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Performance Flux Minerals
                                for sanitaryware glazes


 improve glaze quality with optimised fluxing performance
Engineered flux minerals for		 	
		 optimised sanitaryware glazes
The full range of Sibelco glaze fluxes have been formulated and processed to give exceptional performance in sanitaryware glaze
systems and with Sibelco’s commitment to quality the variation between batches is minimal; ensuring consistent manufacturing results
for the user.
Our range of sanitaryware glaze fluxing minerals is ideal for ensuring optimum sintering and fusion points are reached in glaze
applications, whilst maintaining good glaze flow ability combined with a high quality surface finish even in frit, barium and zinc free
formulations.
Sibelco’s unique range of glaze flux minerals includes Spectrum (Nepheline syenite), FFF (mixed feldspar), Maxum (sodium feldspar) and
Quantum (Potassium Feldspar). With such a wide range of minerals available the portfolio can meet the needs of most manufacturing
formulations.
The key features of the range are:

•	     A high level of fluxing oxides
•	     Low colouring oxide content
•	     Wide range of flux oxide ratios from pure soda and potash to mixed combinations
•	     Unique mineralogy
Ideally suited to being the sole flux in sanitaryware glaze systems, or mixed with other feldspars to enhance current performance


Recommended applications
                                 Vitreous China           Fine Fire Clay &
    Product                                                                   Relative Fluxing ability
                                      Glazes                Gres Glazes
    Spectrum                                                    
    Quantum                                                     
                                                                                                                       * Based on
    Maxum                                                                                                            molar R2O
                                                                                                                       quantity
    FFF                                                         

The performance flux minerals from Sibelco are highly suited for manufacturing low colouring oxide, low defect glazes and combined
with a selection of fusibility profiles make them highly suited to a wide range of sanitaryware firing conditions.
Our performance flux products can benefit customer production processes by improving end glaze aesthetics and helping assist in the
reduction of traditional glaze defects due to:

•	        Low colouring oxide		            =	           exceptional white colour which can assist in the reduction of Zircon in the glaze formula
•	        Consistency			                   =	           Less glaze batch variation and improved colour matching
•	        High fluxing oxides		            =	           Efficient fluxing
•	        Unique Mineralogy1		             =	           Increased fusion
1
    Nepheline based products




Chemical and Analytical Data - Typical values which do not represent a specification
                                                Spectrum         Spectrum          Quantum            Maxum
                          unit                                                                                        FFF
                                                (Canada)         (Norway)        (high potash)      (high soda)
    SiO2                  Mass %                  60.2               55.4            66.6                70.8         69.1
    Al2O3                 Mass %                  23.6               24.6            18.3                18.1         18.1
    Fe2O3                 Mass %                  0.08               0.1              0.1                0.05         0.08
    CaO                   Mass %                  0.35               1.2             0.24                0.02         0.7
                                                                                                                                    These products
    MgO                   Mass %                  0.02               0.1             0.02                0.07         0.1           are available
                                                                                                                                    bulk and ground
    TiO2                  Mass %                  0.01               0.06            0.01                0.04         0.1           with a full range
    K2O                   Mass %                  4.8                8.9             10.9                0.2          6.0           of technical
                                                                                                                                    data available
    Na2O                  Mass %                  10.5               8.2              3.3                10.3         5.8           from your local
                                                                                                                                    Sibelco office
    Loss on Ignition      %                       0.4                0.9              0.4                0.2          0.3
The Performance flux mineral product range offers significant
advantages for sanitaryware glaze manufacture:

1. A wide range of fusibility which can assist in reducing the amount of overall imported flux in the glaze batch
If we consider a typical European sanitaryware glaze chemistry, adjusting the batch recipe to keep the same molar R2O content; then
the following formulations are obtained with Sibelco’s range of Feldspathic materials.


