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AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
Application	
  Guide	
  for	
  the	
  Use	
  of	
  AgroSimplex	
  
Formula	
  -­‐	
  4	
  and	
  AgroSimplex	
  Formula	
  -­‐	
  17	
  	
  in	
  
the	
  treatment	
  of	
  diseases	
  in	
  agricultural	
  crops.	
  
	
  
	
  
Please	
  read	
  all	
  the	
  information	
  and	
  follow	
  the	
  instructions	
  as	
  detailed	
  in	
  this	
  guide.	
  
	
  
	
  
	
  
MANUFACTURERS DISCLAIMER:
The	
  information	
  contained	
  herein	
  is,	
  to	
  the	
  best	
  of	
  the	
  manufacturer’s	
  knowledge	
  and	
  belief,	
  accurate	
  and	
  
reliable	
  as	
  of	
  the	
  date	
  of	
  preparation	
  of	
  this	
  document.	
  However,	
  no	
  warranty	
  or	
  guarantee,	
  express	
  or	
  
implied,	
  is	
  made	
  as	
  to	
  the	
  accuracy	
  or	
  reliability,	
  and	
  the	
  manufacturer	
  shall	
  not	
  be	
  liable	
  for	
  any	
  loss	
  or	
  
damage	
  arising	
  out	
  of	
  the	
  use	
  thereof.	
  No	
  authorisation	
  is	
  given	
  or	
  implied	
  to	
  use	
  any	
  patented	
  invention	
  
without	
  a	
  license.	
  In	
  addition	
  the	
  manufacturer	
  shall	
  not	
  be	
  liable	
  for	
  any	
  damage	
  or	
  injury	
  resulting	
  from	
  
 
AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
abnormal	
  use,	
  from	
  any	
  failure	
  to	
  adhere	
  to	
  recommended	
  practises	
  or	
  from	
  any	
  hazards	
  inherent	
  in	
  the	
  
nature	
  of	
  the	
  product.	
  
	
  
	
  
This	
  guide	
  is	
  intended	
  for	
  the	
  use	
  of	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  and	
  AgroSimplex	
  
Formula	
  -­‐	
  17	
  in	
  the	
  control	
  of	
  diseases	
  in	
  crops.	
  
	
  
	
  
	
  
	
  
	
  
	
  
	
  
AgroSimplex	
  Formula	
  -­‐	
  4	
  is	
  a	
  general	
  fungicide	
  and	
  pesticide	
  that	
  is	
  
used	
  to	
  prevent	
  and	
  control	
  the	
  spread	
  of	
  pathogens	
  in	
  crops,	
  it	
  is	
  
also	
  effective	
  against	
  many	
  soft	
  bodied	
  pests.	
  However	
  it	
  is	
  an	
  
oxidising	
  agent	
  and	
  care	
  must	
  be	
  taken	
  during	
  handling	
  and	
  
application.	
  	
  
Please	
  read	
  MSDS	
  and	
  all	
  Standard	
  Operating	
  Procedures	
  BEFORE	
  
using	
  this	
  product.	
  
AgroSimplex	
  Formula	
  -­‐	
  17	
  is	
  a	
  plant	
  growth	
  enhancer	
  that	
  will	
  help	
  crops	
  
recover	
  after	
  stress	
  induced	
  events	
  and	
  potentially	
  produce	
  a	
  bigger	
  
healthier	
  crop	
  than	
  expected.	
  	
  There	
  are	
  no	
  known	
  hazards	
  associated	
  wi
this	
  product.	
  	
  
Please	
  read	
  MSDS	
  and	
  all	
  Standard	
  Operating	
  Procedures	
  BEFORE	
  using	
  
this	
  product.	
  
	
  
WARNING:	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  contains	
  hydrogen	
  peroxide	
  a	
  chemical	
  which	
  is	
  
available	
  commercially.	
  However	
  the	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  supplied	
  by	
  AgroSimplex	
  
is	
  a	
  specially	
  formulated	
  and	
  stabilised	
  product	
  for	
  agricultural	
  use	
  only	
  and	
  allows	
  
dilution	
  with	
  lower	
  grade	
  waters	
  such	
  as	
  potable	
  supplies	
  without	
  compromising	
  the	
  
efficiency.	
  AgroSimplex	
  will	
  not	
  take	
  responsibility	
  for	
  any	
  plant	
  damage	
  caused	
  by	
  
products	
  not	
  purchased	
  through	
  our	
  certified	
  agents.	
  
 
AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
APPLICATION GUIDE
STANDARD	
  OPERATING	
  PROCEDURE	
  FOR	
  MIXING	
  AND	
  APPLICATION	
  OF	
  AGROSIMPLEX	
  
FORMULA	
  -­‐	
  4	
  (SOP)	
  
General	
  
2	
  People	
  to	
  be	
  present	
  at	
  all	
  times	
  
No	
  food	
  or	
  drinks	
  to	
  be	
  consumed	
  whilst	
  carrying	
  out	
  procedures	
  
All	
  safety	
  equipment	
  to	
  be	
  worn	
  at	
  all	
  times	
  
All	
  safety	
  procedures	
  to	
  be	
  adhered	
  to	
  at	
  all	
  times	
  
Access	
  to	
  cellphone/landline	
  available	
  at	
  all	
  times	
  	
  
Access	
  to	
  Eyewash	
  station	
  available	
  at	
  all	
  times	
  
Access	
  to	
  First	
  Aid	
  station	
  at	
  all	
  times	
  
	
  
Before	
  beginning	
  process	
  it	
  is	
  necessary	
  to	
  ensure:	
  
All	
  equipment	
  required	
  is	
  correct	
  and	
  fully	
  functional	
  
All	
  safety	
  equipment/clothing	
  is	
  present	
  including	
  safety	
  glasses,	
  protective	
  clothing	
  and	
  gloves	
  
All	
  ingredients	
  required	
  are	
  present	
  
Labels	
  to	
  be	
  checked	
  to	
  ensure	
  date	
  compliance	
  
All	
  instructions	
  regarding	
  mixing/dosage	
  and	
  disposal	
  of	
  product	
  are	
  adhered	
  to	
  
SOLUTION	
  PREPARATION	
  
AgroSimplex	
  Formula	
  -­‐	
  4	
  solution	
  should	
  not	
  be	
  combined	
  or	
  mixed	
  with	
  any	
  other	
  pesticide	
  or	
  
fertilizer.	
  
AgroSimplex	
  Formula	
  -­‐	
  4	
  is	
  a	
  strong	
  oxidizing	
  agent	
  and	
  may	
  react	
  with	
  residues	
  of	
  metal-­‐based	
  
fungicides	
  or	
  supplements.	
  Care	
  should	
  be	
  used	
  when	
  applying	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  as	
  a	
  
foliar	
  spray	
  immediately	
  following	
  foliar	
  applications	
  of	
  metal-­‐based	
  products.	
  
AgroSimplex	
  Formula	
  -­‐	
  4	
  is	
  a	
  strong	
  oxidizing	
  agent	
  and	
  may	
  react	
  with	
  residues	
  of	
  metal-­‐based	
  
fungicides	
  or	
  supplements.	
  Care	
  should	
  be	
  used	
  when	
  applying	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  as	
  a	
  
foliar	
  spray	
  immediately	
  following	
  foliar	
  applications	
  of	
  metal-­‐based	
  products.	
  
