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Product Name: Acetic Acid 80%
1-866-282-3384
General use:
SECTION 2 - HAZARDS IDENTIFICATION
Silver Fern Chemical, Inc.
Manufacturer/Distributor
2226 Queen Anne Avenue North
Seattle, WA 98109 USA
Industrial applications
Synonym(s): Ethanoic acid, aqueous solution
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.1 Product identifier
1.3 Details of the supplier and of the safety data sheet
1.4 Emergency telephone number: INFO-TRAC +1-800-535-5053; Outside USA & Canada +1-352-323-3500
REACH Registration Number: No data available at this time
Uses advised against: None known
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
_________________________________________________________________________________________________________________________
Effective Date: Page 1 of 8
Safety Data Sheet
Acetic Acid 80%
Suite C
Supercedes: 29 October 2013
SILVER FERN CHEMICAL, INC.
Safety Data Sheet
10 February 2017
Website - www.silverfernchemical.com; email address - info@silverfernchemical.com
2.1 Classification of substance or mixture
Product definition: Mixture
Flammable liquid - Category 3 [H226]
Skin corrosion - Category 1A [H314]
Classification in accordance with 29 CFR 1910 (OSHA HCS) and Regulation EC No. 1272/2008
Acetic Acid 80%
2.2 Label Elements
Hazard Symbol(s):
Signal Word:
Hazard Statement(s):
[Prevention]
Precautionary Statements:
Danger
H226 - Flammable liquid and vapor
[Response]
P301 + P330 + P331 + P310 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a
POISON CENTER or doctor.
P303 + P361 + P350 - IF ON SKIN: Remove immediately all contaminated clothing. Rinse skin with water or
P264 - Wash hands and other skin areas exposed to material thoroughly after handling.
P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON Center or doctor.
P304 + P340 + P310 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or doctor.
shower.
P280 - Wear protective gloves, protective clothing, eye protection and face protection.
P321 - Specific treatment: Contact a POISON CENTER or doctor. Refer to Section 4 of this SDS.
P260 - Do not breathe vapor, fumes or mist.
P363 - Wash contaminated clothing before reuse.
P210 - Keep away from heat, open flames and hot surfaces. No smoking.
P233 - Keep container tightly closed.
P240 - Ground and bond container and receiving equipment.
P241 + P242 - Use explosion-proof electrical, ventilating, lighting, and mixing equipment; use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P370 + P378 - In case of fire: Use water spray or fog, foam, dry chemical or carbon dioxide for extinction.
H314 - Causes severe skin burns and eye damage
GHS02 GHS05
SECTION 4 - FIRST AID MEASURES
_________________________________________________________________________________________________________________________
Page 2 of 8
3.2 Mixtures
Not applicable
SECTION 5 - FIRE FIGHTING MEASURES
Effective Date:
Safety Data Sheet
Supercedes: 29 October 2013
10 February 2017
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
% by Weight CAS Number EC NumberIngredient GHS Classification
Glacial Acetic Acid 64-19-7 200-580-7 607-002-00-6 H226, H314
Annex Number
There are no ingredients present in this product which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
50 - 80
Ingestion: Rinse mouth with water if the victim is conscious. Remove dentures, if any. Give 2 glasses of water or milk to drink if the victim is
conscious, alert and able to swallow. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
4.2 Most important symptoms and effects, both acute and delayed
Eyes:
Ingestion:
Causes severe skin irritation and burns. May be harmful if absorbed through the skin. Contact with skin may cause blackening andSkin:
Potential health symptoms and effects
Chronic exposure may cause erosion of dental enamel, bronchitis, eye irritation, darkening of the skin and chronic inflammation of the
respiratory tract. May cause occupational asthma. Effects may be delayed. Skin sensitization to acetic acid is rare, but has occurred. Persons
Chronic:
Causes burns serious eye damage. Symptoms may include redness, swelling, pain, tearing, burns, blurred vision, corneal clouding,
Harmful if swallowed. Causes burns to the lips, mouth, throat and gastrointestinal tract. May cause severe and permanent damage to
permanent eye damage and possible blindness. Mist or vapor can cause severe eye irritation and eye damage.
Harmful if inhaled. Causes chemical burns to the respiratory tract with mucousal irritation, cough and shortness of breath. ExposureInhalation:
may lead to bronchitis, pharyngitis, edemas in the respiratory tract and dental erosion. Effects may be delayed. May be absorbed though the lungs.
unconscious or convulsing person. Do not leave the victim unattended. To prevent aspiration of swallowed product, lay victim on one side with
Eyes:
if present and easy to do, after the first 2 minutes and continue rinsing. Seek immediate medical attention, preferably from an ophthalmologist.
Immediately flush eyes with large amounts of water for 15 minutes, occasionally lifting the upper and lower lids. Remove contact lenses,
Skin: Flush skin with large amounts of water while removing contaminated clothing, and continue rinsing for at least 15 minutes. Wash
difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial respiration by trained personnel. Loosen tight fitting clothing
Inhalation:
4.1 Description of first aid measures
If product vapor or mist causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is
contaminated clothing thoroughly before reuse. Discard contaminated shoes. Seek immediate medical attention.
such as a collar, tie, belt or waistband. Seek immediate medical attention.
4.3 Indication of any immediate medical attention and special treatment needed
Advice to Doctor and Hospital Personnel
Treat symptomatically and supportively.
the head lower than the waist. Obtain medical attention immediately.
absorbed from the gastrointestinal tract. Pulmonary failure is possible after aspiration of vomit.
the digestive tract. Causes severe pain, nausea, vomiting, diarrhea and shock. May cause damage to the kidneys and kidney failure. Rapidly
Suitable methods of extinction: Use extinguishing media such as water fog or spray, dry chemical, carbon dioxide or foam.
