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Installation of Fire
Suppression in Gloveboxes
    Michael E. Cournoyer
   and Donivan R. Porterfield
       LAUR 12-20121
LANL Mission Is National
          Security
•  We develop and apply
   science and technology to
  –  Ensure the safety and reliability
     of United States nuclear
     deterrent
  –  Reduce the threat of weapons
     of mass destruction,
     proliferation, and terrorism; and
  –  Solve national problems
     regarding defense, energy,
     environment, and infrastructure.
Typical Glovebox Train"
The Evolution
•  Both NFPA 801 and DOE
   Standard 1066, “Fire
   Protection Design Criteria”,
   require fire suppression to
   be installed in gloveboxes
•  During the design phase of
   a multi-station waste
   processing box we were
   tasked to provide
   recommendations for fire
   suppression system.
Other Suppression Systems
•  We looked at numerous fire suppression, or fire
   mitigation systems.
   –  Water-based
       •  Inexpensive to procure and install
       •  Reliable
       •  Generate large volume of water that may
          be difficult to dispose of
       •  Loss of containment
       •  Criticality issues
Other Suppression Systems
•  Dry Chemical
  –  Expensive to procure and install
  –  Reliable
  –  Expansion of confinement boundary
•  Inertion
  –  Expensive to procure and install
  –  Reliable
Seismic Reliability
•  Water-based
    –  Water supply may be affected by a seismic
       event
•  Dry Chemical
    –  Storage cylinder and distribution piping may
       be compromised seismic event
    –  Response time of the initiating device may
       be adversely affected by a seismic event
•  Inertion
    –  Inerting may be compromised or lost in by a
       seismic event
Automatic Fire Extinguisher




•  Our efforts led us to an automatic clean agent
   fire extinguisher
    –  U.L. Listed (U.L. 2166) for Class B and C
       fires
Envirogel Extinguishing Agent
•  Contents of fire extinguisher:
   –  FE-25 & FE-36
   –  Sodium bicarbonate powder
   –  Charged with an inert gas to 100 psi
•  Manufactures inquiries
   –  Extinguisher is currently utilized for Class A
      applications
   –  Confident fire test would prove extinguisher’s
      ability to successfully extinguish class A fires
   –  U.L. 2166 Class A fire test enclosure volume
      ~3500 cu.ft.
Automatic Fire Extinguisher
•    Self contained and compact
•    Activated by temperature
•    Bolt-on simplicity
•    No mechanical, electrical, or battery systems
     required
•    Rugged construction and maintenance free
•    The extinguisher reacts to all fires
•    Installation and orientation
•    Volume protected
Automatic Fire Extinguisher
•  Extinguisher is vibration and corrosion resistant
•  UL approved for 130 cu.ft. enclosures and
   NRTL Certified for 250 cu.ft. enclosures
•  Airflow
•  Automatic Extinguisher
   –  Extinguisher not affected by a seismic event
   –  Redundancy of extinguishers would yield an
      extinguisher at the top of the glovebox
Operational Impact
•  Cleanup is simple and
   yield significantly less
   waste than water
   based fire suppression
   systems
•  Minimizes
   environmental impact
•  Return to service
Path Forward
•  Test Protocol
•  Proof-of-Concept
   Testing
•  Nationally
   Recognized Testing
   Laboratory (NRTL)
   Certification Testing
Proof-of-Concept
    Testing
Pressure Profile
                                 Glovebox Pressure Profile - Test 6
                    4
                                             Extinguisher tube activated at Time = 3:42 min
                    2


                    0
Pressure (in WC)




                    -2


                    -4


                    -6


                    -8


                   -10


                   -12
                         0   1     2     3          4         5        6         7        8   9

                                                   Time (min)
Temperature Profile
                             Glovebox Temperatures Profile − Test 6

                   600



                   500
Temperature (ºC)




                   400



                   300



                   200



                   100



                     0
                         0        1     2      3          4          5          6   7   8   9

                                                   Time (min)