	
  
Use	
  a	
  dilution	
  of	
  1	
  fl	
  oz	
  per	
  gallon	
  of	
  clean	
  water	
  (30mls	
  per	
  4	
  litres).	
  Diluted	
  product	
  cannot	
  be	
  
stored,	
  make	
  fresh	
  daily.	
  Gloves	
  and	
  eye	
  protection	
  must	
  be	
  worn	
  during	
  preparation	
  and	
  
application	
  of	
  this	
  product.	
  
 
AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
	
  
1. Ensure	
  tanks	
  and	
  all	
  measuring	
  utensils	
  are	
  clean	
  and	
  the	
  solution	
  is	
  not	
  mixed	
  or	
  
combined	
  with	
  any	
  other	
  pesticide	
  or	
  fertilizer	
  as	
  this	
  may	
  cause	
  an	
  adverse	
  reaction	
  
when	
  combined	
  with	
  AgroSimplex	
  Formula	
  -­‐	
  4.	
  It	
  is	
  advisable	
  to	
  keep	
  dedicated	
  
materials	
  for	
  use	
  with	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  only.	
  
2. Product	
  works	
  best	
  when	
  diluted	
  with	
  water	
  containing	
  low	
  levels	
  of	
  organic	
  or	
  inorganic	
  
materials	
  and	
  having	
  a	
  neutral	
  pH.	
  Tap	
  water	
  is	
  okay.	
  It	
  is	
  recommended	
  that	
  mixing	
  
tanks	
  are	
  kept	
  separately	
  for	
  sole	
  use	
  with	
  AgroSimplex	
  Formula	
  -­‐	
  4.	
  This	
  will	
  avoid	
  the	
  
AgroSimplex	
  Formula	
  -­‐	
  4	
  solution	
  being	
  mixed	
  with	
  any	
  previously	
  used	
  products	
  which	
  
may	
  cause	
  a	
  reaction.	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  mixes	
  readily	
  with	
  clean,	
  neutral	
  water	
  
and	
  does	
  not	
  require	
  agitation.	
  
3. AgroSimplex	
  Formula	
  -­‐	
  4	
  is	
  a	
  strong	
  oxidising	
  agent	
  and	
  may	
  react	
  with	
  residues	
  of	
  metal	
  
based	
  fungicides	
  or	
  supplements.	
  Care	
  must	
  be	
  used	
  when	
  applying	
  AgroSimplex	
  Formula	
  
-­‐	
  4	
  as	
  a	
  foliar	
  spray	
  immediately	
  following	
  foliar	
  applications	
  of	
  metal-­‐based	
  products.	
  
4. Surfactant	
  may	
  be	
  added	
  to	
  AgroSimplex	
  Formula	
  -­‐	
  17	
  if	
  needed	
  for	
  treatment	
  of	
  plants	
  with	
  
difficult	
  to	
  reach	
  surfaces	
  or	
  for	
  plants	
  having	
  waxy	
  or	
  hairy	
  surfaces.	
  Surfactant	
  should	
  be	
  added	
  
last.	
  
	
  
APPLICATION	
  OF	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  
	
  
1. Add	
  1	
  gallon	
  (4	
  litres)	
  of	
  water	
  into	
  clean	
  spray	
  tank.	
  	
  
2. Add	
  1fl.oz	
  30	
  mls	
  of	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  
3. Mix	
  solution	
  thoroughly	
  before	
  starting	
  spray	
  pump	
  
Thoroughly	
  wet	
  all	
  surfaces	
  of	
  plant	
  including	
  upper	
  and	
  lower	
  foliage,	
  stems,	
  branches	
  
and	
  stalks	
  to	
  ensure	
  full	
  contact	
  with	
  plant	
  tissue.	
  
4. Work	
  from	
  the	
  back	
  of	
  the	
  area	
  identified	
  through	
  to	
  front	
  to	
  avoid	
  brushing	
  against	
  
plants/trees	
  which	
  have	
  just	
  been	
  treated	
  with	
  AgroSimplex	
  Formula	
  -­‐	
  4.	
  
5. Spray	
  product	
  in	
  a	
  wide	
  circle	
  around	
  the	
  base	
  of	
  each	
  plant/tree.	
  This	
  is	
  to	
  avoid	
  
spores	
  being	
  dispersed	
  into	
  the	
  surrounding	
  area	
  whist	
  treating	
  the	
  affected	
  plants.	
  
6. Spray	
  the	
  soil	
  within	
  the	
  circle	
  around	
  the	
  base	
  of	
  the	
  plant.	
  
7. Work	
  from	
  bottom	
  of	
  plant	
  to	
  top	
  to	
  ensure	
  product	
  does	
  not	
  drip	
  onto	
  clothing	
  or	
  
skin	
  during	
  application.	
  Always	
  wear	
  eye	
  protection	
  to	
  avoid	
  accidental	
  spray	
  or	
  drift	
  
into	
  the	
  eyes.	
  
8. For	
  diseases	
  such	
  as	
  coffee	
  rust	
  which	
  affects	
  the	
  underside	
  of	
  the	
  leaves	
  it	
  is	
  
necessary	
  to	
  spray	
  underneath	
  the	
  leaves	
  to	
  ensure	
  contact	
  with	
  spores.	
  Spray	
  the	
  
topside	
  of	
  leaves	
  for	
  treatment	
  of	
  all	
  diseases	
  which	
  affect	
  the	
  top	
  surface	
  of	
  the	
  
plant.	
  
9. Spray	
  stem	
  and	
  overhanging	
  leaves.	
  
10. Clean	
  hands	
  with	
  disinfectant	
  wipes	
  after	
  removing	
  gloves	
  to	
  ensure	
  there	
  is	
  no	
  
transfer	
  of	
  spores	
  to	
  non-­‐	
  infected	
  areas.	
  
 
AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
11. For	
  optimal	
  results	
  it	
  is	
  recommended	
  that	
  initially	
  crops	
  should	
  be	
  treated	
  with	
  
AgroSimplex	
  Formula	
  -­‐	
  4	
  3	
  times.	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  can	
  be	
  reapplied	
  as	
  soon	
  
as	
  the	
  previous	
  application	
  has	
  dried.	
  Depending	
  on	
  climatic	
  conditions,	
  altitude,	
  etc	
  
it	
  is	
  possible	
  to	
  complete	
  3	
  applications	
  on	
  the	
  same	
  day.	
  However,	
  effective	
  
treatment	
  can	
  be	
  obtained	
  with	
  only	
  1	
  spay	
  (60-­‐	
  80%)	
  to	
  be	
  followed	
  up	
  with	
  regular	
  
spraying	
  of	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  as	
  part	
  of	
  the	
  normal	
  spraying	
  protocol.	
  i.e.	
  If	
  at	
  
present,	
  spraying	
  is	
  undertaken	
  every	
  2	
  weeks	
  for	
  control	
  of	
  disease,	
  then	
  
AgroSimplex	
  Formula	
  -­‐	
  4	
  should	
  be	
  sprayed	
  liberally	
  every	
  2	
  weeks	
  to	
  ensure	
  that	
  the	
  
disease	
  is	
  efficiently	
  controlled	
  and	
  to	
  prevent	
  spread	
  of	
  spores	
  to	
  areas	
  which	
  are	
  
not	
  infected.	
  
