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Analysis of a Municipal Solid Waste Landfill in Jalisco,
                                 Mexico and Mitigation Strategies
                                                                              Caroline J. Saul1, Alberto Rodríguez Gómez1, Nadya Selene Alencastro1
                                                                                           Contact: saulcj@gmail.com, alberto.romez@gmail.com, selenealencastro@gmail.com
                                                                                                                                                  1. École des Mines de Nantes


                                                                Introduction                                                                                                                                                                Materials + Methods
                                                                                                                                                                        The current and future behavior of Los Laureles were simulated and analyzed to identify
Currently receiving over 900,000 tons of waste per year, Los Laureles is a landfill in El Salto,
                                                                                                                                                                        potentially threatening environmental impacts:
Jalisco, Mexico that receives municipal and special-handling solid waste from five of the
eight cities in the Guadalajara Metropolitan Zone. The landfill consists of an intake area, 46                                                                          Leachate
hectares of waste receiving land, partial passive landfill gas venting and several open                                                                                 A Leachate Pollution Index (LPI) score was calculated for four leachate ponds at the land fill
leachate ponds and is situated 500 meters west of the Santiago River. Los Laureles has been                                                                             in accordance with the procedures developed by Kumar and Alappat [1] using data
receiving waste since 1986. Photographs from the site as well as accounts from the State                                                                                provided by Los Laureles. The index ranges from 5-100, with higher pollutant
Environmental Agency employees and newspapers report that the site is not utilizing                                                                                     concentrations associated with higher values.
appropriate waste management practices, which could lead to harm against the surrounding                                                                                Leachate production was calculated using average monthly precipitation and
community and environment, and were not in compliance with solid waste legislation.                                                                                     evapotranspiration values from a local weather station. .
                                                                                                                                                                        Landfill Gas
                                                                                                                                                                        The landfill’s production of gas was simulated using LandGEM and Modelo Mexicano de
                                                                             Aims                                                                                       Biogás 2.0, both of which were developed by the U.S. EPA. These simulations were
                                                                                                                                                                        considered in conjunction with gas chromatography results of analysis of samples from the
• To identify and quantify environmental threats created by the landfill and its operations                                                                             gas vents.
• To propose a treatment and remediation strategy that:                                                                                                                 Miscellaneous
       o Brings the landfill into compliance with local, state and national legislation                                                                                 Legislation, scientific literature, interviews with landfill and government employees
       o Demonstrates sensitivity towards environmental and social effects of the landfill                                                                              newspaper articles and photographs were consulted with regard to waste management
                                                                                                                                                                        practices and the public opinion thereof in Jalisco and in Mexico.
       o Considers economic, geographic and geologic feasibility


                                                                                                                                                  Assessment
                                                                                                                                                            The Site
  Figure 1: Global position and history of Los Laureles. Stage 4 accepted tannery sludge until 2007. [2]                    Figure 2: Waste Composition Analysis of Guadalajara [3]                                                                   Figure 3: Site Images. (a) Leakage form torn lining; (b) Haphazard installation of
                       U.S.A.                                                                                                                                                                                                                         new liner; (c) Unprotected worker digs free flowing leachate channel ; (d) Gas
                                                 N
                                                                                                                                                                                                                                                      build-up poses risk of explosion
                                                                                                                                               Pottery &                  Others          Paper &
                                                                    4                                                                          Ceramics                    8%            Cardboard
                       Mexico                                                                   Pond 2                                            1%                                        9%
                                                                                                                                       Ferrous
    Pacific                                                                            5        Pond 4
                                                                                                                                                                 Sanitary
                                                                                                                                       Metals
    Ocean                Jalisco                                                                                                                                  Waste
  Image: jigzone.com                                                                                                                    0,31
                                                                         3                                                                                         9%                             Plastics
                                                                                                                                                                                                   14%
                                                                                                                                   Other Metals                                                                                                         (a)                                     (b)
                                                                                                                                       2%
                                                                                     Pond 11
                                                                    2                                                                                                                                Glass
                                                                                     Pond 9
                                                     Figure 2.                             Surface   Depth    Operation                Textiles                            Organic                    9%
                                                                                     Stage
                                                         1
                                                                                             (ha)     (m)        years                   2%                                Matter
                                                                                       1     6.63     22.3   1986 - 1992
                                                                                       2     7.99     26.5   1992 - 1996                                                    46%
                                                                                       3    24.82      35    1996 - 2004
)                                                                                     4
                                                                                       5
                                                                                              3.1
                                                                                             2.84
                                                                                                      12.7
                                                                                                       11
                                                                                                              Until 2007
                                                                                                             In operation                                                                                                                               (c)                                     (d)