5.1 Extinguishable media
Unsuitable methods of extinction: None known
5.2 Special hazards arising from the substance or mixture
5.3 Advice for firefighters
Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent
Vapor may form an explosive mixture with air at elevated temperatures, especially in confined spaces.Explosion hazards:
[Disposal] P501 - Dispose of contents and containers in accordance with national and local regulations.
[Storage] P405 + P403 + P233 + P235 - Store locked up in a well-ventilated place. Keep container tightly closed. Keep cool.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
None identified
with pre-existing skin disorders or impaired respiratory or pulmonary function may be at increased risk to the effects of this substance.
hyperkeratosis of the skin and hands.
Flammable liquid and vapor. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Vapors are heavier than air
and can travel along the ground to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Containers may explode if exposed to fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Symptoms of overexposure to these gases may not be apparent. Seek medical advice.
Acetic Acid 80%
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures: Technical measures and appropriate working operations should be given priority over the use of personal protective
8.2 Exposure controls
8.1 Control parameters
Page 3 of 8
SECTION 7 - HANDLING AND STORAGE
equipment. Use adequate ventilation. Local exhaust is preferable.
Respiratory protection:
respirators are appropriate use a full-faced respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a
backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Follow OSHA respirator
regulations found in 29 CFR 1910.134 or European Standard EN 149.
Always use an approved respirator when vapor/aerosols are generated. Where risk assessment shows air-purifying
Individual protection measures: Wear protective clothing to prevent repeated or prolonged contact with product. Protective clothing needs to be
selected specifically for the workplace, depending on concentrations and quantities of hazardous substances handled. The chemical resistance
of the protective equipment should be enquired at the representative supplier.
clothing. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking, smoking or using the lavatory.
Facilities storing or using this material should be equipped with an eyewash station and safety shower. Change contaminatedHygiene measures:
Wear chemical splash goggles or safety glasses with unperforated side shields and a face shield during use.Eye/face protection:
Hand Protection: Wear Chloroprene gloves or those recommended by glove supplier for protection against materials in Section 3. Gloves should
be impermeable to chemicals and oil. Breakthrough time of selected gloves must be greater than the intended use period.
Skin protection: Wear protective clothing. Wear protective boots if the situation requires.
Effective Date:
Safety Data Sheet
Supercedes: 29 October 2013
10 February 2017
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.2 Environmental precautions
Avoid dispersal of spilled material or runoff and prevent contact with soil and entry into drains, sewers or waterways.
6.1 Personal precautions, protective equipment and emergency procedures
Clean up spills immediately. Wear appropriate protective clothing designated in Section 8. Approach spill from upwind. Remove all sources of
ignition. Ventilate the area. Spill creates a slip hazard.
6.4 Reference to other sections
See Section 13 for additional waste treatment information.
6.3 Methods and materials for containment and cleaning up
place into an approved container for proper disposal. Do not use a metal container for disposal. Observe possible material restrictions (Sections
7.2 and 10.5). Dispose of via a licensed waste disposal contractor. Contaminated absorbent may pose the same hazard as the spilled product.
Cover spill with a large quantity of inert absorbent. Do not use combustible material such as sawdust. Collect product using non-sparking tools and
Cover drains and contain spill. Do not flush spill to the drain. Carefully neutralize the spill with soda ash (sodium carbonate) or calcium carbonate.
7.1 Precautions for safe handling
Wear all appropriate personal protective equipment specified in Section 8. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. If normal use of material presents a respiratory hazard, use only adequate ventilation or wear an appropriate respirator. Wash contaminated
Apart from the uses mentioned in Section 1.2, no other specific uses are stipulated.
7.3 Specific end uses
Advice on protection against fire and explosion
7.2 Conditions for safe storage, including any incompatibilities
clothing before reuse. Destroy contaminated shoes.
and bond containers when transferring material. Transfer only to approved containers having correct labeling. DO NOT store in metal containers.
Store in original container in a dry, cool, well ventilated area away from incompatible materials (refer to Section 10.5) and food and drink. Ground
sources. Use appropriate containment to avoid environmental contamination. Ventilate enclosed areas. Do not take internally. Keep locked up
and out or reach of children.
Keep containers tightly closed when not in use. Protect container from physical damage. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not pressurize, cut, weld, braze, solder, drill, grind or expose empty containers to heat or ignition
Keep away from heat and incompatible materials.
Environmental exposure controls: Do not empty into drains.
OSHA - PELCAS Number Ingredient ACGIH NIOSH
Occupational Exposure Limits
10 ppm, 25 mg/m3 TWA64-19-7 Acetic Acid 10 ppm; 25 mg/m3 TWA 10 ppm; 25 mg/m3 TWA; 15 ppm
37 mg/m3 STEL; 50 ppm IDHL15 ppm, 37 mg/m3 STEL
pressure buildup and possible autoignition or explosion when exposed to extreme heat. Water contaminated by this material must be contained
from being discharged to any waterway, sewer or drain to prevent environmental contamination.
_________________________________________________________________________________________________________________________
Acetic Acid 80%
SECTION 10 - STABILITY AND REACTIVITY
Stable under recommended (ambient) storage conditions.
10.1 Reactivity
Stable when used under recommended handling and storage conditions.
10.2 Chemical stability
Heat, flames, sources of ignition and contact with incompatible materials.
10.4 Conditions to avoid
10.3 Possibility of hazardous reactions
Page 4 of 8
9.2 Other data
May be corrosive to metals
Partition Coefficient: n-octanol/water log Pow = -0.17 @ 25 °C
Oxidizing Properties Not applicable
Explosive Properties Not applicable
>80%Volatiles by Weight @ 21 ºC
Upper Explosive Limit (UEL) 19.9% (v)
Vapor Pressure 15.7 mm Hg @ 25 °C
Vapor Density 2.1 (Air = 1)
Specific Gravity
Viscosity
1.05 @ 20 °C
1.22 cps @ 20 °C
Solubility in Water Miscible
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance Clear, colorless liquid
Odor Pungent, vinegar-like
Odor Threshold 0.23 - 100.1 ppm
Molecular Weight 60.05 g/mol (Acetic Acid)
C2H4O2
pH 2.7 (1 M aqueous solution)
Freezing/Melting Point, Range
Initial Boiling Point 116 - 118 °C (241 - 244 °F)
Evaporation Rate 0.97 (n-BuOAc = 1)
Flammability (solid, gas) Not applicable
Flash Point
Autoignition Temperature
Decomposition Temperature No data available
Lower Explosive Limit (LEL) 4% (v)
71 - 91 °C (160 - 196 °F)
17 °C (62.6 °F)
516 °C (960.8 °F)
Generates hydrogen gas in contact with metals.