12. AgroSimplex	
  Formula	
  -­‐	
  17	
  should	
  be	
  sprayed	
  over	
  the	
  top	
  of	
  the	
  plant	
  and	
  leaves.	
  This	
  
can	
  be	
  done	
  anytime	
  	
  after	
  as	
  the	
  AgroSimplex	
  Formula	
  -­‐	
  4	
  has	
  dried.	
  
AgroSimplex	
  Formula	
  -­‐	
  17	
  is	
  an	
  integral	
  part	
  of	
  the	
  protocol	
  in	
  control	
  and	
  recovery	
  of	
  affected	
  
crops	
  and	
  for	
  optimum	
  results	
  should	
  be	
  applied	
  within	
  days	
  of	
  spraying	
  AgroSimplex	
  Formula	
  
-­‐	
  4.	
  
APPLICATION	
  OF	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  	
  
	
  
1. Add	
  1	
  gallon	
  (4	
  litres)	
  of	
  	
  water	
  into	
  clean	
  	
  spray	
  tank	
  
2. Add	
  1fl.oz	
  (30mls)	
  of	
  AgroSimplex	
  Formula	
  -­‐	
  17	
  	
  
3. Mix	
  solution	
  thoroughly	
  before	
  starting	
  spray	
  pump	
  
4. Work	
  from	
  the	
  back	
  of	
  the	
  area	
  to	
  be	
  treated	
  through	
  to	
  front	
  to	
  avoid	
  brushing	
  
against	
  plants/trees	
  which	
  have	
  just	
  been	
  treated	
  with	
  AgroSimplex	
  Formula	
  -­‐	
  17	
  .	
  
5. Always	
  spray	
  over	
  the	
  top	
  of	
  plant,	
  include	
  all	
  leaf	
  surfaces	
  and	
  the	
  soil	
  underneath.	
  
6. Diluted	
  product	
  can	
  be	
  stored	
  maximum	
  1	
  week.	
  
	
  
	
  
It	
  is	
  possible	
  to	
  add	
  fertilisers	
  or	
  other	
  adjuvants	
  to	
  AgroSimplex	
  Formula	
  -­‐	
  17,	
  however	
  
where	
  this	
  is	
  done	
  it	
  is	
  always	
  recommended	
  that	
  the	
  other	
  additives	
  are	
  diluted	
  prior	
  to	
  
adding	
  concentrated	
  AgroSimplex	
  Formula	
  -­‐	
  17	
  	
  at	
  the	
  same	
  dosage	
  as	
  above.	
  Mix	
  well	
  
before	
  spraying.	
  
	
  
	
  
THE	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  4/AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  REGIME	
  SHOULD	
  BE	
  CARRIED	
  
OUT	
  EVERY	
  2-­‐3	
  WEEKS	
  TO	
  ENSURE	
  EFFECTIVE	
  CONTROL	
  OF	
  	
  INFECTIONS.	
  THIS	
  REGIME	
  WILL	
  
ALSO	
  MAXIMISE	
  PLANT	
  RECOVERY	
  AND	
  REGROWTH	
  .	
  
	
  
	
  
	
  
 
AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
	
  
	
  
Material Safety Data Sheet
Product	
  Name:	
  AgroSimplex	
  Formula	
  -­‐	
  4	
   Product	
  description:	
  Liquid	
  	
  	
  	
  	
  
Product	
  Use:	
  Agriculture	
  
Supplier’s	
  Name:	
  AgroSimplex	
  
Address:	
  1313	
  Ross	
  Road,	
  North	
  Vancouver,	
  B.C,	
  Canada	
  	
  
Emergency	
  Telephone:	
  +001	
  778-­‐835-­‐5251	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  
Emergency	
  Contact:	
  Tyler	
  Mackay	
  
Section 1: Product Information
Product Name:
Chemical Name:
DOT Shipping Name:
CAS Registry:
Chemical Family:
Chemical Formula:
Formula Weight:
ACGIH:
OSHA:
AgroSimplex Formula - 4 1
Hydrogen Peroxide 34%
& stabilising agents (Trade Secret)
UN 2014, Hydrogen Peroxide,
Aqueous Solutions,
5.1 (8) PG II
7722-84-1
Inorganic Peroxide
H202
34.02
TLV 1 ppm STEL None
PEL 1 ppm STEL None
 
AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
Section 2: Health Data
Eye Contact: Exposure to the vapors, mists, or liquids can cause severe eye
irritation or burns. Flush eyes with a directed stream of water for at least 15
minutes. Forcibly hold eyelids apart to ensure complete irrigation of all eyelid
tissue. Get immediate attention if irritation occurs. Contact lenses should not be
worn when working with this chemical.
Skin Contact: Exposure can cause severe skin irritation or burns.
Immediately flush skin with water. If the chemical penetrates clothing,
immediately remove the clothing and flush the skin with water. Get prompt
medical attention if irritation occurs. Wash clothing before reuse.
Ingestion: Can cause severe irritation or burns to the entire gastrointestinal
tract. Ingestions of large amounts may be fatal. If person is conscious,
immediately administer large quantities of water.
Never give anything by mouth to an unconscious person. Do not induce
vomiting. GET IMMEDIATE MEDICAL ATTENTION.
Inhalation: Move the exposed person to fresh air at once. If breathing stops,
give artificial respiration. If breathing is difficult, administer oxygen. Seek
medical attention if irritation persists.
Note to Physician: Direct contact with the eye is likely to cause corneal
damage, especially if not washed away immediately. Careful ophthalmologic
evaluation is recommended, and the possibility of local corticosteroid therapy
should be considered. Attempts at evacuating the stomach via emesis induction
or gastric lavage should be avoided. In the event of severe distension of the
stomach or esophagus due to gas formation, insertion of a gastric tube may be
required.
Effects of Overexposure: Contact of the skin with hydrogen peroxide
may cause severe skin irritation. Contact of eye may cause eye irritation with
tearing or blurring vision and possible blindness. Inhalation may include
irritation of the upper respiratory passages, nausea, headache or weakness.
Ingestion may include irritation of the gastrointestinal internal tract and
abdominal pain or red blood cell destruction.
 
AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
Toxicity:
Laboratory Animals: Acute Oral Toxicity:
LD50 for different species are in the
range of 700mg/kg (90% H202)
9,200mg/kg (70% H202). LC50 for rat
is greater than 200mb/m3 (75% H202)
Acute Dermal Toxicity Non - Toxic
(Rabbit):
Primary Skin Irritation Mildly irritating
(Rabbit):
Primary Eye Irritation Extreme irritation
(Rabbit):
Carcinogenicity: Non identified
NTP: No
IARC: No
ACGIH: No
OSHA: No
 
AGROSIMPLEX	
  FORMULA	
  -­‐	
  4	
  AND	
  AGROSIMPLEX	
  FORMULA	
  -­‐	
  17	
  
	
  
