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POLYMER
WHAT IS POLYMER?


POLYMER IS A MARCOMOLECULE WHICH
ARE JOINED TOGTHER BY SMALL
MOLECULE.



EXAMPLE: POLYETHYLENE
HEAT
n CH2=CH2

ETHYLENE
CATALYST
POLYETYLENE

(CH-CH2)
CHARACTERISTICS OF POLYMER


LOW DENSITY



GOOD MOULDABILITY



GOOD CORROSION RESISTANCE



POOR TENSILE STRENGTH



LOW MECHANICAL PROPERTIES



POOR TEMPERATURE RESISTANCE
CLASSIFICATION OF POLYMER


POLYMERS ARE MAINLY CLASSIFIED
INTO TWO TYPES
NATURAL POLYMER
SYNTHETIC POLYMER
NATURAL POLYMER


NATURAL POLYMER ARE THE POLYMER
EXIST AS NATURAL RESOURCE



SUCH AS CELLOUSE WHICH IS THE MAIN
CONSITUTENT OF WOOD AND PAPER.



EXAMPLES:CELLOUSE
AMINO ACIDS etc..,
SYNTHETIC POLYMER
POLYMER MADE BY ARTIFICIALLY USING
CHEMICAL ARE CALLED AS SYNTHETIC
POLYMERS.
 EXAMPLE:BAKELITE
NEOPRENE
NYLON
POLYVINYL CHOLRIDE
POLYSTYRENE

NYLON 6-6


IT IS OTBTAINED BY POLYMERIZATION OF
HEXAMETHYLENE DIAMINE AND ADIPIC
ACID.
PROPERTIES
NYLON 6:6 IS LESS SOFT AND STIFF
MATERIAL.
 THEY BEHAVE AS PLASTIC AS WELL AS
FIBER.
 THAY HAVE GOOD MECHANICAL
STRENGTH.
 HIGH ABRASION RESISTANCE.

USES
USED IN FIBERS IN MAKING
SCOKS,DRESSES etc.,
 USED IN MOULDING PURPOSE FOR
MAKING GEAR.
 USED FOR MAKING FILAMENTS IN
TOOTH BRUSHES.

EPOXY RESIN


IT IS PREPARED BY CONDENSING
EPICHLOROHYDRIN WITH BISPHENOL.
PROPERTIES
HIGHLY CHEMICAL RESISTANCE TO
WATER,ACIDICS,ALKALIS AND OTHER
CHEMICALS.
 THEY ARE FLEXIBLE AND TOUGH.
 POSSES VERY GOOD HEAT
RESISTANCE.
 POSSES EXCELLENT ADHESION
QUALITY.

USES
EPOXY RESIN ARE USED AS SURFACE
COATINGS AND ADHESIVE.
 USED AS LAMINATING MATERIAL IN
ELECTRICAL EQUIPMENTS.
 USED FOR THE PRODUCTION OF
COMPONENTS FOR AIRCRAFTS AND
AUOTMOBLIES.

MECHANISM OF ADDITION
POLYMERIZATION


IT CAN BE EXPLAINED BY THE TWO
FOLLOWING METHODS
FREE RADICAL

MECHANISM
IONIC RADICAL

MECHANISM
FREE RADICAL


IT OCCURS IN THREE STEPS
INITIATION

PROPAGATION
TERMINATION
INTIATION
 PRODUCTION OF FREE RADICAL BY
HOMOLYTIC DISSOCIATION.
I

2R0
INTIATOR
FREE RADICAL
 ADDITION OF FREE RADICAL TO THE
FIRST MONOMER.

PROPAGATION
 GROWTH OF CHAIN INTIATING
SPECIES

TERMINATION
 COUPLING
 INVOLVES COUPLING OF FREE RADICAL
ONE CHAIN END TO ANOTHER.

DISPROPORTIONATION
 INVOLVES TRANSFER OF HYDROGEN
ATOM OF ONE RADICAL CENTRE TO
ANOTHER,FORMING SATURATED AND
UNSATURATED MOLECULE.

IONIC MECHANISN


IT IS INITIATED BY A POSITIVE ION AND
NEGATIVE ION.
CATIONIC POLYMERIZATION
ANIONIC POLYMERIZATION
CATIONIC POLYMERISATION


IT TAKES PLACE WHEN ELECTRON
DONATING GROUPS LIKE PRESENT IN
MONOMER.

THESE GROUPS STABILISE THE
CABONIUM ION FORMATION.
STYRENE
INTIATOR USED TO INTIATE THE
REACTION ARE



INTIATOR
PROPAGATION
 IT INOLVES THE GROWTH OF CHAIN
INITIATING SPECIES.

TERMINATION
 IT INVOLVES THE REMOVAL OF
CATALYST BY THE ADDITION OF PROTON

ANIONIC POLYMERIZATION
IT TAKE PLACE WHEN ELECTRON
WITHDRAWING
GROUP LIKE ()PRESENT IN MONOMER.


THESE GROUP STABILISE CARBANION
FORMATION.
ACRYLONITRILE
INITIATOR USED TO INITIATE THE REACTION
ARE LEWIS BASES LIKE()

INTIATION
IT INVOLVES THE FORMATION OF CHAIN
INITIATING SPECIES.
PROPAGATION
 IT INVOLVES THE GROWTH OF CHAIN
INTIATING SPECIES.

TERMINATION
IT OCCURS BY ADDING AMMONIA.


Presented by
dhayanidhi.e
gokul.s
amarnath.a
MUTHAYAMMAL ENGINEERING COLLEGE
RASIPURAM
NAMAKKAL

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Polymers in simple