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Use of treated sewage in mining
industry: a case study in Brazil´s
most important iron mining region
PIMENTA, Fernando José Gonzaga¹, SILVA, Lucas de Almeida Chamhum¹, BRESSANI
RIBEIRO, Thiago¹, BIANCHETTI, Fábio José¹, CHERNICHARO, Carlos Augusto Lemos¹ and
MOTA FILHO, Cesar Rossas¹*
1. Department of Sanitary and Environmental Engineering, Federal University of Minas
Gerais, Brazil
Introduction
• Mining: 7.5% of Minas Gerais
PIB
• Environmental impacts and
water usage
• 29.17 m³/s granted for mining
– 98% surface water
abstraction
– 11% of MG total water
grants
• Focus on iron ore – 83 Mtpa
in study area
Exportaminas, 2016
Objectives
• Literature review: water use in mining
• Evaluation of the demand: quality and
quantity
• Definition of most appealing usages for
sewage
• Study case: Rio das Velhas watershed
Water in mining
• Usual sources: surface and underground water, recycling
• Reuse: ~80%
• Water use: extraction, processing and other diffuse uses (dust
control)
Vale, 2016
Ore Processing
• 5.5 m³ water/ton; 1.18 m³ “new” water, considering reuse and recirculation
Ore Processing
• Filtration and water clarification at the port
Ore Flotation
• Separation of ore and tailings
• Water consumption: 1.13
m³/ton
• High pH (CaO)
• Chemical reagents: amine and
starch
• Water quality is an important
parameter
• Efficiency measured by ore
recovery
COCHILO, 2006
Ore Flotation: Water quality
• Arizona Bureau of mines (1976) – use of secondary
effluents (copper and molybdenum): thick foam and
lower recovery
• Levay, Smart and Skinner (2001) – similar results for
effluent use in nickel flotation
• Carvalho e Peres (2004) – negative effects of excess
calcium ions
• Liu, Moran e Vink (2013) – negative effects of
suspended ions
• Anglo American (2016) – recirculated water with high
conductivity, low DO and low redox potential
– Better with tertiary treatment (active carbon)
Ore Flotation: Water quality
Parameter Raw
sewage
Secondary
effluent
Tertiary
effluent
(active
carbon)
BOD
(mg/l)
200-400 20-100 1
COD
(mg/l)
400-600 80-160 30-60
SS (mg/l) 160-350 5-20 0,5
Turbidity
(NTU)
50-150 20-60 0,5
Phosphate
(mg/l)
15-35 10-50 0,4-2,0
• Active carbon treatment: satisfactory results in two studies
• Lower cost in comparison to other tertiary treatments
• Removal of organic matter, nutrients and SS up to 99%
• Scale tests needed: variations in ore, reagents and effluent quality
Pipeline transportation
• 0.42 m³ water/ton
transported
• Viscosity and % solids
• Addition of CaO
avoids the
formations of plugs
• pH > 10.5 to avoid
internal corrosion
• MG: Samarco (1630
m³/h) and Anglo
American (1400
m³/h)
Pipeline transportation
• Operational and
environmental
security; low cost;
environmental impacts
• Criticism: basin
transposal
• Price paid for water
abstraction vs. treated
water
Adapted from Fraser (2015) and Argus (2014).