_________________________________________________________________________________________________________________________
11.1 Information on toxicological effects
10.6 Hazardous decomposition products
Thermal decomposition products include oxides of carbon, hydrogen gas, irritating and toxic fumes.
SECTION 11 - TOXICOLOGICAL INFORMATION
10.5 Incompatible materials
Strong oxidizing agents, strong alkalis, strong bases, metals, amines, halogens, alcohols, peroxides, peroxi compounds, metal salts, alcohols,
Effective Date:
Safety Data Sheet
Supercedes: 29 October 2013
10 February 2017
Chemical Formula
Acute Oral Toxicity
LD50, rat: 3,310 mg/kg
Acute inhalation toxicity
Acute dermal toxicity
LC50, rat: 11.40 mg/m3, 4 h
LC50, rabbit: 1,112 mg/kg
Hazardous polymerization will not occur.
potassium permanganate, acetaldehyde, carbonates, nonmetallic halides. Incompatible with some plastics, rubbers and coatings.
maintain, clean fit and use. Consult a competent industrial hygiene resource to determine hazard potential and/or the PPE manufacturers to ensure
adequate protection.
PPE must not be considered a long-term solution to exposure control. PPE usage must be accompanied by employer programs to properly select,
Acetic Acid 80%
SECTION 13 - DISPOSAL CONSIDERATIONS
The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some
13.1 Waste treatment methods
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a
Methods of disposal:
licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff
Page 5 of 8
Do not allow material to run into surface waters, wastewater or soil.
12.6 Other adverse effects
Additional ecological information
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
No data available
Mutagenicity
No data available
Specific organ toxicity - single exposure
No data available
Specific organ toxicity - repeated exposure
11.2 Further information
Aspiration hazard
No data available
SECTION 12 - ECOLOGICAL INFORMATION
Handle in accordance with good industrial hygiene and safety practice.
this product, nor is there any available data that indicates it causes adverse developmental or fertility effects.
This product contains no substances present at levels greater than or equal to the 0.1% threshold (de minimis) that are identified as a probable,
possible, potential or confirmed carcinogens by ACGIH, IARC, NTP or OSHA. No data is available regarding the mutagenicity or teratogenicity of
_________________________________________________________________________________________________________________________
and contact with soil, waterways, drains and sewers.
No listingRCRA P-Series:
No listingRCRA U-Series:
SECTION 14 - TRANSPORT INFORMATION
Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations
TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials
and methods of shipping.
Effective Date:
Safety Data Sheet
Supercedes: 29 October 2013
10 February 2017
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulation potential
Product will not bioaccumulate.
Readily biodegradable
Large discharges of Glacial Acetic Acid to the environment may decrease the pH of aquatic systems to a value <2, which may be fatal to aquatic life
and soil micro-organisms.
Acute and prolonged toxicity to fish: LC50 - Lepomis macrochirus (Bluegill/Sunfish), 96 h: 75 mg/l
LC50 - Pimephales promelas (Fathead minnow), static, 96 h: 88 mg/l
Acute toxicity to aquatic invertebrates: EC50 - Daphnia magna (Water flea), 24 - 48 h: 32 - 47 mg/l
Acute and prolonged toxicity to Aquatic plants: IC50 - Scenedesmus quadricauda (Green algae), 16 h: 4,000 mg/l
12.5 Results of PBT and vPvB assessment
Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
12.4 Mobility in soil
No data available
No data available
Sensitization
Cause severe skin irritation and burns
Eye irritation/corrosion
Causes burns and permanent eye damage. Risk of blindness.
Skin irritation/corrosion
Genotoxicity in vitro
No data available
Acetic Acid 80%
SECTION 15 - REGULATORY INFORMATION
U. S. Federal Regulations
OSHA Hazard Communication Standard:
15.1 Safety, health and environmental regulations/legislation specific for substance or mixture
This substance is classified as hazardous in accordance with OSHA 29 CFR 1910-1200.
OSHA Process Safety Management Standard: This product is not regulated under OSHA PSM Standard 29 CFR 1910.119.
EPA Risk Management Planning Standard: This product is not regulated under EPA RMP Standard (RMP) 40 CFR Part 68.
Toxic Substance Control Act (TSCA) Inventory: This substance is listed on the TSCA Inventory. It is not subject to TSCA 12(b) Export
EPA Federal Insecticide, Fungicide and Rodenticide Act: This product is not a registered Pesticide under the FIFRA, 40 CFR Part 150.
Notification.
Drug Enforcement Administration (DEA) List s1 & 2, Exempt Chemical Mixtures (21 CFR 1310.12(c)) and Code Number
Not listed
Department of Homeland Security (DHS) Chemical Facility Anti-Terrorism Standards (CFATS) Chemicals
Not listed
Drug Enforcement Administration (DEA) List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.4(f)(2) and Chemical Code Number
Not listed
Page 6 of 8
Comprehensive Response Compensation and Liability Act (CERCLA): This product contains the following CERCLA reportable substance(s):
SARA 302/304 Emergency Planning & Notification:
established by of these sections of Title III of SARA.
None of the components of the product exceed the threshold (de minimis) reporting levels
This product does not contain any chemicals listed as Hazardous Air Pollutants (HAPs) designated in CAA Section 112 (b).
Clean Air Act (CAA)
This product does not contain any Class 1 Ozone depletors.
