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Biological molecules consist predominantly of carbon
atoms bound to other carbon atoms
and/ or atoms of O, N, S, P or H.
Hydrocarbons: only C and H.
Since both atoms have similar electronegativity
the bonds are non-polar.
Therefore simple hydrocarbons are hydrophobic.
In addition to hydrocarbons, biological
molecules include carbohydrates
which have oxygen in addition
to C and H.
C:H:O 1:2:1 (CH2O)n
A functional group is a molecular group attached
to a hydrocarbon that confers chemical properties
or reactivities.
Examples include –OH, -COOH, -NH2.
Page
47
Carbon is in period 4.
Needs 4 electrons to
complete its outer shell (L)
A carbon atom bound to 4 different
groups has a distinct 3 dimensional
shape
A carbon atom bound to 4 different
groups has a distinct 3 dimensional
shape
D L
The groups are followed from greatest electronegativity to least.
If the rotation is clockwise it is D for dextro because it rotates
polarized light to the right (also called R for right).
If the rotation is counter-clockwise it is L for levo.
The convention is the two vertical
bonds are projecting
into the page and the two
horizontal bonds are projecting
out of the page.
This is D-glyceraldehyde.
If the –OH and –H bound
to carbon 2 were interchanged,
it would be L-glyceraldehyde
Same formula
Different bonds
Same formula
Same bonds
Different 3D structure
ISOMERS Both C6H12O6
Glucose
alpha
beta
 Monosaccharides
 Disaccharides
 A polymer is a long molecule built
by linking together a large number
of small, similar subunits called
monomers.
 Polysaccharide
Glucose + Fructose
Examples of disaccharides-
Common transport form of sugars
Lactose (milk sugar) is a disaccharide
of glucose and galactose
Starch is polymer of alpha-glucose
 Maltose is a disaccharide of alpha
glucose.
 Starch consists of hundreds of alpha
glucose molecules linked together
 (insoluble).
 Amylose is the simplest starch consisting
of polymers of hundreds of alpha glucose
molecules in unbranched chains.
 Amylopectin is a varient of amylose
where there are additional linkages
beteen some subunits (alpha 1-6)
causing branching.
 In animals, bacteria and fungi the alpha
glucose polymers are branched and
known as glycogen.
Polymers
of alpha
glucose
plants
animals
plants
Cellulose is unbranched and
resistant to metabolic breakdown.
 Starch alpha linkages
 Cellulose beta linkages
Test
3 dimensional
Second lecture b
Second lecture b
Second lecture b
Second lecture b

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Second lecture b

  • 1. Biological molecules consist predominantly of carbon atoms bound to other carbon atoms and/ or atoms of O, N, S, P or H. Hydrocarbons: only C and H. Since both atoms have similar electronegativity the bonds are non-polar. Therefore simple hydrocarbons are hydrophobic.
  • 2. In addition to hydrocarbons, biological molecules include carbohydrates which have oxygen in addition to C and H. C:H:O 1:2:1 (CH2O)n
  • 3. A functional group is a molecular group attached to a hydrocarbon that confers chemical properties or reactivities. Examples include –OH, -COOH, -NH2.
  • 4.
  • 5.
  • 6.
  • 8. Carbon is in period 4. Needs 4 electrons to complete its outer shell (L)
  • 9. A carbon atom bound to 4 different groups has a distinct 3 dimensional shape
  • 10. A carbon atom bound to 4 different groups has a distinct 3 dimensional shape
  • 11.
  • 12. D L The groups are followed from greatest electronegativity to least. If the rotation is clockwise it is D for dextro because it rotates polarized light to the right (also called R for right). If the rotation is counter-clockwise it is L for levo.
  • 13. The convention is the two vertical bonds are projecting into the page and the two horizontal bonds are projecting out of the page.
  • 14. This is D-glyceraldehyde. If the –OH and –H bound to carbon 2 were interchanged, it would be L-glyceraldehyde
  • 15. Same formula Different bonds Same formula Same bonds Different 3D structure ISOMERS Both C6H12O6
  • 18.
  • 19.  Monosaccharides  Disaccharides  A polymer is a long molecule built by linking together a large number of small, similar subunits called monomers.  Polysaccharide
  • 20.
  • 21.
  • 22.
  • 23.
  • 24. Glucose + Fructose Examples of disaccharides- Common transport form of sugars Lactose (milk sugar) is a disaccharide of glucose and galactose
  • 25. Starch is polymer of alpha-glucose
  • 26.  Maltose is a disaccharide of alpha glucose.  Starch consists of hundreds of alpha glucose molecules linked together  (insoluble).  Amylose is the simplest starch consisting of polymers of hundreds of alpha glucose molecules in unbranched chains.
  • 27.  Amylopectin is a varient of amylose where there are additional linkages beteen some subunits (alpha 1-6) causing branching.  In animals, bacteria and fungi the alpha glucose polymers are branched and known as glycogen.
  • 30.
  • 31. Cellulose is unbranched and resistant to metabolic breakdown.
  • 32.  Starch alpha linkages  Cellulose beta linkages
  • 33.
  • 34.
  • 35.
  • 36.
  • 37.
  • 38.
  • 39. Test
  • 40.
  • 41.
  • 42.
  • 43.
  • 44.