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You might be surprised at what
might be in our drinking water
ECO Green Group Thursday March 10, 2016
by
Tony Green
Agenda
 O p e n i n g T h o u g h t - L e a d i n o u r Wa t e r ?
 E n s u r i n g y o u r w a t e r i s s a f e
 H o w c a n t h e s e t h i n g s g e t i n o u r w a t e r ?
 W h a t m i g h t b e i n y o u r w a t e r ?
 A n d l e t ’s n o t f o r g e t t h e s e
 W h a t c a n w e d o a b o u t o u r w a t e r ?
 I n C l o s i n g – k e e p i n m i n d t h a t …
 Q u e s t i o n s a n d A n s w e r s
Would you drink this water?
http://www.pressdemocrat
.com/csp/mediapool/sites
https://www.google.com/maps/place/Healdsburg,+CA
Lead in our Water
https://www.cityofflint.com/wp-content/uploads/pipe-with-corrosion-
538x218.jpg
https://www.cityofflint.com/wp-
content/uploads/Faucet-Web-538x218.png
http://mytechbits.com/wp-
content/uploads/2016/01/Flint-Michigan-
water-contamin.jpg
E n s u r i n g yo u r w a t e r i s s a f e
Should we
feel safe
about
our water ?
E n s u r i n g yo u r w a t e r i s s a f e
B y 1 9 7 0 s t u d i e s s h o w e d t h a t h a l f o f t h e
U. S . d r i n k i n g w a t e r w a s c o n t a m i n a t e d … . .
I n 1 9 7 2 t h e C WA e s t a b l i s h e s t h e b a s i c
s t r u c t u r e f o r r e g u l a t i n g d i s c h a r g e s o f
p o l l u t a n t s i n t o t h e w a t e r s o f t h e U n i t e d
S t a t e s
Copyright @ Tony Green 2016
Ensuring our Water is safe
F e d e r a l d r i n k i n g w a t e r s t a n d a r d s a r e o r g a n i z e d i n t o
s i x g r o u p s :
 M i c r o o r g a n i s m s
 D i s i n f e c t a n t s
 D i s i n f e c t i o n B y p r o d u c t s
 I n o r g a n i c C h e m i c a l s
 O r g a n i c C h e m i c a l s
 R a d i o n u c l i d e s
U n d e r t h e S D WA’ s N a t i o n a l P r i m a r y D r i n k i n g Wa t e r
R e g u l a t i o n s , d r i n k i n g w a t e r s t a n d a r d s k n o w n a s
“ m a x i m u m c o n t a m i n a n t l e v e l s ” o r ( M C L’ s )
Copyright @ Tony Green 2016
Ensuring our Water is safe
Copyright @ Tony Green 2016
Radiation
Silicone
Octane
Lysol
Bacteria
Chloroform
Ensuring our Water is safe
Pollu tants
W a t e r p o l l u t i o n c a n b e n a t u r a l l y o c c u r r i n g - f r o m
m i c r o - o r g a n i s m s i n s o i l s a n d w i l d l i f e , r a d i o n u l l
l i e d i n u n d e r l y i n g r o c k a n d F l o r i d a , n i t r o g e n a n d
h e a v y m e t a l s s u c h a s l e a d , c a d m i u m , a r s e n i c a n d
s e l e n i u m .
B u t i n m a n y c a s e s , w a t e r q u a l i t y i s m o s t a f f e c t e d
b y w h a t h u m a n s p u t i n t o i t .
Source : Alex Del’homme ‘s “The Ripple Effect”
How do these contaminants
get in our water?
www.dreamstime.com www.dreamstime.com
Presenter Personal Image
Cocaine
Copyright @ Tony Green 2016
https://www.drugabuse.gov/publications/drugfacts/cocainehttps://www.drugabuse.gov/publications/drugfacts/cocaine
https://www.dreamstime.com
Cocaine
http://iml.jou.ufl.edu/projects/spring08/Cantwell/how.html
http://www.dreamstime.com
Cocaine
Cocaine
Me t hy l - b e n z oy l e c go n i n e
a c t i ve p r i n c i p a l o b t a i n e d f r o m
l e ave s ( 0 . 5 - 1 % )
B e n z oy l e c g i n i n e ( B E ) t h e m a j o r
m e t a b o l i t e o f co c a i n e – f o u n d i n
d r i n k i n g w a t e r.