                                                                                               Leachate                                                                                                                                                                  Landfill Gas
The results of a laboratory leachate analysis from the four leachate ponds identified above, were compared with                                                                                      Landfill gas production was modeled with LandGEM and Modelo
the federal discharge limits for wastewater and used to calculate LPI for the landfill. Ponds 2 and 4 are near the                                                                                   Mexicano de Biogás 2.0. As can be seen in Figure 4 , both models
working face of the landfill and ponds 9 and 11 are close to the receiving area and oldest garbage. Table 1 exhibits                                                                                 predicted similar peak production levels and times. According to the
how all of the wells had at least double the allowable chromium concentration. Wells 2 and 4 exhibited the most                                                                                      LandGEM simulation, the landfill has released 265 Gt of CH4 since it
problematic water, exceeding legal discharge limits for BOD5, Fats, Oils and Total Suspended Solids. The LPI                                                                                         became operational in 1987, but in the next twenty years it will
calculations in Table 2 show that the organic pollutants are of great concern for all wells, especially Wells 2 and 4.                                                                               produce over 4 times as much.
                                                                                                                                                                                                                                          300
                                   Discharge                                                   Exceeding
                                                                                                                                                                                                        Annual Gas Production ( 106 m3)




                                               Well 2     Well 4        Well 9    Well 11                                                                                             Discharge
                                     Limit                                                       Wells                            Lagoon 2      Lagoon 4    Lagoon 9     Lagoon 11
                                                                                                                                                                                      Standard                                            250                                                     Total Landfill Gas: LandGEM
BOD Total                            150       >15000        4231        201         21          2,4,9         LPI Organic          78.3          68.6         41.3         39.2          -                                                                                                       Methane: LandGEM
Fats and Oils                         25       190.3      113.9         14.4        16.4          2,4          LPI Inorganic        24.6          35.5         34.5         27.1          -                                               200                                                     Total Landfill Gas: Modelo Mexicano
Total Phosphorous                     30        27.6         28.6       34.0        18.0             9         LPI Heavy
                                                                                                                                     6.6           6.1         5.7          7.1          8.5                                                                                                      Methane: Modelo Mexicano
Total Suspended                                                                                                Metals                                                                                                                     150
                                     125        6680         605         85         300          2,4,11        Total LPI            25.9          25.6         19.2         18.1          -
Solids
Chromium                              1        3.027         2.49       2.079      3.279          All                                                                                                                                     100
                                                                                                                                Table 2: Leachate Pollution Index and Sub-Index scores
 Table 1: Pollutants Exceeding National Discharge Limits. Temperature, Total Settleable
                                                                                                                                                                                                                                           50
 Solids, Total Nitrogen, As, Cd, Cu, Cyanide, Hg, Ni, Pb and Zn were all within limits.
                                                                                                                                                                                                                                            0
Using average monthly precipitation, evapotranspiration values and estimates of leachate generation due to                                                                                                                                   1986       2006             2026              2046                2066                 2086
                                                                                                                                                                                                                                                                                    Year
waste decomposition, the annual leachate production is estimated to be 384 m3/day, which is comparable to the
                                                                                                                                                                                                      Figure 4: Projected annual landfill gas production and composition simulated with LandGem and Modelo
landfill’s measurement of 300m3/day, considering the prevalence of leaks (i.e. leaks in the liner).                                                                                                   Mexicano de Biogas 2.0



