2. INTRODUCTION
Nanofiber is any fiber with dimensions within the nano
range(i.e., < 100nm)
Nanofibers are created by a process called Electrospinning
Main advantage of nanofiber: High surface to volume ratio
Electrospinning uses an electrical charge to draw very fine
(typically on the micro or nano scale) fibres from a liquid
3. ELECTROSPINNING
Electrospinning is a fiber production method which uses
electric force to draw charged threads of polymer solutions
or polymer melts up to fiber diameters in the order of some
hundred nanometers.
Strong mutual electrical repulsive forces overcome
weaker forces of surface tension in the charged polymer
liquid.
Principle:
4. ELECTROSPINNING SETUP
1. A high voltage power supply (between 10 and
30kV)
2. A polymer reservoir that can maintain a
constant flow rate of solution
3. A conductive needle as polymer source
connected to the high voltage power supply
4. A conductive collector(Plate, drum, etc.)
5. PROCESS
• A polymer is dissolved in a suitable solvent
• Polymer solution is filled in the capillary reservoir.
• An electrostatic potential is applied between a spinneret and a
collector.
• The droplet is held by its own surface tension at the
spinneret tip.
• When the electric field reaches a critical value, the repulsive
electrical forces overcomes the fluid surface tension.
• The droplet becomes unstable, and a liquid jet is ejected:-
Taylor Cone
6. The distribution of charge in the fiber changes as the fiber
dries out during eruption:
7. PARAMETERS
• Molecular Weight, Molecular-Weight Distribution and Architecture
(branched, linear etc.) of the polymer
• Solution properties (viscosity, conductivity & and surface
tension)
• Electric potential, Flow rate & Concentration
• Distance between the capillary and collection screen
• Ambient parameters (temperature, humidity and air velocity in
the chamber)
• Motion of target screen (collector)
8. ADVANTAGES
High surface to volume ratio
Very high porosity
Enhanced physico-mechanical properties
Manipulation of the solution and process parameters can be
easily done to get the desired fiber morphology and
mechanical strength
9. CHARACTERIZATIONS
Geometric(fiber diameter, diameter distribution , fiber
orientation, and fiber morphology):
SEM, TEM, AFM
Chemical(Molecular structure):
FTIR, NMR
Mechanical(Mechanical properties):
nanoindentation, bending tests, resonance frequency
measurements, and microscale tension tests.
11. Advantageous applications
Ultrafiltration of water: High efficiency, Low fouling, High
flux
Drug delivery: Superior adhesiveness to biological surfaces
Tissue engineering: 3D nanofibrous scaffolds