Copyright @ Tony Green 2016
Source: www.mapsofworld.com Source: www.mapsofworld.com Source: www.mapsofworld.com
Cocaine
• P r e s c r i p t i o n a n d o v e r -
t h e c o u n t e r d r u g s
• Ve t e r i n a r y d r u g s
• F r a g r a n c e s
• C o s m e t i c s
• S u n - s c r e e n p r o d u c t s
• D i a g n o s t i c a g e n t s
• N u t r a c e u t i c a l s ( e . g . ,
v i t a m i n s )
P h a r m a ce u t i c a l s a n d
Pe r s o n a l C a r e P r o d u c t s a s
Po l l u t a n t s ( PP C P )
http://fipaonline.com/documents/Presentations/Proper%20Medication%20Disposal%20Program%20by%20Susanna%20Littell%20%20FINAL.ppt
• I n g e s t e d t h e n e x c r e t e d
• D i s c h a r g e d d u r i n g b a t h i n g
• D i s c h a r g e d d u r i n g m e d i c a t i o n d i s p o s a l
• 5 0 % o f a l l u n u s e d p r e s c r i p t i o n s
• 8 0 % o f a l l u n u s e d a n t i b i o t i c s
PPCP Source Pathways to the
Sewer
http://fipaonline.com/documents/Presentations/Proper%20Medication%20Disposal%20Program%20by%20Susanna%20Littell%20%20FINAL.ppt
Routes of Release of Human and
Veterinary Pharmaceuticals
http://www.globalchange.umich.edu/globalchange2/current/labs/Example%20Power%20Point%20Presentations%20(taken%20from%20GC1)/Environment%20and%20Pharmaceuticals.ppt
Too Many Pharmaceuticals Go Unused…
• PhRMA uses an estimate of 3% of all meds go unused:
– 82% of antibiotics go unused
– 50% of antidepressants
– 50% of beta-blockers
– 20% of pain meds
•Waste management compliance rates for some medications
are < 20%
Unu sed Pharmace u ticals
PPCPs Are Present in Our
Nation’s Waterbodies
One or more chemicals were detected in 80 percent
of the streams sampled, and 82 of the 95 chemicals
were detected at least once.
Generally, these chemicals were found at very low
concentrations (in most cases, less than 1 part per
billion).
Mixtures of the chemicals were common:
– 75 percent of the streams had more than one
– 50 percent had 7 or more
– 34 percent had 10 or more.
https://extension.usu.edu/waterquality/files/uploads/Whats_in_your_water/pharmaceuticals/Proper_Medication_Disposal_Program.ppt
PPCPs Are Present in Our
Nation’s Waterbodies
• The most frequently detected chemicals (found in more than half of the streams) were:
– Coprostanol (fecal steroid)
– Cholesterol (plant and animal steroid)
– N-N-diethyltoluamide (insect repellent)
– Caffeine (stimulant)
– Triclosan (antimicrobial disinfectant)
– Tri (2-chloroethyl) phosphate (fire retardant)
– 4-nonylphenol (nonionic detergent metabolite).
• Steroids, nonprescription drugs, and insect repellent were the chemical groups most
frequently detected.
• Detergent metabolites, steroids, and plasticizers generally were measured at the highest
concentrations.
https://extension.usu.edu/waterquality/files/uploads/Whats_in_your_water/pharmaceuticals/Proper_Medication_Disposal_Program.ppt
Source: Pesticides in Drinking Water from the New Jersey Division of Environmental and Occupational Health Consumer and Environmental Health Services
P e s t i c i d e s c o n s i s t o f a l a r g e g r o u p o f c h e m i c a l s t h a t
a r e u s e d i n a g r i c u l t u r e a n d r e s i d e n t i a l s e t t i n g s t o
c o n t r o l p l a n t a n d a n i m a l i n f e s t a t i o n . T h e r e a r e s e v e r a l
d i f f e r e n t t y p e s o f p e s t i c i d e s :
.
