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Coal AshCoal Ash BeneficiationBeneficiation forfor
Quality Construction MaterialsQuality Construction Materials
and Sustainabilityand Sustainability
NETL 2003 Conference on
Unburned Carbon on Utility Fly Ash
October 28, 2003
Pittsburgh, PA
2002 CCP’s Utilization2002 CCP’s Utilization (Tons)(Tons)
! Concrete 190,000
! Waste Stabilization 170,000
! Supplemental Fuel 131,000
! Sub-Base (Btm. Ash) 130,000
! Cement Raw Feed 30,000
! Soil/Asphalt Stabilization 12,000
Total 663,000
We Energies
CCP Production & Utilization
0
100,000
200,000
300,000
400,000
500,000
600,000
700,000
800,000
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
Tons
Coal Ash Produced (Tons)
Coal Ash Utilized (Tons)
Quality ManagementQuality Management
!Environmental
Regulations
!User Specifications
!Chemistry
!Physical
!Storage - Shelf Life
Quality of CCP’sQuality of CCP’s
! Importance of Consistency
–Loss on Ignition (LOI)
–Foam Index
–Chemistry (Coal Changes)
–Fineness (Mill Performance)
! Ash Sample Requests
–Quality Record
–Outside Research
Lower Quality CCP’s?Lower Quality CCP’s?
!No Users?
!Solution = Change the
CCP to a material that is
needed and can be
beneficially used.
WhyWhy BeneficiateBeneficiate??
!Economics
!Quality Enhancement
!More Revenue
!Avoid Landfilling and Expense
!Sustainability
Carbon (LOI) ReductionCarbon (LOI) Reduction
!Ash Fuel Reburn
!Fluidized Bed Combustion
!Electrostatic Seperation
!Froth Floatation
Ash FuelAsh Fuel
ReburnReburn
ProcessProcess
Patent # 5,992,336
Valley Power Plant
•Located near downtown Milwaukee
•Responsible for 280 megawatts of power for the downtown area
•Provides all of the steam for the district heating system
•Fly Ash has LOI near 25 %, bottom ash has LOI near 50 %
Pleasant Prairie Power PlantPleasant Prairie Power Plant
! Wisconsin’s largest power plant (2 units)
! Located near Wisconsin-Illinois border
! Serves as baseload plant for system
! Fly ash has LOI of less than 1%
Old System
Coal
Power Plant
Landfill
Coal
Virgin Ash
From Other
Plants
Power Plant
Energy
Building
Materials
New System
Wet
Process
Dry Process
Test Burn ResultsTest Burn Results
"Bottom Ash
VAPP LOI In = 37.9%
PPPP LOI Out = 0.3%
"Fly Ash
VAPP LOI In = 26.5%
PPPP LOI Out = 0.3%
BenefitsBenefits
" Recover Otherwise Lost Energy
" Preserve Existing Landfill Capacity
" Reduce Need for New Landfills
" Provide Additional Improved Fly Ash
for Concrete
" Reduce Additional CO2 and other
Emissions from Cement Production
" Avoided Cost of Landfilling
RecoveringRecovering
Ash Stored InAsh Stored In
LandfillsLandfills
Coal fired power plants have
existed for several decades, but
only recently has ash utilization
become prominent.
The question is,
where is all the ash
from years past?
In Landfills!
Licensing and constructing
landfills is becoming less
attractive as an option
because:
#There is less space for new
construction of landfills
#Increased regulations make landfills
more expensive to license and build
#People do not want landfills to be
built near their homes or businesses
In addition to the expense of
building and maintaining landfills,
hundreds of thousands of acres of
landfills contain significant amounts
of ash that either was not or could
not be utilized.
Much of this ash has a high L.O.I.
