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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
1 / 18
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name : RANCONA i-MIX
Product code : 000000001256
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub-
stance/Mixture
: Fungicide
Recommended restrictions
on use
: Agriculture, For professional users only.
1.3 Details of the supplier of the safety data sheet
Manufacturer or supplier's details
Company: Chemtura Europe Limited
Brooklands Farm, Cheltenham Road
Evesham, Worcestershire
United Kingdom
WR11 2LS
Telephone : +44 1386 425500
Prepared by sds.request@arysta.com
Further information for the safety data sheet :
sds.request@arysta.com
1.4 Emergency telephone number
Emergency telephone num-
ber:
+44 (0) 1235 239 670 (NCEC)
For additional emergency telephone numbers see section 16 of
the Safety Data Sheet.
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
2 / 18
effects.
Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting
effects.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Supplemental Hazard
Statements
: EUH401 To avoid risks to human health and the
environment, comply with the instructions
for use.
Hazard pictograms :
Signal word : Warning
Hazard statements : H410 Very toxic to aquatic life with long lasting
effects.
Precautionary statements : Prevention:
P273 Avoid release to the environment.
Response:
P391 Collect spillage.
Disposal:
P501 Dispose of contents/ container to an ap-
proved waste disposal plant.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumula-
tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Chemical nature : Ipconazole - 20 gm/L
Imazalil - 50 g/L
Hazardous components
Chemical Name CAS-No.
EC-No.
Registration number
Classification Concentration
(% w/w)
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
3 / 18
1-[2-(allyloxy)-2-(2,4-
dichlorophenyl)ethyl]-1H-
imidazole
35554-44-0
252-615-0
Acute Tox. 4; H302
Acute Tox. 4; H332
Eye Dam. 1; H318
Aquatic Acute 1;
H400
Aquatic Chronic 1;
H410
>= 3 - < 10
Ipconazole 125225-28-7 Acute Tox. 4; H302
Acute Tox. 4; H332
Repr. 2; H361
STOT RE 2; H373
Aquatic Acute 1;
H400
Aquatic Chronic 1;
H410
>= 1 - < 2.5
For explanation of abbreviations see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
If inhaled : Move to fresh air.
Obtain medical attention.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with warm water and soap.
If symptoms persist, call a physician.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
If symptoms persist, call a physician.
If swallowed : Do NOT induce vomiting.
Rinse mouth with water.
Obtain medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Cancer
Symptoms may be delayed.
Risks : Suspected of causing cancer.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : The first aid procedure should be established in consultation
with the doctor responsible for industrial medicine.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media : Extinguishing media - large fires
Alcohol-resistant foam
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
4 / 18
(on small fires)
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: Water spray jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-
fighting
: No information available.
5.3 Advice for firefighters
Special protective equipment
for firefighters
: Wear self-contained breathing apparatus for firefighting if nec-
essary. Complete suit protecting against chemicals Flame-
resistant clothing
Further information : Prevent fire extinguishing water from contaminating surface
water or the ground water system.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Wear suitable protective equipment.
Avoid contact with skin and eyes.
6.2 Environmental precautions
Environmental precautions : Do not allow uncontrolled discharge of product into the envi-
ronment.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Dam up.
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
Large spills should be collected mechanically (remove by
pumping) for disposal.
6.4 Reference to other sections
For personal protection see section 8.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Advice on safe handling : Avoid inhalation, ingestion and contact with skin and eyes.
Wash thoroughly after handling.
Do not use in areas without adequate ventilation.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
5 / 18
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage
areas and containers
: Keep in a dry, cool place.
Advice on common storage : Never allow product to get in contact with water during stor-
age.
Other data : Stable under normal conditions.
7.3 Specific end use(s)
Specific use(s) : Fungicide
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure Limits
Components CAS-No. Value type (Form
of exposure)
Control parameters Basis
propane-1,2-diol 57-55-6 TWA (particles) 10 mg/m3 GB EH40
Further information Where no specific short-term exposure limit is listed, a figure three times the
long-term exposure should be used
TWA (Total va-
pour and parti-
cles)
150 ppm
474 mg/m3
GB EH40
Further information Where no specific short-term exposure limit is listed, a figure three times the
long-term exposure should be used
8.2 Exposure controls
Engineering measures
Ensure that eyewash stations and safety showers are close to the workstation location.