Section 3: Fire and Explosion Hazard Data
Extinguishing Media: Use water only to fight fire where hydrogen
peroxide is involved.
Special Fire Fighting Procedure and Personal Protection:
Avoid all bodily contact. Wear self-contained breathing apparatus and
appropriate protective equipment. In case of external fire, cool hydrogen
peroxide and surrounding containers with plenty of water.
Unusual Fire and Explosive Hazards: Spontaneous combustion can
occur if allowed to remain in contact with oxidizable materials. Drying product in
clothing or combustible material may cause fire. Do not heat solution to
concentrations of 74% or greater. Do not allow temperature of storage tank to
rise above 100° F (38° C). Mixtures with combustible material may be explosive.
Flashpoint: Non-Flammable
Hazardous Reactivity
Stability: Unstable when heated or contaminated with heavy metals, reducing
agents, rust, dirt or organic materials.
Incompatibility: Incompatible with cyanides, iron, copper and its alloys,
hexavalent, chromium compounds, nitric acid, potassium permanganate,
reducing agents and other flammables and combustibles.
Hazardous Products of Decomposition: Contamination from any
source may cause rapid decomposition, oxygen gas release, and dangerous
pressures.
Polymerization: Will not occur.
Section 4: Handling and Storage
Precautions: Store in a properly vented container or in approved bulk
storage facilities. Do not block vent. Store drums on flame retardant pallets. Do
not store where contact with incompatible materials could occur, even with a
spill. Have water source available for diluting. Keep containers out of sun and
away from heat, sparks, and flames. Do not add any other product to container.
Never return any unused product to container. Rinse empty containers
thoroughly with clean water before discarding.
Section 5: Environmental Protection
Procedure in case of spill or release: Obtain full protective
equipment, including respiratory protection. Review fire and explosion hazards and safety
precautions before proceeding with clean up.
Dilute with a large volume of water, and contain runoff until hydrogen peroxide
decomposes. Do not allow to escape into sewers or natural watercourses before
decomposition. May be destroyed with sodium metabisulfite or sodium sulfite
(1.7lbs SO2 equivalent per lb of hydrogen peroxide) after diluting to 5-10%
hydrogen peroxide. Care must be exercised because of temperature rise.
Waste disposal method: After decomposition, consult with local, state
and federal officials, and, subject to their approval, discharge into suitable treatment system.
If product is released prior to decomposition, it is termed hazardous waste as defined by 40
CFR261 and would have the following EPA hazardous waste: D001.
Section 6: Regulatory Status
Sara Title III Section 311/312 classifies hydrogen peroxide as an immediate health
hazard and a fire hazard. The minimum threshold quantity for reporting is
10,000 pounds.
Extremely Hazardous Substance: No
CERCLA Hazardous Substance: No
SARA Title III Section 313 Toxic Chemicals: No
TSCA Inventory: Yes
Process Safety Management: No
RISK Management Program: No
Section 7: Transportation Data
UN 2014, Hydrogen Peroxide, Aqueous Solutions, 5.1 (8) PG II
Hydrogen peroxide above 8% concentration is classified as an "oxidizer and corrosive" by the
DOT and must be labeled accordingly.
	
  
	
  
11	
  
	
  
	
  
Document	
  prepared	
  by	
  Dr.	
  H.E.	
  Keenan	
  
30th
	
  July	
  2014	
  
MATERIAL SAFETY DATA SHEET (MSDS)
	
  	
  
Date	
  MSDS	
  Prepared	
  26/1/2014	
   	
   	
  	
  	
  	
  	
  	
  	
   	
   	
   	
   	
   	
   24	
  Hour	
  Emergency	
  Contacts	
  
Revision	
  Number	
  1:	
  Revised	
  July	
  2014	
   	
   	
   	
   	
   	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  	
  Tyler	
  Mackay	
  +001	
  778-­‐835-­‐5251	
  	
  
MSDS	
  Prepared	
  By:	
  Dr	
  H	
  Keenan	
  Cchem	
  Csci	
  MRSC	
  	
  	
   	
   	
   	
  	
  	
  	
  	
  	
  
Phone	
  Number	
  +4407944706642	
  
SECTION	
  1	
  —	
  CHEMICAL	
  PRODUCT	
  AND	
  COMPANY	
  IDENTIFICATION	
  
Product	
  Name:	
  AgroSimplex	
  Formula	
  -­‐	
  17	
  	
   Product	
  description:	
  Mixture	
  	
  	
  	
  	
  Product	
  Use:	
  Plant	
  Stimulant	
  
Manufacturer’s	
  Name:	
  AgroSimplex	
   	
   Supplier’s	
  Name:	
  AgroSimplex	
  
Address:	
  1313	
  Ross	
  Road,	
  North	
  Vancouver,	
  BC,	
  Canada	
  	
   	
  	
  	
  	
  Emergency	
  Telephone:	
  	
  +001	
  778-­‐835-­‐5251	
  	
   	
  
	
  
SECTION 2 — COMPOSITION / INFORMATION ON INGREDIENTS
Product Description : Liquid Mixture This Mixture is claimed as a Trade Secret and as such
the composition is withheld.
Registered as International Class 001- Substances for regulating plant growth.
However it is disclosed that the mixture is a combination of several chemicals at different
concentrations.
Active Ingredients
INGREDIENT Quantity
Volume % OSHA PEL ACGIH TLV
1 <10% 3ppm, 6 mg/m3
3ppm
2 <10% Not Listed Not Listed
3 20-40% Not Listed Not Listed
4 2-5% Not Listed Not Listed
5 10-15% Not Listed Not Listed
6 <10% Not Listed Not Listed
12	
  
	
  
	
  
Document	
  prepared	
  by	
  Dr.	
  H.E.	
  Keenan	
  
30th
	
  July	
  2014	
  
SECTION 3 — HAZARDS IDENTIFICATION
Potential Health Effects
OSHA regulatory Status: This mixture is not considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200)
SECTION 4 — FIRST AID MEASURES
Skin Contact:
Take off contaminated clothing. Rinse skin immediately with plenty of water. Call a Poison Control Centre or Doctor
for further treatment advice.
Eye Contact:
Hold eye open and rinse slowly and gently with water for 15-20mins. Remove contact lenses, if present after first 5
minutes then continue rinsing the eye. Call a Poison Control Centre or Doctor for further treatment advice.
Inhalation:
Move to Fresh air. If person not breathing call emergency doctor or ambulance, then give artificial respiration (mouth
to mouth if possible) until assistance arrives. Call a Poison Control Centre or Doctor for further treatment advice.
Ingestion:
Have person sip a glass of water if able to swallow. Do NOT induce vomiting. Do not give anything by mouth to an
unconcious person. Call a Poison Control Centre or Doctor for further treatment advice.
SECTION 5 — FIRE FIGHTING MEASURES	
  
Flammable
❐Yes ☑ No
If yes, under which conditions?
Means of Extinction
Water spray, carbon dioxide, fine-earth or sand.
Flashpoint (° C) and Method
Not Determined
Upper Flammable Limit (% by volume)
Not Determined
Lower Flammable Limit (% by volume)
Not Determined
Autoignition Temperature (°C)
Not Determined
Explosion Data — Sensitivity to Impact
Not Determined
Explosion Data — Sensitivity to Static Discharge
Not Determined
Hazardous Combustion Products
Not Determined
	
  
SECTION 6 — ACCIDENTAL RELEASE MEASURES
General Procedures: Extinguish all ignition sources. Flush area with water.
13	
  
	
  
	
  
Document	
  prepared	
  by	
  Dr.	
  H.E.	
  Keenan	
  
30th
	
  July	
  2014	
  
	
   If checked, please specify type
Safety Glasses with side shield are recommended when handling undiluted Product. Disposable gloves. Overall or apron. 	
  
