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HIGHLIGHTS
POLINOVA TECHNOLOGIES
2013
1
Highlights
Polinova has four main research areas:
 High performance coating
 Epoxy putty

43 products ready

 Structural adhesives
 Structural reinforcement with composite

Others secondary research areas are:
 Tools for leakage control in pipe (2 prototypes developed)
 Special coatings for subsea applications (laboratory research)
 Pipe support manufacture in composite (in test at Petrobras)

2
Highlights

 The highlights of Polinova technologies are the use of nanoparticules and
chemical modifications of epoxy matrix to produce nanoepoxy structures.

 The objectives of this research are improve the mechanical properties,
adhesion strength and chemical resistance of new generations of
Polinova’s products.

 The new nanoepoxy adhesive and nanoepoxy coating will go to market in
2014.

3
Highlights

Our Technical Team has more than 14 years of experience in modifications
of epoxy resin in partnership with Federal University of Rio de Janeiro
(UFRJ) and Petrobras. Furthermore, the project of nano modification of
epoxy products has 0.6 million dollars to apply in this research in two years
(FINEP financing).

4
Highlights
Architecture of our
technology
Different epoxy resins
Dispersion and
surface modification

Chemical reactions

Modifications with
polymers

Carbon nanotubes
Nano ceramics

Products from
chemical modification

Products from
physic modification
Products from
hybrid technologies
5
Highlights
Actual stage of nanotechnologies
1- Matrix
 2 epoxy matrix developed from physics modifications
 6 epoxy matrix developed from chemical modifications
 2 epoxy matrix developed from hybrid technology

2- Preliminary tests
 Chemical resistance
 Lap Shear and pull off (adhesion tests)
 Tension tests

6
Highlights

1- No modified epoxy resin
2- Physic modification
3- Chemical modification
4- Hybrid Technology

Cured samples to realize chemical test
and Lap Shear samples to test

7
Highlights
Benefits of nanotechnologies in development by Polinova
1- Physic modifications:
 improve abrasion resistance
 improve chemical and corrosion resistances
 improve toughening
2- Chemical modifications:
 improve adhesion strength
 improve mechanical properties in general
3- Hybrid Technologies:
 Ultra High Performance Coatings, Adhesives, Epoxy Putty and
Composites
8
Highlights
Some possible applications of Polinova’s nanotechnologies:
 High strength adhesives for composites parts in aeronautic market
 Special coatings to protect Pre-Salt equipments against wearing or
chemical attack
 Intelligent coating to indicated specific situations
 High performance epoxy matrix

to produce fiber

reinforcement

composites to use in automotive market, aeronautic, marine, subsea, etc.

9
Highlights
Certifications
 ISO 9001
Main Corporative Supplier Register in Brazil
 Petrobras (CRCC)
 Marinha do Brasil
 ONIP / CadFor
Qualifications of products (Type Approval)
 (Petrobras) 2 for epoxy putty + 2 for Novolac coatings
 (Marinha do Brasil) 1 for epoxy putty
 (SAC Votorantin) 3 for epoxy putty + 3 for coatings
 (Instituto Adolfo Lutz - water and food contact) 1 for epoxy putty
10
Highlights
Technologies in qualification process
 (Petrobras) 4 coatings (1 with carbon nanotubes)
 (Petrobras) 1 pipe support in composite
 (Petrobras) 1 structural reinforcement composite for pipe
 (National Oil Vargo) 1 nano adhesive to joint glass fiber pipes
 (TSA) 1 coating for water pipe, drill pipe and tubing
 (Vallourec Mannesmann) 2 coatings for drill pipe
 (Instituto Adolfo Lutz) 1 coating for water and food
 (Idutto) 2 epoxy sealants for subsea sensors
 (Houston Distributor) 6 epoxy putty and 2 coatings in test
 (Florida Distributor) 7 epoxy putty and 3 coatings in test
11
Highlights
Others R&D projects that we are working now
 (FMC Technologies) 1 insulation coating for subsea application
 (Petrobras) 2 compact equipments to separated water and oil

Some opportunities not explored
 (Soco Therm) test of 2 coatings
 (Embraer / Helibras) test of 1 or 2 Hybrid adhesives
 (Defense) development invisible coating for radar with nanotechnology

