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1
Powerpoint




     2
1.Top Guideline



       3
1.Top Guideline
•   In the Audience’s Shoes
•   Have A Skeleton
•   Don’t Read Slides
•   Don’t Inundate Your Listener
•   Put Only Important Information
•   Grammar and Spelling



                         4
1-1 In the audience’s shoes
• Who’s the listener?
• Can he/she remember my previous
  work?



      ?   !                 ZZ




                     5
1-2 Have a skeleton
• Outline
• Remind audience where are we!




                      6
1-3 Don’t Read Slides
• Get the control of presentation!
• Extract the most important key words.




                       7
Introduction
 There are two Possible Ways to Minimize Corrosion

  The first is to strengthening the corrosion of copper so that
   copper would not be corroded easily. When it comes to
   strengthen, nanotwins give people an image of strengthening.
   Therefore, is it possible to strengthen material by nanotwins is
   an interesting topic.

  Another possible way to increase corrosion resistance is to
   shield the copper from contacting the corrosive agent. One of
   the most effective protective agent for copper from corrosion is
   BTA.
                                                                      8
                                                            Chih-Jie Yang
Introduction

 Possible Ways to Minimize Corrosion

  Strengthen the corrosion resistance.(Strengthening)

  Shield copper from corrosive agents (Shield)




                                                         9
                                               Chih-Jie Yang
1-4. Don’t inundate your audience

• Too much information
• Unorganized information




                     10
DC      PO     BTADC    BTAPO
                                                  (111)    0.16    0.10    0.32     0.28
                                                  (200)    0.08    0.05    0.18     0.20
                                                  (220)    2.76    2.85    2.50     2.52

Samples share similar preferred orientation Cu(220).→Corrosion difference from crystal. orient. is eliminated.




                                                                                            Chih-Jie Yang
Discussion
 2.Cryst. Orientation




                                        DC     PO BTADC BTAPO
                                (111)   0.16   0.10 0.32 0.28
                                (200)   0.08   0.05 0.18 0.20
                                (220)   2.76   2.85 2.50 2.52
  All samples share similar preferred orientation Cu(220).
  →Corrosion difference from crystal. orient. is eliminated.
                                                             12
                                                    Chih-Jie Yang
Discussion
     3.G.S Analysis




                                                      We can not explain corrosion
                                                      behavior by grain size variation!!

  Luo et al. J. Electrochem. Soc.2012, 159, C80-C85

                                                                                       13
                                                                              Chih-Jie Yang
1-5. Put Only Important Things
• Weight the importance of your info




                      14
Outline

   Motivation

   Review

   Results

   Discussion


                          15
                 Chih-Jie Yang
Outline
   Motivation
    Why we are concerned about corrosion?
    What are the possible ways to minimize corrosion?
   Review
   Results
     A corrosion resistance relationship b/w specimens was found.
   Reasoning for the Relationship
     Study of possible factors.
     Explanation of the observed results.


                                                                 16
                                                        Chih-Jie Yang
1-6. Grammar and Spelling
• Double check your unfamiliar words
  nail oil-> nail polish
• Do not create special word usage.
• Beware of typos

                                     ╳
               Crystal lattice is destroyed

               Crystal lattice is damaged


                         17
2.Arrange Your Slides



          18
Arrange Your Slides
                    Figure
Individual
  Object
             Animation Illustration


                     Color

 Overall
                   Alignment
 Layout

                   Animation

              19
2-1-1 Literature Figure
• Clear
• Cite reference




                   Zhigang et. al. IEEE Trans. Device Mater. Reliab. 2005,5,206



                                20
2-1-2. Data Plot
• Easy to read
• Avoid ambiguity
• Unit and Legend




                    21
2-1-2. Data Plot
• Easy to read




                    22
2-1-2. Data Plot
• Avoid ambiguity




                    23
2-1-3 Mind map
• Avail the SmartArt objects
• Not to be limited




                       24
2-1-3 Mind map
• Avail the SmartArt objects

     Egun            CVD          ECD

            • Grain size
    Grain   • Grain orientation

           • Passivation film
   Passive • Native oxide


                             25
2-1-3 Mind map
• Not to be limited




                      26
Discussion

                                 Corrosion

  Surface              Crystal                                   Twinning
 Roughness            Orientation
                                            Grain Size
                                                                   BTA?
                                                                Twinned
                                                                BTA incorporated
Polish all samples   Control to Cu(220)
                     by Cl- addition
                                          Contradictory Trend
                                                                      ?
                                                                Corrodes Slower




                                                                     Chih-Jie Yang
Arrange Your Slides
                        Figure
Individual
  Object
             Animation/Figure Illustration


                         Color

 Overall
                       Alignment
 Layout

                       Animation

                  28
2-2 Animation/Figure Illustration
• Use animation/Figure to illustrate your
  idea