	
  
SECTION 7 — HANDLING AND STORAGE
General Procedures: Rinse all equipment after use. All rinse water can be applied as product.
Handling: Wear Safety Goggles and Gloves when working with undiluted product. Wash hands with
water after handling product.
Storage: Store in a cool dry area in closed container. Keep in original container, do not reuse
container for consumables. KEEP OUT OF REACH OF CHILDREN.
Diluted product is safe for handling without personal protective equipment.
SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Limits: ACGIH TLV Applies to pure chemical. This product is a mix in which <10% is present therefore it is unlikely TLV will be exceeded.
☑ ACGIH TLV ❐ OSHA PEL ❐ Other (specify)
Specific Engineering Controls (such as ventilation, enclosed process)
Ensure adequate ventilation during dilution.
Personal Protective Equipment ☑ Gloves ❐ Respirator ☑ Eye ❐ Footwear ☑ Clothing ❐ Other
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Liquid
Odour and Appearance
Alcohol/amine smell, slightly viscous green/yellow liquid
Odour Threshold (ppm)
Not Determined
Specific Gravity 1.03-1.05
Not Determined
Vapour Density (air = 1)
Not Determined
Vapour Pressure (mmHg)
Not Determined
Evaporation Rate
Not Determined
Boiling Point (° C)
Not Determined
Freezing Point (° C)
Not Determined
pH 9.9-10.2 Coefficient of Water/Oil Distribution
Not Determined
[Solubility in Water]
100%
	
  
SECTION 10 — STABILITY AND REACTIVITY
Stability: Stable
Reactivity, and under what conditions? Not Determined.
Hazardous Decomposition Products: None
14	
  
	
  
	
  
Document	
  prepared	
  by	
  Dr.	
  H.E.	
  Keenan	
  
30th
	
  July	
  2014	
  
SECTION 11 — TOXICOLOGICAL INFORMATION
The Toxicological information is based on the individual ingredients in the product. The dilution effect must be taken
into consideration when considering the toxicology of the mixture that is AgroSimplex Formula - 17 .
Carcinogenicity: IARC: No NTP: No OSHA: No
This product contains Ingredient 1 at a concentration of <10%. This chemical has a stated occupational exposure limit
(ACGIH, OSHA) of 3ppm or 6 mg/m3
. However the volatility and effect of this chemical is much reduced by dilution,
and therefore the stated level would be difficult to achieve. This product (AgroSimplex Formula - 17) should also be
diluted prior to use and the final concentration of AgroSimplex Formula - 17 is < 0.5% when diluted at recommended
rates.
SECTION 12 — ECOLOGICAL INFORMATION
[Aquatic Toxicity]
The active ingredients 1,2 & 5 were all considered below criteria for persistence, bioaccumulation and toxicity. i.e.
they are non persistent, non bioaccumulative & non toxic. (http://www.pbtprofiler.net/default.asp see
http://www.pbtprofiler.net/Details.asp for criteria)
Ingredient 3 cannot be modelled due to insolubility, it is however a naturally derived ingredient. The MSDS supplied
with the chemical shows no toxicity (all values >1000mg/l fish & daphnia) and states that it is readily biodegradeable.
Ingredient 4 cannot be modelled as it has no entry in database, however the MSDS shows no toxicity and states that
it is readily biodegradable.
This product (AgroSimplex Formula - 17 ) is highly beneficial to plant life and there are no known adverse effects on
aquatic life.
A Full Ecological Assessment is available on request.
SECTION 13 — DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Waste disposal must be in accordance with Federal, state, and local
regulations. Be aware that the waste owner has responsibility for final disposal. Regulations may
also apply to empty containers. This material can be safely disposed to drain, flush with plenty of
water.
SECTION 14 — TRANSPORT INFORMATION
This product is non hazardous by the OSHA classification as set out in document
https://www.osha.gov/dsg/hazcom/ghs.html#3.0
Not DOT/ ICAA/ IMDG regulated.	
   	
  
	
  
15	
  
	
  
	
  
Document	
  prepared	
  by	
  Dr.	
  H.E.	
  Keenan	
  
30th
	
  July	
  2014	
  
	
  
SECTION 15 — REGULATORY INFORMATION
NA
Fire:No Pressure Generating:No Reactivity:No Acute:No Chronic:No
	
  
SECTION 16 — OTHER INFORMATION
REVISION	
  SUMMARY:	
  Revised	
  July	
  2014	
  New	
  MSDS	
  

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AgroSimplex Application Guide

