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PLASTICS AS
PACKAGING MATERIALS
INTRODUCTION
• Plastics - organic polymers
• Polycondensation and polyaddition
• Plastics packages - wraps, pouches, cartons,
tubes, bottles, jars and boxes
• Thermosetting and thermoplastic resins
POLYOLEFINS AND POLYESTERS
POLYOLEFINS
• Polyethylene and Polypropylene
• PE – LDPE, HDPE, LLDPE
POLYESTERS
• PET
• PEN
• Polycarbonate
LDPE
• Polymerization of ethylene gas under
high pressure and temperature
• Density = 910 to 940 kg/m3
• Soft, slightly translucent flexible material with
waxy feel
• Resistance to chemicals
• Good barrier properties to water vapor but less
to oxygen
• High permeability to volatile oils
• Good heat sealing properties - Laminating layer
HDPE
• Linear thermoplastic
• Density = 941 to 965 kg/m3
• Stiffer and harder
• Tensile and burst strengths – higher
• Impact and tear strengths – lower
• Better resistance to oil and grease
• Excellent moisture protection
• Decreased gas permeability
• Heat sealing is difficult
LLDPE
• Stronger and tougher than LDPE
• Absence of long chain branches
• Density = 900 to 935 kg/m3
• Stiffer
• High tensile strength, puncture resistant
• Combined features of LDPE and HDPE
• Improved chemical resistance
• Improved performance at low and high
temperatures
• Better heat sealing properties
• Greater resistance to environmental stress
cracking
POLYPROPYLENE
• Linear polymer containing little or no
unsaturation
• Lower density (900 kg/m3)
• Higher softening point (140 to 150°C)
• Low water vapour transmission
• Medium gas permeability
• Good resistance to greases and chemicals
• Good abrasion resistance
• Good gloss and high clarity
POLYSTYRENE
• Addition polymerization of styrene
• Low barrier properties
• Can be blown, extruded, thermo formed and
injection moulded
• Used for packing vegetables and fresh meat
on trays, yoghurt in cups, over wrapping of
fruits and vegetables.
PVC
• There are two types – rigid and
plasticized.
• Good moisture, gas barrier properties and
resistance to fats.
• Packing butter or margarine, and for making
transparent bottles for mineral water, edible
oils, fruit juices, carbonated beverages and
beer
• The plasticised form is used for packing meat,
fruits and vegetables and for shrink wrapping
POLYVINYLIDENE CHLORIDE (PVdC)
• Lowest water vapour, gas permeability
amongst all
• Resistance to fats and chemicals
• Used as a coating material on other plastics
• Used for packing dense materials like cheese,
poultry, etc.
ETHYLENEVINYL ALCOHOL (EVOH)
• EVOH - copolymer of ethylene and vinyl
alcohol
• Excellent barrier to oil, fat and oxygen
• Replaces glass and metal containers
• Manufacture of bulk bags used for aseptic
packaging, retort pouches and containers
PET
• Linear, transparent thermoplastic polymer
• PET bottles
• Great tensile strength
• Excellent chemical resistance
• Light weight, elasticity and stability over a wide range
of temperatures (-60 to 220°C)
• Low permeability to moisture and gases
• Poor sealing property- hence it has to be laminated
with PE.
• PET containers are used widely for packing mineral
water, carbonated and non-carbonated beverages,
syrups, edible oils and liquors.