Personal protective equipment
Eye protection : Safety glasses with side-shields
Hand protection
Remarks : Impervious butyl rubber gloves
Skin and body protection : Impervious clothing
Long sleeved clothing
Respiratory protection : In the case of vapour formation use a respirator with an ap-
proved filter.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance : liquid
Colour : red
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
6 / 18
Odour : characteristic
Odour Threshold : No data available
pH : 6 - 8
Melting point/range : Not applicable
Boiling point/boiling range : 100 °C
Flash point : > 100 °C
Evaporation rate : No data available
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapour pressure : No data available
Relative vapour density : No data available
Relative density : No data available
Density : 1.070 g/cm3
Solubility(ies)
Water solubility : completely miscible
Solubility in other solvents : No data available
Partition coefficient: n-
octanol/water
: No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity
Viscosity, dynamic : No data available
Viscosity, kinematic : No data available
9.2 Other information
Oxidizing potential : No information available.
SECTION 10: Stability and reactivity
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
7 / 18
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.
10.4 Conditions to avoid
Conditions to avoid : Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Materials to avoid : Oxidizing agents
Strong acids and strong bases
10.6 Hazardous decomposition products
Thermal decomposition can lead to release of irritating gases and vapours.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): > 2,500 mg/kg
GLP: yes
Acute inhalation toxicity : LC50 (Rat): > 5.66 mg/l
Test atmosphere: dust/mist
GLP: yes
Acute toxicity estimate: > 5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg
GLP: yes
Components:
1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]-1H-imidazole:
Acute oral toxicity : Acute toxicity estimate: 500 mg/kg
Method: Converted acute toxicity point estimate
Ipconazole:
Acute oral toxicity : LD50 (Rat, male): 1,338 mg/kg
Method: OECD Test Guideline 401
GLP: yes
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
8 / 18
LD50 (Rat, female): 888 mg/kg
Method: OECD Test Guideline 401
GLP: yes
LD50 (Mouse, male): 537 mg/kg
Method: OECD Test Guideline 401
GLP: yes
LD50 (Mouse, female): 468 mg/kg
Method: OECD Test Guideline 401
GLP: yes
Acute inhalation toxicity : LC50 (Rat, male and female): > 1.88 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
GLP: yes
LC50 (Rat, male and female): > 3.53 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
GLP: yes
Acute dermal toxicity : LD50 (Rat, male and female): > 2,000 mg/kg
Method: OECD Test Guideline 402
GLP: yes
Skin corrosion/irritation
Product:
Species: Rabbit
Result: No skin irritation
GLP: yes
Components:
Ipconazole:
Species: Rabbit
Exposure time: 4 h
Result: No skin irritation
GLP: yes
Serious eye damage/eye irritation
Product:
Species: Rabbit
Result: No eye irritation
GLP: yes
Components:
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
9 / 18
Ipconazole:
Species: Rabbit
Result: No eye irritation
GLP: yes
Respiratory or skin sensitisation
Product:
Species: Guinea pig
Result: Did not cause sensitisation on laboratory animals.
GLP: yes
Components:
Ipconazole:
Species: Guinea pig
Method: Magnusson-Kligmann-Test
Result: Did not cause sensitisation on laboratory animals.
GLP: yes
Germ cell mutagenicity
Components:
Ipconazole:
Genotoxicity in vitro : Test Type: Ames test
Metabolic activation: with and without metabolic activation
Method: Mutagenicity (Escherichia coli - reverse mutation
assay)
Result: negative
: Test Type: In Vitro mammalian Cell Gene Mutation Test
Metabolic activation: with and without metabolic activation
Result: negative
: Test Type: Chromosome aberration test in vitro
Metabolic activation: with and without metabolic activation
Result: negative
Genotoxicity in vivo : Test Type: Micronucleus test
Species: Mouse (male and female)
Cell type: Bone marrow
Application Route: Oral
Dose: 750, 1000 mg/kg bw/day
Result: negative
GLP: yes
Germ cell mutagenicity- As-
sessment
: In vitro tests did not show mutagenic effects
Carcinogenicity
Components:
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
10 / 18
Ipconazole:
Species: Mouse, (male and female)
Exposure time: 78 weeks
Dose: 0, 15, 175, 350 ppm
NOAEL: 15 ppm
LOAEL: 175 ppm
GLP: yes
Carcinogenicity - Assess-
ment
: Animal testing did not show any carcinogenic effects.
Reproductive toxicity
Components:
Ipconazole:
Effects on fertility : Species: Rat, male and female
Dose: 0, 30, 100 or 300 ppm
General Toxicity F1: No observed adverse effect level: 9 - 10
mg/kg bw/day
GLP: yes
Effects on foetal develop-
ment
: Species: Rabbit
Application Route: Oral
Dose: 0, 2, 10, 50 milligram per kilogram
General Toxicity Maternal: 10 mg/kg bw/day
Teratogenicity: 10 mg/kg bw/day
STOT - repeated exposure
Product:
Assessment: Not classified due to lack of data.
