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Gold Recovery During Cyanide Detox
In Heap Leach Pads
Pintail Systems Inc.
Presentation Authors
Caren Caldwell
Leslie Thompson
 Cyanide is used in heap
leach pads to complex
gold and silver in the
mining industry
 Cyanide detoxification is
required for mine closure.
 PSI’s bio-detoxification
process, which uses native
bacteria, has proven to be
more efficient than
conventional chemical
processes
Bacteria culture used in cyanide detox
Pintail Systems, Inc. was founded in 1987 by
Leslie Thompson
Primary focus was on cyanide detoxification in
gold and silver heap leach pads using native
bacteria cultures.
In 1991,The Hecla
Mining Company
contracted with PSI to
develop a treatment
process for the Yellow
Pine Mine using
native bacteria
cultures.
 Located Near Yellow
Pine, Idaho
 Alpine Climate
 1.2 Million Ton Spent
Ore Heap
 Environmentally
sensitive area
 Detox Goals
 To degrade WAD cyanide
to 0.2 mg/L or less in heap
leachate solutions in one
operating season
 Prior to contracting with
PSI, Hecla investigated
chemical methods and was
quoted 2 to 4 operating
seasons.
Heap Bio-Detox
WAD Cyanide in Heap Effluent Solutions
0
10
20
30
40
50
1
29
25
50
59
71
85
94
107
114
121
128
136
146
155
Time, Days
WADCyanide
 Detox goal of 0.2 mg/l
WAD cyanide was achieved
in one operating season,
(155) days
 During the detox process,
there was a significant
increase in gold production
 Increased gold production
was unexpected and more
than paid for the detox
process
Increased gold recovery paid for mine
operations through the end of detox
Mine closure was signed off by the Idaho
Department of Environmental Quality
The Hecla Mining Company won the 1992
Pacific Northwest Pollution Control
Association’s Idaho Award for the
Innovative use of Bacteria in Improving
Water Quality
 1.3 million ton heap
 Located near Parker,
AZ
 Detox goal was 0.2
mg/L total cyanide in
heap leachate solution
 Total cyanide closure
goal of <0.2 mg/L TCN
met in 111 days
 Significant Gold
Recovery Improvement.
>3000 oz.
 Mine closure signed off
by the State of Arizona
DEQ
 Located near Victor,
Colorado
 5 million ton cyanide-
leached spent ore heap
 Heap was water-rinsed
for 4 years prior to bio-
detox
 Average detox solution
temperature = 35 deg F
 Altitude 10,000 ft above
sea level.
 Detox Goals
 Detox WAD cyanide
to 0.2 mg/L in heap
leachate solution
 Decrease the bond
requirement for
closure by the state of
Colorado
l
Cripple Creek WAD Cyanide
0
0.5
1
1.5
2
2.5
3
1 24 47 70 93 116 139 162 185 208 231 254 277 300 323 346
time, days
leachateWADCN,mg/L
Cripple Creek Gold Recovery
0.00
1000.00
2000.00
3000.00
4000.00
5000.00
6000.00
1 26 51 76 101 126 151 176 201 226 251 276 301 326 351
time, days
cumulativeouncesgold
Increased gold recovery during
cyanide detox
Met the goal of 0.2 mg/L WAD
cyanide in heap leachate solution
in 346 days
 CC&V water rinse and peroxide treatment (30 pore
volumes) did not detoxify cyanide to regulatory limits
 Pintail bio-detox achieved cyanide limits with
application of less than 3 pore volumes of treatment
solution
 Bond requirement for mine closure was reduced
 Increased gold recovery paid for the detox process.
The detox process actually became a profit center for
the mine.