value, and is therefore
WASTED ENERGY
Ash Recovery Process
(Patent #6,637,354)
Coal
Stored Ash
Construction
Materials
Pleasant Prairie
Power Plant
Energy
Environmental
Benefits
Ash Reclamation at Former
Landfill Site
By reclaiming, reburning, and treating
ash from landfills:
$Landfill space is reclaimed and is
available for more productive uses
$Energy is recovered
$Concrete quality fly ash is produced
$Raw fuel is conserved for future
generations
Other Benefits Include:Other Benefits Include:
! Reduced Risk to Soil/Groundwater
! Allows Redevelopment of Former Landfills
! Reduced Mining and Transportation of Coal
! Reduced Limestone and Clay Quarried for
Portland Cement Production
! Reduced Emissions from Cement Kilns
– CO2, NOx, HCl, SOx
! Higher Quality/Strength Concrete
! Production of Product Close to Market
P4P4
Ash Fuel ReburnAsh Fuel Reburn
ResultsResults
Reburn StatisticsReburn Statistics
Ash
Reburned
(tons)
Coal
Displaced
(tons)
Fly ash
produced
(tons)
P4 280,000 120,000 125,000
PIPP 10,000 2,500 4,500
Ash Fuel BlendingAsh Fuel Blending
! Coal typically has 5% Ash Content
! High Carbon Supplemental Fuel has
80% Ash Content
! For 2% Ash Fuel Addition:
Resulting Coal Ash Influence =
(.98 X .05) + (.02 X .80)
.049 + .016 = .065
So for .016/.065 we have 25% influence in
total ash by adding 2% Ash Fuel.
CaO vs. Ash Fuel Addition Trend
15.00
16.00
17.00
18.00
19.00
20.00
21.00
22.00
23.00
24.00
25.00
26.00
27.00
1/1/2000
9/7/2000
5/15/2001
1/20/2002
9/27/2002
CaO(%)
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
CaO (%)
Ash Fuel Addition (%)
Fly Ash Characterists for P4 Ash Fuel
50.0
60.0
70.0
80.0
90.0
100.0
110.0
1/1/2000
9/7/2000
5/15/2001
1/20/2002
9/27/2002
6/4/2003
SiO2+Al2O3+Fe2O3andSAI
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
AshFuelAddition
SiO2 + Al2O3 + Fe2O3 (%) 7 Day SAI, (% of Control) Ash Fuel Addition (%)
Fly Ash Characterists for P4 Ash Fuel
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
1/1/2000
9/7/2000
5/15/2001
1/20/2002
9/27/2002
6/4/2003
LOI,EquivalentNa2O,Density,AshFuelAddition
LOI (%) Equivalent Na2O (%) Ash Fuel Addition (%) Density, g/cm3
ConclusionsConclusions
"“The Right Thing to Do.”
–Environment
–Cement Industry
–Utility Customers
–Utility Stockholders
–Global Community
–Sustainable Development for the
Future

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Coal Ash Beneficiation Provides Quality Construction Materials

  • 1. Coal AshCoal Ash BeneficiationBeneficiation forfor Quality Construction MaterialsQuality Construction Materials and Sustainabilityand Sustainability NETL 2003 Conference on Unburned Carbon on Utility Fly Ash October 28, 2003 Pittsburgh, PA
  • 2.
  • 3.
  • 4.
  • 5. 2002 CCP’s Utilization2002 CCP’s Utilization (Tons)(Tons) ! Concrete 190,000 ! Waste Stabilization 170,000 ! Supplemental Fuel 131,000 ! Sub-Base (Btm. Ash) 130,000 ! Cement Raw Feed 30,000 ! Soil/Asphalt Stabilization 12,000 Total 663,000
  • 6. We Energies CCP Production & Utilization 0 100,000 200,000 300,000 400,000 500,000 600,000 700,000 800,000 1980 1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 Tons Coal Ash Produced (Tons) Coal Ash Utilized (Tons)
  • 7. Quality ManagementQuality Management !Environmental Regulations !User Specifications !Chemistry !Physical !Storage - Shelf Life
  • 8. Quality of CCP’sQuality of CCP’s ! Importance of Consistency –Loss on Ignition (LOI) –Foam Index –Chemistry (Coal Changes) –Fineness (Mill Performance) ! Ash Sample Requests –Quality Record –Outside Research
  • 9.
  • 10. Lower Quality CCP’s?Lower Quality CCP’s? !No Users? !Solution = Change the CCP to a material that is needed and can be beneficially used.
  • 11. WhyWhy BeneficiateBeneficiate?? !Economics !Quality Enhancement !More Revenue !Avoid Landfilling and Expense !Sustainability
  • 12. Carbon (LOI) ReductionCarbon (LOI) Reduction !Ash Fuel Reburn !Fluidized Bed Combustion !Electrostatic Seperation !Froth Floatation
  • 14. Valley Power Plant •Located near downtown Milwaukee •Responsible for 280 megawatts of power for the downtown area •Provides all of the steam for the district heating system •Fly Ash has LOI near 25 %, bottom ash has LOI near 50 %
  • 15. Pleasant Prairie Power PlantPleasant Prairie Power Plant ! Wisconsin’s largest power plant (2 units) ! Located near Wisconsin-Illinois border ! Serves as baseload plant for system ! Fly ash has LOI of less than 1%
  • 17. Coal Virgin Ash From Other Plants Power Plant Energy Building Materials New System
  • 19.