  • 1.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17                           Application  Guide  for  the  Use  of  AgroSimplex   Formula  -­‐  4  and  AgroSimplex  Formula  -­‐  17    in   the  treatment  of  diseases  in  agricultural  crops.       Please  read  all  the  information  and  follow  the  instructions  as  detailed  in  this  guide.         MANUFACTURERS DISCLAIMER: The  information  contained  herein  is,  to  the  best  of  the  manufacturer’s  knowledge  and  belief,  accurate  and   reliable  as  of  the  date  of  preparation  of  this  document.  However,  no  warranty  or  guarantee,  express  or   implied,  is  made  as  to  the  accuracy  or  reliability,  and  the  manufacturer  shall  not  be  liable  for  any  loss  or   damage  arising  out  of  the  use  thereof.  No  authorisation  is  given  or  implied  to  use  any  patented  invention   without  a  license.  In  addition  the  manufacturer  shall  not  be  liable  for  any  damage  or  injury  resulting  from  
  • 2.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17     abnormal  use,  from  any  failure  to  adhere  to  recommended  practises  or  from  any  hazards  inherent  in  the   nature  of  the  product.       This  guide  is  intended  for  the  use  of  AgroSimplex  Formula  -­‐  4  and  AgroSimplex   Formula  -­‐  17  in  the  control  of  diseases  in  crops.                 AgroSimplex  Formula  -­‐  4  is  a  general  fungicide  and  pesticide  that  is   used  to  prevent  and  control  the  spread  of  pathogens  in  crops,  it  is   also  effective  against  many  soft  bodied  pests.  However  it  is  an   oxidising  agent  and  care  must  be  taken  during  handling  and   application.     Please  read  MSDS  and  all  Standard  Operating  Procedures  BEFORE   using  this  product.   AgroSimplex  Formula  -­‐  17  is  a  plant  growth  enhancer  that  will  help  crops   recover  after  stress  induced  events  and  potentially  produce  a  bigger   healthier  crop  than  expected.    There  are  no  known  hazards  associated  wi this  product.     Please  read  MSDS  and  all  Standard  Operating  Procedures  BEFORE  using   this  product.     WARNING:  AgroSimplex  Formula  -­‐  4  contains  hydrogen  peroxide  a  chemical  which  is   available  commercially.  However  the  AgroSimplex  Formula  -­‐  4  supplied  by  AgroSimplex   is  a  specially  formulated  and  stabilised  product  for  agricultural  use  only  and  allows   dilution  with  lower  grade  waters  such  as  potable  supplies  without  compromising  the   efficiency.  AgroSimplex  will  not  take  responsibility  for  any  plant  damage  caused  by   products  not  purchased  through  our  certified  agents.  
  • 3.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17     APPLICATION GUIDE STANDARD  OPERATING  PROCEDURE  FOR  MIXING  AND  APPLICATION  OF  AGROSIMPLEX   FORMULA  -­‐  4  (SOP)   General   2  People  to  be  present  at  all  times   No  food  or  drinks  to  be  consumed  whilst  carrying  out  procedures   All  safety  equipment  to  be  worn  at  all  times   All  safety  procedures  to  be  adhered  to  at  all  times   Access  to  cellphone/landline  available  at  all  times     Access  to  Eyewash  station  available  at  all  times   Access  to  First  Aid  station  at  all  times     Before  beginning  process  it  is  necessary  to  ensure:   All  equipment  required  is  correct  and  fully  functional   All  safety  equipment/clothing  is  present  including  safety  glasses,  protective  clothing  and  gloves   All  ingredients  required  are  present   Labels  to  be  checked  to  ensure  date  compliance   All  instructions  regarding  mixing/dosage  and  disposal  of  product  are  adhered  to   SOLUTION  PREPARATION   AgroSimplex  Formula  -­‐  4  solution  should  not  be  combined  or  mixed  with  any  other  pesticide  or   fertilizer.   AgroSimplex  Formula  -­‐  4  is  a  strong  oxidizing  agent  and  may  react  with  residues  of  metal-­‐based   fungicides  or  supplements.  Care  should  be  used  when  applying  AgroSimplex  Formula  -­‐  4  as  a   foliar  spray  immediately  following  foliar  applications  of  metal-­‐based  products.   AgroSimplex  Formula  -­‐  4  is  a  strong  oxidizing  agent  and  may  react  with  residues  of  metal-­‐based   fungicides  or  supplements.  Care  should  be  used  when  applying  AgroSimplex  Formula  -­‐  4  as  a   foliar  spray  immediately  following  foliar  applications  of  metal-­‐based  products.     Use  a  dilution  of  1  fl  oz  per  gallon  of  clean  water  (30mls  per  4  litres).  Diluted  product  cannot  be   stored,  make  fresh  daily.  Gloves  and  eye  protection  must  be  worn  during  preparation  and   application  of  this  product.  
  • 4.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17       1. Ensure  tanks  and  all  measuring  utensils  are  clean  and  the  solution  is  not  mixed  or   combined  with  any  other  pesticide  or  fertilizer  as  this  may  cause  an  adverse  reaction   when  combined  with  AgroSimplex  Formula  -­‐  4.  It  is  advisable  to  keep  dedicated   materials  for  use  with  AgroSimplex  Formula  -­‐  4  only.   2. Product  works  best  when  diluted  with  water  containing  low  levels  of  organic  or  inorganic   materials  and  having  a  neutral  pH.  Tap  water  is  okay.  It  is  recommended  that  mixing   tanks  are  kept  separately  for  sole  use  with  AgroSimplex  Formula  -­‐  4.  This  will  avoid  the   AgroSimplex  Formula  -­‐  4  solution  being  mixed  with  any  previously  used  products  which   may  cause  a  reaction.  AgroSimplex  Formula  -­‐  4  mixes  readily  with  clean,  neutral  water   and  does  not  require  agitation.   3. AgroSimplex  Formula  -­‐  4  is  a  strong  oxidising  agent  and  may  react  with  residues  of  metal   based  fungicides  or  supplements.  Care  must  be  used  when  applying  AgroSimplex  Formula   -­‐  4  as  a  foliar  spray  immediately  following  foliar  applications  of  metal-­‐based  products.   4. Surfactant  may  be  added  to  AgroSimplex  Formula  -­‐  17  if  needed  for  treatment  of  plants  with   difficult  to  reach  surfaces  or  for  plants  having  waxy  or  hairy  surfaces.  Surfactant  should  be  added   last.     APPLICATION  OF  AGROSIMPLEX  FORMULA  -­‐  4     1. Add  1  gallon  (4  litres)  of  water  into  clean  spray  tank.     2. Add  1fl.oz  30  mls  of  AgroSimplex  Formula  -­‐  4   3. Mix  solution  thoroughly  before  starting  spray  pump   Thoroughly  wet  all  surfaces  of  plant  including  upper  and  lower  foliage,  stems,  branches   and  stalks  to  ensure  full  contact  with  plant  tissue.   4. Work  from  the  back  of  the  area  identified  through  to  front  to  avoid  brushing  against   plants/trees  which  have  just  been  treated  with  AgroSimplex  Formula  -­‐  4.   5. Spray  product  in  a  wide  circle  around  the  base  of  each  plant/tree.  This  is  to  avoid   spores  being  dispersed  into  the  surrounding  area  whist  treating  the  affected  plants.   6. Spray  the  soil  within  the  circle  around  the  base  of  the  plant.   7. Work  from  bottom  of  plant  to  top  to  ensure  product  does  not  drip  onto  clothing  or   skin  during  application.  Always  wear  eye  protection  to  avoid  accidental  spray  or  drift   into  the  eyes.   8. For  diseases  such  as  coffee  rust  which  affects  the  underside  of  the  leaves  it  is   necessary  to  spray  underneath  the  leaves  to  ensure  contact  with  spores.  Spray  the   topside  of  leaves  for  treatment  of  all  diseases  which  affect  the  top  surface  of  the   plant.   9. Spray  stem  and  overhanging  leaves.   10. Clean  hands  with  disinfectant  wipes  after  removing  gloves  to  ensure  there  is  no   transfer  of  spores  to  non-­‐  infected  areas.  