                       29
2-2 Animation/Figure Illustration
1.E-gun deposition: Ti 30nm Cu 300nm
2.Photolithography:spin coating AZ4620 5um
3.Electrodeposition:H2SO41M,pH=1,NaCl10- 3M
4.Mechanical Polish:2400 grit paper->clothing
5.Polarization test: Electrolyte:HNO3 0.1M
6. Immersion Test: Electrolyte:HNO3 0.1M
7. Characterization:TEM,SEM,AFM,XRD



                         30
Exp. Flow
  E-Gun Deposition      Mechanical Polish       Immersion Test
  Cu Seed Ti:30nm
    Ti                        2400 grit paper          Electrolyte:
          Cu:300nm
    Si                              ↓                  HNO3 0.1M
                               300 nm Al2O3            Test time
                                                       12 hours
  Photolithography
            AZ-4620
            5㎛          Polarization Test
                                                Characterization
                                Electrolyte:
  Electrodeposition
                                HNO3 0.1M         SEM
           H2SO4 1M
                                Sweep V:
                                -0.5~2V
                                                  XRD
           pH=1                 Sweep rate:       AFM
           NaCl 10-3M
           BTA 10-4M
                                0.05V/S
                                                  TEM

                                                           Chih-Jie Yang
Discussion
 Better R. for BTA
         Corrosion                        Copper Oxidation
          Protected Regions
                                            1


 2
 1   1        1
              2   1
                  2   1       1
                              2   2
                                  1   1
                          1


                                      1         2

                                          Conclusion
                                      Incorporated Amount:
                                      BTAPO>BTADC
                                      Corrosion Resistance
                                      BTAPO>BTADC
                                                             Chih-Jie Yang
Arrange Your Slides
                        Figure
Individual
  Object
             Animation/Figure Illustration


                         Color

 Overall
                       Alignment
 Layout

                       Animation

                  33
2-3. Color
• Use similar color through the ppt
• Simple background
• Avoid bright/fluorescent color
2-3. Color
• Avoid bright/fluorescent color

Twin structures in specimen were
characterized by TEM technique.
Copper foil was stripped from
substrate first.

Then it was adhered to copper grid by
AB glue and placed still for 12 hours
for the glue to dry
Arrange Your Slides
                        Figure
Individual
  Object
             Animation/Figure Illustration


                         Color

 Overall
                       Alignment
 Layout

                       Animation

                  36
2-4. Alignment
• Alignment all the objects
  (Centered/Left)




                       37
Exp. Flow
 E-Gun Deposition       Mechanical Polish            Immersion Test
 Cu Seed Ti:30nm
   Ti                           2400 grit paper             Electrolyte:
         Cu:300nm
   Si                                 ↓                     HNO3 0.1M
                                 300 nm Al2O3               Test time
                                                            12 hours
   Photolithography
             AZ-4620
             5㎛         Polarization Test

                                                  Characterization
                                Electrolyte:
  Electrodeposition             HNO3 0.1M
                                Sweep V:            SEM
           H2SO4 1M
                                -0.5~2V             XRD
                                Sweep rate:
           pH=1
                                0.05V/S             AFM
           NaCl 10-3M
           BTA 10-4M                                TEM
                                                          Chih-Jie Yang
Exp. Flow
  E-Gun Deposition      Mechanical Polish       Immersion Test
  Cu Seed Ti:30nm
    Ti                        2400 grit paper          Electrolyte:
           Cu:300nm
    Si                              ↓                  HNO3 0.1M
                               300 nm Al2O3            Test time
                                                       12 hours
  Photolithography
            AZ-4620
            5㎛          Polarization Test
                                                Characterization
                                Electrolyte:
  Electrodeposition
                                HNO3 0.1M         SEM
           H2SO4 1M
                                Sweep V:
                                -0.5~2V
                                                  XRD
           pH=1                 Sweep rate:       AFM
           NaCl 10-3M
           BTA 10-4M
                                0.05V/S
                                                  TEM

                                                           Chih-Jie Yang
Arrange Your Slides
                        Figure
Individual
  Object
             Animation/Figure Illustration


                         Color

 Overall
                       Alignment
 Layout

                       Animation

                  40
2-5. Animation
• Use animation to highlight your key
  point.
• Get the control
• Keep it simple




                       41
Review-Shield
 Benzotriazole (BTA)
                                                                         BTA
                                                            CMP Corr.               ED
                                                             Inhibitor            Additives

                                                                                 Roughness
                                                            Inhibitive       
   Matjaz et al. Corrosion Science 2010,52, 2737–2749
                                                                                  G.S.
                                                             Capability          C.E.
                                              W/O BTA
                                                                                 Inclusion
      W/ BTA
      Protection                              Protection



                                                              BTA as additives
                                                                          ?
                                                              Discuss Corr. Ability
           Mansfeld et al. Corrosion 1971,27, 289-293