  • 20.
  • 22.
  • 23.
  • 24. Test Burn ResultsTest Burn Results "Bottom Ash VAPP LOI In = 37.9% PPPP LOI Out = 0.3% "Fly Ash VAPP LOI In = 26.5% PPPP LOI Out = 0.3%
  • 25. BenefitsBenefits " Recover Otherwise Lost Energy " Preserve Existing Landfill Capacity " Reduce Need for New Landfills " Provide Additional Improved Fly Ash for Concrete " Reduce Additional CO2 and other Emissions from Cement Production " Avoided Cost of Landfilling
  • 26. RecoveringRecovering Ash Stored InAsh Stored In LandfillsLandfills
  • 27. Coal fired power plants have existed for several decades, but only recently has ash utilization become prominent. The question is, where is all the ash from years past?
  • 29. Licensing and constructing landfills is becoming less attractive as an option because: #There is less space for new construction of landfills #Increased regulations make landfills more expensive to license and build #People do not want landfills to be built near their homes or businesses
  • 30. In addition to the expense of building and maintaining landfills, hundreds of thousands of acres of landfills contain significant amounts of ash that either was not or could not be utilized. Much of this ash has a high L.O.I. value, and is therefore WASTED ENERGY
  • 31. Ash Recovery Process (Patent #6,637,354) Coal Stored Ash Construction Materials Pleasant Prairie Power Plant Energy Environmental Benefits
  • 32. Ash Reclamation at Former Landfill Site
  • 33. By reclaiming, reburning, and treating ash from landfills: $Landfill space is reclaimed and is available for more productive uses $Energy is recovered $Concrete quality fly ash is produced $Raw fuel is conserved for future generations
  • 34. Other Benefits Include:Other Benefits Include: ! Reduced Risk to Soil/Groundwater ! Allows Redevelopment of Former Landfills ! Reduced Mining and Transportation of Coal ! Reduced Limestone and Clay Quarried for Portland Cement Production ! Reduced Emissions from Cement Kilns – CO2, NOx, HCl, SOx ! Higher Quality/Strength Concrete ! Production of Product Close to Market
  • 35. P4P4 Ash Fuel ReburnAsh Fuel Reburn ResultsResults
  • 36. Reburn StatisticsReburn Statistics Ash Reburned (tons) Coal Displaced (tons) Fly ash produced (tons) P4 280,000 120,000 125,000 PIPP 10,000 2,500 4,500
  • 37. Ash Fuel BlendingAsh Fuel Blending ! Coal typically has 5% Ash Content ! High Carbon Supplemental Fuel has 80% Ash Content ! For 2% Ash Fuel Addition: Resulting Coal Ash Influence = (.98 X .05) + (.02 X .80) .049 + .016 = .065 So for .016/.065 we have 25% influence in total ash by adding 2% Ash Fuel.
  • 38. CaO vs. Ash Fuel Addition Trend 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 1/1/2000 9/7/2000 5/15/2001 1/20/2002 9/27/2002 CaO(%) 0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 CaO (%) Ash Fuel Addition (%)
  • 39. Fly Ash Characterists for P4 Ash Fuel 50.0 60.0 70.0 80.0 90.0 100.0 110.0 1/1/2000 9/7/2000 5/15/2001 1/20/2002 9/27/2002 6/4/2003 SiO2+Al2O3+Fe2O3andSAI 0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 AshFuelAddition SiO2 + Al2O3 + Fe2O3 (%) 7 Day SAI, (% of Control) Ash Fuel Addition (%)
  • 40. Fly Ash Characterists for P4 Ash Fuel 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 1/1/2000 9/7/2000 5/15/2001 1/20/2002 9/27/2002 6/4/2003 LOI,EquivalentNa2O,Density,AshFuelAddition LOI (%) Equivalent Na2O (%) Ash Fuel Addition (%) Density, g/cm3
  • 41. ConclusionsConclusions "“The Right Thing to Do.” –Environment –Cement Industry –Utility Customers –Utility Stockholders –Global Community –Sustainable Development for the Future