Pes ticid es
S u r f a c e
w a t e r r u n o f f
R a i n a n d
S n o w
I m p r o p e r l y
d i s p o s e d
p e s t i c i d e s
Pes ticid es
Source: Pesticides in Drinking Water from the New Jersey Division of Environmental and Occupational Health Consumer and Environmental Health Services
D e p e n d i n g o n t h e p e s t i c i d e s i n v o l v e d , y o u m a y
c o n s i d e r i n s t a l l i n g a G r a n u l a t e d A c t i v a t e d C a r b o n
( G A C ) s y s t e m o r a r e v e r s e o s m o s i s u n i t .
Source: dreamstime.com
Source: Pesticides in Drinking Water from the New Jersey Division of Environmental and Occupational Health Consumer and Environmental Health Services
http://www.cabotcorp.com/solutions/products-plus/activated-carbon
http://www.cabotcorp.com/solutions/products-plus/activated-carbon
Pes ticid es
T h e i n s e c t i c i d e D D T,
t h o u g h b a n n e d f o r n e a r l y
t w e n t y y e a r s , c a n s t i l l b e
f o u n d a t t r a c e l e v e l s i n
s o m e g r o u n d w a t e r .
Pes ticid es
Source: Pesticides in Drinking Water from the New Jersey Division of Environmental and Occupational Health Consumer and Environmental Health Services
Source: dreamstime.com
Endocrine Disruptors
E n v i r o n m e n t a l
c o m p o u n d s t h a t
i n t e r f e r e w i t h t h e
n o r m a l f u n c t i o n o f
e n d o g e n o u s h o r m o n e s -
m a y s t i m u l a t e o r b l o c k
t h e a c t i o n s o f
h o r m o n e s , o r c a n
i n t e r f e r e w i t h t h e i r
m e t a b o l i s m .
https://www.arhp.org/uploadDocs/RH06_Jones.ppt
A m o r e r e c e n t d e f i n i t i o n
o f a “ h o r m o n e ” ( b y N o b e l
L a u r e a t e R o g e r
G u i l l e m i n ) s u g g e s t s a
m u c h b r o a d e r d e f i n i t i o n :
" A n y s u b s t a n c e r e l e a s e d
b y a c e l l w h i c h a c t s o n
a n o t h e r c e l l , n e a r o r
f a r. . . "
Endocrine Disruptors
For ove r 50 ye ars, the re have
be e n re ports conce rning
che micals in the e nvironme nt
with hormone - like e ffe cts on
wildlife
Sile nt Spring
https://www.arhp.org/uploadDocs/RH06_Jones.ppt
https://www.arhp.org/uploadDocs/RH06_Jones.ppt
Endocrine Disruptors
Endocrine Disruptors
They have been recognized to
include a diverse range of
chemicals including pesticides,
plasticizers, flame retardants,
industrial byproducts,
pharmaceuticals, and plant-
derived compounds
https://www.arhp.org/uploadDocs/RH06_Jones.ppt
Bacteria
E C o l i I s t h e c o m m o n
a b b r e v i a t i o n f o r E s c h e r i a C o l i -
t r a n s m i t t e d b y a n i m a l o r
h u m a n f e c e s .
C o l i f o r m s a r e a f a m i l y o f
b a c t e r i a
A c c o r d i n g t o t h e E PA , t h e s a f e
l i m i t f o r b o t h E C o l i a n d o t h e r
c o l i f o r m s i s z e r o .
Source: Alex Del’homme ‘s “The Ripple Effect”
Crypto can potentially survive
outside of a human and animal
host for weeks and is often
resistant to antibacterial cleaners
and disinfectants.