                                                                                   Chih-Jie Yang
Review-Shield
 Benzotriazole (BTA)
                                                                         BTA
                                                            CMP Corr.               ED
                                                             Inhibitor            Additives

                                                                                 Roughness
                                                            Inhibitive       
   Matjaz et al. Corrosion Science 2010,52, 2737–2749
                                                                                  G.S.
                                                             Capability          C.E.
                                              W/O BTA
                                                                                 Inclusion
      W/ BTA
      Protection                              Protection



                                                              BTA as additives
                                                                          ?
                                                              Discuss Corr. Ability
           Mansfeld et al. Corrosion 1971,27, 289-293

                                                                                   Chih-Jie Yang
3.The Most Important Thing



            44
The Most Important Thing
• In the audience’s shoes
• Get the control of the present




                   45
46

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Tips for presentation

  • 1. 1
  • 4. 1.Top Guideline • In the Audience’s Shoes • Have A Skeleton • Don’t Read Slides • Don’t Inundate Your Listener • Put Only Important Information • Grammar and Spelling 4
  • 5. 1-1 In the audience’s shoes • Who’s the listener? • Can he/she remember my previous work? ? ! ZZ 5
  • 6. 1-2 Have a skeleton • Outline • Remind audience where are we! 6
  • 7. 1-3 Don’t Read Slides • Get the control of presentation! • Extract the most important key words. 7
  • 8. Introduction There are two Possible Ways to Minimize Corrosion  The first is to strengthening the corrosion of copper so that copper would not be corroded easily. When it comes to strengthen, nanotwins give people an image of strengthening. Therefore, is it possible to strengthen material by nanotwins is an interesting topic.  Another possible way to increase corrosion resistance is to shield the copper from contacting the corrosive agent. One of the most effective protective agent for copper from corrosion is BTA. 8 Chih-Jie Yang
  • 9. Introduction Possible Ways to Minimize Corrosion  Strengthen the corrosion resistance.(Strengthening)  Shield copper from corrosive agents (Shield) 9 Chih-Jie Yang
  • 10. 1-4. Don’t inundate your audience • Too much information • Unorganized information 10
  • 11. DC PO BTADC BTAPO (111) 0.16 0.10 0.32 0.28 (200) 0.08 0.05 0.18 0.20 (220) 2.76 2.85 2.50 2.52 Samples share similar preferred orientation Cu(220).→Corrosion difference from crystal. orient. is eliminated. Chih-Jie Yang
  • 12. Discussion 2.Cryst. Orientation DC PO BTADC BTAPO (111) 0.16 0.10 0.32 0.28 (200) 0.08 0.05 0.18 0.20 (220) 2.76 2.85 2.50 2.52 All samples share similar preferred orientation Cu(220). →Corrosion difference from crystal. orient. is eliminated. 12 Chih-Jie Yang
  • 13. Discussion 3.G.S Analysis We can not explain corrosion behavior by grain size variation!! Luo et al. J. Electrochem. Soc.2012, 159, C80-C85 13 Chih-Jie Yang
  • 14. 1-5. Put Only Important Things • Weight the importance of your info 14
  • 15. Outline Motivation Review Results Discussion 15 Chih-Jie Yang
  • 16. Outline Motivation Why we are concerned about corrosion? What are the possible ways to minimize corrosion? Review Results A corrosion resistance relationship b/w specimens was found. Reasoning for the Relationship Study of possible factors. Explanation of the observed results. 16 Chih-Jie Yang
  • 17. 1-6. Grammar and Spelling • Double check your unfamiliar words nail oil-> nail polish • Do not create special word usage. • Beware of typos ╳ Crystal lattice is destroyed Crystal lattice is damaged 17
  • 19. Arrange Your Slides Figure Individual Object Animation Illustration Color Overall Alignment Layout Animation 19
