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Thorium Fuel Cycle
SHAWN ROBINSON
NUCLEAR PHYSICS
12/1/15
1
Discovery of Thorium
 Thorium was discovered in 1828 by the Swedish chemist Jons Jakob
Berzelius as thorite (ThSiO4)
 232Th has Half Life Of 1.4 E10 years! No stable Isotopes
 Fertile not Fissile
 Atomic Number: 90
 Atomic Weight: 232.03806
 Phase at Room Temperature: Solid
 Element Classification: Metal
2
Why Thorium when we have Uranium?
 Cross section σy = 7.34b, 85; σf <1µb
 Fast Flux reduces unwanted isotopes
3
Thorium Requires high energy neutron flux Transitioning Thorium Breeds fuel
Flaws of Liquid Drop Model
 B(A,Z) A= 232, Z=92
 Binding energy approximation: 12.83 Mev/A
 Actual Binding Energy : 7.615 Mev/A
4
It’s Magic, You Know!
 Double Magic number Z=92, A=232
 Closed Shell, Jπ = 0 Making it super stable
 Explains The long half life
5
Thorium In Action 6
Fission product Distribution
Thorium to 233 Uranium fuel
Thorium Decay
 Mainly Alpha Decay
 D-Double Magic!
 208
82Pb Ultra Stable
7
Thorium In Nature
 Predicted abundance of about 15 parts per million in the earth’s crust
(.0007%), many times greater than that of uranium.
 More thorium energy available than all fossil fuels and other nuclear
sources combined
 It’s decay thought to be responsible for the earth’s internal temperature.
8
Magnified Green
Thorite crystal
The FLiBe Juice
 FLiBe (Li2BeF4) is a molten salt made from a mixture of lithium fluoride (LiF)
and beryllium fluoride (BeF2).
 Molten FLiBe flowing sample's green tint is from dissolved uranium
tetrafluoride.
 Melting point of 459 °C, a boiling point of 1430 °C, and a density of 1.94
g/cm3. Its heat capacity is 4540 kJ/m3
9
Molten FLiBeFleeb (Plumbus)
Thorium is Safe!
 The fissile material weapon quality is evaluated by considering three
properties:
 The critical mass is different for different isotopic composition of Pu;
 weapon yield degradation due to pre-initiation caused by spontaneous
fission neutrons;
 weapon stability degradation caused by heat emission.
 No enrichment facilities
 No 239 Pu generation
10
Sustainable Thorium! 11
Sustainable Thorium processing
References & Images
 http://www.thegreenage.co.uk/tech/thorium-nuclear-energy/
 https://en.wikipedia.org/wiki/Thorium_fuel_cycle
 http://www.world-nuclear.org/info/current-and-future-
generation/thorium/
 http://www-pub.iaea.org/mtcd/publications/pdf/te_1450_web.pdf
 http://www.halexandria.org/dward472.htm
 Sustainability 2012, 4(8), 1933-1945; doi:10.3390/su4081933
 http://education.jlab.org/itselemental/ele090.html
 http://mpa.ac.uk/muarc/school/Thorium_nuclear_clock.pdf
12
Questions? 13

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Thorium Fuel Cycle

  • 1. Thorium Fuel Cycle SHAWN ROBINSON NUCLEAR PHYSICS 12/1/15 1
  • 2. Discovery of Thorium  Thorium was discovered in 1828 by the Swedish chemist Jons Jakob Berzelius as thorite (ThSiO4)  232Th has Half Life Of 1.4 E10 years! No stable Isotopes  Fertile not Fissile  Atomic Number: 90  Atomic Weight: 232.03806  Phase at Room Temperature: Solid  Element Classification: Metal 2
  • 3. Why Thorium when we have Uranium?  Cross section σy = 7.34b, 85; σf <1µb  Fast Flux reduces unwanted isotopes 3 Thorium Requires high energy neutron flux Transitioning Thorium Breeds fuel
  • 4. Flaws of Liquid Drop Model  B(A,Z) A= 232, Z=92  Binding energy approximation: 12.83 Mev/A  Actual Binding Energy : 7.615 Mev/A 4
  • 5. It’s Magic, You Know!  Double Magic number Z=92, A=232  Closed Shell, Jπ = 0 Making it super stable  Explains The long half life 5
  • 6. Thorium In Action 6 Fission product Distribution Thorium to 233 Uranium fuel
  • 7. Thorium Decay  Mainly Alpha Decay  D-Double Magic!  208 82Pb Ultra Stable 7
  • 8. Thorium In Nature  Predicted abundance of about 15 parts per million in the earth’s crust (.0007%), many times greater than that of uranium.  More thorium energy available than all fossil fuels and other nuclear sources combined  It’s decay thought to be responsible for the earth’s internal temperature. 8 Magnified Green Thorite crystal
  • 9. The FLiBe Juice  FLiBe (Li2BeF4) is a molten salt made from a mixture of lithium fluoride (LiF) and beryllium fluoride (BeF2).  Molten FLiBe flowing sample's green tint is from dissolved uranium tetrafluoride.  Melting point of 459 °C, a boiling point of 1430 °C, and a density of 1.94 g/cm3. Its heat capacity is 4540 kJ/m3 9 Molten FLiBeFleeb (Plumbus)
  • 10. Thorium is Safe!  The fissile material weapon quality is evaluated by considering three properties:  The critical mass is different for different isotopic composition of Pu;  weapon yield degradation due to pre-initiation caused by spontaneous fission neutrons;  weapon stability degradation caused by heat emission.  No enrichment facilities  No 239 Pu generation 10
  • 12. References & Images  http://www.thegreenage.co.uk/tech/thorium-nuclear-energy/  https://en.wikipedia.org/wiki/Thorium_fuel_cycle  http://www.world-nuclear.org/info/current-and-future- generation/thorium/  http://www-pub.iaea.org/mtcd/publications/pdf/te_1450_web.pdf  http://www.halexandria.org/dward472.htm  Sustainability 2012, 4(8), 1933-1945; doi:10.3390/su4081933  http://education.jlab.org/itselemental/ele090.html  http://mpa.ac.uk/muarc/school/Thorium_nuclear_clock.pdf 12