12
13

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Highlights Polinova 2013

  • 2. Highlights Polinova has four main research areas:  High performance coating  Epoxy putty 43 products ready  Structural adhesives  Structural reinforcement with composite Others secondary research areas are:  Tools for leakage control in pipe (2 prototypes developed)  Special coatings for subsea applications (laboratory research)  Pipe support manufacture in composite (in test at Petrobras) 2
  • 3. Highlights  The highlights of Polinova technologies are the use of nanoparticules and chemical modifications of epoxy matrix to produce nanoepoxy structures.  The objectives of this research are improve the mechanical properties, adhesion strength and chemical resistance of new generations of Polinova’s products.  The new nanoepoxy adhesive and nanoepoxy coating will go to market in 2014. 3
  • 4. Highlights Our Technical Team has more than 14 years of experience in modifications of epoxy resin in partnership with Federal University of Rio de Janeiro (UFRJ) and Petrobras. Furthermore, the project of nano modification of epoxy products has 0.6 million dollars to apply in this research in two years (FINEP financing). 4
  • 5. Highlights Architecture of our technology Different epoxy resins Dispersion and surface modification Chemical reactions Modifications with polymers Carbon nanotubes Nano ceramics Products from chemical modification Products from physic modification Products from hybrid technologies 5
  • 6. Highlights Actual stage of nanotechnologies 1- Matrix  2 epoxy matrix developed from physics modifications  6 epoxy matrix developed from chemical modifications  2 epoxy matrix developed from hybrid technology 2- Preliminary tests  Chemical resistance  Lap Shear and pull off (adhesion tests)  Tension tests 6
  • 7. Highlights 1- No modified epoxy resin 2- Physic modification 3- Chemical modification 4- Hybrid Technology Cured samples to realize chemical test and Lap Shear samples to test 7
  • 8. Highlights Benefits of nanotechnologies in development by Polinova 1- Physic modifications:  improve abrasion resistance  improve chemical and corrosion resistances  improve toughening 2- Chemical modifications:  improve adhesion strength  improve mechanical properties in general 3- Hybrid Technologies:  Ultra High Performance Coatings, Adhesives, Epoxy Putty and Composites 8
  • 9. Highlights Some possible applications of Polinova’s nanotechnologies:  High strength adhesives for composites parts in aeronautic market  Special coatings to protect Pre-Salt equipments against wearing or chemical attack  Intelligent coating to indicated specific situations  High performance epoxy matrix to produce fiber reinforcement composites to use in automotive market, aeronautic, marine, subsea, etc. 9
  • 10. Highlights Certifications  ISO 9001 Main Corporative Supplier Register in Brazil  Petrobras (CRCC)  Marinha do Brasil  ONIP / CadFor Qualifications of products (Type Approval)  (Petrobras) 2 for epoxy putty + 2 for Novolac coatings  (Marinha do Brasil) 1 for epoxy putty  (SAC Votorantin) 3 for epoxy putty + 3 for coatings  (Instituto Adolfo Lutz - water and food contact) 1 for epoxy putty 10
  • 11. Highlights Technologies in qualification process  (Petrobras) 4 coatings (1 with carbon nanotubes)  (Petrobras) 1 pipe support in composite  (Petrobras) 1 structural reinforcement composite for pipe  (National Oil Vargo) 1 nano adhesive to joint glass fiber pipes  (TSA) 1 coating for water pipe, drill pipe and tubing  (Vallourec Mannesmann) 2 coatings for drill pipe  (Instituto Adolfo Lutz) 1 coating for water and food  (Idutto) 2 epoxy sealants for subsea sensors  (Houston Distributor) 6 epoxy putty and 2 coatings in test  (Florida Distributor) 7 epoxy putty and 3 coatings in test 11
  • 12. Highlights Others R&D projects that we are working now  (FMC Technologies) 1 insulation coating for subsea application  (Petrobras) 2 compact equipments to separated water and oil Some opportunities not explored  (Soco Therm) test of 2 coatings  (Embraer / Helibras) test of 1 or 2 Hybrid adhesives  (Defense) development invisible coating for radar with nanotechnology 12
  • 13. 13