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MATERIAL SAFETY DATA SHEET
MENTHOL CRYSTALS
SECTION I: Identification of the Substance and the Company
1. Identification:
Product form : Substance
Substance name : Menthol Crystals
CAS-No. : 2216-51-5
Formula : C10H20O
Synonyms : 5-Methyl-2-(propan-2-yl)cyclohexan-1-ol /
2-Isopropyl-5-methylcyclohexan-1-ol / 2-Isopropyl-5-methylcyclohexanol /
3-p-Menthanol / Hexahydrothymol / Menthomenthol / Peppermint camphor
2. Recommended Use and Restriction of Use:
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Use of the substance/mixture : Flavorings
3. Supplier Details:
Company name: BizinBiz Technologies Pvt Ltd
Company Address: A-448, Pocket 2, Sector 8, Rohini,
New Delhi, Pin Code: 110085, India
Company Web Site: www.elchemy.com
Mobile number: +919867099519
Email Id: info@elchemy.com
SECTION II: Hazards Identification
1. Classification of substance or mixture:
GHS US Classification : Skin irritation (Category 2), H315
Serious Eye Damage (Category 1) H318
Specific target organ toxicity-single exposure (Category 3)
Respiratory System H335
Acute aquatic toxicity (Category 3), H402
Chronic aquatic toxicity (Category 3), H412
2. Label Elements:
Hazard Pictogram :
Signal Word : Warning
Hazard statements : H315 - Causes skin irritation
H319 - Causes serious eye irritation
Precautionary Statements : P261 Avoid breathing dust / fumes / gas / mist /
vapors
P305+P351+P338 - IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
3. Other hazards:
No Information available
4. Unknown Acute Toxicity:
Not applicable
SECTION III: Composition/Information on Ingredients
1. Substance:
Name: MENTHOL CRYSTALS (Main constituent)
Molecular Weight: 156.27g/mol
Product identifier: CAS-No.: 2216-51-5
GHS US classification: Skin irritation (2), H315, Serious Eye Damage (1) H318,
Specific target organ toxicity-single exposure (3) Respiratory System H335, Acute
aquatic toxicity (3), H402, Chronic aquatic toxicity (3), H412,
2. Mixtures: Not applicable
SECTION IV: First Aid Measures
1. Description of necessary first aid measures:
a. First-aid measures general : Consult a physician. Show this safety data
sheet to the doctor in attendance. Move out of dangerous area.
b. First-aid measures after inhalation : Provide fresh air; keep at rest and at a
comfortable position to breathe. Consult a physician.
c. First-aid measures after skin contact : Remove contaminated clothing.
Rinse skin with cool water then wash with mild soap and warm water. Consult
a physician
d. First-aid measures after eye contact : Rinse thoroughly with plenty of water
for at least 15 minutes as a precaution. Consult a physician.
e. First-aid measures after ingestion : DO NOT induce vomiting. Never give
anything by mouth to an unconscious person. Rinse mouth with water.
Consult a physician.
2. Most important symptoms and effects, both acute and delayed:
a. Symptoms/effects after inhalation : : May cause respiratory irritation..
b. Symptoms/effects after skin contact : Causes skin irritation.
c. Symptoms/effects after eye contact : Causes serious eye damage
d. Symptoms/effects after ingestion : AFTER INGESTION OF HIGH
QUANTITIES: Gastrointestinal complaints.
e. Chronic symptoms : No effects known.
3. Indication of any immediate medical attention and special treatment needed:
Treat symptomatically
SECTION V: Fire Fighting Measures
1. Extinguishing Media:
a. Suitable extinguishing media : For small (incipient) fires, use media such
as alcohol foam, dry chemicals, carbon dioxide. For large fires, apply water
from as far as possible. Use very large quantities (flooding) of water applied
as a mist or spray; solid streams of water may be ineffective. Cool all affected
containers with flooding quantities of water
b. Unsuitable extinguishing media : Do not use a heavy water stream.
2. Special hazards arising from the substance or mixture:
No additional information available
3. Advice for firefighters:
a. Firefighting instructions : Cool containers exposed to flame with water
spray. Spray extinguishing media directly into the base of fire.
b. Protection during firefighting : Do not attempt to take action without
suitable protective equipment.
SECTION VI: Accidental Release Measures
1. Personal precautions, protective equipment and emergency procedures:
Wear a NOISH approved respirator. Avoid ingestion or contact with skin and eyes.
Follow good industrial practice as to housekeeping, personal hygiene and avoidance
of prolonged or repeated contact with the skin or eyes. Wear eye protection, gloves
and aprons. Ventilate the area well.