Components:
Ipconazole:
Target Organs: Eyes
Assessment: May cause damage to organs through prolonged or repeated exposure.
Repeated dose toxicity
Components:
Ipconazole:
Species: Rat, female
NOAEL: 7 mg/kg
LOAEL: 33.2 mg/kg
Application Route: Oral
Exposure time: 13 weeks
Dose: 3.1, 7.0, 15.4 and 33.2 mg/kg
GLP: yes
Target Organs: Adrenal gland, thymus gland
Species: Rat, male
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
11 / 18
NOAEL: 25.9 mg/kg
LOAEL: 52.2 mg/kg
Application Route: Oral
Exposure time: 13 weeks
Dose: 2.5, 5.8, 12.6, 25.9 and 52.2
GLP: yes
Target Organs: Adrenal gland, thymus gland
Species: Dog, male and female
NOAEL: 10 mg/kg
LOAEL: 40 mg/kg
Application Route: Dermal
Exposure time: 13 weeks
Dose: 0, 2, 10 or 40 mg/kg bw/day
GLP: yes
Species: Rat, male and female
NOAEL: 30 mg/kg
LOAEL: 100 mg/kg
Application Route: Inhalation
Test atmosphere: dust/mist
Exposure time: 28-day
Dose: 0, 30, 100, 300 or 1000 mg/m3
GLP: yes
Target Organs: Liver, Adrenal gland, spleen
Species: Dog, male and female
NOAEL: 1.5 mg/kg
LOAEL: 5 mg/kg
Exposure time: 13 weeks
Dose: 0, 1.5, 5, 20 mg/kg bw/day
GLP: yes
Target Organs: Eyes, Liver, Adrenal gland
Further information
Product:
Remarks: No data available
SECTION 12: Ecological information
12.1 Toxicity
Product:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 25 mg/l
Exposure time: 96 h
GLP: yes
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 40.68 mg/l
Exposure time: 48 h
GLP: yes
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
12 / 18
Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 1.56 mg/l
Exposure time: 72 h
GLP: yes
Components:
Ipconazole:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.4 mg/l
Exposure time: 96 h
Test Type: flow-through test
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 3.1 mg/l
Exposure time: 48 h
Test Type: flow-through test
Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): 0.17 mg/l
Exposure time: 120 h
Test Type: static test
M-Factor (Acute aquatic tox-
icity)
: 1
Toxicity to fish (Chronic toxic-
ity)
: NOEC: 0.12 mg/l
Exposure time: 90 d
Test Type: flow-through test
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)
: NOEC: 0.0109 mg/l
Exposure time: 21 d
Species: Daphnia magna (Water flea)
GLP: yes
NOEC: 0.37 mg/l
Exposure time: 21 d
Test Type: flow-through test
M-Factor (Chronic aquatic
toxicity)
: 100
Plant toxicity : 2.5 mg/kg
12.2 Persistence and degradability
Product:
Biodegradability : Remarks: No data available
Components:
Ipconazole:
Biodegradability : Remarks: Not readily biodegradable.
Stability in water : Degradation half life (DT50): 92 h pH: 5
Hydrolysis: at 25 °C
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
13 / 18
12.3 Bioaccumulative potential
Product:
Bioaccumulation : Remarks: No data available
Components:
Ipconazole:
Bioaccumulation : Bioconcentration factor (BCF): 165
Partition coefficient: n-
octanol/water
: log Pow: 4.28 - 4.49
12.4 Mobility in soil
Product:
Mobility : Remarks: No data available
12.5 Results of PBT and vPvB assessment
Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..
Components:
Ipconazole:
Assessment : This substance is not considered to be persistent, bioaccumu-
lating and toxic (PBT)..
12.6 Other adverse effects
Product:
Additional ecological informa-
tion
: An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Very toxic to aquatic life with long lasting effects.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product : Dispose of as hazardous waste in compliance with local and
national regulations.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
14 / 18
SECTION 14: Transport information
14.1 UN number
ADN : UN 3082
ADR : UN 3082
RID : UN 3082
IMDG : UN 3082
IATA : UN 3082
14.2 UN proper shipping name
ADN : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(Imazalil, Ipconazole)
ADR : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(Imazalil, Ipconazole)
RID : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(Imazalil, Ipconazole)
IMDG : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(Imazalil, Ipconazole)
IATA : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S., Environmentally hazardous substance, liquid, n.o.s.