ADVANTAGES OF PLASTICS
• Barrier to water vapor and gases
• Light weight
• Good strength
• Design flexibility
• Resistance to breakage
• Machinability
• Glossy and transparent
• Coloring is possible
• High tensile strength
• High tear strength
• High printability
• Low cost
LAMINATING AND COATING
PROCESS
LAMINATING PROCESS
• Combination of two or more webs by bonding
them together
• Adhesives used – EVA
• Wet bonding – solvent or aqueous based
adhesives
• Dry bonding – Adhesive dried on one of the
layers – heat applied while binding
COATING
• Extrusion coating - melted thermoplastic
applied onto a substrate such as paper
• LDPE coated milk cartons, juice cartons,
drinking cups
• Advantages over Lamination – handling of thin
films of PE is difficult while laminating
plastic as a packaging material.pptx

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plastic as a packaging material.pptx

  • 2. INTRODUCTION • Plastics - organic polymers • Polycondensation and polyaddition • Plastics packages - wraps, pouches, cartons, tubes, bottles, jars and boxes • Thermosetting and thermoplastic resins
  • 3. POLYOLEFINS AND POLYESTERS POLYOLEFINS • Polyethylene and Polypropylene • PE – LDPE, HDPE, LLDPE POLYESTERS • PET • PEN • Polycarbonate
  • 4. LDPE • Polymerization of ethylene gas under high pressure and temperature • Density = 910 to 940 kg/m3 • Soft, slightly translucent flexible material with waxy feel • Resistance to chemicals • Good barrier properties to water vapor but less to oxygen • High permeability to volatile oils • Good heat sealing properties - Laminating layer
  • 5. HDPE • Linear thermoplastic • Density = 941 to 965 kg/m3 • Stiffer and harder • Tensile and burst strengths – higher • Impact and tear strengths – lower • Better resistance to oil and grease • Excellent moisture protection • Decreased gas permeability • Heat sealing is difficult
  • 6. LLDPE • Stronger and tougher than LDPE • Absence of long chain branches • Density = 900 to 935 kg/m3 • Stiffer • High tensile strength, puncture resistant • Combined features of LDPE and HDPE • Improved chemical resistance • Improved performance at low and high temperatures • Better heat sealing properties • Greater resistance to environmental stress cracking
  • 7. POLYPROPYLENE • Linear polymer containing little or no unsaturation • Lower density (900 kg/m3) • Higher softening point (140 to 150°C) • Low water vapour transmission • Medium gas permeability • Good resistance to greases and chemicals • Good abrasion resistance • Good gloss and high clarity
  • 8. POLYSTYRENE • Addition polymerization of styrene • Low barrier properties • Can be blown, extruded, thermo formed and injection moulded • Used for packing vegetables and fresh meat on trays, yoghurt in cups, over wrapping of fruits and vegetables.
  • 9. PVC • There are two types – rigid and plasticized. • Good moisture, gas barrier properties and resistance to fats. • Packing butter or margarine, and for making transparent bottles for mineral water, edible oils, fruit juices, carbonated beverages and beer • The plasticised form is used for packing meat, fruits and vegetables and for shrink wrapping
  • 10. POLYVINYLIDENE CHLORIDE (PVdC) • Lowest water vapour, gas permeability amongst all • Resistance to fats and chemicals • Used as a coating material on other plastics • Used for packing dense materials like cheese, poultry, etc.
  • 11. ETHYLENEVINYL ALCOHOL (EVOH) • EVOH - copolymer of ethylene and vinyl alcohol • Excellent barrier to oil, fat and oxygen • Replaces glass and metal containers • Manufacture of bulk bags used for aseptic packaging, retort pouches and containers
  • 12. PET • Linear, transparent thermoplastic polymer • PET bottles • Great tensile strength • Excellent chemical resistance • Light weight, elasticity and stability over a wide range of temperatures (-60 to 220°C) • Low permeability to moisture and gases • Poor sealing property- hence it has to be laminated with PE. • PET containers are used widely for packing mineral water, carbonated and non-carbonated beverages, syrups, edible oils and liquors.
  • 13. ADVANTAGES OF PLASTICS • Barrier to water vapor and gases • Light weight • Good strength • Design flexibility • Resistance to breakage • Machinability • Glossy and transparent • Coloring is possible • High tensile strength • High tear strength • High printability • Low cost
  • 14.
  • 15.
  • 17. LAMINATING PROCESS • Combination of two or more webs by bonding them together • Adhesives used – EVA • Wet bonding – solvent or aqueous based adhesives • Dry bonding – Adhesive dried on one of the layers – heat applied while binding
  • 18.
  • 19. COATING • Extrusion coating - melted thermoplastic applied onto a substrate such as paper • LDPE coated milk cartons, juice cartons, drinking cups • Advantages over Lamination – handling of thin films of PE is difficult while laminating