                                                                        Mitigation Opportunities                                                                                                                                                                         Conclusions
             Constructed Wetland                                                      Biofilter Cover                                          Organics Diversion: Composting                                                                   The operating conditions and pollution potential of Los
                                                                                                                                     • Increase the lifespan of the landfill                                                                    Laureles were assessed and quantified. Based on this a
Constructed Wetlands are a low                                                                                                       • Decrease the leachate & biogas production                                                                three-fold mitigation approach was developed, which will
                                                                                       CH4 +CO2
maintenance and relatively                                                                                                           • Production of nutrient rich of organic fertilizer                                                        reduce the organics and heavy metals concentrations in the
inexpensive way to treat leachate.                                                                                                   • Can be applied as biofilter for final cover                                                              effluent, decrease the greenhouse gas emissions and extend
                                                                              Compost with methanophiles
 The chromium is primarily Cr(VI), a                                                                                                 • Improve social acceptance of Los Laureles                                                                the life of the landfill by reducing the rate of incoming
carcinogen. So it is of great concern.                                           Gas Distribution Media                              • Potential revenue stream                                                                                 refuse.
                                                                                            Cap system                               • Eligible for carbon credits                                                                              Further work must be done to determine a cost-effective
A pre-treatment to reduce chromium                                                                                                   • Legislation mandates segregation of organic                                                              composting system, proper wetland design, type of
concentration will be necessary, if                                                                                                    components at the generation source                                                                      chromium treatment fly ash and to hone other parameters.
discharge limits are to be met. A fly                                                       CH4 + CO2                                • Available market for the compost products.                                                               Additionally, other attributes of the landfill will be
ash adsorption process could be                                                                                                      • Long term reduction of landfill operating costs
                                                                                               Waste                                                                                                                                            quantified, like noise and aesthetics as well as impacts on
appropriate.                                                                                                                         • High organic content of waste means plenty of
                                                                         Figure 5: Schematic of the effect a biofilter landfill                                                                                                                 the ecosystem.
                                                                         cover can have. [4]                                           input material.


                                                                                                                                      Acknowledgements
 Many thanks to Babu Alappat and Josiane Nikiema for technical and industrial guidance. Eng. Adrian Giombni provided access to operating procedures and data from Los Laureles.
 SEMADES (Secretaría de Medio Ambiente para el Desarrollo Sustentable) supplied images and data from the Guadalajara Metropolitan Zone. We would like to extend our gratitude to the
 European Commission for their support of the ME3 program as well as CONACYT and IJJ for their endorsement of international education.

[1] Kumar, D., & Alappat, B. (2005). Analysis of leachate pollution index and formulation of sub-leachate pollution indices. Waste Management & Research 22, 230-239.
[2] Bernache-Pérez, G. (2009). El impacto social de las operaciones del vertedero Los Laureles. Iberoamerica Symposium of Waste Engineers.
[3] Bernache-Pérez, G. et. al (2001) Solid waste characterisation study in the Guadalajara Metropolitan Zone, Mexico.
[4] Hummer, M., & Lechner, P. (2001). Design of a landfill cover layer to enhance methane oxidation – Results of a two year field investigation. 8th International Waste Management and Landfill Symposium.