2. Environmental precautions:
Avoid release to the environment.
3. Methods and materials for containment and cleaning up:
Eliminate all sources of ignition Ventilate area Prevent liquid from entering sewers
Small spills can be wiped up with paper rags (place in closed metal waste container)
Large spills can be absorbed onto non-flammable absorbent. Wash the area with
soap and water.
SECTION VII: Handling and Storage
1. Precautions for safe handling:
a. Precautions for safe handling : Avoid ingestion or contact with skin and
eyes. Follow good industrial practice as to housekeeping, personal hygiene
and avoidance of prolonged or repeated contact with the skin or eyes.
b. Hygiene measures : Wash thoroughly after handling.
2. Conditions for safe storage, including any incompatibilities:
Keep away from heat. Keep away from sources of ignition. Keep the
container tightly closed. Keep in a cool, well-ventilated place. Ground all
equipment containing material. Keep the container dry. Keep in a cool place.
SECTION VIII: Exposure Controls
1. Control parameters: Components with workplace control parameters: Contains no
substance with workplace control parameters Contains no substance with workplace
control parameters
2. Appropriate engineering controls: Handle in accordance with good industrial
hygiene and safety practices
3. Individual protection measures, such as personal protective equipment:
a. Body protection: Complete suit protection against chemicals should be
selected specifically for the workplace, depending on concentration and
quantity of the hazardous substances handled. The resistance of the
protective clothing to chemicals should be ascertained with the respective
supplier
b. Eye/face protection: Wear appropriate safety glasses and face shield.
NIOSH (US) or EN 166 (EU) tested and approved.
c. Skin protection: Wear chemically resistant Nitrile rubber gloves. Use proper
glove removal techniques (without touching gloves outer surface) to avoid
skin contact with this product. Dispose of contaminated gloves after use.
Wash and dry hands
d. Respiratory protection: Where risk assessment shows air-purifying
respirators are appropriate, use a full-face respirator with multi=purpose
combination (U) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a
full face supplied air respirator. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (U) or
CEN (EU).
SECTION IX: Physical and Chemical Properties
General Information:
1. Appearance: Colorless to white crystals
2. Color: Colorless crystals.
3. Odor: Peppermint odor.
4. Odor threshold: No data available
5. pH: No data available
6. Melting point/freezing point: 34 – 36 °C
7. Boiling point/boiling range (ºC): 216 °C
8. Flash point: 93.4 °C
9. Evaporation rate: No data available
10. Flammability: No data available
11. Lower flammability/Explosive limit: Not determined
12. Upper flammability/Explosive limit: Not determined
13. Vapour pressure: No data available
14. Vapour Density: Not determined
15. Density: 0.89 g/cm³
16. Molecular Mass: 156.27 g/mol
17. Solubility in other solvents: Water: Slightly soluble in water
18. Auto-ignition temperature: No data available
19. Decomposition temperature: Not determined
20. Viscosity, dynamic: Not determined
21. Viscosity, kinematic: Not determined
22. Explosive properties: Not determined
23. Oxidizing properties: : No data available
SECTION X: Stability and Reactivity
1. Reactivity: No additional information available
2. Chemical stability: Stable under normal conditions.
3. Possibility of hazardous reactions: No additional information available.
4. Conditions to Avoid Conditions to Avoid: Direct sunlight. Air contact. Moisture.
5. Incompatible materials: Strong oxidizing agents
6. Hazardous decomposition products: No additional information available.
SECTION XI: Toxicological Information
1. Acute toxicity : Not classified
2. LD50 oral rat: 800 mg/kg
3. LD50 dermal rat: 3,400 mg/kg
4. LC50 Inhalation – Rat: No data available
5. Skin corrosion/irritation : Not classified
6. Serious eye damage/irritation : Not classified
7. Respiratory or skin sensitisation : Not classified
8. Germ cell mutagenicity : Not classified
9. Carcinogenicity : Not classified
10. Reproductive toxicity : Not classified
11. STOT-single exposure : Not classified
12. STOT-repeated exposure : Not classified
13. Aspiration hazard : Not classified
14. Potential adverse human health effects and symptoms : To the best of our
knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated
SECTION XII: Ecological Information
1. Toxicity: LC50 - Fish [1], Pimephales promelas (fathead minnow) – 18.9 mg/l – 96
hr
2. Persistence and degradability: No data available
3. Bioaccumulative potential: No data available
4. Mobility in soil: No data available
5. Other adverse effects: Harmful to aquatic life
SECTION XIII: Disposal Considerations
1. Disposal methods:
a. Regional legislation (waste) : Disposal must be done according to official
regulations.