Crypto is a microscopic
protozoan parasite that is the
leading cause of waterborne
illness in the U.S
Bacteria
O n e o f t h e m o s t f r e q u e n t l y f o u n d c o m p o u n d s
i n U S G S s t r e a m r e c o n n a i s s a n c e
A n a n t i m i c r o b i a l p r e s e r v a t i v e f o u n d i n :
H a n d s o a p
D i s h - w a s h i n g p r o d u c t s
L a u n d r y d e t e r g e n t s a n d s o f t e n e r s
P l a s t i c s ( e . g . , t o y s , c u t t i n g b o a r d s )
T o o t h p a s t e
D e o d o r a n t s a n d a n t i p e r s p i r a n t s
C o s m e t i c s
H a i r c o n d i t i o n e r s
P e s t i c i d e s
Triclosan
http://www.dos.ny.gov/watershed/ppt/PolimeniWestPointSept162008.ppt
In closing
U s e a a B r i t a F i l t e r i n y o u r h o m e
T h i n k a b o u t w h a t g o e s d o w n t h e d r a i n
C o n s i d e r Wa t e r Tr e a t m e n t
S y s t e m ( C a r b o n F i l t e r o r R e v e r s e
O s m o s i s )
)
Questions & Answers

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What is in your water might surprise you 03102016 Final DOOVER

  • 1. You might be surprised at what might be in our drinking water ECO Green Group Thursday March 10, 2016 by Tony Green
  • 2. Agenda  O p e n i n g T h o u g h t - L e a d i n o u r Wa t e r ?  E n s u r i n g y o u r w a t e r i s s a f e  H o w c a n t h e s e t h i n g s g e t i n o u r w a t e r ?  W h a t m i g h t b e i n y o u r w a t e r ?  A n d l e t ’s n o t f o r g e t t h e s e  W h a t c a n w e d o a b o u t o u r w a t e r ?  I n C l o s i n g – k e e p i n m i n d t h a t …  Q u e s t i o n s a n d A n s w e r s
  • 3. Would you drink this water?
  • 6. E n s u r i n g yo u r w a t e r i s s a f e Should we feel safe about our water ?
  • 7. E n s u r i n g yo u r w a t e r i s s a f e
  • 8. B y 1 9 7 0 s t u d i e s s h o w e d t h a t h a l f o f t h e U. S . d r i n k i n g w a t e r w a s c o n t a m i n a t e d … . . I n 1 9 7 2 t h e C WA e s t a b l i s h e s t h e b a s i c s t r u c t u r e f o r r e g u l a t i n g d i s c h a r g e s o f p o l l u t a n t s i n t o t h e w a t e r s o f t h e U n i t e d S t a t e s Copyright @ Tony Green 2016 Ensuring our Water is safe
  • 9. F e d e r a l d r i n k i n g w a t e r s t a n d a r d s a r e o r g a n i z e d i n t o s i x g r o u p s :  M i c r o o r g a n i s m s  D i s i n f e c t a n t s  D i s i n f e c t i o n B y p r o d u c t s  I n o r g a n i c C h e m i c a l s  O r g a n i c C h e m i c a l s  R a d i o n u c l i d e s U n d e r t h e S D WA’ s N a t i o n a l P r i m a r y D r i n k i n g Wa t e r R e g u l a t i o n s , d r i n k i n g w a t e r s t a n d a r d s k n o w n a s “ m a x i m u m c o n t a m i n a n t l e v e l s ” o r ( M C L’ s ) Copyright @ Tony Green 2016 Ensuring our Water is safe
  • 10. Copyright @ Tony Green 2016 Radiation Silicone Octane Lysol Bacteria Chloroform Ensuring our Water is safe
  • 11. Pollu tants W a t e r p o l l u t i o n c a n b e n a t u r a l l y o c c u r r i n g - f r o m m i c r o - o r g a n i s m s i n s o i l s a n d w i l d l i f e , r a d i o n u l l l i e d i n u n d e r l y i n g r o c k a n d F l o r i d a , n i t r o g e n a n d h e a v y m e t a l s s u c h a s l e a d , c a d m i u m , a r s e n i c a n d s e l e n i u m . B u t i n m a n y c a s e s , w a t e r q u a l i t y i s m o s t a f f e c t e d b y w h a t h u m a n s p u t i n t o i t . Source : Alex Del’homme ‘s “The Ripple Effect”
  • 12. How do these contaminants get in our water? www.dreamstime.com www.dreamstime.com Presenter Personal Image
  • 16. Cocaine Me t hy l - b e n z oy l e c go n i n e a c t i ve p r i n c i p a l o b t a i n e d f r o m l e ave s ( 0 . 5 - 1 % ) B e n z oy l e c g i n i n e ( B E ) t h e m a j o r m e t a b o l i t e o f co c a i n e – f o u n d i n d r i n k i n g w a t e r. Copyright @ Tony Green 2016