(Imazalil, Ipconazole)
14.3 Transport hazard class(es)
ADN : 9
ADR : 9
RID : 9
IMDG : 9
IATA : 9
14.4 Packing group
ADN
Packing group : III
Classification Code : M6
Hazard Identification Number : 90
Labels : 9
ADR
Packing group : III
Classification Code : M6
Hazard Identification Number : 90
Labels : 9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
15 / 18
Tunnel restriction code : (E)
RID
Packing group : III
Classification Code : M6
Hazard Identification Number : 90
Labels : 9
IMDG
Packing group : III
Labels : 9
EmS Code : F-A, S-F
IATA
Packing instruction (cargo
aircraft)
: 964
Packing instruction (passen-
ger aircraft)
: 964
Packing instruction (LQ) : Y964
Packing group : III
Labels : Miscellaneous
14.5 Environmental hazards
ADN
Environmentally hazardous : yes
ADR
Environmentally hazardous : yes
RID
Environmentally hazardous : yes
IMDG
Marine pollutant : yes
14.6 Special precautions for user
Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Regulation (EC) No 649/2012 of the European Parlia-
ment and the Council concerning the export and import
of dangerous chemicals
: Not applicable
REACH - Candidate List of Substances of Very High
Concern for Authorisation (Article 59).
: Not applicable
Regulation (EC) No 1005/2009 on substances that de-
plete the ozone layer
: Not applicable
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
16 / 18
Regulation (EC) No 850/2004 on persistent organic pol-
lutants
: Not applicable
Quantity 1 Quantity 2
9b Dangerous for the envi-
ronment
200 t 500 t
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
E1 ENVIRONMENTAL
HAZARDS
100 t 200 t
Water contaminating class
(Germany)
: WGK 2 water endangering
Classification according VwVwS, Annex 4.
15.2 Chemical Safety Assessment
No information available.
SECTION 16: Other information
Full text of H-Statements
H302 : Harmful if swallowed.
H318 : Causes serious eye damage.
H332 : Harmful if inhaled.
H361 : Suspected of damaging fertility or the unborn child.
H373 : May cause damage to organs through prolonged or repeated
exposure.
H400 : Very toxic to aquatic life.
H410 : Very toxic to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Acute : Acute aquatic toxicity
Aquatic Chronic : Chronic aquatic toxicity
Eye Dam. : Serious eye damage
Repr. : Reproductive toxicity
STOT RE : Specific target organ toxicity - repeated exposure
(Q)SAR - (Quantitative) Structure Activity Relationship; ADN - European Agreement concerning
the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agree-
ment concerning the International Carriage of Dangerous Goods by Road; ASTM - American So-
ciety for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging
Regulation; Regulation (EC) No 1272/2008; DIN - Standard of the German Institute for Standardi-
sation; ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ErCx - Concentration associated with x% growth rate response;
GHS - Globally Harmonized System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and Equip-
ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra-
tion; ICAO - International Civil Aviation Organization; IMDG - International Maritime Dangerous
Goods; IMO - International Maritime Organization; ISO - International Organisation for Standardi-
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
17 / 18
zation; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a
test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; OECD - Organization for Economic Co-operation and Development; OPPTS - Of-
fice of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic
substance; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID
- Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TRGS - Technical Rule for
Hazardous Substances; UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative;
DSL - Domestic Substances List (Canada); KECI - Korea Existing Chemicals Inventory; TSCA -
Toxic Substances Control Act (United States); AICS - Australian Inventory of Chemical Sub-
stances; IECSC - Inventory of Existing Chemical Substances in China; ENCS - Existing and New
Chemical Substances (Japan); ISHL - Industrial Safety and Health Law (Japan); PICCS - Philip-
pines Inventory of Chemicals and Chemical Substances; NZIoC - New Zealand Inventory of
Chemicals; TCSI - Taiwan Chemical Substance Inventory; CMR - Carcinogen, Mutagen or Re-
productive Toxicant; GLP - Good Laboratory Practice
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
GB / EN
Carechem24 International Worldwide Coverage
Emergency Phone Number
Europe: All European Countries +44 (0) 1235 239 670 (NCEC)
Asia Pacific: East / South East Asia – Regional Number +65 3158 1074
Australia +61 2801 44558
New Zealand +64 9929 1483
China +86 532 8388 9090
China Taiwan +86 10 5100 3039
Japan +81 345 789 341
Indonesia 00780 3011 0293
