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Geometric
Isomers
Sarah Gilbert
two isomers for 2-butene
• Cis-: “on the near side of”
• Trans-: “across, beyond, transverse”
• These are almost the same the only difference is
whether the fourth carbon added goes on the
same side as the third or not.
• Chemical formula is C4H8
• Average molar mass 56.11 g/mol
Cis-2-butene
• Same line
formula as
trans-2-butene
Trans-2-butene
Extra Fact
• This is the most simple alkene
showing cis/trans isomerism,
meaning it exists as two geometric
isomers.
• They are very difficult to separate by
distillation due to their close boiling
points
Summary
• Double bonds can not rotate due to the strength
of their bonds, but single bonds can because they
have less connection.
• Even though these two isomers have the same
formula they are very different structures with
different names.

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Geometric isomers

  • 2. two isomers for 2-butene • Cis-: “on the near side of” • Trans-: “across, beyond, transverse” • These are almost the same the only difference is whether the fourth carbon added goes on the same side as the third or not. • Chemical formula is C4H8 • Average molar mass 56.11 g/mol
  • 5. Extra Fact • This is the most simple alkene showing cis/trans isomerism, meaning it exists as two geometric isomers. • They are very difficult to separate by distillation due to their close boiling points
  • 6. Summary • Double bonds can not rotate due to the strength of their bonds, but single bonds can because they have less connection. • Even though these two isomers have the same formula they are very different structures with different names.