b. Sewage disposal recommendations : Disposal must be done according to
official regulations.
c. Product/Packaging disposal recommendations : Do not discharge into
drains or the environment. Remove waste in accordance with local and/or
national regulations. Hazardous waste shall not be mixed together with other
waste. Different types of hazardous waste shall not be mixed together if this
may entail a risk of pollution or create problems for the further management of
the waste. Hazardous waste shall be managed responsibly. All entities that
store, transport or handle hazardous waste shall take the necessary
measures to prevent risks of pollution or damage to people or animals.
Recycle by distillation. Remove to an authorized waste incinerator for
solvents with energy recovery. Obtain the consent of pollution control
authorities before discharging to wastewater treatment plants.
SECTION XIV: Transport Information
In accordance with DOT / TDG / IMDG / IATA
1. UN Number:
Not regulated for transport
2. UN proper shipping name:
Proper Shipping Name (DOT) : Not applicable
Proper Shipping Name (TDG) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
3. Transport hazard class(es):
DOT Transport hazard class(es) (DOT) : Not applicable
TDG Transport hazard class(es) (TDG) : Not applicable
IMDG Transport hazard class(es) (IMDG) : Not applicable
IATA Transport hazard class(es) (IATA) : Not applicable
4. Packing Group:
Packing group (DOT) : Not applicable
Packing group (TDG) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
5. Environmental Hazards:
Other information : No supplementary information available.
6. Special precautions for user:
DOT: No data available
TDG: No data available
IMDG: No data available
IATA: No data available
7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code:
NA
SECTION XV: Regulatory Information
1. US Federal regulations:
a. Not subject to reporting requirements of the United States SARA Section 313
b. No chemicals in this material are subject to the reporting requirements of
SARA Title III, Section 302
2. International regulations:
a. Germany: Water hazard class (WGK) 1, slightly hazardous to water
(Classification according to VwVwS, Annex 3; WGK No 8252)
b. Denmark: Class for fire hazard : Class III-1 Store unit : 50 liter Classification
remarks : Flammable according to the Danish Ministry of Justice; Emergency
management guidelines for the storage of flammable liquids must be followed
c. EU-Regulations: No REACH Annex XVII restrictions, MENTHOL CRYSTALS
is not on the REACH Candidate List MENTHOL CRYSTALS is not on the
REACH Annex XIV List
3. US State regulations:
a. This product does not contain any chemicals known to State of California to
cause cancer, birth defects, or any other reproductive harm.
b. No components are subject to the Massachusetts Right to Know Act
SECTION XVI: Other Information
Full text of R-, H- and EUH-phrases:
Eye Irrit. 2: Serious eye damage/eye irritation, Category 2
Skin Irrit. 2: Skin corrosion/irritation, Category 2
H315: Causes skin irritation
H319: Causes serious eye irritation
R37/38: Irritating to respiratory system and skin
R41: Risk of serious damage to eyes
Xi: Irritant

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Menthol Crystal MSDS | Elchemy

  • 1. MATERIAL SAFETY DATA SHEET MENTHOL CRYSTALS SECTION I: Identification of the Substance and the Company 1. Identification: Product form : Substance Substance name : Menthol Crystals CAS-No. : 2216-51-5 Formula : C10H20O Synonyms : 5-Methyl-2-(propan-2-yl)cyclohexan-1-ol / 2-Isopropyl-5-methylcyclohexan-1-ol / 2-Isopropyl-5-methylcyclohexanol / 3-p-Menthanol / Hexahydrothymol / Menthomenthol / Peppermint camphor 2. Recommended Use and Restriction of Use: Use of the substance/mixture : Laboratory chemicals, Manufacture of substances Use of the substance/mixture : Flavorings 3. Supplier Details: Company name: BizinBiz Technologies Pvt Ltd Company Address: A-448, Pocket 2, Sector 8, Rohini, New Delhi, Pin Code: 110085, India Company Web Site: www.elchemy.com Mobile number: +919867099519 Email Id: info@elchemy.com SECTION II: Hazards Identification 1. Classification of substance or mixture: GHS US Classification : Skin irritation (Category 2), H315 Serious Eye Damage (Category 1) H318 Specific target organ toxicity-single exposure (Category 3) Respiratory System H335 Acute aquatic toxicity (Category 3), H402 Chronic aquatic toxicity (Category 3), H412