  • 17. Source: www.mapsofworld.com Source: www.mapsofworld.com Source: www.mapsofworld.com Cocaine
  • 18. • P r e s c r i p t i o n a n d o v e r - t h e c o u n t e r d r u g s • Ve t e r i n a r y d r u g s • F r a g r a n c e s • C o s m e t i c s • S u n - s c r e e n p r o d u c t s • D i a g n o s t i c a g e n t s • N u t r a c e u t i c a l s ( e . g . , v i t a m i n s ) P h a r m a ce u t i c a l s a n d Pe r s o n a l C a r e P r o d u c t s a s Po l l u t a n t s ( PP C P ) http://fipaonline.com/documents/Presentations/Proper%20Medication%20Disposal%20Program%20by%20Susanna%20Littell%20%20FINAL.ppt
  • 19. • I n g e s t e d t h e n e x c r e t e d • D i s c h a r g e d d u r i n g b a t h i n g • D i s c h a r g e d d u r i n g m e d i c a t i o n d i s p o s a l • 5 0 % o f a l l u n u s e d p r e s c r i p t i o n s • 8 0 % o f a l l u n u s e d a n t i b i o t i c s PPCP Source Pathways to the Sewer http://fipaonline.com/documents/Presentations/Proper%20Medication%20Disposal%20Program%20by%20Susanna%20Littell%20%20FINAL.ppt
  • 20. Routes of Release of Human and Veterinary Pharmaceuticals http://www.globalchange.umich.edu/globalchange2/current/labs/Example%20Power%20Point%20Presentations%20(taken%20from%20GC1)/Environment%20and%20Pharmaceuticals.ppt
  • 21. Too Many Pharmaceuticals Go Unused… • PhRMA uses an estimate of 3% of all meds go unused: – 82% of antibiotics go unused – 50% of antidepressants – 50% of beta-blockers – 20% of pain meds •Waste management compliance rates for some medications are < 20% Unu sed Pharmace u ticals
  • 22. PPCPs Are Present in Our Nation’s Waterbodies One or more chemicals were detected in 80 percent of the streams sampled, and 82 of the 95 chemicals were detected at least once. Generally, these chemicals were found at very low concentrations (in most cases, less than 1 part per billion). Mixtures of the chemicals were common: – 75 percent of the streams had more than one – 50 percent had 7 or more – 34 percent had 10 or more. https://extension.usu.edu/waterquality/files/uploads/Whats_in_your_water/pharmaceuticals/Proper_Medication_Disposal_Program.ppt
  • 23. PPCPs Are Present in Our Nation’s Waterbodies • The most frequently detected chemicals (found in more than half of the streams) were: – Coprostanol (fecal steroid) – Cholesterol (plant and animal steroid) – N-N-diethyltoluamide (insect repellent) – Caffeine (stimulant) – Triclosan (antimicrobial disinfectant) – Tri (2-chloroethyl) phosphate (fire retardant) – 4-nonylphenol (nonionic detergent metabolite). • Steroids, nonprescription drugs, and insect repellent were the chemical groups most frequently detected. • Detergent metabolites, steroids, and plasticizers generally were measured at the highest concentrations. https://extension.usu.edu/waterquality/files/uploads/Whats_in_your_water/pharmaceuticals/Proper_Medication_Disposal_Program.ppt
  • 24. Source: Pesticides in Drinking Water from the New Jersey Division of Environmental and Occupational Health Consumer and Environmental Health Services P e s t i c i d e s c o n s i s t o f a l a r g e g r o u p o f c h e m i c a l s t h a t a r e u s e d i n a g r i c u l t u r e a n d r e s i d e n t i a l s e t t i n g s t o c o n t r o l p l a n t a n d a n i m a l i n f e s t a t i o n . T h e r e a r e s e v e r a l d i f f e r e n t t y p e s o f p e s t i c i d e s : . Pes ticid es
  • 25. S u r f a c e w a t e r r u n o f f R a i n a n d S n o w I m p r o p e r l y d i s p o s e d p e s t i c i d e s Pes ticid es Source: Pesticides in Drinking Water from the New Jersey Division of Environmental and Occupational Health Consumer and Environmental Health Services