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MSWLandfillAnalysisMexico

  • 1. Analysis of a Municipal Solid Waste Landfill in Jalisco, Mexico and Mitigation Strategies Caroline J. Saul1, Alberto Rodríguez Gómez1, Nadya Selene Alencastro1 Contact: saulcj@gmail.com, alberto.romez@gmail.com, selenealencastro@gmail.com 1. École des Mines de Nantes Introduction Materials + Methods The current and future behavior of Los Laureles were simulated and analyzed to identify Currently receiving over 900,000 tons of waste per year, Los Laureles is a landfill in El Salto, potentially threatening environmental impacts: Jalisco, Mexico that receives municipal and special-handling solid waste from five of the eight cities in the Guadalajara Metropolitan Zone. The landfill consists of an intake area, 46 Leachate hectares of waste receiving land, partial passive landfill gas venting and several open A Leachate Pollution Index (LPI) score was calculated for four leachate ponds at the land fill leachate ponds and is situated 500 meters west of the Santiago River. Los Laureles has been in accordance with the procedures developed by Kumar and Alappat [1] using data receiving waste since 1986. Photographs from the site as well as accounts from the State provided by Los Laureles. The index ranges from 5-100, with higher pollutant Environmental Agency employees and newspapers report that the site is not utilizing concentrations associated with higher values. appropriate waste management practices, which could lead to harm against the surrounding Leachate production was calculated using average monthly precipitation and community and environment, and were not in compliance with solid waste legislation. evapotranspiration values from a local weather station. . Landfill Gas The landfill’s production of gas was simulated using LandGEM and Modelo Mexicano de Aims Biogás 2.0, both of which were developed by the U.S. EPA. These simulations were considered in conjunction with gas chromatography results of analysis of samples from the • To identify and quantify environmental threats created by the landfill and its operations gas vents. • To propose a treatment and remediation strategy that: Miscellaneous o Brings the landfill into compliance with local, state and national legislation Legislation, scientific literature, interviews with landfill and government employees o Demonstrates sensitivity towards environmental and social effects of the landfill newspaper articles and photographs were consulted with regard to waste management practices and the public opinion thereof in Jalisco and in Mexico. o Considers economic, geographic and geologic feasibility Assessment The Site Figure 1: Global position and history of Los Laureles. Stage 4 accepted tannery sludge until 2007. [2] Figure 2: Waste Composition Analysis of Guadalajara [3] Figure 3: Site Images. (a) Leakage form torn lining; (b) Haphazard installation of U.S.A. new liner; (c) Unprotected worker digs free flowing leachate channel ; (d) Gas N build-up poses risk of explosion Pottery & Others Paper & 4 Ceramics 8% Cardboard Mexico Pond 2 1% 9% Ferrous Pacific 5 Pond 4 Sanitary Metals Ocean Jalisco Waste Image: jigzone.com 0,31 3 9% Plastics 14% Other Metals (a) (b) 2% Pond 11 2 Glass Pond 9 Figure 2. Surface Depth Operation Textiles Organic 9% Stage 1 (ha) (m) years 2% Matter 1 6.63 22.3 1986 - 1992 2 7.99 26.5 1992 - 1996 46% 3 24.82 35 1996 - 2004 ) 4 5 3.1 2.84 12.7 11 Until 2007 In operation (c) (d) Leachate Landfill Gas The results of a laboratory leachate analysis from the four leachate ponds identified above, were compared with Landfill gas production was modeled with LandGEM and Modelo the federal discharge limits for wastewater and used to calculate LPI for the landfill. Ponds 2 and 4 are near the Mexicano de Biogás 2.0. As can be seen in Figure 4 , both models working face of the landfill and ponds 9 and 11 are close to the receiving area and oldest garbage. Table 1 exhibits predicted similar peak production levels and times. According to the how all of the wells had at least double the allowable chromium concentration. Wells 2 and 4 exhibited the most LandGEM simulation, the landfill has released 265 Gt of CH4 since it problematic water, exceeding legal discharge limits for BOD5, Fats, Oils and Total Suspended Solids. The LPI became operational in 1987, but in the next