  • 5.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17     11. For  optimal  results  it  is  recommended  that  initially  crops  should  be  treated  with   AgroSimplex  Formula  -­‐  4  3  times.  AgroSimplex  Formula  -­‐  4  can  be  reapplied  as  soon   as  the  previous  application  has  dried.  Depending  on  climatic  conditions,  altitude,  etc   it  is  possible  to  complete  3  applications  on  the  same  day.  However,  effective   treatment  can  be  obtained  with  only  1  spay  (60-­‐  80%)  to  be  followed  up  with  regular   spraying  of  AgroSimplex  Formula  -­‐  4  as  part  of  the  normal  spraying  protocol.  i.e.  If  at   present,  spraying  is  undertaken  every  2  weeks  for  control  of  disease,  then   AgroSimplex  Formula  -­‐  4  should  be  sprayed  liberally  every  2  weeks  to  ensure  that  the   disease  is  efficiently  controlled  and  to  prevent  spread  of  spores  to  areas  which  are   not  infected.   12. AgroSimplex  Formula  -­‐  17  should  be  sprayed  over  the  top  of  the  plant  and  leaves.  This   can  be  done  anytime    after  as  the  AgroSimplex  Formula  -­‐  4  has  dried.   AgroSimplex  Formula  -­‐  17  is  an  integral  part  of  the  protocol  in  control  and  recovery  of  affected   crops  and  for  optimum  results  should  be  applied  within  days  of  spraying  AgroSimplex  Formula   -­‐  4.   APPLICATION  OF  AGROSIMPLEX  FORMULA  -­‐  17       1. Add  1  gallon  (4  litres)  of    water  into  clean    spray  tank   2. Add  1fl.oz  (30mls)  of  AgroSimplex  Formula  -­‐  17     3. Mix  solution  thoroughly  before  starting  spray  pump   4. Work  from  the  back  of  the  area  to  be  treated  through  to  front  to  avoid  brushing   against  plants/trees  which  have  just  been  treated  with  AgroSimplex  Formula  -­‐  17  .   5. Always  spray  over  the  top  of  plant,  include  all  leaf  surfaces  and  the  soil  underneath.   6. Diluted  product  can  be  stored  maximum  1  week.       It  is  possible  to  add  fertilisers  or  other  adjuvants  to  AgroSimplex  Formula  -­‐  17,  however   where  this  is  done  it  is  always  recommended  that  the  other  additives  are  diluted  prior  to   adding  concentrated  AgroSimplex  Formula  -­‐  17    at  the  same  dosage  as  above.  Mix  well   before  spraying.       THE  AGROSIMPLEX  FORMULA  -­‐  4/AGROSIMPLEX  FORMULA  -­‐  17  REGIME  SHOULD  BE  CARRIED   OUT  EVERY  2-­‐3  WEEKS  TO  ENSURE  EFFECTIVE  CONTROL  OF    INFECTIONS.  THIS  REGIME  WILL   ALSO  MAXIMISE  PLANT  RECOVERY  AND  REGROWTH  .        
  • 6.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17         Material Safety Data Sheet Product  Name:  AgroSimplex  Formula  -­‐  4   Product  description:  Liquid           Product  Use:  Agriculture   Supplier’s  Name:  AgroSimplex   Address:  1313  Ross  Road,  North  Vancouver,  B.C,  Canada     Emergency  Telephone:  +001  778-­‐835-­‐5251                           Emergency  Contact:  Tyler  Mackay   Section 1: Product Information Product Name: Chemical Name: DOT Shipping Name: CAS Registry: Chemical Family: Chemical Formula: Formula Weight: ACGIH: OSHA: AgroSimplex Formula - 4 1 Hydrogen Peroxide 34% & stabilising agents (Trade Secret) UN 2014, Hydrogen Peroxide, Aqueous Solutions, 5.1 (8) PG II 7722-84-1 Inorganic Peroxide H202 34.02 TLV 1 ppm STEL None PEL 1 ppm STEL None
  • 7.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17     Section 2: Health Data Eye Contact: Exposure to the vapors, mists, or liquids can cause severe eye irritation or burns. Flush eyes with a directed stream of water for at least 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of all eyelid tissue. Get immediate attention if irritation occurs. Contact lenses should not be worn when working with this chemical. Skin Contact: Exposure can cause severe skin irritation or burns. Immediately flush skin with water. If the chemical penetrates clothing, immediately remove the clothing and flush the skin with water. Get prompt medical attention if irritation occurs. Wash clothing before reuse. Ingestion: Can cause severe irritation or burns to the entire gastrointestinal tract. Ingestions of large amounts may be fatal. If person is conscious, immediately administer large quantities of water. Never give anything by mouth to an unconscious person. Do not induce vomiting. GET IMMEDIATE MEDICAL ATTENTION. Inhalation: Move the exposed person to fresh air at once. If breathing stops, give artificial respiration. If breathing is difficult, administer oxygen. Seek medical attention if irritation persists. Note to Physician: Direct contact with the eye is likely to cause corneal damage, especially if not washed away immediately. Careful ophthalmologic evaluation is recommended, and the possibility of local corticosteroid therapy should be considered. Attempts at evacuating the stomach via emesis induction or gastric lavage should be avoided. In the event of severe distension of the stomach or esophagus due to gas formation, insertion of a gastric tube may be required. Effects of Overexposure: Contact of the skin with hydrogen peroxide may cause severe skin irritation. Contact of eye may cause eye irritation with tearing or blurring vision and possible blindness. Inhalation may include irritation of the upper respiratory passages, nausea, headache or weakness. Ingestion may include irritation of the gastrointestinal internal tract and abdominal pain or red blood cell destruction.
  • 8.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17     Toxicity: Laboratory Animals: Acute Oral Toxicity: LD50 for different species are in the range of 700mg/kg (90% H202) 9,200mg/kg (70% H202). LC50 for rat is greater than 200mb/m3 (75% H202) Acute Dermal Toxicity Non - Toxic (Rabbit): Primary Skin Irritation Mildly irritating (Rabbit): Primary Eye Irritation Extreme irritation (Rabbit): Carcinogenicity: Non identified NTP: No IARC: No ACGIH: No OSHA: No
  • 9.   AGROSIMPLEX  FORMULA  -­‐  4  AND  AGROSIMPLEX  FORMULA  -­‐  17     Section 3: Fire and Explosion Hazard Data Extinguishing Media: Use water only to fight fire where hydrogen peroxide is involved. Special Fire Fighting Procedure and Personal Protection: Avoid all bodily contact. Wear self-contained breathing apparatus and appropriate protective equipment. In case of external fire, cool hydrogen peroxide and surrounding containers with plenty of water. Unusual Fire and Explosive Hazards: Spontaneous combustion can occur if allowed to remain in contact with oxidizable materials. Drying product in clothing or combustible material may cause fire. Do not heat solution to concentrations of 74% or greater. Do not allow temperature of storage tank to rise above 100° F (38° C). Mixtures with combustible material may be explosive. Flashpoint: Non-Flammable Hazardous Reactivity Stability: Unstable when heated or contaminated with heavy metals, reducing agents, rust, dirt or organic materials. Incompatibility: Incompatible with cyanides, iron, copper and its alloys, hexavalent, chromium compounds, nitric acid, potassium permanganate, reducing agents and other flammables and combustibles. Hazardous Products of Decomposition: Contamination from any source may cause rapid decomposition, oxygen gas release, and dangerous pressures. Polymerization: Will not occur. Section 4: Handling and Storage Precautions: Store in a properly vented container or in approved bulk storage facilities. Do not block vent. Store drums on flame retardant pallets. Do not store where contact with incompatible materials could occur, even with a spill. Have water source available for diluting. Keep containers out of sun and away from heat, sparks, and flames. Do not add any other product to container. Never return any unused product to container. Rinse empty containers thoroughly with clean water before discarding.