Adapted from COPASA (2016)
Dust Suppression
• Environmental control
• High demand: 4 liters
per day/m²
• Water lost through
evaporation and
infiltration
• Quality needed: low
• Critical issues:
– Hardness
– Contaminants
– Debris (nozzle opening)
• Domestic effluents are
usually not hard
Mercedes-Benz (2016)
Methodology
• Iron ore production data: Vale (2015) and Minérios and
Minerales ranking (2014)
• 1.18 m³/ton of new water: mines using pipelines
– Vale South System (MG): 0.66 m³/ton
• RDV watershed analysis: distance from STPs to mining sites
• Average flow from each STP
• Simulations: % of demand met by treated effluents
– Maximum abstraction distance of 5, 15 and 25 km
• Two scenarios:
– Only operational STPs
– Universal access to sewage collection and treatment
Rio das Velhas Watershed
• High RDV basin
– 58% of the watershed
mining areas
– All iron mines
• Estimated demand for
iron mining: 1.73 m³/s
– Vale: 89,84%
Mining demand
Mine Enterprise
Ore
processed
(Mtpa)
Estimated
demand
for new
water (l/s)
Sapecado/Galinheiro Vale 20.03 419.3
Capitão do Mato Vale 13.79 288.7
Segredo/João Pereira Vale 11.58 242.4
Capão Xavier Vale 9.66 202.2
Tamanduá Vale 9.34 195.5
Abóboras Vale 6.12 128.1
Várzea do Lopes Gerdau Açominas 4.31 90.3
Mar Azul Vale 3.84 80.4
Miguel Burnier Gerdau Açominas 2.45 51.3
Ponto Verde SAFM Mineração 1.08 22.6
Posse Crusader do Brasil 0.57 11.9
Total - 82.79 1732.8
Mapping STPs and mines
Results: Current scenario
• Demand surpasses effluent supply in all cases
• 766.8 l/s come from Arrudas ETP (780 m);
mines over 1200 m
• Estimated cost: ~US$ 850/h
Maximum abstraction
distance (km) Demand met by ETPs (l/s) % of global demand
5 10.0 0.58
15 264.8 15.28
25 1086.5 62.70
Results: All sewage collected and
treated
• Raise in %
collected and
treated: increased
reuse
• Social and
environmental
interests
Maximum abstraction
distance (km) Demand met by ETPs (l/s) % of global demand
5 100.0 5.77
15 486.5 28.07
25 1304.1 75.26
Conclusions
• Low volume of effluents
effectively collected and
treated
• Distance from populated
areas
• High RDV: High distances
and level difference
• Economic factors
– Water abstraction still very
cheap
– “Abundant” hydric supply
– Legal obligation may be needed
Usage Ore processing and
transportation
Dust control
Volume needed High: 1.13 m³/ton
(processing) and 0.42
m³/ton
(transportation)
Moderate: 4
liters/day/m²
Quality needed Moderate to high:
negative effects on
flotation
Low: worst
quality
available
Can the water
be recycled?
Partially (pipeline) No;
evaporation
and infiltration
Post treatment
needed?
Active carbon
adsorption
Probably not
Viability of
effluent use
Medium High
THANK YOU

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Use of treated sewage in mining industry: a case study in Brazil´s most important iron mining region

  • 1. Use of treated sewage in mining industry: a case study in Brazil´s most important iron mining region PIMENTA, Fernando José Gonzaga¹, SILVA, Lucas de Almeida Chamhum¹, BRESSANI RIBEIRO, Thiago¹, BIANCHETTI, Fábio José¹, CHERNICHARO, Carlos Augusto Lemos¹ and MOTA FILHO, Cesar Rossas¹* 1. Department of Sanitary and Environmental Engineering, Federal University of Minas Gerais, Brazil
  • 2. Introduction • Mining: 7.5% of Minas Gerais PIB • Environmental impacts and water usage • 29.17 m³/s granted for mining – 98% surface water abstraction – 11% of MG total water grants • Focus on iron ore – 83 Mtpa in study area Exportaminas, 2016
  • 3. Objectives • Literature review: water use in mining • Evaluation of the demand: quality and quantity • Definition of most appealing usages for sewage • Study case: Rio das Velhas watershed
  • 4. Water in mining • Usual sources: surface and underground water, recycling • Reuse: ~80% • Water use: extraction, processing and other diffuse uses (dust control) Vale, 2016
  • 5. Ore Processing • 5.5 m³ water/ton; 1.18 m³ “new” water, considering reuse and recirculation
  • 6. Ore Processing • Filtration and water clarification at the port
  • 7. Ore Flotation • Separation of ore and tailings • Water consumption: 1.13 m³/ton • High pH (CaO) • Chemical reagents: amine and starch • Water quality is an important parameter • Efficiency measured by ore recovery COCHILO, 2006
