1. Thầy Lê Ngọc Cát Băng - THPT Gò Vấp. Hóa 11
Lưu hành nội bộ 1
SƠ ĐỒ LIEÂN QUAN GIÖÕA CAÙC HIDROCARBON
CH3-CHO
CaCO3 1
CaO 2
CaC2 CH3 - CH3 14
9 10 CH3 - CH2Cl
Al4C3 4 3 12 13 15 16 19 20
CH3COONa 5
CH4 8
CHCH 11
CH2 = CH2 17
CH3CH2OH
C3H8
6 23 21
18
C
7
CH2 = CHCl P.E
22
25
24 27
30
P.V.C CH2 - CH2
OH OH
CH C - CH = CH2 26
CH2 = CH – CH = CH2 29
C4H10
28
(n-butan)
AgC  CAg Cao su Buna
31
34 HOOC – COOH (axit oxalic)
CH  CH 36
C6H5Cl 37
C6H5OH (phenol)
32
35
38
C6H5NO2 39
C6H5NH2 (Anilin)
CH2 = CH-OCOCH3
40
 T.N.B
(Vinyl Acetat)
41
C6H12 ( ciclohexan)
33 42
C6H6Cl6
P.V.A CH3
43 44
C6H5COOH (Axit benzoic )
(Toluen) 45
CH=CH2 T.N.T
46
47
P.S
(Stiren)
1. CaCO3
1000o
C
 CaO + CO2 2. CaO + 3C 2000o
C
 CaC2 + CO
3. CaC2 +2H2O  CH  CH + Ca(OH)2 4. Al4C3 + 12H2O  3CH4  + 4Al(OH)3
5. CH3COONa + NaOH   tCaO,
CH4  + Na2CO3
6. C3H8
o
cracking
t
 CH4 + C2H4
7. C + 2H2 
o
xt,t
CH4
8. 2CH4 
o
1500 C
laøm laïnh nhanh
CH  CH + 3H2
9. CH CH + H2O 4
80
o
HgSO
C
CH3CHO (Aldehid acetic) 10. CH  CH + 2H2
Ni
t
CH3 – CH3
11. CH  CH + H2
3Pd/PbCO ,t
 CH2 = CH2
12. CH2 = CH2 + H2   tNi,
CH3 – CH3
13. CH3 – CH3  txt,
CH2 = CH2 + H2 14. CH3CH3 + Cl2 askt
CH3CH2 Cl + HCl
15. CH2 = CH2 + HCl  CH3 – CH2 Cl 16. C2H5Cl + KOHñ o
Röôïu
t
CH2 = CH2 + KCl + H2O
17. CH2 = CH2 + H2O 2 4
o
H SO loaõng
t
CH3CH2OH 18. CH3CH2OH 2 4
o
H SO ñaëc
180 C
CH2 = CH2 + H2O

2. Thầy Lê Ngọc Cát Băng - THPT Gò Vấp. Hóa 11
Lưu hành nội bộ 2
CH3
19. CH3CH2OH + HCl CH3CH2 Cl + H2O 20.C2H5Cl + NaOH
o
t C
CH3CH2OH + NaCl
21. n CH2= CH2
o
xt,t
P
 ( CH2 - CH2 ) n (P.E) 22.3 CH2 = CH2 + 2KMnO4 + 4H2O 3 C2H4(OH)4 +
2 MnO2 + 2 KOH
23. CH  CH + HCl
2
o
Hg
t

 CH2 = CH - Cl 24. n CH2 = CH - Cl  
 ptxt ,,
( CH2 - CH ) n
Cl
25. 2CH  CH 4
o
NH Cl,CuCl
t
CH2 = CH - C  CH 26.CH  C – CH = CH2 + H2
3Pd/PbCO ,t

CH2 = CH - CH = CH2
27.2C2H5OH 2 3
o
Al O
450 C
CH2 = CH - CH = CH2 +H2
+2H2O
28.n CH2 = CH - CH = CH2
o
Na,t
P

( CH2 - CH = CH - CH2 ) n
29. CH2 = CH - CH = CH2 + 2 H2 O
Ni
t

CH3 - CH2 - CH2 - CH3
30.CH  CH + 2AgNO3 + 2NH3  AgCCAg +
2 NH4NO3
31. AgC Cag + 2HCl CHCH + 2AgCl 32.CH  CH + CH3COOH  CH2 = CH -OCOCH3
33. n CH2 = CH - OCOCH3
o
xt,t
P
 ( CH2 - CH )n
34. CH  CH + KMnO4 + H2O  HOOC - COOH + MnO2 + KOH
35. 3 CH  CH o
C hoaïttính
600 C
(C6H6 : benzen )
36. C6H6 + Cl2  
tFe,
C6H5Cl + HCl
37. C6H5Cl + NaOH  
 pt ,
C6H5OH + NaCl
38. C6H6 + HNO3ñ
2 4H SO ñaëc
C6H5NO2 + H2O
39. C6H5NO2 + 6 [H] Fe HCl
C6H5NH2 + 2H2O
40. C6H5NO2 + 2HNO3ñ
2 4H SO ñaëc
 + 2H2O
41. C6H6 + 3H2   tNi,
C6H12
42. C6H6 + 3Cl2 askt
C6H6Cl6 (6.6.6)
43. C6H6 + CH3Cl 3
o
AlCl
t
C6H5CH3 + HCl
44. C6H5CH3 + 3[O] 4 ñaëcKMnO
C6H5COOH + H2O
45. C6H5CH3 + 3HNO3ñ
2 4H SO ñaëc
 + 3 H2O
46. C6H6 + CH2 = CH - Cl 3
o
AlCl
t
 C6H5 - CH= CH2 + HCl
47. n C6H5 - CH= CH2  
 ptxt ,,
( CH - CH2 )n
C6H5 ( P.S: poli Stiren)
OCOCH3
NO2
NO2O2N
NO2
NO2
O2N