  • 10. Section 5: Environmental Protection Procedure in case of spill or release: Obtain full protective equipment, including respiratory protection. Review fire and explosion hazards and safety precautions before proceeding with clean up. Dilute with a large volume of water, and contain runoff until hydrogen peroxide decomposes. Do not allow to escape into sewers or natural watercourses before decomposition. May be destroyed with sodium metabisulfite or sodium sulfite (1.7lbs SO2 equivalent per lb of hydrogen peroxide) after diluting to 5-10% hydrogen peroxide. Care must be exercised because of temperature rise. Waste disposal method: After decomposition, consult with local, state and federal officials, and, subject to their approval, discharge into suitable treatment system. If product is released prior to decomposition, it is termed hazardous waste as defined by 40 CFR261 and would have the following EPA hazardous waste: D001. Section 6: Regulatory Status Sara Title III Section 311/312 classifies hydrogen peroxide as an immediate health hazard and a fire hazard. The minimum threshold quantity for reporting is 10,000 pounds. Extremely Hazardous Substance: No CERCLA Hazardous Substance: No SARA Title III Section 313 Toxic Chemicals: No TSCA Inventory: Yes Process Safety Management: No RISK Management Program: No Section 7: Transportation Data UN 2014, Hydrogen Peroxide, Aqueous Solutions, 5.1 (8) PG II Hydrogen peroxide above 8% concentration is classified as an "oxidizer and corrosive" by the DOT and must be labeled accordingly.    
  • 11. 11       Document  prepared  by  Dr.  H.E.  Keenan   30th  July  2014   MATERIAL SAFETY DATA SHEET (MSDS)     Date  MSDS  Prepared  26/1/2014                             24  Hour  Emergency  Contacts   Revision  Number  1:  Revised  July  2014                                                Tyler  Mackay  +001  778-­‐835-­‐5251     MSDS  Prepared  By:  Dr  H  Keenan  Cchem  Csci  MRSC                       Phone  Number  +4407944706642   SECTION  1  —  CHEMICAL  PRODUCT  AND  COMPANY  IDENTIFICATION   Product  Name:  AgroSimplex  Formula  -­‐  17     Product  description:  Mixture          Product  Use:  Plant  Stimulant   Manufacturer’s  Name:  AgroSimplex     Supplier’s  Name:  AgroSimplex   Address:  1313  Ross  Road,  North  Vancouver,  BC,  Canada            Emergency  Telephone:    +001  778-­‐835-­‐5251         SECTION 2 — COMPOSITION / INFORMATION ON INGREDIENTS Product Description : Liquid Mixture This Mixture is claimed as a Trade Secret and as such the composition is withheld. Registered as International Class 001- Substances for regulating plant growth. However it is disclosed that the mixture is a combination of several chemicals at different concentrations. Active Ingredients INGREDIENT Quantity Volume % OSHA PEL ACGIH TLV 1 <10% 3ppm, 6 mg/m3 3ppm 2 <10% Not Listed Not Listed 3 20-40% Not Listed Not Listed 4 2-5% Not Listed Not Listed 5 10-15% Not Listed Not Listed 6 <10% Not Listed Not Listed
  • 12. 12       Document  prepared  by  Dr.  H.E.  Keenan   30th  July  2014   SECTION 3 — HAZARDS IDENTIFICATION Potential Health Effects OSHA regulatory Status: This mixture is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) SECTION 4 — FIRST AID MEASURES Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water. Call a Poison Control Centre or Doctor for further treatment advice. Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20mins. Remove contact lenses, if present after first 5 minutes then continue rinsing the eye. Call a Poison Control Centre or Doctor for further treatment advice. Inhalation: Move to Fresh air. If person not breathing call emergency doctor or ambulance, then give artificial respiration (mouth to mouth if possible) until assistance arrives. Call a Poison Control Centre or Doctor for further treatment advice. Ingestion: Have person sip a glass of water if able to swallow. Do NOT induce vomiting. Do not give anything by mouth to an unconcious person. Call a Poison Control Centre or Doctor for further treatment advice. SECTION 5 — FIRE FIGHTING MEASURES   Flammable ❐Yes ☑ No If yes, under which conditions? Means of Extinction Water spray, carbon dioxide, fine-earth or sand. Flashpoint (° C) and Method Not Determined Upper Flammable Limit (% by volume) Not Determined Lower Flammable Limit (% by volume) Not Determined Autoignition Temperature (°C) Not Determined Explosion Data — Sensitivity to Impact Not Determined Explosion Data — Sensitivity to Static Discharge Not Determined Hazardous Combustion Products Not Determined   SECTION 6 — ACCIDENTAL RELEASE MEASURES General Procedures: Extinguish all ignition sources. Flush area with water.
  • 13. 13       Document  prepared  by  Dr.  H.E.  Keenan   30th  July  2014     If checked, please specify type Safety Glasses with side shield are recommended when handling undiluted Product. Disposable gloves. Overall or apron.     SECTION 7 — HANDLING AND STORAGE General Procedures: Rinse all equipment after use. All rinse water can be applied as product. Handling: Wear Safety Goggles and Gloves when working with undiluted product. Wash hands with water after handling product. Storage: Store in a cool dry area in closed container. Keep in original container, do not reuse container for consumables. KEEP OUT OF REACH OF CHILDREN. Diluted product is safe for handling without personal protective equipment. SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits: ACGIH TLV Applies to pure chemical. This product is a mix in which <10% is present therefore it is unlikely TLV will be exceeded. ☑ ACGIH TLV ❐ OSHA PEL ❐ Other (specify) Specific Engineering Controls (such as ventilation, enclosed process) Ensure adequate ventilation during dilution. Personal Protective Equipment ☑ Gloves ❐ Respirator ☑ Eye ❐ Footwear ☑ Clothing ❐ Other SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Odour and Appearance Alcohol/amine smell, slightly viscous green/yellow liquid Odour Threshold (ppm) Not Determined Specific Gravity 1.03-1.05 Not Determined Vapour Density (air = 1) Not Determined Vapour Pressure (mmHg) Not Determined Evaporation Rate Not Determined Boiling Point (° C) Not Determined Freezing Point (° C) Not Determined pH 9.9-10.2 Coefficient of Water/Oil Distribution Not Determined [Solubility in Water] 100%   SECTION 10 — STABILITY AND REACTIVITY Stability: Stable Reactivity, and under what conditions? Not Determined. Hazardous Decomposition Products: None
  • 14. 14       Document  prepared  by  Dr.  H.E.  Keenan   30th  July  2014   SECTION 11 — TOXICOLOGICAL INFORMATION The Toxicological information is based on the individual ingredients in the product. The dilution effect must be taken into consideration when considering the toxicology of the mixture that is AgroSimplex Formula - 17 . Carcinogenicity: IARC: No NTP: No OSHA: No This product contains Ingredient 1 at a concentration of <10%. This chemical has a stated occupational exposure limit (ACGIH, OSHA) of 3ppm or 6 mg/m3 . However the volatility and effect of this chemical is much reduced by dilution, and therefore the stated level would be difficult to achieve. This product (AgroSimplex Formula - 17) should also be diluted prior to use and the final concentration of AgroSimplex Formula - 17 is < 0.5% when diluted at recommended rates. SECTION 12 — ECOLOGICAL INFORMATION [Aquatic Toxicity] The active ingredients 1,2 & 5 were all considered below criteria for persistence, bioaccumulation and toxicity. i.e. they are non persistent, non bioaccumulative & non toxic. (http://www.pbtprofiler.net/default.asp see http://www.pbtprofiler.net/Details.asp for criteria) Ingredient 3 cannot be modelled due to insolubility, it is however a naturally derived ingredient. The MSDS supplied with the chemical shows no toxicity (all values >1000mg/l fish & daphnia) and states that it is readily biodegradeable. Ingredient 4 cannot be modelled as it has no entry in database, however the MSDS shows no toxicity and states that it is readily biodegradable. This product (AgroSimplex Formula - 17 ) is highly beneficial to plant life and there are no known adverse effects on aquatic life. A Full Ecological Assessment is available on request. SECTION 13 — DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Waste disposal must be in accordance with Federal, state, and local regulations. Be aware that the waste owner has responsibility for final disposal. Regulations may also apply to empty containers. This material can be safely disposed to drain, flush with plenty of water. SECTION 14 — TRANSPORT INFORMATION This product is non hazardous by the OSHA classification as set out in document https://www.osha.gov/dsg/hazcom/ghs.html#3.0 Not DOT/ ICAA/ IMDG regulated.      
  • 15. 15       Document  prepared  by  Dr.  H.E.  Keenan   30th  July  2014     SECTION 15 — REGULATORY INFORMATION NA Fire:No Pressure Generating:No Reactivity:No Acute:No Chronic:No   SECTION 16 — OTHER INFORMATION REVISION  SUMMARY:  Revised  July  2014  New  MSDS