Raman spectroscopy.pptx M Pharm, M Sc, Advanced Spectral Analysis
Poor quality water management
1. Residual sodium carbonate in under
ground water of Punjab
Range
(me L-1)
Mean
No. of
polygons
Area
(ha)
Per cent
area of
state
<2.5 0.892 297 27,92,571 55
2.5-5.0 3.365 179 18,81,354 37
>5.0 7.24 44 3,62,080 8
5. Geo-statistics of generalized quality
of underground water in Punjab
Categories
No. of
polygons
Area (ha)
Per cent area
of state
Fit
EC:< 2 (dS m-1)
RSC: <2.5 (me L-1)
224 23,01,956 45.7
Marginal
EC: 2 - 4
RSC: 2.5 - 5 245 23,19,380 46.1
Unfit
EC:> 4
RSC: >5 51 4,14,664 8.2
6. Leaching requirement
• Leaching requirement (LR) is that amount of water
required to leach the salt beyond the root zone for
maintaining the salt balance
• Leaching requirement (LR)= EC iw
• EC dw
• Where:
• LR=Leaching requirement
• ECiw = Electrical conductivity of irrigation water
• ECdw = Electrical conductivity of drainage or leaching
water
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16. Cross-Checking Chemical Analyses for Consistency and
Reliability
A means of locating gross errors in the chemical analyses of soils is
provided by the considerable number of interrelations that exist
among the values obtained for various determinations. An
understanding of the principles involved in these interrelations aids
in the interpretation of the analyses.
ELECTRICAL CONDUCTIVITY AND TOTAL CATION and
CONCENTRATION.-
1. The EC of soil solutions and saturation extracts when
expressed in millimhos per centimeter at 25” C. and
multiplied by 10 is approximately equal to the total
soluble-cation concentration in milliequivalents per liter.
2. CATION AND ANION CONCENTRATION.-The total soluble-
anion concentration or content and the total soluble
cation concentration or content, expressed on an
equivalent basis, are nearly equal
17. Cross-Checking Chemical Analyses
3. pH AND CARBONATE AND BICARBONATE
CONCENTRATIONS.-
If carbonate ions are present in a s&oil extract in titratable
quantities, the pH reading of the extract must exceed 9. The
bicarbonate concentration seldom
exceeds 10 meq./l. in the absence of carbonate ions, and at
pH readings of about 7 or less seldom exceeds 3 or 4 meq./l.
4.pH AND CALCIUM AND MAGNESIUM CONCENTRATIONS.-
The concentration of calcium and magnesium in a saturation
extract seldom exceeds 2 meq./l. at pH readings above 9.
Therefore, calcium plus magnesium is low if carbonate ions
are present in titratable amounts, and
calcium plus magnesium is never high in the presence
of a high concentration of bicarbonate ions.
18. Acknowledge and Thanks
Author is immensely thankful to all the
websites and books whom I contacted to make
these slides more informative and attractive
By Dr. Kamini Roy