Yellow Pine
1.2 million tons
Cyprus
Copperstone
1.3 million tons
Cripple Creek
Victor
5 million tons
Cyanide
Concentration at
start of detox
50 mg/L WAD CN
in heap leachate
solution
20 mg/L TCN in heap
leachate solution
Just over 3 mg/L
WAD CN in heap
leachate solution
Cyanide
concentration at
end of detox
< 0.2 mg/L WAD
CN heap leachate
solution
< 0.2 mg/L TCN in
heap leachate solution
< 0.2 mg/L WAD CN
in heap leachate
solution
Gold Recovery > 2700 >3000 oz >6700 oz
Treatment Days 155 days 111 days 350 days
Regulatory
Goals Met
Yes Yes Yes
1
Technical advances have produced more gold over the
last 160 years than the previous 6000.
2
Majority of gold produced in the U.S. is from the Heap
Leaching Process
3
Heap Leaching leaves 25 – 40% of the original gold in
the ore at mine closure
Pintail Bio-Processes are the solution to economically
recover heap gold4
 Cyanide typically recovers 55% to 75% of the
gold in a heap leach pad. 25% to 45% residual
gold is left in the heap.
 Using PSI’s microbial treatment system has
been shown to get significant recovery of
residual gold during cyanide detoxification.
Ore Tonnage Ore Grade
(oz/ton)
Estimated
Total
remaining
gold (oz)
Estimated
PSI gold
recovery
Mine A 71,000,000 0.009 642,550 417,657
Mine B 81,000,000 0.008 648,000 421,200
Mine C 68,000,000 0.007 465,000 302,250
Mine D 23,000,000 0.008 174,000 113,100
Mine E 36,000,000 0.009 324,000 210,000
Mine F 150,000,000 0.010 1,500,000 975,000
Mine G 170,000,000 0.005 850,000 552,500
Totals 650,000,000 4,603,550 2,992,307
$1100/ oz gross $1300/ oz gross $1500/ oz gross
Estimated
PSI Gold
Recovery
$900/ oz net $1100/ oz net $1300/ oz net
Mine A 417,657 $375,891,300 $459,422,700 $542,954,100
Mine D 113,100 $101,790,000 $124,410,000 $147,030,000
Mine F 975,000 $877,500,000 $!,072,500,000 $1,267,500,000
Potential profits based on $200/ oz production cost using PSI Bio Processes

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Detox t to gold 2 short version

  • 1. Gold Recovery During Cyanide Detox In Heap Leach Pads Pintail Systems Inc.
  • 3.  Cyanide is used in heap leach pads to complex gold and silver in the mining industry  Cyanide detoxification is required for mine closure.  PSI’s bio-detoxification process, which uses native bacteria, has proven to be more efficient than conventional chemical processes Bacteria culture used in cyanide detox
  • 4. Pintail Systems, Inc. was founded in 1987 by Leslie Thompson Primary focus was on cyanide detoxification in gold and silver heap leach pads using native bacteria cultures.
  • 5. In 1991,The Hecla Mining Company contracted with PSI to develop a treatment process for the Yellow Pine Mine using native bacteria cultures.
  • 6.  Located Near Yellow Pine, Idaho  Alpine Climate  1.2 Million Ton Spent Ore Heap  Environmentally sensitive area
  • 7.  Detox Goals  To degrade WAD cyanide to 0.2 mg/L or less in heap leachate solutions in one operating season  Prior to contracting with PSI, Hecla investigated chemical methods and was quoted 2 to 4 operating seasons. Heap Bio-Detox WAD Cyanide in Heap Effluent Solutions 0 10 20 30 40 50 1 29 25 50 59 71 85 94 107 114 121 128 136 146 155 Time, Days WADCyanide
  • 8.  Detox goal of 0.2 mg/l WAD cyanide was achieved in one operating season, (155) days  During the detox process, there was a significant increase in gold production  Increased gold production was unexpected and more than paid for the detox process
  • 9. Increased gold recovery paid for mine operations through the end of detox Mine closure was signed off by the Idaho Department of Environmental Quality The Hecla Mining Company won the 1992 Pacific Northwest Pollution Control Association’s Idaho Award for the Innovative use of Bacteria in Improving Water Quality
  • 10.  1.3 million ton heap  Located near Parker, AZ
  • 11.  Detox goal was 0.2 mg/L total cyanide in heap leachate solution
  • 12.  Total cyanide closure goal of <0.2 mg/L TCN met in 111 days  Significant Gold Recovery Improvement. >3000 oz.  Mine closure signed off by the State of Arizona DEQ
  • 13.  Located near Victor, Colorado  5 million ton cyanide- leached spent ore heap  Heap was water-rinsed for 4 years prior to bio- detox  Average detox solution temperature = 35 deg F  Altitude 10,000 ft above sea level.