  • 2. 2. Label Elements: Hazard Pictogram : Signal Word : Warning Hazard statements : H315 - Causes skin irritation H319 - Causes serious eye irritation Precautionary Statements : P261 Avoid breathing dust / fumes / gas / mist / vapors P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 3. Other hazards: No Information available 4. Unknown Acute Toxicity: Not applicable SECTION III: Composition/Information on Ingredients 1. Substance: Name: MENTHOL CRYSTALS (Main constituent) Molecular Weight: 156.27g/mol Product identifier: CAS-No.: 2216-51-5 GHS US classification: Skin irritation (2), H315, Serious Eye Damage (1) H318, Specific target organ toxicity-single exposure (3) Respiratory System H335, Acute aquatic toxicity (3), H402, Chronic aquatic toxicity (3), H412, 2. Mixtures: Not applicable SECTION IV: First Aid Measures 1. Description of necessary first aid measures: a. First-aid measures general : Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. b. First-aid measures after inhalation : Provide fresh air; keep at rest and at a
  • 3. comfortable position to breathe. Consult a physician. c. First-aid measures after skin contact : Remove contaminated clothing. Rinse skin with cool water then wash with mild soap and warm water. Consult a physician d. First-aid measures after eye contact : Rinse thoroughly with plenty of water for at least 15 minutes as a precaution. Consult a physician. e. First-aid measures after ingestion : DO NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 2. Most important symptoms and effects, both acute and delayed: a. Symptoms/effects after inhalation : : May cause respiratory irritation.. b. Symptoms/effects after skin contact : Causes skin irritation. c. Symptoms/effects after eye contact : Causes serious eye damage d. Symptoms/effects after ingestion : AFTER INGESTION OF HIGH QUANTITIES: Gastrointestinal complaints. e. Chronic symptoms : No effects known. 3. Indication of any immediate medical attention and special treatment needed: Treat symptomatically SECTION V: Fire Fighting Measures 1. Extinguishing Media: a. Suitable extinguishing media : For small (incipient) fires, use media such as alcohol foam, dry chemicals, carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water b. Unsuitable extinguishing media : Do not use a heavy water stream. 2. Special hazards arising from the substance or mixture: No additional information available 3. Advice for firefighters: a. Firefighting instructions : Cool containers exposed to flame with water spray. Spray extinguishing media directly into the base of fire.
  • 4. b. Protection during firefighting : Do not attempt to take action without suitable protective equipment. SECTION VI: Accidental Release Measures 1. Personal precautions, protective equipment and emergency procedures: Wear a NOISH approved respirator. Avoid ingestion or contact with skin and eyes. Follow good industrial practice as to housekeeping, personal hygiene and avoidance of prolonged or repeated contact with the skin or eyes. Wear eye protection, gloves and aprons. Ventilate the area well. 2. Environmental precautions: Avoid release to the environment. 3. Methods and materials for containment and cleaning up: Eliminate all sources of ignition Ventilate area Prevent liquid from entering sewers Small spills can be wiped up with paper rags (place in closed metal waste container) Large spills can be absorbed onto non-flammable absorbent. Wash the area with soap and water. SECTION VII: Handling and Storage 1. Precautions for safe handling: a. Precautions for safe handling : Avoid ingestion or contact with skin and eyes. Follow good industrial practice as to housekeeping, personal hygiene and avoidance of prolonged or repeated contact with the skin or eyes. b. Hygiene measures : Wash thoroughly after handling. 2. Conditions for safe storage, including any incompatibilities: Keep away from heat. Keep away from sources of ignition. Keep the container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing material. Keep the container dry. Keep in a cool place. SECTION VIII: Exposure Controls 1. Control parameters: Components with workplace control parameters: Contains no substance with workplace control parameters Contains no substance with workplace
  • 5. control parameters 2. Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practices 3. Individual protection measures, such as personal protective equipment: a. Body protection: Complete suit protection against chemicals should be selected specifically for the workplace, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier b. Eye/face protection: Wear appropriate safety glasses and face shield. NIOSH (US) or EN 166 (EU) tested and approved. c. Skin protection: Wear chemically resistant Nitrile rubber gloves. Use proper glove removal techniques (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use. Wash and dry hands d. Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate, use a full-face respirator with multi=purpose combination (U) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (U) or CEN (EU). SECTION IX: Physical and Chemical Properties General Information: 1. Appearance: Colorless to white crystals 2. Color: Colorless crystals. 3. Odor: Peppermint odor. 4. Odor threshold: No data available 5. pH: No data available 6. Melting point/freezing point: 34 – 36 °C 7. Boiling point/boiling range (ºC): 216 °C 8. Flash point: 93.4 °C 9. Evaporation rate: No data available