This product does not contain any Class 2 Ozone depletors.
SARA 313 Information: None of the components of the product exceed the threshold (de minimis) reporting requirements of Section 13 of the
Emergency Planning and Community Right-to Know Act of 1986.
Superfund Amendments and Reauthorization Act (SARA)
SARA Section 311/312 Hazard Categories: Fire Hazard, Acute Health Hazard, Chronic Health Hazard
SARA 302/304 Extremely Hazardous Substance:
established by of these sections of Title III of SARA.
None of the components of the product exceed the threshold (de minimis) reporting levels
_________________________________________________________________________________________________________________________
U.S. State Regulations
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986
This product contains no chemical(s) known to the State of California to cause cancer, birth defects or other reproductive harm.
Clean Water Act (CWA)
Acetic Acid (CAS #64-19-7) is listed as a Hazardous Substance under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
Effective Date:
Safety Data Sheet
Supercedes: 29 October 2013
10 February 2017
RID/ADR (Rail Transportation)
Proper Shipping Name:
Hazard Class: 8
Packing Group: II
UN2790UN/NA:
ICAO/IATA (Air Transportation)
Proper Shipping Name:
Hazard Class: 8
Packing Group:
UN2790
II
UN/NA:
Quantity Limitations: 49 CFR 173.27 and 175.75 - Cargo Aircraft Only: 30 l; Passenger Aircraft: 1 l
Acetic acid solution
Acetic acid solution
IMO/IMDG (Water Transportation)
EMS Number: F-A, S-B
Proper Shipping Name:
Hazard Class: 8
Packing Group:
UN2790
II
UN/NA:
Marine Pollutant: No
Acetic acid solution
Proper Shipping Name: Acetic acid solution
Hazard Class: 8
Packing Group: II
UN2790UN/NA:
US DOT (Domestic Ground Transportation)
NAERG: Guide #132
Packaging Authorization: Non-Bulk: 49 CFR 173.202; Bulk: 173.242
Packaging Exceptions: 49 CFR 173.154
Acetic Acid (CAS #64-19-7), RQ - 2,267.96 kg (5,000 lbs)
Acetic Acid 80%
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out.
Page 7 of 8
Europe: Inventory of New and Existing Chemicals (EINECS)
United States: Toxic Substance Control Act (TSCA)
Australia: Australian Inventory of Chemical Substances (AICS)
China: Inventory of Existing Chemical Substances in China (IECSC)
Canada: Domestic Substance List (DSL)
Japan: Inventory of Existing and New Chemical Substances (ENCS)
Korea: Existing Chemicals List (ECL)
Philippines: Philippines Inventory of Chemicals and Chemical Substances (PICCS)
Global Chemical Inventory Lists
New Zealand: New Zealand Inventory of Chemicals (NZIoC)
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
*Yes - All components of this product are in compliance with the inventory requirements administered by the governing country.
No - One or more components of this product are not on the inventory or are exempt from listing.
Canada: Non-Domestic Substance List (NDSL) No
Country Inventory Name Inventory Listing*
SECTION 16 - OTHER INFORMATION
Hazardous Material Information System (HMIS)
Health
Flammability
Physical Hazard
Personal Protection
0
2
C
3
Health
Flammability
Instability
Special
3 0
National Fire Protection Association (NFPA)
2
HMIS Hazard Rating Legend
0 = Minimal 1 = Slight 2 = Moderate 3 = Serious
4 = Severe * = Chronic Health Hazard
NFPA Hazard Rating Legend
0 = Insignificant 1 = Slight 2 = Moderate
3 = High 4 = Extreme
Abbreviation Key
ACGIH American Conference of Governmental Industrial Hygienists
ADR Accord Dangereux Routier (European regulations concerning the international transport of dangerous goods by road)
CAS Chemical Abstract Services
CFR Code of Federal Regulations
DOT Department of Transportation
EMS Guide Emergency Response Procedures for Ships Carrying Dangerous Goods
EPA Environmental Protection Agency
ERG Emergency Response Guide Book
FDA Food and DrugAdministration
GHS Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
HCS Hazard Communication Standard
IARC International Agency for Research on Cancer
IATA International Air Transport Association half maximal
ICAO International Civil Aviation Organization
IDLH Immediately Dangerous to Life and Health
IMDG International Maritime Dangerous Goods
IMO International Maritime Organization
_________________________________________________________________________________________________________________________
mppcf Millions of Particles Per Cubic Foot
NA North America
NAERG North American Emergency Response Guide Book
NIOSH National Institute for Occupational Safety
Effective Date:
Safety Data Sheet
Supercedes: 29 October 2013
10 February 2017
European Economic Community
None of the substances in this product are listed on the NPRI.Canadian National Pollutant Release Inventory (NPRI):
1WGK, Germany (Water danger/protection):
Other U.S. State Inventories
Glacial Acetic Acid (CAS #64-19-7) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/Air
Pollutants lists: CA, DE, FL, ID, MA, MN, NC, NJ, NY, PA, RI, WA, WI.
Canada
WHMIS Hazard Symbol and Classification
E - Corrosive
B3 - Flammable liquid with flash points greater than
38 °C (100 °F) but inferior to 93 °C (199.4 °F)
Acetic Acid 80%
Page 8 of 8
DISCLAIMER OF RESPONSIBILITY
The information on this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,
expressed or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test
data on the substance itself. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be
beyond our knowledge. For this and other reasons, we do not assume damage or expense arising out of or in any way responsibility and expressly
disclaim liability for loss, connected with handling, storage, use, or disposal of this product. If the product is used as a component in another product,
this SDS information may not be applicable.