  • 14.  Detox Goals  Detox WAD cyanide to 0.2 mg/L in heap leachate solution  Decrease the bond requirement for closure by the state of Colorado
  • 15. l Cripple Creek WAD Cyanide 0 0.5 1 1.5 2 2.5 3 1 24 47 70 93 116 139 162 185 208 231 254 277 300 323 346 time, days leachateWADCN,mg/L Cripple Creek Gold Recovery 0.00 1000.00 2000.00 3000.00 4000.00 5000.00 6000.00 1 26 51 76 101 126 151 176 201 226 251 276 301 326 351 time, days cumulativeouncesgold Increased gold recovery during cyanide detox Met the goal of 0.2 mg/L WAD cyanide in heap leachate solution in 346 days
  • 16.  CC&V water rinse and peroxide treatment (30 pore volumes) did not detoxify cyanide to regulatory limits  Pintail bio-detox achieved cyanide limits with application of less than 3 pore volumes of treatment solution  Bond requirement for mine closure was reduced  Increased gold recovery paid for the detox process. The detox process actually became a profit center for the mine.
  • 17. Yellow Pine 1.2 million tons Cyprus Copperstone 1.3 million tons Cripple Creek Victor 5 million tons Cyanide Concentration at start of detox 50 mg/L WAD CN in heap leachate solution 20 mg/L TCN in heap leachate solution Just over 3 mg/L WAD CN in heap leachate solution Cyanide concentration at end of detox < 0.2 mg/L WAD CN heap leachate solution < 0.2 mg/L TCN in heap leachate solution < 0.2 mg/L WAD CN in heap leachate solution Gold Recovery > 2700 >3000 oz >6700 oz Treatment Days 155 days 111 days 350 days Regulatory Goals Met Yes Yes Yes
  • 18. 1 Technical advances have produced more gold over the last 160 years than the previous 6000. 2 Majority of gold produced in the U.S. is from the Heap Leaching Process 3 Heap Leaching leaves 25 – 40% of the original gold in the ore at mine closure Pintail Bio-Processes are the solution to economically recover heap gold4
  • 19.  Cyanide typically recovers 55% to 75% of the gold in a heap leach pad. 25% to 45% residual gold is left in the heap.  Using PSI’s microbial treatment system has been shown to get significant recovery of residual gold during cyanide detoxification.
  • 20. Ore Tonnage Ore Grade (oz/ton) Estimated Total remaining gold (oz) Estimated PSI gold recovery Mine A 71,000,000 0.009 642,550 417,657 Mine B 81,000,000 0.008 648,000 421,200 Mine C 68,000,000 0.007 465,000 302,250 Mine D 23,000,000 0.008 174,000 113,100 Mine E 36,000,000 0.009 324,000 210,000 Mine F 150,000,000 0.010 1,500,000 975,000 Mine G 170,000,000 0.005 850,000 552,500 Totals 650,000,000 4,603,550 2,992,307
  • 21. $1100/ oz gross $1300/ oz gross $1500/ oz gross Estimated PSI Gold Recovery $900/ oz net $1100/ oz net $1300/ oz net Mine A 417,657 $375,891,300 $459,422,700 $542,954,100 Mine D 113,100 $101,790,000 $124,410,000 $147,030,000 Mine F 975,000 $877,500,000 $!,072,500,000 $1,267,500,000 Potential profits based on $200/ oz production cost using PSI Bio Processes