  • 6. 10. Flammability: No data available 11. Lower flammability/Explosive limit: Not determined 12. Upper flammability/Explosive limit: Not determined 13. Vapour pressure: No data available 14. Vapour Density: Not determined 15. Density: 0.89 g/cm³ 16. Molecular Mass: 156.27 g/mol 17. Solubility in other solvents: Water: Slightly soluble in water 18. Auto-ignition temperature: No data available 19. Decomposition temperature: Not determined 20. Viscosity, dynamic: Not determined 21. Viscosity, kinematic: Not determined 22. Explosive properties: Not determined 23. Oxidizing properties: : No data available SECTION X: Stability and Reactivity 1. Reactivity: No additional information available 2. Chemical stability: Stable under normal conditions. 3. Possibility of hazardous reactions: No additional information available. 4. Conditions to Avoid Conditions to Avoid: Direct sunlight. Air contact. Moisture. 5. Incompatible materials: Strong oxidizing agents 6. Hazardous decomposition products: No additional information available. SECTION XI: Toxicological Information 1. Acute toxicity : Not classified 2. LD50 oral rat: 800 mg/kg
  • 7. 3. LD50 dermal rat: 3,400 mg/kg 4. LC50 Inhalation – Rat: No data available 5. Skin corrosion/irritation : Not classified 6. Serious eye damage/irritation : Not classified 7. Respiratory or skin sensitisation : Not classified 8. Germ cell mutagenicity : Not classified 9. Carcinogenicity : Not classified 10. Reproductive toxicity : Not classified 11. STOT-single exposure : Not classified 12. STOT-repeated exposure : Not classified 13. Aspiration hazard : Not classified 14. Potential adverse human health effects and symptoms : To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated SECTION XII: Ecological Information 1. Toxicity: LC50 - Fish [1], Pimephales promelas (fathead minnow) – 18.9 mg/l – 96 hr 2. Persistence and degradability: No data available 3. Bioaccumulative potential: No data available 4. Mobility in soil: No data available 5. Other adverse effects: Harmful to aquatic life SECTION XIII: Disposal Considerations 1. Disposal methods: a. Regional legislation (waste) : Disposal must be done according to official regulations. b. Sewage disposal recommendations : Disposal must be done according to official regulations.
  • 8. c. Product/Packaging disposal recommendations : Do not discharge into drains or the environment. Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Recycle by distillation. Remove to an authorized waste incinerator for solvents with energy recovery. Obtain the consent of pollution control authorities before discharging to wastewater treatment plants. SECTION XIV: Transport Information In accordance with DOT / TDG / IMDG / IATA 1. UN Number: Not regulated for transport 2. UN proper shipping name: Proper Shipping Name (DOT) : Not applicable Proper Shipping Name (TDG) : Not applicable Proper Shipping Name (IMDG) : Not applicable Proper Shipping Name (IATA) : Not applicable 3. Transport hazard class(es): DOT Transport hazard class(es) (DOT) : Not applicable TDG Transport hazard class(es) (TDG) : Not applicable IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : Not applicable 4. Packing Group: Packing group (DOT) : Not applicable Packing group (TDG) : Not applicable Packing group (IMDG) : Not applicable Packing group (IATA) : Not applicable 5. Environmental Hazards: Other information : No supplementary information available.
  • 9. 6. Special precautions for user: DOT: No data available TDG: No data available IMDG: No data available IATA: No data available 7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: NA SECTION XV: Regulatory Information 1. US Federal regulations: a. Not subject to reporting requirements of the United States SARA Section 313 b. No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302 2. International regulations: a. Germany: Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 8252) b. Denmark: Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed c. EU-Regulations: No REACH Annex XVII restrictions, MENTHOL CRYSTALS is not on the REACH Candidate List MENTHOL CRYSTALS is not on the REACH Annex XIV List 3. US State regulations: a. This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. b. No components are subject to the Massachusetts Right to Know Act SECTION XVI: Other Information Full text of R-, H- and EUH-phrases: Eye Irrit. 2: Serious eye damage/eye irritation, Category 2 Skin Irrit. 2: Skin corrosion/irritation, Category 2 H315: Causes skin irritation H319: Causes serious eye irritation R37/38: Irritating to respiratory system and skin R41: Risk of serious damage to eyes Xi: Irritant