  • 20. 2-1-1 Literature Figure • Clear • Cite reference Zhigang et. al. IEEE Trans. Device Mater. Reliab. 2005,5,206 20
  • 21. 2-1-2. Data Plot • Easy to read • Avoid ambiguity • Unit and Legend 21
  • 22. 2-1-2. Data Plot • Easy to read 22
  • 23. 2-1-2. Data Plot • Avoid ambiguity 23
  • 24. 2-1-3 Mind map • Avail the SmartArt objects • Not to be limited 24
  • 25. 2-1-3 Mind map • Avail the SmartArt objects Egun CVD ECD • Grain size Grain • Grain orientation • Passivation film Passive • Native oxide 25
  • 26. 2-1-3 Mind map • Not to be limited 26
  • 27. Discussion Corrosion Surface Crystal Twinning Roughness Orientation Grain Size BTA? Twinned BTA incorporated Polish all samples Control to Cu(220) by Cl- addition Contradictory Trend ? Corrodes Slower Chih-Jie Yang
  • 28. Arrange Your Slides Figure Individual Object Animation/Figure Illustration Color Overall Alignment Layout Animation 28
  • 29. 2-2 Animation/Figure Illustration • Use animation/Figure to illustrate your idea 29
  • 30. 2-2 Animation/Figure Illustration 1.E-gun deposition: Ti 30nm Cu 300nm 2.Photolithography:spin coating AZ4620 5um 3.Electrodeposition:H2SO41M,pH=1,NaCl10- 3M 4.Mechanical Polish:2400 grit paper->clothing 5.Polarization test: Electrolyte:HNO3 0.1M 6. Immersion Test: Electrolyte:HNO3 0.1M 7. Characterization:TEM,SEM,AFM,XRD 30
  • 31. Exp. Flow E-Gun Deposition Mechanical Polish Immersion Test Cu Seed Ti:30nm Ti 2400 grit paper Electrolyte: Cu:300nm Si ↓ HNO3 0.1M 300 nm Al2O3 Test time 12 hours Photolithography AZ-4620 5㎛ Polarization Test Characterization Electrolyte: Electrodeposition HNO3 0.1M SEM H2SO4 1M Sweep V: -0.5~2V XRD pH=1 Sweep rate: AFM NaCl 10-3M BTA 10-4M 0.05V/S TEM Chih-Jie Yang
  • 32. Discussion Better R. for BTA Corrosion Copper Oxidation Protected Regions 1 2 1 1 1 2 1 2 1 1 2 2 1 1 1 1 2 Conclusion Incorporated Amount: BTAPO>BTADC Corrosion Resistance BTAPO>BTADC Chih-Jie Yang
  • 33. Arrange Your Slides Figure Individual Object Animation/Figure Illustration Color Overall Alignment Layout Animation 33
  • 34. 2-3. Color • Use similar color through the ppt • Simple background • Avoid bright/fluorescent color
  • 35. 2-3. Color • Avoid bright/fluorescent color Twin structures in specimen were characterized by TEM technique. Copper foil was stripped from substrate first. Then it was adhered to copper grid by AB glue and placed still for 12 hours for the glue to dry
  • 36. Arrange Your Slides Figure Individual Object Animation/Figure Illustration Color Overall Alignment Layout Animation 36
  • 37. 2-4. Alignment • Alignment all the objects (Centered/Left) 37
  • 38. Exp. Flow E-Gun Deposition Mechanical Polish Immersion Test Cu Seed Ti:30nm Ti 2400 grit paper Electrolyte: Cu:300nm Si ↓ HNO3 0.1M 300 nm Al2O3 Test time 12 hours Photolithography AZ-4620 5㎛ Polarization Test Characterization Electrolyte: Electrodeposition HNO3 0.1M Sweep V: SEM H2SO4 1M -0.5~2V XRD Sweep rate: pH=1 0.05V/S AFM NaCl 10-3M BTA 10-4M TEM Chih-Jie Yang
  • 39. Exp. Flow E-Gun Deposition Mechanical Polish Immersion Test Cu Seed Ti:30nm Ti 2400 grit paper Electrolyte: Cu:300nm Si ↓ HNO3 0.1M 300 nm Al2O3 Test time 12 hours Photolithography AZ-4620 5㎛ Polarization Test Characterization Electrolyte: Electrodeposition HNO3 0.1M SEM H2SO4 1M Sweep V: -0.5~2V XRD pH=1 Sweep rate: AFM NaCl 10-3M BTA 10-4M 0.05V/S TEM Chih-Jie Yang
  • 40. Arrange Your Slides Figure Individual Object Animation/Figure Illustration Color Overall Alignment Layout Animation 40
  • 41. 2-5. Animation • Use animation to highlight your key point. • Get the control • Keep it simple 41
  • 42. Review-Shield Benzotriazole (BTA) BTA CMP Corr. ED Inhibitor Additives  Roughness  Inhibitive  Matjaz et al. Corrosion Science 2010,52, 2737–2749 G.S. Capability  C.E. W/O BTA  Inclusion W/ BTA Protection Protection BTA as additives ? Discuss Corr. Ability Mansfeld et al. Corrosion 1971,27, 289-293 Chih-Jie Yang
  • 43. Review-Shield Benzotriazole (BTA) BTA CMP Corr. ED Inhibitor Additives  Roughness  Inhibitive  Matjaz et al. Corrosion Science 2010,52, 2737–2749 G.S. Capability  C.E. W/O BTA  Inclusion W/ BTA Protection Protection BTA as additives ? Discuss Corr. Ability Mansfeld et al. Corrosion 1971,27, 289-293 Chih-Jie Yang
  • 45. The Most Important Thing • In the audience’s shoes • Get the control of the present 45
  • 46. 46