2. Cement : A basic overview
• Cement is a fine powder material, which can work as a binder when water is
added to it.
• The word “cement” is derived from the Latin word “caementum”, which means
chipped rock fragments.
6. Cement : A basic overview
Chemically cement is a mixture of Silicates, Aluminates & aluminoferrites with some amount of MgO
and gypsum.
Various complexes contained in cement:
(2CaO.SiO2) Di Calcium Silicate (C2S) 22-24%
(3CaO.SiO2) Tri Calcium Silicate (C3S) 50-58%
(3CaO.Al2O3) Tri Calcium Aluminate (C3A) 10-11%
(4CaO.Al2O3.Fe2O3) Tetra Calcium Aluminoferrite
(C4AF) 8-9%
(6CaO.Al2O3.Fe2O3) Hexa Calcium Aluminoferrite
(C6AF) traces
MgO <5%
Gypsum (CaSO4.2H2O) 4-5%
Various oxides contained in cement:
CaO 60-66%
Total silica 20-15%
Combined silica/active silica
Uncombined or inert silica
Alumina (Al2O3) 3-8%
Fe2O3 1-5%
MgO <5%
Alkalis <5%0
7. Cement : A basic overview
Colour
The gray color in cement is due to presence of complexes of Ferric ions in O.P.C (ordinary Portland cement).
White cement is produced from those raw materials which contain extremely low conc. of Iron & even like low
conc. of Iron is converted from Fe+3 to Fe+2 (which can be done by reducing or maintaining atmosphere in the kiln)
& eventually the product appears to be white.
Raw Materials required for Cement manufacturing
Limestone ( CaCO3, MgCo3, SiO2)
Clay (SiO2, Al2O3, Fe2O3 Mg(OH)2, Alkali)
Sandstone (SiO2, Fe2O3, CaO, Alkali)
Gypsum (CaSO4.2H2O)