twenty years it will calculations in Table 2 show that the organic pollutants are of great concern for all wells, especially Wells 2 and 4. produce over 4 times as much. 300 Discharge Exceeding Annual Gas Production ( 106 m3) Well 2 Well 4 Well 9 Well 11 Discharge Limit Wells Lagoon 2 Lagoon 4 Lagoon 9 Lagoon 11 Standard 250 Total Landfill Gas: LandGEM BOD Total 150 >15000 4231 201 21 2,4,9 LPI Organic 78.3 68.6 41.3 39.2 - Methane: LandGEM Fats and Oils 25 190.3 113.9 14.4 16.4 2,4 LPI Inorganic 24.6 35.5 34.5 27.1 - 200 Total Landfill Gas: Modelo Mexicano Total Phosphorous 30 27.6 28.6 34.0 18.0 9 LPI Heavy 6.6 6.1 5.7 7.1 8.5 Methane: Modelo Mexicano Total Suspended Metals 150 125 6680 605 85 300 2,4,11 Total LPI 25.9 25.6 19.2 18.1 - Solids Chromium 1 3.027 2.49 2.079 3.279 All 100 Table 2: Leachate Pollution Index and Sub-Index scores Table 1: Pollutants Exceeding National Discharge Limits. Temperature, Total Settleable 50 Solids, Total Nitrogen, As, Cd, Cu, Cyanide, Hg, Ni, Pb and Zn were all within limits. 0 Using average monthly precipitation, evapotranspiration values and estimates of leachate generation due to 1986 2006 2026 2046 2066 2086 Year waste decomposition, the annual leachate production is estimated to be 384 m3/day, which is comparable to the Figure 4: Projected annual landfill gas production and composition simulated with LandGem and Modelo landfill’s measurement of 300m3/day, considering the prevalence of leaks (i.e. leaks in the liner). Mexicano de Biogas 2.0 Mitigation Opportunities Conclusions Constructed Wetland Biofilter Cover Organics Diversion: Composting The operating conditions and pollution potential of Los • Increase the lifespan of the landfill Laureles were assessed and quantified. Based on this a Constructed Wetlands are a low • Decrease the leachate & biogas production three-fold mitigation approach was developed, which will CH4 +CO2 maintenance and relatively • Production of nutrient rich of organic fertilizer reduce the organics and heavy metals concentrations in the inexpensive way to treat leachate. • Can be applied as biofilter for final cover effluent, decrease the greenhouse gas emissions and extend Compost with methanophiles The chromium is primarily Cr(VI), a • Improve social acceptance of Los Laureles the life of the landfill by reducing the rate of incoming carcinogen. So it is of great concern. Gas Distribution Media • Potential revenue stream refuse. Cap system • Eligible for carbon credits Further work must be done to determine a cost-effective A pre-treatment to reduce chromium • Legislation mandates segregation of organic composting system, proper wetland design, type of concentration will be necessary, if components at the generation source chromium treatment fly ash and to hone other parameters. discharge limits are to be met. A fly CH4 + CO2 • Available market for the compost products. Additionally, other attributes of the landfill will be ash adsorption process could be • Long term reduction of landfill operating costs Waste quantified, like noise and aesthetics as well as impacts on appropriate. • High organic content of waste means plenty of Figure 5: Schematic of the effect a biofilter landfill the ecosystem. cover can have. [4] input material. Acknowledgements Many thanks to Babu Alappat and Josiane Nikiema for technical and industrial guidance. Eng. Adrian Giombni provided access to operating procedures and data from Los Laureles. SEMADES (Secretaría de Medio Ambiente para el Desarrollo Sustentable) supplied images and data from the Guadalajara Metropolitan Zone. We would like to extend our gratitude to the European Commission for their support of the ME3 program as well as CONACYT and IJJ for their endorsement of international education. [1] Kumar, D., & Alappat, B. (2005). Analysis of leachate pollution index and formulation of sub-leachate pollution indices. Waste Management & Research 22, 230-239. [2] Bernache-Pérez, G. (2009). El impacto social de las operaciones del vertedero Los Laureles. Iberoamerica Symposium of Waste Engineers. [3] Bernache-Pérez, G. et. al (2001) Solid waste characterisation study in the Guadalajara Metropolitan Zone, Mexico. [4] Hummer, M., & Lechner, P. (2001). Design of a landfill cover layer to enhance methane oxidation – Results of a two year field investigation. 8th International Waste Management and Landfill Symposium.