UPC OPC 0:1 UPC 6 hours 24 hours 2 days 7 days 14 days 28 days compressive strength (Mpa) compressive strength
  • 15. based on the chemical reaction on hydration by fast release of alumina ions from its main phase 12CaO 7Al2O3 (C12A7 ”mayenite”) reacting quickly with available calcium and sulphate ions forming high amounts of so called “ettringite” crystals (Aft also KLEIN’s compound) tri-sulpho-aluminate salt;
  • 16. ettringite crystals needle, ladth or rod like crystals (morphology can vary) formed at early stage of hydration • fine needles, hexagonal shaped crystals • on average 1 ~ 7 μ in size • volume increase on hydration • binds excess water (32 water molecules) • improve the density filling the pore structure ettringite crystal 0,007 mm 7 μ 0.0003 inch human hair 0,070 mm 70 μ 0.0035 inch
  • 17.
  • 18.
  • 19. combines all features of Calcium Sulpho Aluminate Cement with a white consistent colour; ü rapid hardening ü high early strength ü excess water bound on hydration ü progressive strength development ü compensated shrinkage ü improved bond strength ü reduced alkali ü accelerated autogenous drying ü closed pore structure ü low porosity
  • 20.
  • 21.
  • 22. European Standard for tile adhesives and –grouts modern unglazed tiles called “ultragres” or “porcelanosa” and getting bigger and thinner thickness between 3 and 6 mm.(0,12”~0,24”) is becoming the standard. water absorbency is <0.05% on the surface and water absorbency on the bottom < 0.3% (EN-ISO 10545-3) use of class C2 is advised to garantee sufficient bond strength
  • 23. EUF (European Tile Setters Federation ) divides large sized tiles in; XL (surface area of 1 square meter or 10 square feet) XXL (surface area of at least 3m or 32 squarefeet)
  • 24. how to obtain sufficient contact surface when installing these type of large “gres” tiles assuring sufficient bond strength to comply to standard C2 FTE S2 ? • C2 : improved adhesive • F :Fast Setting • T :Thixotropic • E : Extended Working Time • S2 : Highly Deformable
  • 25. large size tiles are inserted on a flat surface with a back and forth movement, crosswise to the adhesive grooves pressed firmly from the center towards the edges in order to flatten the adhesive grooves, minimizing the amount of air inclusions a maximum contact surface and an optimal adhesive distribution gives the optimum bond
  • 26. cellulose ethers and higher dosage of redispersible polymer powder (RDP dosage advised S2 is more than 5%) delay cement hydration, impact rheology and cause air entrapment allowing a possible further reduction of the bond strength UPC WHITE as binder / addition to Portlandcement; • accelerated set • rheology modification • low porosity, high density • improved bond strength • excess water bound, autogenous drying • positive volume change, less stress • rapid and complete drying of interfacial surface • low alkali cement placing natural stone the risk of stains forming on the surface is minimized
  • 27. controlled formation of ettringite crystals play an important role in cement tile grouts in order to fill the thin, fine joints used in the application of large size tiles the grout contains a lot of water impacting shrinkage, porosity, efflorescence and wear resistance CALUMEX UPC WHITE as binder • quick hardening and drying • closed fine matrix • high density • leaving less pores • high wear resistance • compensating shrinkage ensuring a durable and stable joint • low alkali content prevents discoloration • no lime bloom ®
  • 28. for making ‘’ fast set terrazzo’’ ü high reflection value ü quick de-molding ü compatible with various aggregates ü recycled glass ü reduced risk efflorescence ü fast polishing
  • 29. self leveling easy handling rapid hardening fast polishable
  • 30. • decorative concrete • countertops • glass fiber reinforced concrete (GRC) • architectural precast • dry-mixed mortars • self levelling topping mortar