Malaysia +60 3 6207 4347
Thailand 001800 1 2066 6751
Korea +65 3158 1285
+82 (0)234 798 401
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
RANCONA i-MIX
Version
2.2
Revision Date:
19.11.2015
MSDS Number:
000000001256
Country: GB
Language: EN
18 / 18
Vietnam +65 3158 1255
India +65 3158 1198
0800 100 7479
Pakistan +65 3158 1329
Philippines +65 31581203
Sri Lanka +65 3158 1195
Emergency Phone Number +65 3158 1200
Middle East / Africa: Arabic speaking countries +44 (0) 1235 239 671
South Africa +27 21 300 2732
All other countries +44 (0) 1235 239 670
America United States of America and Canada +1866 928 0789
+1 215 207 0061
Latin America: Brazil +55 11 3197 5891
Mexico +52 555 004 8763
Chile +56 225 829 336
All other countries +44 (0) 1235 239 670

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Safety data

  • 1. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 1 / 18 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : RANCONA i-MIX Product code : 000000001256 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Sub- stance/Mixture : Fungicide Recommended restrictions on use : Agriculture, For professional users only. 1.3 Details of the supplier of the safety data sheet Manufacturer or supplier's details Company: Chemtura Europe Limited Brooklands Farm, Cheltenham Road Evesham, Worcestershire United Kingdom WR11 2LS Telephone : +44 1386 425500 Prepared by sds.request@arysta.com Further information for the safety data sheet : sds.request@arysta.com 1.4 Emergency telephone number Emergency telephone num- ber: +44 (0) 1235 239 670 (NCEC) For additional emergency telephone numbers see section 16 of the Safety Data Sheet. SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting
  • 2. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 2 / 18 effects. Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Supplemental Hazard Statements : EUH401 To avoid risks to human health and the environment, comply with the instructions for use. Hazard pictograms : Signal word : Warning Hazard statements : H410 Very toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P273 Avoid release to the environment. Response: P391 Collect spillage. Disposal: P501 Dispose of contents/ container to an ap- proved waste disposal plant. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumula- tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients 3.2 Mixtures Chemical nature : Ipconazole - 20 gm/L Imazalil - 50 g/L Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification Concentration (% w/w)
  • 3. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 3 / 18 1-[2-(allyloxy)-2-(2,4- dichlorophenyl)ethyl]-1H- imidazole 35554-44-0 252-615-0 Acute Tox. 4; H302 Acute Tox. 4; H332 Eye Dam. 1; H318 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 >= 3 - < 10 Ipconazole 125225-28-7 Acute Tox. 4; H302 Acute Tox. 4; H332 Repr. 2; H361 STOT RE 2; H373 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 >= 1 - < 2.5 For explanation of abbreviations see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures If inhaled : Move to fresh air. Obtain medical attention. In case of skin contact : Take off contaminated clothing and shoes immediately. Wash off with warm water and soap. If symptoms persist, call a physician. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. If swallowed : Do NOT induce vomiting. Rinse mouth with water. Obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : Cancer Symptoms may be delayed. Risks : Suspected of causing cancer. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Extinguishing media - large fires Alcohol-resistant foam
  • 4. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 4 / 18 (on small fires) Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : Water spray jet 5.2 Special hazards arising from the substance or mixture Specific hazards during fire- fighting : No information available. 5.3 Advice for firefighters Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if nec- essary. Complete suit protecting against chemicals Flame- resistant clothing Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Wear suitable protective equipment. Avoid contact with skin and eyes. 6.2 Environmental precautions Environmental precautions : Do not allow uncontrolled discharge of product into the envi- ronment. Do not contaminate ponds, waterways or ditches with chemi- cal or used container. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Large spills should be collected mechanically (remove by pumping) for disposal. 6.4 Reference to other sections For personal protection see section 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Avoid inhalation, ingestion and contact with skin and eyes. Wash thoroughly after handling. Do not use in areas without adequate ventilation.