Revision Date: 10 February 2017
<end of document>
TWA Time-weighted Average
UN United Nations
VOC Volatile Organic Compounds
vPvB tingVery Persistent and Very Bioaccumulating
WHMIS Workplace Hazardous Materials Information System
_________________________________________________________________________________________________________________________
Effective Date:
Safety Data Sheet
Supercedes: 29 October 2013
10 February 2017
TCC/Tag Tagliabue Closed Cup
TLV Threshold Limit Value
TSCA Toxic Substance Control Act
RQ Reportable Quantity
OSHA Occupational Safety and Health Administration
PBT Persistent, Bioaccumulating and Toxic
NTP National Toxicology Program
PEL Permissible exposure limit
PMCC Pensky-Martens Closed Cup
ppm Parts Per Million
RCRA Resource Conservation and Recovery Act
RID Dangerous Goods by Rail
Acetic Acid 80%

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Material Safety Data Sheet ACETIC ACID - Acetic Acid 80%

  • 1. Product Name: Acetic Acid 80% 1-866-282-3384 General use: SECTION 2 - HAZARDS IDENTIFICATION Silver Fern Chemical, Inc. Manufacturer/Distributor 2226 Queen Anne Avenue North Seattle, WA 98109 USA Industrial applications Synonym(s): Ethanoic acid, aqueous solution 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.1 Product identifier 1.3 Details of the supplier and of the safety data sheet 1.4 Emergency telephone number: INFO-TRAC +1-800-535-5053; Outside USA & Canada +1-352-323-3500 REACH Registration Number: No data available at this time Uses advised against: None known SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION _________________________________________________________________________________________________________________________ Effective Date: Page 1 of 8 Safety Data Sheet Acetic Acid 80% Suite C Supercedes: 29 October 2013 SILVER FERN CHEMICAL, INC. Safety Data Sheet 10 February 2017 Website - www.silverfernchemical.com; email address - info@silverfernchemical.com 2.1 Classification of substance or mixture Product definition: Mixture Flammable liquid - Category 3 [H226] Skin corrosion - Category 1A [H314] Classification in accordance with 29 CFR 1910 (OSHA HCS) and Regulation EC No. 1272/2008 Acetic Acid 80% 2.2 Label Elements Hazard Symbol(s): Signal Word: Hazard Statement(s): [Prevention] Precautionary Statements: Danger H226 - Flammable liquid and vapor [Response] P301 + P330 + P331 + P310 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor. P303 + P361 + P350 - IF ON SKIN: Remove immediately all contaminated clothing. Rinse skin with water or P264 - Wash hands and other skin areas exposed to material thoroughly after handling. P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON Center or doctor. P304 + P340 + P310 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor. shower. P280 - Wear protective gloves, protective clothing, eye protection and face protection. P321 - Specific treatment: Contact a POISON CENTER or doctor. Refer to Section 4 of this SDS. P260 - Do not breathe vapor, fumes or mist. P363 - Wash contaminated clothing before reuse. P210 - Keep away from heat, open flames and hot surfaces. No smoking. P233 - Keep container tightly closed. P240 - Ground and bond container and receiving equipment. P241 + P242 - Use explosion-proof electrical, ventilating, lighting, and mixing equipment; use only non-sparking tools. P243 - Take precautionary measures against static discharge. P370 + P378 - In case of fire: Use water spray or fog, foam, dry chemical or carbon dioxide for extinction. H314 - Causes severe skin burns and eye damage GHS02 GHS05
  • 2. SECTION 4 - FIRST AID MEASURES _________________________________________________________________________________________________________________________ Page 2 of 8 3.2 Mixtures Not applicable SECTION 5 - FIRE FIGHTING MEASURES Effective Date: Safety Data Sheet Supercedes: 29 October 2013 10 February 2017 SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances % by Weight CAS Number EC NumberIngredient GHS Classification Glacial Acetic Acid 64-19-7 200-580-7 607-002-00-6 H226, H314 Annex Number There are no ingredients present in this product which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 50 - 80 Ingestion: Rinse mouth with water if the victim is conscious. Remove dentures, if any. Give 2 glasses of water or milk to drink if the victim is conscious, alert and able to swallow. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an 4.2 Most important symptoms and effects, both acute and delayed Eyes: Ingestion: Causes severe skin irritation and burns. May be harmful if absorbed through the skin. Contact with skin may cause blackening andSkin: Potential health symptoms and effects Chronic exposure may cause erosion of dental enamel, bronchitis, eye irritation, darkening of the skin and chronic inflammation of the respiratory tract. May cause occupational asthma. Effects may be delayed. Skin sensitization to acetic acid is rare, but has occurred. Persons Chronic: Causes burns serious eye damage. Symptoms may include redness, swelling, pain, tearing, burns, blurred vision, corneal clouding, Harmful if swallowed. Causes burns to the lips, mouth, throat and gastrointestinal tract. May cause severe and permanent damage to permanent eye damage and possible blindness. Mist or vapor can cause severe eye irritation and eye damage. Harmful if inhaled. Causes chemical burns to the respiratory tract with mucousal irritation, cough and shortness of breath. ExposureInhalation: may lead to bronchitis, pharyngitis, edemas in the respiratory tract and dental erosion. Effects may be delayed. May be absorbed though the lungs. unconscious or convulsing person. Do not leave the victim unattended. To prevent aspiration of swallowed product, lay victim on one side with Eyes: if present and easy to do, after the first 2 minutes and continue rinsing. Seek immediate medical attention, preferably from an ophthalmologist. Immediately flush eyes with large amounts of water for 15 minutes, occasionally lifting the upper and lower lids. Remove contact lenses, Skin: Flush skin with large amounts of water while removing contaminated clothing, and continue rinsing for at least 15 minutes. Wash difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial respiration by trained personnel. Loosen tight fitting clothing Inhalation: 4.1 Description of first aid measures If product vapor or mist causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is contaminated clothing thoroughly before reuse. Discard contaminated shoes. Seek immediate medical attention. such as a collar, tie, belt or waistband. Seek immediate medical attention. 