                                                   TC 1       TC 3       TC 5
Test Protocol
•  Lack of industry
   standard fire test
•  Test Protocol
  – Structured for our
    application
Collaboration with UT"
•  Collaborated with the
   Mechanical Engineering
   Department of the
   University of Texas at
   Austin continues
•  This effort is lead by
   Professor Sheldon
   Landsberger and Ofodike
   A. Ezekoye
Experiments"
•  Alpha experiments - Curium Source
  –  10 microcuries on 3/1/98
  –  18.11 year half-life
  –  5 mm active area diameter
•  Neutron experiments
  –  Irradiation 4+ months of glove samples
  –  Tensile testing
•  More neutron experiments
  –  5 Ci PuBe homogeneous neutron source
  –  Duration: 2 months
Fire Modeling
       While LANL glovebox systems are designed and
       operated with fire safety goals in mind,
       suppression systems that meet strict reliability
       requirements are integral parts of the overall fire
       protection system for these systems.

       Our project goal is to use calibrated and validated
       fire and mechanical modeling tools to understand
       the operating characteristics of the QuickFire Fire
       Foe suppression system for gloveboxes.


http://www.quick-fire.com/products-01.asp
Research Framework
Small-Scale Filled Nylon-6 Tube
         Experiments
Development of Computational
           Model




Schematic of small-scale FDS    Gas temperature slice in
     geometry setup            small-scale FDS glovebox
Heat Release Rate Characterization
A fire of unknown size occurs…


                                        The compartment is
                                        instrumented with
                                        thermocouples.

                                                     What HRR
               Temperature




                                                     would cause
                                                     those
                                                     temperature
                                                     profiles?

                                 Time

                                                We use inversion.
Model Calibration to Experiment




      Experimental
      thermocouple
                           Gas temperature
temperatures compared
                          slice in small-scale
  to FDS thermocouple
                             FDS glovebox
   temperatures in the
 small-scale experiment
Analytical Heat Transfer Model

•  Fire Foe is modeled as a cylinder under
   constant, uniform radiative heat flux.
•  Forced convection with constant heat
   transfer coefficient.
•  Specific heat and density do not vary with
   temperature.
CFD Prediction of Heat Flux




Time sequence of net heat flux of Fire Foe tube in
            the small-scale case
Finite Element Analysis Tools

•  SolidWorks Software – Finite element
   analysis of Nylon 6-6 tube
•  LibMesh – Open-source finite element
   solver
Simulations
•  Variables
  –  Size of glove box
  –  Intensity of fire
  –  Location of fire suppression system
  –  Location of vent hood
  –  Location of glass
•  Results
  –  Is the Fire Foe system reliable for all cases?
  –  Optimal location for Fire Foe system
  –  Worst-case scenario
Testing Results Summary
•  This result shows that even at a relatively low
   internal temperature of approximately 150 °C,
   the internal pressure and the relative loss of
   strength of the PA66 will likely result in failure of
   the tube.
•  As more detailed modeling of the PA66 failure
   process takes place, we will use data from
   Kohan on the elongation (%) at break and at
   yield for PA66. Kohan presents data at 23 °C
   and 77 °C for tensile strength, tensile yield
   strength, elongation at break, and elongation at
   yield.
Collaboration with MSU"
•  Collaborated with the
   Mechanical Engineering
   Department of the Montana
   State University.
•  This effort is lead by
   Professor David A. Miller
Tensile Testing"
•  Test Resources 1000R
   tensile testing machine
   was used to evaluate
   mechanical properties.
•  Maximum stress and
   strain are reported from
   industry standard tensile
   test - ASTM 1708
Summary
•  The extinguisher has been independently
   certified to successfully extinguish Class A, B,
   and C fires, based on LANL test criteria.
•  The extinguisher presents the most reliable
   means of suppression in a post seismic event
•  Installation of the extinguisher will satisfy DOE
   and NFPA requirements for automatic fire
   suppression in gloveboxes.
•  A computational fire model is being developed to
   predict fire extinguisher activation time for a wide
   range of fire inputs and glovebox configurations.
•  Any questions?
Acknowledgements"
•  The authors would like to acknowledge the
   Department of Energy and LANL's Plutonium
   Science & Manufacturing; Chemistry, Life, and
   Earth Sciences; Engineering and Engineering
   Sciences; and Nuclear & High Hazard Operations
   Directorates, for support of this work.

