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Seasonal Analysis and Source Apportionment of Hourly Volatile Organic Compound Data In the Corpus Christi Urban Airshed ,[object Object],[object Object],[object Object]
Objectives ,[object Object],[object Object],[object Object],[object Object],[object Object]
Study Area
Data Set ,[object Object],[object Object],[object Object],[object Object],5. U.S. Environmental Protection Agency Center for Environmental Research Information Office of Research and Development  Compendium Method TO-14 Determination of Volatile Organic Compounds (VOC)s in Air Collected in specially Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS) ; EPA/625/R-96/010b; United States Environmental Protection Agency: January,  1999 .
Source Receptor Modeling ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[X] = [ G][F] +[ E]
Positive Matrix Factorization (PMF) Model 3 ,[object Object],[object Object],[object Object],3. Paatero, P.; Tapper, U., Positive Matrix Factorization: a Non-negative Factor Model With Optimal Utilization of Error Estimates of Data Values.  Environmetrics  1994,  5, 111-126. 4. Hopke, P. K.  A Guide to Positive Matrix Factorization ; Clarkson University, Department of Chemical Engineering: Potsdam, New York.
Natural Gas Source Isobutane Propane N-Butane Ethane
Fugitive Gasoline Source Isopentane n-Butane n-Pentane
Vehicle Exhaust Source Isopentane Toluene M&P-Xylene Benzene
Catalytic Reforming Source Cyclohexane Methylcyclohexane Methylcyclopentane N-Hexane
Refinery Evaporative Source Isopentane n-Butane 1-butene Trans-2-Butene
Source Contributions
Seasonal Analysis of VOC Species at Solar Estates C633
Seasonal Analysis of VOC Species at Oak Park C634
Seasonal Analysis of the Source Contribution at Solar Estates C633
Seasonal Analysis of Source Contribution at Oak Park C634
Summary and Conclusions ,[object Object],[object Object],[object Object],[object Object]
Summary and Co conclusions Continued ,[object Object],[object Object],[object Object],[object Object]
Acknowledgments ,[object Object],[object Object]
Thank You ,[object Object]

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VOC source apportionment in Corpus Christi using PMF analysis

Editor's Notes

  1. The objectives of this paper were to evalute the long therm trends of Volatile Organic Compounds (VOC)measured at two air toxics monitoring sites in Corpus Christi Texas; perform source receptor analysis using the the Positive Matrix Factorization model to identify VOC source profiles and quantify the VOC source contributions; relate the long term trends to changes in the source contributions; and use conditional probablity function analysis to determine which wind direction the VOC sources are associated with.