4.3 Indication of any immediate medical attention and special treatment needed Advice to Doctor and Hospital Personnel Treat symptomatically and supportively. the head lower than the waist. Obtain medical attention immediately. absorbed from the gastrointestinal tract. Pulmonary failure is possible after aspiration of vomit. the digestive tract. Causes severe pain, nausea, vomiting, diarrhea and shock. May cause damage to the kidneys and kidney failure. Rapidly Suitable methods of extinction: Use extinguishing media such as water fog or spray, dry chemical, carbon dioxide or foam. 5.1 Extinguishable media Unsuitable methods of extinction: None known 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent Vapor may form an explosive mixture with air at elevated temperatures, especially in confined spaces.Explosion hazards: [Disposal] P501 - Dispose of contents and containers in accordance with national and local regulations. [Storage] P405 + P403 + P233 + P235 - Store locked up in a well-ventilated place. Keep container tightly closed. Keep cool. 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS None identified with pre-existing skin disorders or impaired respiratory or pulmonary function may be at increased risk to the effects of this substance. hyperkeratosis of the skin and hands. Flammable liquid and vapor. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Vapors are heavier than air and can travel along the ground to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Containers may explode if exposed to fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Symptoms of overexposure to these gases may not be apparent. Seek medical advice. Acetic Acid 80%
  • 3. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Technical measures and appropriate working operations should be given priority over the use of personal protective 8.2 Exposure controls 8.1 Control parameters Page 3 of 8 SECTION 7 - HANDLING AND STORAGE equipment. Use adequate ventilation. Local exhaust is preferable. Respiratory protection: respirators are appropriate use a full-faced respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Follow OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use an approved respirator when vapor/aerosols are generated. Where risk assessment shows air-purifying Individual protection measures: Wear protective clothing to prevent repeated or prolonged contact with product. Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the representative supplier. clothing. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking, smoking or using the lavatory. Facilities storing or using this material should be equipped with an eyewash station and safety shower. Change contaminatedHygiene measures: Wear chemical splash goggles or safety glasses with unperforated side shields and a face shield during use.Eye/face protection: Hand Protection: Wear Chloroprene gloves or those recommended by glove supplier for protection against materials in Section 3. Gloves should be impermeable to chemicals and oil. Breakthrough time of selected gloves must be greater than the intended use period. Skin protection: Wear protective clothing. Wear protective boots if the situation requires. Effective Date: Safety Data Sheet Supercedes: 29 October 2013 10 February 2017 SECTION 6 - ACCIDENTAL RELEASE MEASURES 6.2 Environmental precautions Avoid dispersal of spilled material or runoff and prevent contact with soil and entry into drains, sewers or waterways. 6.1 Personal precautions, protective equipment and emergency procedures Clean up spills immediately. Wear appropriate protective clothing designated in Section 8. Approach spill from upwind. Remove all sources of ignition. Ventilate the area. Spill creates a slip hazard. 6.4 Reference to other sections See Section 13 for additional waste treatment information. 6.3 Methods and materials for containment and cleaning up place into an approved container for proper disposal. Do not use a metal container for disposal. Observe possible material restrictions (Sections 7.2 and 10.5). Dispose of via a licensed waste disposal contractor. Contaminated absorbent may pose the same hazard as the spilled product. Cover spill with a large quantity of inert absorbent. Do not use combustible material such as sawdust. Collect product using non-sparking tools and Cover drains and contain spill. Do not flush spill to the drain. Carefully neutralize the spill with soda ash (sodium carbonate) or calcium carbonate. 7.1 Precautions for safe handling Wear all appropriate personal protective equipment specified in Section 8. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. If normal use of material presents a respiratory hazard, use only adequate ventilation or wear an appropriate respirator. Wash contaminated Apart from the uses mentioned in Section 1.2, no other specific uses are stipulated. 7.3 Specific end uses Advice on protection against fire and explosion 7.2 Conditions for safe storage, including any incompatibilities clothing before reuse. Destroy contaminated shoes. and bond containers when transferring material. Transfer only to approved containers having correct labeling. DO NOT store in metal containers. Store in original container in a dry, cool, well ventilated area away from incompatible materials (refer to Section 10.5) and food and drink. Ground sources. Use appropriate containment to avoid environmental contamination. Ventilate enclosed areas. Do not take internally. Keep locked up and out or reach of children. Keep containers tightly closed when not in use. Protect container from physical damage. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not pressurize, cut, weld, braze, solder, drill, grind or expose empty containers to heat or ignition Keep away from heat and incompatible materials. Environmental exposure controls: Do not empty into drains. OSHA - PELCAS Number Ingredient ACGIH NIOSH Occupational Exposure Limits 10 ppm, 25 mg/m3 TWA64-19-7 Acetic Acid 10 ppm; 25 mg/m3 TWA 10 ppm; 25 mg/m3 TWA; 15 ppm 37 mg/m3 STEL; 50 ppm IDHL15 ppm, 37 mg/m3 STEL pressure buildup and possible autoignition or explosion when exposed to extreme heat. Water contaminated by this material must be contained from being discharged to any waterway, sewer or drain to prevent environmental contamination. _________________________________________________________________________________________________________________________ Acetic Acid 80%