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Fire foe

  • 1. Installation of Fire Suppression in Gloveboxes Michael E. Cournoyer and Donivan R. Porterfield LAUR 12-20121
  • 2. LANL Mission Is National Security •  We develop and apply science and technology to –  Ensure the safety and reliability of United States nuclear deterrent –  Reduce the threat of weapons of mass destruction, proliferation, and terrorism; and –  Solve national problems regarding defense, energy, environment, and infrastructure.
  • 4. The Evolution •  Both NFPA 801 and DOE Standard 1066, “Fire Protection Design Criteria”, require fire suppression to be installed in gloveboxes •  During the design phase of a multi-station waste processing box we were tasked to provide recommendations for fire suppression system.
  • 5. Other Suppression Systems •  We looked at numerous fire suppression, or fire mitigation systems. –  Water-based •  Inexpensive to procure and install •  Reliable •  Generate large volume of water that may be difficult to dispose of •  Loss of containment •  Criticality issues
  • 6. Other Suppression Systems •  Dry Chemical –  Expensive to procure and install –  Reliable –  Expansion of confinement boundary •  Inertion –  Expensive to procure and install –  Reliable
  • 7. Seismic Reliability •  Water-based –  Water supply may be affected by a seismic event •  Dry Chemical –  Storage cylinder and distribution piping may be compromised seismic event –  Response time of the initiating device may be adversely affected by a seismic event •  Inertion –  Inerting may be compromised or lost in by a seismic event
  • 8. Automatic Fire Extinguisher •  Our efforts led us to an automatic clean agent fire extinguisher –  U.L. Listed (U.L. 2166) for Class B and C fires
  • 9. Envirogel Extinguishing Agent •  Contents of fire extinguisher: –  FE-25 & FE-36 –  Sodium bicarbonate powder –  Charged with an inert gas to 100 psi •  Manufactures inquiries –  Extinguisher is currently utilized for Class A applications –  Confident fire test would prove extinguisher’s ability to successfully extinguish class A fires –  U.L. 2166 Class A fire test enclosure volume ~3500 cu.ft.
  • 10. Automatic Fire Extinguisher •  Self contained and compact •  Activated by temperature •  Bolt-on simplicity •  No mechanical, electrical, or battery systems required •  Rugged construction and maintenance free •  The extinguisher reacts to all fires •  Installation and orientation •  Volume protected
  • 11. Automatic Fire Extinguisher •  Extinguisher is vibration and corrosion resistant •  UL approved for 130 cu.ft. enclosures and NRTL Certified for 250 cu.ft. enclosures •  Airflow •  Automatic Extinguisher –  Extinguisher not affected by a seismic event –  Redundancy of extinguishers would yield an extinguisher at the top of the glovebox
  • 12. Operational Impact •  Cleanup is simple and yield significantly less waste than water based fire suppression systems •  Minimizes environmental impact •  Return to service
  • 13. Path Forward •  Test Protocol •  Proof-of-Concept Testing •  Nationally Recognized Testing Laboratory (NRTL) Certification Testing
  • 14. Proof-of-Concept Testing
  • 15. Pressure Profile Glovebox Pressure Profile - Test 6 4 Extinguisher tube activated at Time = 3:42 min 2 0 Pressure (in WC) -2 -4 -6 -8 -10 -12 0 1 2 3 4 5 6 7 8 9 Time (min)
  • 16. Temperature Profile Glovebox Temperatures Profile − Test 6 600 500 Temperature (ºC) 400 300 200 100 0 0 1 2 3 4 5 6 7 8 9 Time (min) TC 1 TC 3 TC 5
  • 17. Test Protocol •  Lack of industry standard fire test •  Test Protocol – Structured for our application
  • 18. Collaboration with UT" •  Collaborated with the Mechanical Engineering Department of the University of Texas at Austin continues •  This effort is lead by Professor Sheldon Landsberger and Ofodike A. Ezekoye