 Formulations                 Spectrum           Spectrum            Quantum             Maxum
                                                                                                              FFF
                              (Canada)           (Norway)          (high potash)       (high soda)
 Spectrum (Canada)              31.9                   -                 -                  -                  -
 Spectrum (Norway)                  -              31.5                  -                  -                  -
 FFF                                -                  -                 -                  -                 44.6
 Maxum                              -                  -                 -                41.7                 -
 Quantum                            -                  -               41.5                 -                  -
 Quartz                         18.1               21.0                10.8               10.7                8.8
 Kaolin                         10.3                9.2                9.3                 8.1                8.3
 Zircon                         15.8               15.6                15.4               15.8                15.5
 Wollastonite                   19.8               18.7                19.2               19.8                19.0
 Talc                              3.7              3.7                3.5                 3.7                3.5
 Binder                            0.3              0.3                0.3                 0.3                0.3
 TOTAL                          100                 100                100                100                 100
K2O:Na2O Ratio                 1:1.8                1.2:1            2.3:1             1:22.5                1.1:1
Typicaly 25% less feldspathic material is required when using the Spectrum range due to their high alkali and alumina content.



2. Low colouring oxides to assist in the attainment of high whiteness glaze aesthetics
If we consider the quality of the glaze produced, we can see that, due to the low colouring oxides in Sibelco Glaze Feldspathic
materials, they all produce high whiteness glazes.


        Colour           Spectrum             Spectrum             Quantum              Maxum
                                                                                                              FFF
                         (Canada)             (Norway)           (high potash)        (high soda)
          L                93.35                93.85                93.5                92.67               93.14
          a*               -0.46                -0.55               -0.47                -0.33               -0.23
          b*                2.09                2.17                 1.92                2.02                 2.06



3. Improved glaze flow and optimised sintering which can assist with improved degassing and lower glaze surface defects
As the sodium oxide content reduces, in favour of potassium oxide, the glaze sintering/fusion point decreases, and conversely, as the
potassium oxide content reduces, the glaze flow increases. This occurs until a minima is reached at the sodium/potassium eutectic,
before rising again at high potassium ratios. Thus, a grade (or combinations of grades) can be selected that optimises the degassing of
the body and flow of glaze that suits all sanitaryware glaze needs.




3.1 Effect of Na:K ratio on glaze fusion temperature            3.2 Effect of Na:K ratio on glaze flow
everything flows, nothing stands still
                                                      Heraclitus


Sibelco
Quellinstraat 49
2018 ANTWERPEN Belgium

For further information please email:
qualityceramics@sibelco.com                 www.sibelcoceramics.com

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Performance fluxs for sanitaryware