  • 4. SECTION 10 - STABILITY AND REACTIVITY Stable under recommended (ambient) storage conditions. 10.1 Reactivity Stable when used under recommended handling and storage conditions. 10.2 Chemical stability Heat, flames, sources of ignition and contact with incompatible materials. 10.4 Conditions to avoid 10.3 Possibility of hazardous reactions Page 4 of 8 9.2 Other data May be corrosive to metals Partition Coefficient: n-octanol/water log Pow = -0.17 @ 25 °C Oxidizing Properties Not applicable Explosive Properties Not applicable >80%Volatiles by Weight @ 21 ºC Upper Explosive Limit (UEL) 19.9% (v) Vapor Pressure 15.7 mm Hg @ 25 °C Vapor Density 2.1 (Air = 1) Specific Gravity Viscosity 1.05 @ 20 °C 1.22 cps @ 20 °C Solubility in Water Miscible SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Clear, colorless liquid Odor Pungent, vinegar-like Odor Threshold 0.23 - 100.1 ppm Molecular Weight 60.05 g/mol (Acetic Acid) C2H4O2 pH 2.7 (1 M aqueous solution) Freezing/Melting Point, Range Initial Boiling Point 116 - 118 °C (241 - 244 °F) Evaporation Rate 0.97 (n-BuOAc = 1) Flammability (solid, gas) Not applicable Flash Point Autoignition Temperature Decomposition Temperature No data available Lower Explosive Limit (LEL) 4% (v) 71 - 91 °C (160 - 196 °F) 17 °C (62.6 °F) 516 °C (960.8 °F) Generates hydrogen gas in contact with metals. _________________________________________________________________________________________________________________________ 11.1 Information on toxicological effects 10.6 Hazardous decomposition products Thermal decomposition products include oxides of carbon, hydrogen gas, irritating and toxic fumes. SECTION 11 - TOXICOLOGICAL INFORMATION 10.5 Incompatible materials Strong oxidizing agents, strong alkalis, strong bases, metals, amines, halogens, alcohols, peroxides, peroxi compounds, metal salts, alcohols, Effective Date: Safety Data Sheet Supercedes: 29 October 2013 10 February 2017 Chemical Formula Acute Oral Toxicity LD50, rat: 3,310 mg/kg Acute inhalation toxicity Acute dermal toxicity LC50, rat: 11.40 mg/m3, 4 h LC50, rabbit: 1,112 mg/kg Hazardous polymerization will not occur. potassium permanganate, acetaldehyde, carbonates, nonmetallic halides. Incompatible with some plastics, rubbers and coatings. maintain, clean fit and use. Consult a competent industrial hygiene resource to determine hazard potential and/or the PPE manufacturers to ensure adequate protection. PPE must not be considered a long-term solution to exposure control. PPE usage must be accompanied by employer programs to properly select, Acetic Acid 80%
  • 5. SECTION 13 - DISPOSAL CONSIDERATIONS The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some 13.1 Waste treatment methods product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a Methods of disposal: licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff Page 5 of 8 Do not allow material to run into surface waters, wastewater or soil. 12.6 Other adverse effects Additional ecological information An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. No data available Mutagenicity No data available Specific organ toxicity - single exposure No data available Specific organ toxicity - repeated exposure 11.2 Further information Aspiration hazard No data available SECTION 12 - ECOLOGICAL INFORMATION Handle in accordance with good industrial hygiene and safety practice. this product, nor is there any available data that indicates it causes adverse developmental or fertility effects. This product contains no substances present at levels greater than or equal to the 0.1% threshold (de minimis) that are identified as a probable, possible, potential or confirmed carcinogens by ACGIH, IARC, NTP or OSHA. No data is available regarding the mutagenicity or teratogenicity of _________________________________________________________________________________________________________________________ and contact with soil, waterways, drains and sewers. No listingRCRA P-Series: No listingRCRA U-Series: SECTION 14 - TRANSPORT INFORMATION Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping. Effective Date: Safety Data Sheet Supercedes: 29 October 2013 10 February 2017 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulation potential Product will not bioaccumulate. Readily biodegradable Large discharges of Glacial Acetic Acid to the environment may decrease the pH of aquatic systems to a value <2, which may be fatal to aquatic life and soil micro-organisms. Acute and prolonged toxicity to fish: LC50 - Lepomis macrochirus (Bluegill/Sunfish), 96 h: 75 mg/l LC50 - Pimephales promelas (Fathead minnow), static, 96 h: 88 mg/l Acute toxicity to aquatic invertebrates: EC50 - Daphnia magna (Water flea), 24 - 48 h: 32 - 47 mg/l Acute and prolonged toxicity to Aquatic plants: IC50 - Scenedesmus quadricauda (Green algae), 16 h: 4,000 mg/l 12.5 Results of PBT and vPvB assessment Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII. 12.4 Mobility in soil No data available No data available Sensitization Cause severe skin irritation and burns Eye irritation/corrosion Causes burns and permanent eye damage. Risk of blindness. Skin irritation/corrosion Genotoxicity in vitro No data available Acetic Acid 80%
  • 6. SECTION 15 - REGULATORY INFORMATION U. S. Federal Regulations OSHA Hazard Communication Standard: 15.1 Safety, health and environmental regulations/legislation specific for substance or mixture This substance is classified as hazardous in accordance with OSHA 29 CFR 1910-1200. OSHA Process Safety Management Standard: This product is not regulated under OSHA PSM Standard 29 CFR 1910.119. EPA Risk Management Planning Standard: This product is not regulated under EPA RMP Standard (RMP) 40 CFR Part 68. Toxic Substance Control Act (TSCA) Inventory: This substance is listed on the TSCA Inventory. It is not subject to TSCA 12(b) Export EPA Federal Insecticide, Fungicide and Rodenticide Act: This product is not a registered Pesticide under the FIFRA, 40 CFR Part 150. Notification. Drug Enforcement Administration (DEA) List s1 & 2, Exempt Chemical Mixtures (21 CFR 1310.12(c)) and Code Number Not listed Department of Homeland Security (DHS) Chemical Facility Anti-Terrorism Standards (CFATS) Chemicals Not listed Drug Enforcement Administration (DEA) List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.4(f)(2) and Chemical Code Number Not listed Page 6 of 8 Comprehensive Response Compensation and Liability Act (CERCLA): This product contains the following CERCLA reportable substance(s): SARA 302/304 Emergency Planning & Notification: established by of these sections of Title III of SARA. None of the components of the product exceed the threshold (de minimis) reporting