  • 19. Experiments" •  Alpha experiments - Curium Source –  10 microcuries on 3/1/98 –  18.11 year half-life –  5 mm active area diameter •  Neutron experiments –  Irradiation 4+ months of glove samples –  Tensile testing •  More neutron experiments –  5 Ci PuBe homogeneous neutron source –  Duration: 2 months
  • 20. Fire Modeling While LANL glovebox systems are designed and operated with fire safety goals in mind, suppression systems that meet strict reliability requirements are integral parts of the overall fire protection system for these systems. Our project goal is to use calibrated and validated fire and mechanical modeling tools to understand the operating characteristics of the QuickFire Fire Foe suppression system for gloveboxes. http://www.quick-fire.com/products-01.asp
  • 22. Small-Scale Filled Nylon-6 Tube Experiments
  • 23. Development of Computational Model Schematic of small-scale FDS Gas temperature slice in geometry setup small-scale FDS glovebox
  • 24. Heat Release Rate Characterization A fire of unknown size occurs… The compartment is instrumented with thermocouples. What HRR Temperature would cause those temperature profiles? Time We use inversion.
  • 25. Model Calibration to Experiment Experimental thermocouple Gas temperature temperatures compared slice in small-scale to FDS thermocouple FDS glovebox temperatures in the small-scale experiment
  • 26. Analytical Heat Transfer Model •  Fire Foe is modeled as a cylinder under constant, uniform radiative heat flux. •  Forced convection with constant heat transfer coefficient. •  Specific heat and density do not vary with temperature.
  • 27. CFD Prediction of Heat Flux Time sequence of net heat flux of Fire Foe tube in the small-scale case
  • 28. Finite Element Analysis Tools •  SolidWorks Software – Finite element analysis of Nylon 6-6 tube •  LibMesh – Open-source finite element solver
  • 29. Simulations •  Variables –  Size of glove box –  Intensity of fire –  Location of fire suppression system –  Location of vent hood –  Location of glass •  Results –  Is the Fire Foe system reliable for all cases? –  Optimal location for Fire Foe system –  Worst-case scenario
  • 30. Testing Results Summary •  This result shows that even at a relatively low internal temperature of approximately 150 °C, the internal pressure and the relative loss of strength of the PA66 will likely result in failure of the tube. •  As more detailed modeling of the PA66 failure process takes place, we will use data from Kohan on the elongation (%) at break and at yield for PA66. Kohan presents data at 23 °C and 77 °C for tensile strength, tensile yield strength, elongation at break, and elongation at yield.
  • 31. Collaboration with MSU" •  Collaborated with the Mechanical Engineering Department of the Montana State University. •  This effort is lead by Professor David A. Miller
  • 32. Tensile Testing" •  Test Resources 1000R tensile testing machine was used to evaluate mechanical properties. •  Maximum stress and strain are reported from industry standard tensile test - ASTM 1708
  • 33. Summary •  The extinguisher has been independently certified to successfully extinguish Class A, B, and C fires, based on LANL test criteria. •  The extinguisher presents the most reliable means of suppression in a post seismic event •  Installation of the extinguisher will satisfy DOE and NFPA requirements for automatic fire suppression in gloveboxes. •  A computational fire model is being developed to predict fire extinguisher activation time for a wide range of fire inputs and glovebox configurations. •  Any questions?
  • 34. Acknowledgements" •  The authors would like to acknowledge the Department of Energy and LANL's Plutonium Science & Manufacturing; Chemistry, Life, and Earth Sciences; Engineering and Engineering Sciences; and Nuclear & High Hazard Operations Directorates, for support of this work.