  • 26. D e p e n d i n g o n t h e p e s t i c i d e s i n v o l v e d , y o u m a y c o n s i d e r i n s t a l l i n g a G r a n u l a t e d A c t i v a t e d C a r b o n ( G A C ) s y s t e m o r a r e v e r s e o s m o s i s u n i t . Source: dreamstime.com Source: Pesticides in Drinking Water from the New Jersey Division of Environmental and Occupational Health Consumer and Environmental Health Services http://www.cabotcorp.com/solutions/products-plus/activated-carbon http://www.cabotcorp.com/solutions/products-plus/activated-carbon Pes ticid es
  • 27. T h e i n s e c t i c i d e D D T, t h o u g h b a n n e d f o r n e a r l y t w e n t y y e a r s , c a n s t i l l b e f o u n d a t t r a c e l e v e l s i n s o m e g r o u n d w a t e r . Pes ticid es Source: Pesticides in Drinking Water from the New Jersey Division of Environmental and Occupational Health Consumer and Environmental Health Services Source: dreamstime.com
  • 28. Endocrine Disruptors E n v i r o n m e n t a l c o m p o u n d s t h a t i n t e r f e r e w i t h t h e n o r m a l f u n c t i o n o f e n d o g e n o u s h o r m o n e s - m a y s t i m u l a t e o r b l o c k t h e a c t i o n s o f h o r m o n e s , o r c a n i n t e r f e r e w i t h t h e i r m e t a b o l i s m . https://www.arhp.org/uploadDocs/RH06_Jones.ppt
  • 29. A m o r e r e c e n t d e f i n i t i o n o f a “ h o r m o n e ” ( b y N o b e l L a u r e a t e R o g e r G u i l l e m i n ) s u g g e s t s a m u c h b r o a d e r d e f i n i t i o n : " A n y s u b s t a n c e r e l e a s e d b y a c e l l w h i c h a c t s o n a n o t h e r c e l l , n e a r o r f a r. . . "
  • 30. Endocrine Disruptors For ove r 50 ye ars, the re have be e n re ports conce rning che micals in the e nvironme nt with hormone - like e ffe cts on wildlife Sile nt Spring https://www.arhp.org/uploadDocs/RH06_Jones.ppt
  • 32. Endocrine Disruptors They have been recognized to include a diverse range of chemicals including pesticides, plasticizers, flame retardants, industrial byproducts, pharmaceuticals, and plant- derived compounds https://www.arhp.org/uploadDocs/RH06_Jones.ppt
  • 33. Bacteria E C o l i I s t h e c o m m o n a b b r e v i a t i o n f o r E s c h e r i a C o l i - t r a n s m i t t e d b y a n i m a l o r h u m a n f e c e s . C o l i f o r m s a r e a f a m i l y o f b a c t e r i a A c c o r d i n g t o t h e E PA , t h e s a f e l i m i t f o r b o t h E C o l i a n d o t h e r c o l i f o r m s i s z e r o . Source: Alex Del’homme ‘s “The Ripple Effect”
  • 34. Crypto can potentially survive outside of a human and animal host for weeks and is often resistant to antibacterial cleaners and disinfectants. Crypto is a microscopic protozoan parasite that is the leading cause of waterborne illness in the U.S Bacteria
  • 35. O n e o f t h e m o s t f r e q u e n t l y f o u n d c o m p o u n d s i n U S G S s t r e a m r e c o n n a i s s a n c e A n a n t i m i c r o b i a l p r e s e r v a t i v e f o u n d i n : H a n d s o a p D i s h - w a s h i n g p r o d u c t s L a u n d r y d e t e r g e n t s a n d s o f t e n e r s P l a s t i c s ( e . g . , t o y s , c u t t i n g b o a r d s ) T o o t h p a s t e D e o d o r a n t s a n d a n t i p e r s p i r a n t s C o s m e t i c s H a i r c o n d i t i o n e r s P e s t i c i d e s Triclosan http://www.dos.ny.gov/watershed/ppt/PolimeniWestPointSept162008.ppt
  • 36. In closing U s e a a B r i t a F i l t e r i n y o u r h o m e T h i n k a b o u t w h a t g o e s d o w n t h e d r a i n C o n s i d e r Wa t e r Tr e a t m e n t S y s t e m ( C a r b o n F i l t e r o r R e v e r s e O s m o s i s ) )