levels This product does not contain any chemicals listed as Hazardous Air Pollutants (HAPs) designated in CAA Section 112 (b). Clean Air Act (CAA) This product does not contain any Class 1 Ozone depletors. This product does not contain any Class 2 Ozone depletors. SARA 313 Information: None of the components of the product exceed the threshold (de minimis) reporting requirements of Section 13 of the Emergency Planning and Community Right-to Know Act of 1986. Superfund Amendments and Reauthorization Act (SARA) SARA Section 311/312 Hazard Categories: Fire Hazard, Acute Health Hazard, Chronic Health Hazard SARA 302/304 Extremely Hazardous Substance: established by of these sections of Title III of SARA. None of the components of the product exceed the threshold (de minimis) reporting levels _________________________________________________________________________________________________________________________ U.S. State Regulations California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986 This product contains no chemical(s) known to the State of California to cause cancer, birth defects or other reproductive harm. Clean Water Act (CWA) Acetic Acid (CAS #64-19-7) is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. Effective Date: Safety Data Sheet Supercedes: 29 October 2013 10 February 2017 RID/ADR (Rail Transportation) Proper Shipping Name: Hazard Class: 8 Packing Group: II UN2790UN/NA: ICAO/IATA (Air Transportation) Proper Shipping Name: Hazard Class: 8 Packing Group: UN2790 II UN/NA: Quantity Limitations: 49 CFR 173.27 and 175.75 - Cargo Aircraft Only: 30 l; Passenger Aircraft: 1 l Acetic acid solution Acetic acid solution IMO/IMDG (Water Transportation) EMS Number: F-A, S-B Proper Shipping Name: Hazard Class: 8 Packing Group: UN2790 II UN/NA: Marine Pollutant: No Acetic acid solution Proper Shipping Name: Acetic acid solution Hazard Class: 8 Packing Group: II UN2790UN/NA: US DOT (Domestic Ground Transportation) NAERG: Guide #132 Packaging Authorization: Non-Bulk: 49 CFR 173.202; Bulk: 173.242 Packaging Exceptions: 49 CFR 173.154 Acetic Acid (CAS #64-19-7), RQ - 2,267.96 kg (5,000 lbs) Acetic Acid 80%
  • 7. 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out. Page 7 of 8 Europe: Inventory of New and Existing Chemicals (EINECS) United States: Toxic Substance Control Act (TSCA) Australia: Australian Inventory of Chemical Substances (AICS) China: Inventory of Existing Chemical Substances in China (IECSC) Canada: Domestic Substance List (DSL) Japan: Inventory of Existing and New Chemical Substances (ENCS) Korea: Existing Chemicals List (ECL) Philippines: Philippines Inventory of Chemicals and Chemical Substances (PICCS) Global Chemical Inventory Lists New Zealand: New Zealand Inventory of Chemicals (NZIoC) Yes Yes Yes Yes Yes Yes Yes Yes Yes *Yes - All components of this product are in compliance with the inventory requirements administered by the governing country. No - One or more components of this product are not on the inventory or are exempt from listing. Canada: Non-Domestic Substance List (NDSL) No Country Inventory Name Inventory Listing* SECTION 16 - OTHER INFORMATION Hazardous Material Information System (HMIS) Health Flammability Physical Hazard Personal Protection 0 2 C 3 Health Flammability Instability Special 3 0 National Fire Protection Association (NFPA) 2 HMIS Hazard Rating Legend 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic Health Hazard NFPA Hazard Rating Legend 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme Abbreviation Key ACGIH American Conference of Governmental Industrial Hygienists ADR Accord Dangereux Routier (European regulations concerning the international transport of dangerous goods by road) CAS Chemical Abstract Services CFR Code of Federal Regulations DOT Department of Transportation EMS Guide Emergency Response Procedures for Ships Carrying Dangerous Goods EPA Environmental Protection Agency ERG Emergency Response Guide Book FDA Food and DrugAdministration GHS Globally Harmonized System of Classification and Labelling of Chemicals (GHS) HCS Hazard Communication Standard IARC International Agency for Research on Cancer IATA International Air Transport Association half maximal ICAO International Civil Aviation Organization IDLH Immediately Dangerous to Life and Health IMDG International Maritime Dangerous Goods IMO International Maritime Organization _________________________________________________________________________________________________________________________ mppcf Millions of Particles Per Cubic Foot NA North America NAERG North American Emergency Response Guide Book NIOSH National Institute for Occupational Safety Effective Date: Safety Data Sheet Supercedes: 29 October 2013 10 February 2017 European Economic Community None of the substances in this product are listed on the NPRI.Canadian National Pollutant Release Inventory (NPRI): 1WGK, Germany (Water danger/protection): Other U.S. State Inventories Glacial Acetic Acid (CAS #64-19-7) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/Air Pollutants lists: CA, DE, FL, ID, MA, MN, NC, NJ, NY, PA, RI, WA, WI. Canada WHMIS Hazard Symbol and Classification E - Corrosive B3 - Flammable liquid with flash points greater than 38 °C (100 °F) but inferior to 93 °C (199.4 °F) Acetic Acid 80%
  • 8. Page 8 of 8 DISCLAIMER OF RESPONSIBILITY The information on this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, expressed or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume damage or expense arising out of or in any way responsibility and expressly disclaim liability for loss, connected with handling, storage, use, or disposal of this product. If the product is used as a component in another product, this SDS information may not be applicable. Revision Date: 10 February 2017 <end of document> TWA Time-weighted Average UN United Nations VOC Volatile Organic Compounds vPvB tingVery Persistent and Very Bioaccumulating WHMIS Workplace Hazardous Materials Information System _________________________________________________________________________________________________________________________ Effective Date: Safety Data Sheet Supercedes: 29 October 2013 10 February 2017 TCC/Tag Tagliabue Closed Cup TLV Threshold Limit Value TSCA Toxic Substance Control Act RQ Reportable Quantity OSHA Occupational Safety and Health Administration PBT Persistent, Bioaccumulating and Toxic NTP National Toxicology Program PEL Permissible exposure limit PMCC Pensky-Martens Closed Cup ppm Parts Per Million RCRA Resource Conservation and Recovery Act RID Dangerous Goods by Rail Acetic Acid 80%