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Argentium Silver and
Firescale Prevention
A Note on Impurities and Alloys
• Whether for jewelry or industry, precious
metals can contain impurities for
different reasons.
• Sometimes impurities are naturally
occurring, and other times they are
added to create an alloy with new
aesthetics or “features” that pure
precious metals don’t have.
• Argentium sterling silver is one such alloy.
Makeup of Argentium Silver
• Argentium silver was patented in the early ‘90s by
Argentium Silver Company in the UK.
• This alloy is just like normal sterling silver except for
one small difference: germanium.
• While sterling silver is about 92.5% silver and 7.5%
copper, Argentium sterling silver replaces a small
amount of the copper (about 1.2%) with germanium.
Properties of Argentium Silver
The addition of germanium to the alloy confers
several beneficial new properties, including:
• Firestain / Firescale elimination
• Better tarnish resistance
• Precipitation hardening / heat-hardening
properties
• Increased ductility
• Increased thermal and electrical resistance
Argentium Silver 960
• The addition of germanium can benefit other silver
alloys as well.
• Another alloy, Argentium Silver 960, is just like
Britannia Silver in terms of silver
purity.
• As with Argentium sterling silver,
some of the copper is replaced
with germanium.
The Problem of Firescale
• Firescale is a dark discoloration on silver caused by
heating.
• Firescale is a serious cosmetic problem that inhibits the
work of many jewelry craftsman.
• The only way to fix an unsightly firescale is to either
buff it off with acids or abrasives, remove the
affected silver, or plate over it with a fresh layer of
silver.
Firescale Explained
• The reason why silver alloys are vulnerable to firescale
is because of their copper content.
• As the silver is heated, it allows oxygen molecules to
pass through.
• This causes the copper to oxidize well below the surface –
creating firescale that is difficult to remove.
• Germanium can prevent firescale because it oxidizes
preferentially to the copper.
• Unlike copper, germanium oxide is transparent and does not
discolor the silver.
How to Prevent Firescale
• When Argentium silver is heated, the germanium
oxidizes creating a transparent layer that protects the
copper in the alloy from oxygen exposure.
• Without that exposure, copper oxide never forms and
firescale never appears.
• Since germanium oxide is self-regenerating, the alloy is
permanently protected from firescale – making it a
superior coating compared to rhodium, which will wear
away eventually.
About MGS
Manhattan Gold & Silver (MGS) is a precious metals refiner that has been based in
Manhattan’s historic Diamond District since 1985. We are a B2B company that
buys and recycles precious metal scraps that accumulate in other businesses.
We serve:
• Jewelers
• Pawnbrokers
• Dentists
• The industrial sector
• Antique dealers
• Machinists
• Domestic mining
• And more!
• MGS also creates charts, calculators, and other online tools for our customers to
use.
• Try our Precious Metals Prices app, which lets you monitor the real-time precious metals
market situation from anywhere, right from your iPhone, iPad, or Android device.
Recycle your Precious
Metals for Profit
• MGS accepts gold, silver, platinum, and palladium.
• Payouts are based on the London Fixing.
• Up to 99% payout (among the highest in the US)
• Up to 98.5% for gold brought in for hand testing.
• Not in NYC? Ship us your precious metals using our Ship &
Sell service which offers:
• Same day wired payment (once lot is received)
• Discounted, insured shipping
• Payout calculator
Connect with MGS
• For amazing facts, history and news, read our gold and precious metals blog.
• Join the conversation about precious metals on the MGS page on Facebook.
• Follow gold, silver, and other precious metal trends at the MGS Twitter account.
• Circle MGS on Google+ to hear our latest updates.
• If you do business with us, connect with us on the MGS LinkedIn page.
• To see precious metal melting and refinement in action, visit the MGS YouTube
channel.

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Argentium Silver and Firescale Prevention

  • 2. A Note on Impurities and Alloys • Whether for jewelry or industry, precious metals can contain impurities for different reasons. • Sometimes impurities are naturally occurring, and other times they are added to create an alloy with new aesthetics or “features” that pure precious metals don’t have. • Argentium sterling silver is one such alloy.
  • 3. Makeup of Argentium Silver • Argentium silver was patented in the early ‘90s by Argentium Silver Company in the UK. • This alloy is just like normal sterling silver except for one small difference: germanium. • While sterling silver is about 92.5% silver and 7.5% copper, Argentium sterling silver replaces a small amount of the copper (about 1.2%) with germanium.
  • 4. Properties of Argentium Silver The addition of germanium to the alloy confers several beneficial new properties, including: • Firestain / Firescale elimination • Better tarnish resistance • Precipitation hardening / heat-hardening properties • Increased ductility • Increased thermal and electrical resistance
  • 5. Argentium Silver 960 • The addition of germanium can benefit other silver alloys as well. • Another alloy, Argentium Silver 960, is just like Britannia Silver in terms of silver purity. • As with Argentium sterling silver, some of the copper is replaced with germanium.
  • 6. The Problem of Firescale • Firescale is a dark discoloration on silver caused by heating. • Firescale is a serious cosmetic problem that inhibits the work of many jewelry craftsman. • The only way to fix an unsightly firescale is to either buff it off with acids or abrasives, remove the affected silver, or plate over it with a fresh layer of silver.
  • 7. Firescale Explained • The reason why silver alloys are vulnerable to firescale is because of their copper content. • As the silver is heated, it allows oxygen molecules to pass through. • This causes the copper to oxidize well below the surface – creating firescale that is difficult to remove. • Germanium can prevent firescale because it oxidizes preferentially to the copper. • Unlike copper, germanium oxide is transparent and does not discolor the silver.
  • 8. How to Prevent Firescale • When Argentium silver is heated, the germanium oxidizes creating a transparent layer that protects the copper in the alloy from oxygen exposure. • Without that exposure, copper oxide never forms and firescale never appears. • Since germanium oxide is self-regenerating, the alloy is permanently protected from firescale – making it a superior coating compared to rhodium, which will wear away eventually.
  • 9. About MGS Manhattan Gold & Silver (MGS) is a precious metals refiner that has been based in Manhattan’s historic Diamond District since 1985. We are a B2B company that buys and recycles precious metal scraps that accumulate in other businesses. We serve: • Jewelers • Pawnbrokers • Dentists • The industrial sector • Antique dealers • Machinists • Domestic mining • And more! • MGS also creates charts, calculators, and other online tools for our customers to use. • Try our Precious Metals Prices app, which lets you monitor the real-time precious metals market situation from anywhere, right from your iPhone, iPad, or Android device.
  • 10. Recycle your Precious Metals for Profit • MGS accepts gold, silver, platinum, and palladium. • Payouts are based on the London Fixing. • Up to 99% payout (among the highest in the US) • Up to 98.5% for gold brought in for hand testing. • Not in NYC? Ship us your precious metals using our Ship & Sell service which offers: • Same day wired payment (once lot is received) • Discounted, insured shipping • Payout calculator
  • 11. Connect with MGS • For amazing facts, history and news, read our gold and precious metals blog. • Join the conversation about precious metals on the MGS page on Facebook. • Follow gold, silver, and other precious metal trends at the MGS Twitter account. • Circle MGS on Google+ to hear our latest updates. • If you do business with us, connect with us on the MGS LinkedIn page. • To see precious metal melting and refinement in action, visit the MGS YouTube channel.