  • 1. Performance Flux Minerals for sanitaryware glazes improve glaze quality with optimised fluxing performance
  • 2. Engineered flux minerals for optimised sanitaryware glazes The full range of Sibelco glaze fluxes have been formulated and processed to give exceptional performance in sanitaryware glaze systems and with Sibelco’s commitment to quality the variation between batches is minimal; ensuring consistent manufacturing results for the user. Our range of sanitaryware glaze fluxing minerals is ideal for ensuring optimum sintering and fusion points are reached in glaze applications, whilst maintaining good glaze flow ability combined with a high quality surface finish even in frit, barium and zinc free formulations. Sibelco’s unique range of glaze flux minerals includes Spectrum (Nepheline syenite), FFF (mixed feldspar), Maxum (sodium feldspar) and Quantum (Potassium Feldspar). With such a wide range of minerals available the portfolio can meet the needs of most manufacturing formulations. The key features of the range are: • A high level of fluxing oxides • Low colouring oxide content • Wide range of flux oxide ratios from pure soda and potash to mixed combinations • Unique mineralogy Ideally suited to being the sole flux in sanitaryware glaze systems, or mixed with other feldspars to enhance current performance Recommended applications Vitreous China Fine Fire Clay & Product Relative Fluxing ability Glazes Gres Glazes Spectrum   Quantum   * Based on Maxum   molar R2O quantity FFF   The performance flux minerals from Sibelco are highly suited for manufacturing low colouring oxide, low defect glazes and combined with a selection of fusibility profiles make them highly suited to a wide range of sanitaryware firing conditions. Our performance flux products can benefit customer production processes by improving end glaze aesthetics and helping assist in the reduction of traditional glaze defects due to: • Low colouring oxide = exceptional white colour which can assist in the reduction of Zircon in the glaze formula • Consistency = Less glaze batch variation and improved colour matching • High fluxing oxides = Efficient fluxing • Unique Mineralogy1 = Increased fusion 1 Nepheline based products Chemical and Analytical Data - Typical values which do not represent a specification Spectrum Spectrum Quantum Maxum unit FFF (Canada) (Norway) (high potash) (high soda) SiO2 Mass % 60.2 55.4 66.6 70.8 69.1 Al2O3 Mass % 23.6 24.6 18.3 18.1 18.1 Fe2O3 Mass % 0.08 0.1 0.1 0.05 0.08 CaO Mass % 0.35 1.2 0.24 0.02 0.7 These products MgO Mass % 0.02 0.1 0.02 0.07 0.1 are available bulk and ground TiO2 Mass % 0.01 0.06 0.01 0.04 0.1 with a full range K2O Mass % 4.8 8.9 10.9 0.2 6.0 of technical data available Na2O Mass % 10.5 8.2 3.3 10.3 5.8 from your local Sibelco office Loss on Ignition % 0.4 0.9 0.4 0.2 0.3
  • 3. The Performance flux mineral product range offers significant advantages for sanitaryware glaze manufacture: 1. A wide range of fusibility which can assist in reducing the amount of overall imported flux in the glaze batch If we consider a typical European sanitaryware glaze chemistry, adjusting the batch recipe to keep the same molar R2O content; then the following formulations are obtained with Sibelco’s range of Feldspathic materials. Formulations Spectrum Spectrum Quantum Maxum FFF (Canada) (Norway) (high potash) (high soda) Spectrum (Canada) 31.9 - - - - Spectrum (Norway) - 31.5 - - - FFF - - - - 44.6 Maxum - - - 41.7 - Quantum - - 41.5 - - Quartz 18.1 21.0 10.8 10.7 8.8 Kaolin 10.3 9.2 9.3 8.1 8.3 Zircon 15.8 15.6 15.4 15.8 15.5 Wollastonite 19.8 18.7 19.2 19.8 19.0 Talc 3.7 3.7 3.5 3.7 3.5 Binder 0.3 0.3 0.3 0.3 0.3 TOTAL 100 100 100 100 100 K2O:Na2O Ratio 1:1.8 1.2:1 2.3:1 1:22.5 1.1:1 Typicaly 25% less feldspathic material is required when using the Spectrum range due to their high alkali and alumina content. 2. Low colouring oxides to assist in the attainment of high whiteness glaze aesthetics If we consider the quality of the glaze produced, we can see that, due to the low colouring oxides in Sibelco Glaze Feldspathic materials, they all produce high whiteness glazes. Colour Spectrum Spectrum Quantum Maxum FFF (Canada) (Norway) (high potash) (high soda) L 93.35 93.85 93.5 92.67 93.14 a* -0.46 -0.55 -0.47 -0.33 -0.23 b* 2.09 2.17 1.92 2.02 2.06 3. Improved glaze flow and optimised sintering which can assist with improved degassing and lower glaze surface defects As the sodium oxide content reduces, in favour of potassium oxide, the glaze sintering/fusion point decreases, and conversely, as the potassium oxide content reduces, the glaze flow increases. This occurs until a minima is reached at the sodium/potassium eutectic, before rising again at high potassium ratios. Thus, a grade (or combinations of grades) can be selected that optimises the degassing of the body and flow of glaze that suits all sanitaryware glaze needs. 3.1 Effect of Na:K ratio on glaze fusion temperature 3.2 Effect of Na:K ratio on glaze flow
  • 4. everything flows, nothing stands still Heraclitus Sibelco Quellinstraat 49 2018 ANTWERPEN Belgium For further information please email: qualityceramics@sibelco.com www.sibelcoceramics.com