  • 8. Ore Flotation: Water quality • Arizona Bureau of mines (1976) – use of secondary effluents (copper and molybdenum): thick foam and lower recovery • Levay, Smart and Skinner (2001) – similar results for effluent use in nickel flotation • Carvalho e Peres (2004) – negative effects of excess calcium ions • Liu, Moran e Vink (2013) – negative effects of suspended ions • Anglo American (2016) – recirculated water with high conductivity, low DO and low redox potential – Better with tertiary treatment (active carbon)
  • 9. Ore Flotation: Water quality Parameter Raw sewage Secondary effluent Tertiary effluent (active carbon) BOD (mg/l) 200-400 20-100 1 COD (mg/l) 400-600 80-160 30-60 SS (mg/l) 160-350 5-20 0,5 Turbidity (NTU) 50-150 20-60 0,5 Phosphate (mg/l) 15-35 10-50 0,4-2,0 • Active carbon treatment: satisfactory results in two studies • Lower cost in comparison to other tertiary treatments • Removal of organic matter, nutrients and SS up to 99% • Scale tests needed: variations in ore, reagents and effluent quality
  • 10. Pipeline transportation • 0.42 m³ water/ton transported • Viscosity and % solids • Addition of CaO avoids the formations of plugs • pH > 10.5 to avoid internal corrosion • MG: Samarco (1630 m³/h) and Anglo American (1400 m³/h)
  • 11. Pipeline transportation • Operational and environmental security; low cost; environmental impacts • Criticism: basin transposal • Price paid for water abstraction vs. treated water Adapted from Fraser (2015) and Argus (2014). Adapted from COPASA (2016)
  • 12. Dust Suppression • Environmental control • High demand: 4 liters per day/m² • Water lost through evaporation and infiltration • Quality needed: low • Critical issues: – Hardness – Contaminants – Debris (nozzle opening) • Domestic effluents are usually not hard Mercedes-Benz (2016)
  • 13. Methodology • Iron ore production data: Vale (2015) and Minérios and Minerales ranking (2014) • 1.18 m³/ton of new water: mines using pipelines – Vale South System (MG): 0.66 m³/ton • RDV watershed analysis: distance from STPs to mining sites • Average flow from each STP • Simulations: % of demand met by treated effluents – Maximum abstraction distance of 5, 15 and 25 km • Two scenarios: – Only operational STPs – Universal access to sewage collection and treatment
  • 14. Rio das Velhas Watershed • High RDV basin – 58% of the watershed mining areas – All iron mines • Estimated demand for iron mining: 1.73 m³/s – Vale: 89,84%
  • 15. Mining demand Mine Enterprise Ore processed (Mtpa) Estimated demand for new water (l/s) Sapecado/Galinheiro Vale 20.03 419.3 Capitão do Mato Vale 13.79 288.7 Segredo/João Pereira Vale 11.58 242.4 Capão Xavier Vale 9.66 202.2 Tamanduá Vale 9.34 195.5 Abóboras Vale 6.12 128.1 Várzea do Lopes Gerdau Açominas 4.31 90.3 Mar Azul Vale 3.84 80.4 Miguel Burnier Gerdau Açominas 2.45 51.3 Ponto Verde SAFM Mineração 1.08 22.6 Posse Crusader do Brasil 0.57 11.9 Total - 82.79 1732.8
  • 17. Results: Current scenario • Demand surpasses effluent supply in all cases • 766.8 l/s come from Arrudas ETP (780 m); mines over 1200 m • Estimated cost: ~US$ 850/h Maximum abstraction distance (km) Demand met by ETPs (l/s) % of global demand 5 10.0 0.58 15 264.8 15.28 25 1086.5 62.70
  • 18. Results: All sewage collected and treated • Raise in % collected and treated: increased reuse • Social and environmental interests Maximum abstraction distance (km) Demand met by ETPs (l/s) % of global demand 5 100.0 5.77 15 486.5 28.07 25 1304.1 75.26
  • 19. Conclusions • Low volume of effluents effectively collected and treated • Distance from populated areas • High RDV: High distances and level difference • Economic factors – Water abstraction still very cheap – “Abundant” hydric supply – Legal obligation may be needed Usage Ore processing and transportation Dust control Volume needed High: 1.13 m³/ton (processing) and 0.42 m³/ton (transportation) Moderate: 4 liters/day/m² Quality needed Moderate to high: negative effects on flotation Low: worst quality available Can the water be recycled? Partially (pipeline) No; evaporation and infiltration Post treatment needed? Active carbon adsorption Probably not Viability of effluent use Medium High