  • 5. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 5 / 18 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep in a dry, cool place. Advice on common storage : Never allow product to get in contact with water during stor- age. Other data : Stable under normal conditions. 7.3 Specific end use(s) Specific use(s) : Fungicide SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components CAS-No. Value type (Form of exposure) Control parameters Basis propane-1,2-diol 57-55-6 TWA (particles) 10 mg/m3 GB EH40 Further information Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used TWA (Total va- pour and parti- cles) 150 ppm 474 mg/m3 GB EH40 Further information Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used 8.2 Exposure controls Engineering measures Ensure that eyewash stations and safety showers are close to the workstation location. Personal protective equipment Eye protection : Safety glasses with side-shields Hand protection Remarks : Impervious butyl rubber gloves Skin and body protection : Impervious clothing Long sleeved clothing Respiratory protection : In the case of vapour formation use a respirator with an ap- proved filter. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : red
  • 6. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 6 / 18 Odour : characteristic Odour Threshold : No data available pH : 6 - 8 Melting point/range : Not applicable Boiling point/boiling range : 100 °C Flash point : > 100 °C Evaporation rate : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : No data available Relative density : No data available Density : 1.070 g/cm3 Solubility(ies) Water solubility : completely miscible Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : No data available 9.2 Other information Oxidizing potential : No information available. SECTION 10: Stability and reactivity
  • 7. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 7 / 18 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : No dangerous reaction known under conditions of normal use. 10.4 Conditions to avoid Conditions to avoid : Extremes of temperature and direct sunlight. 10.5 Incompatible materials Materials to avoid : Oxidizing agents Strong acids and strong bases 10.6 Hazardous decomposition products Thermal decomposition can lead to release of irritating gases and vapours. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Product: Acute oral toxicity : LD50 (Rat): > 2,500 mg/kg GLP: yes Acute inhalation toxicity : LC50 (Rat): > 5.66 mg/l Test atmosphere: dust/mist GLP: yes Acute toxicity estimate: > 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg GLP: yes Components: 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]-1H-imidazole: Acute oral toxicity : Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate Ipconazole: Acute oral toxicity : LD50 (Rat, male): 1,338 mg/kg Method: OECD Test Guideline 401 GLP: yes
  • 8. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 8 / 18 LD50 (Rat, female): 888 mg/kg Method: OECD Test Guideline 401 GLP: yes LD50 (Mouse, male): 537 mg/kg Method: OECD Test Guideline 401 GLP: yes LD50 (Mouse, female): 468 mg/kg Method: OECD Test Guideline 401 GLP: yes Acute inhalation toxicity : LC50 (Rat, male and female): > 1.88 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 GLP: yes LC50 (Rat, male and female): > 3.53 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 GLP: yes Acute dermal toxicity : LD50 (Rat, male and female): > 2,000 mg/kg Method: OECD Test Guideline 402 GLP: yes Skin corrosion/irritation Product: Species: Rabbit Result: No skin irritation GLP: yes Components: Ipconazole: Species: Rabbit Exposure time: 4 h Result: No skin irritation GLP: yes Serious eye damage/eye irritation Product: Species: Rabbit Result: No eye irritation GLP: yes Components:
  • 9. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 9 / 18 Ipconazole: Species: Rabbit Result: No eye irritation GLP: yes Respiratory or skin sensitisation Product: Species: Guinea pig Result: Did not cause sensitisation on laboratory animals. GLP: yes Components: Ipconazole: Species: Guinea pig Method: Magnusson-Kligmann-Test Result: Did not cause sensitisation on laboratory animals. GLP: yes Germ cell mutagenicity Components: Ipconazole: Genotoxicity in vitro : Test Type: Ames test Metabolic activation: with and without metabolic activation Method: Mutagenicity (Escherichia coli - reverse mutation assay) Result: negative : Test Type: In Vitro mammalian Cell Gene Mutation Test Metabolic activation: with and without metabolic activation Result: negative : Test Type: Chromosome aberration test in vitro Metabolic activation: with and without metabolic activation Result: negative Genotoxicity in vivo : Test Type: Micronucleus test Species: Mouse (male and female) Cell type: Bone marrow Application Route: Oral Dose: 750, 1000 mg/kg bw/day Result: negative GLP: yes Germ cell mutagenicity- As- sessment : In vitro tests did not show mutagenic effects Carcinogenicity Components:
  • 10. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 10 / 18 Ipconazole: Species: Mouse, (male and female) Exposure time: 78 weeks Dose: 0, 15, 175, 350 ppm NOAEL: 15 ppm LOAEL: 175 ppm GLP: yes Carcinogenicity - Assess- ment : Animal testing did not show any carcinogenic effects. Reproductive toxicity Components: Ipconazole: Effects on fertility : Species: Rat, male and female Dose: 0, 30, 100 or 300 ppm General Toxicity F1: No observed adverse effect level: 9 - 10 mg/kg bw/day GLP: yes Effects on foetal develop- ment : Species: Rabbit Application Route: Oral Dose: 0, 2, 10, 50 milligram per kilogram General Toxicity Maternal: 10 mg/kg bw/day Teratogenicity: 10 mg/kg bw/day STOT - repeated exposure Product: Assessment: Not classified due to lack of data. Components: Ipconazole: Target Organs: Eyes Assessment: May cause damage to organs through prolonged or repeated exposure. Repeated dose toxicity Components: Ipconazole: Species: Rat, female NOAEL: 7 mg/kg LOAEL: 33.2 mg/kg Application Route: Oral Exposure time: 13 weeks Dose: 3.1, 7.0, 15.4 and 33.2 mg/kg GLP: yes Target Organs: Adrenal gland, thymus gland Species: Rat, male
  • 11. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 11 / 18 NOAEL: 25.9 mg/kg LOAEL: 52.2 mg/kg Application Route: Oral Exposure time: 13 weeks Dose: 2.5, 5.8, 12.6, 25.9 and 52.2 GLP: yes Target Organs: Adrenal gland, thymus gland Species: Dog, male and female NOAEL: 10 mg/kg LOAEL: 40 mg/kg Application Route: Dermal Exposure time: 13 weeks Dose: 0, 2, 10 or 40 mg/kg bw/day GLP: yes Species: Rat, male and female NOAEL: 30 mg/kg LOAEL: 100 mg/kg Application Route: Inhalation Test atmosphere: dust/mist Exposure time: 28-day Dose: 0, 30, 100, 300 or 1000 mg/m3 GLP: yes Target Organs: Liver, Adrenal gland, spleen Species: Dog, male and female NOAEL: 1.5 mg/kg LOAEL: 5 mg/kg Exposure time: 13 weeks Dose: 0, 1.5, 5, 20 mg/kg bw/day GLP: yes Target Organs: Eyes, Liver, Adrenal gland Further information Product: Remarks: No data available SECTION 12: Ecological information 12.1 Toxicity Product: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 25 mg/l Exposure time: 96 h GLP: yes Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 40.68 mg/l Exposure time: 48 h GLP: yes
  • 12. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 12 / 18 Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 1.56 mg/l Exposure time: 72 h GLP: yes Components: Ipconazole: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.4 mg/l Exposure time: 96 h Test Type: flow-through test Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 3.1 mg/l Exposure time: 48 h Test Type: flow-through test Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): 0.17 mg/l Exposure time: 120 h Test Type: static test M-Factor (Acute aquatic tox- icity) : 1 Toxicity to fish (Chronic toxic- ity) : NOEC: 0.12 mg/l Exposure time: 90 d Test Type: flow-through test Toxicity to daphnia and other aquatic invertebrates (Chron- ic toxicity) : NOEC: 0.0109 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) GLP: yes NOEC: 0.37 mg/l Exposure time: 21 d Test Type: flow-through test M-Factor (Chronic aquatic toxicity) : 100 Plant toxicity : 2.5 mg/kg 12.2 Persistence and degradability Product: Biodegradability : Remarks: No data available Components: Ipconazole: Biodegradability : Remarks: Not readily biodegradable. Stability in water : Degradation half life (DT50): 92 h pH: 5 Hydrolysis: at 25 °C
  • 13. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 13 / 18 12.3 Bioaccumulative potential Product: Bioaccumulation : Remarks: No data available Components: Ipconazole: Bioaccumulation : Bioconcentration factor (BCF): 165 Partition coefficient: n- octanol/water : log Pow: 4.28 - 4.49 12.4 Mobility in soil Product: Mobility : Remarks: No data available 12.5 Results of PBT and vPvB assessment Product: Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.. Components: Ipconazole: Assessment : This substance is not considered to be persistent, bioaccumu- lating and toxic (PBT).. 12.6 Other adverse effects Product: Additional ecological informa- tion : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life with long lasting effects. SECTION 13: Disposal considerations 13.1 Waste treatment methods Product : Dispose of as hazardous waste in compliance with local and national regulations. Do not contaminate ponds, waterways or ditches with chemi- cal or used container. Contaminated packaging : Empty remaining contents. Dispose of as unused product.
  • 14. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 14 / 18 SECTION 14: Transport information 14.1 UN number ADN : UN 3082 ADR : UN 3082 RID : UN 3082 IMDG : UN 3082 IATA : UN 3082 14.2 UN proper shipping name ADN : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Imazalil, Ipconazole) ADR : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Imazalil, Ipconazole) RID : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Imazalil, Ipconazole) IMDG : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Imazalil, Ipconazole) IATA : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., Environmentally hazardous substance, liquid, n.o.s. (Imazalil, Ipconazole) 14.3 Transport hazard class(es) ADN : 9 ADR : 9 RID : 9 IMDG : 9 IATA : 9 14.4 Packing group ADN Packing group : III Classification Code : M6 Hazard Identification Number : 90 Labels : 9 ADR Packing group : III Classification Code : M6 Hazard Identification Number : 90 Labels : 9
  • 15. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 15 / 18 Tunnel restriction code : (E) RID Packing group : III Classification Code : M6 Hazard Identification Number : 90 Labels : 9 IMDG Packing group : III Labels : 9 EmS Code : F-A, S-F IATA Packing instruction (cargo aircraft) : 964 Packing instruction (passen- ger aircraft) : 964 Packing instruction (LQ) : Y964 Packing group : III Labels : Miscellaneous 14.5 Environmental hazards ADN Environmentally hazardous : yes ADR Environmentally hazardous : yes RID Environmentally hazardous : yes IMDG Marine pollutant : yes 14.6 Special precautions for user Not applicable 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mix- ture Regulation (EC) No 649/2012 of the European Parlia- ment and the Council concerning the export and import of dangerous chemicals : Not applicable REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : Not applicable Regulation (EC) No 1005/2009 on substances that de- plete the ozone layer : Not applicable
  • 16. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 16 / 18 Regulation (EC) No 850/2004 on persistent organic pol- lutants : Not applicable Quantity 1 Quantity 2 9b Dangerous for the envi- ronment 200 t 500 t Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. E1 ENVIRONMENTAL HAZARDS 100 t 200 t Water contaminating class (Germany) : WGK 2 water endangering Classification according VwVwS, Annex 4. 15.2 Chemical Safety Assessment No information available. SECTION 16: Other information Full text of H-Statements H302 : Harmful if swallowed. H318 : Causes serious eye damage. H332 : Harmful if inhaled. H361 : Suspected of damaging fertility or the unborn child. H373 : May cause damage to organs through prolonged or repeated exposure. H400 : Very toxic to aquatic life. H410 : Very toxic to aquatic life with long lasting effects. Full text of other abbreviations Acute Tox. : Acute toxicity Aquatic Acute : Acute aquatic toxicity Aquatic Chronic : Chronic aquatic toxicity Eye Dam. : Serious eye damage Repr. : Reproductive toxicity STOT RE : Specific target organ toxicity - repeated exposure (Q)SAR - (Quantitative) Structure Activity Relationship; ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agree- ment concerning the International Carriage of Dangerous Goods by Road; ASTM - American So- ciety for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; DIN - Standard of the German Institute for Standardi- sation; ECHA - European Chemicals Agency; EC-Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equip- ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra- tion; ICAO - International Civil Aviation Organization; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISO - International Organisation for Standardi-
  • 17. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 17 / 18 zation; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; OECD - Organization for Economic Co-operation and Development; OPPTS - Of- fice of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self- Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TRGS - Technical Rule for Hazardous Substances; UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative; DSL - Domestic Substances List (Canada); KECI - Korea Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); AICS - Australian Inventory of Chemical Sub- stances; IECSC - Inventory of Existing Chemical Substances in China; ENCS - Existing and New Chemical Substances (Japan); ISHL - Industrial Safety and Health Law (Japan); PICCS - Philip- pines Inventory of Chemicals and Chemical Substances; NZIoC - New Zealand Inventory of Chemicals; TCSI - Taiwan Chemical Substance Inventory; CMR - Carcinogen, Mutagen or Re- productive Toxicant; GLP - Good Laboratory Practice Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. GB / EN Carechem24 International Worldwide Coverage Emergency Phone Number Europe: All European Countries +44 (0) 1235 239 670 (NCEC) Asia Pacific: East / South East Asia – Regional Number +65 3158 1074 Australia +61 2801 44558 New Zealand +64 9929 1483 China +86 532 8388 9090 China Taiwan +86 10 5100 3039 Japan +81 345 789 341 Indonesia 00780 3011 0293 Malaysia +60 3 6207 4347 Thailand 001800 1 2066 6751 Korea +65 3158 1285 +82 (0)234 798 401
  • 18. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 RANCONA i-MIX Version 2.2 Revision Date: 19.11.2015 MSDS Number: 000000001256 Country: GB Language: EN 18 / 18 Vietnam +65 3158 1255 India +65 3158 1198 0800 100 7479 Pakistan +65 3158 1329 Philippines +65 31581203 Sri Lanka +65 3158 1195 Emergency Phone Number +65 3158 1200 Middle East / Africa: Arabic speaking countries +44 (0) 1235 239 671 South Africa +27 21 300 2732 All other countries +44 (0) 1235 239 670 America United States of America and Canada +1866 928 0789 +1 215 207 0061 Latin America: Brazil +55 11 3197 5891 Mexico +52 555 004 8763 Chile +56 225 829 336 All other countries +44 (0) 1235 239 670