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Bulletin of Electrochemistry
Volume 12, Issue 3-4, March 1996, Pages 234-236
Electrodeposition of lead and its dioxide from Egyptial
carbonate ore residuum (Article)
Madkour, L.H.
Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt
View references (19)
Abstract
Acid-leach residue resulting from the sulphate roasting of Zn-Pb Egyptial carbonate ore is used for the production of
lead, after hydrometallurgical treatments. Studies to investigate various baths for the deposition of lead and lead
dioxide have been carried out. The results showed a wide variety of electrolysis, either soluble simple salts, or those
containing complex anions and in virtually all cases, very high current efficiencies are obtained. The effects of various
factors on the electrodeposition of Pb and PbO2 are discussed. In commercial practice, the properties and service
requirements dictate the precise electrolyte that should be used since the properties of electrodeposited lead vary
with the baths. Mechanism of the electrolytic production of the element and its dioxide is discussed. The results
spectrophotometric and chemical analyses revealed that the purity of the metal is > 99%.
Author keywords
Carbonate ore residuum; Hydrometallurgical treatments; Lead extraction
ISSN: 02561654 CODEN: BUELESource Type: Journal Original language: English
Document Type: Article
View in search results format
References (19)
1
Madkour, Loutfy H.
THERMODYNAMIC STUDIES ON SULPHATE ROASTING FOR ZINC ELECTROWINNING FROM CARBONATE
ORE.
(1986) Journal of Chemical Technology and Biotechnology, 36 (5), pp. 197-211. Cited 2 times.
 View at Publisher
2
Morris, J.A.
ELECTROPLATING IN THE PLAIN BEARING INDUSTRY.
(1973) Transactions of the Institute of Metal Finishing, 51 (Part 2 Conf), pp. 56-61.
3
Fraunhofer, J.A.
(1976) Basic Metal Finishing Elek Science
London

4
Afifi, S.E., Taha, F., Madkour, L.H.
(1984) Egypt J Chem, 27 (3), p. 275. Cited 3 times.

5
Madkour, Loutfy H.
RECOMMENDED FLOWSHEETS FOR THE ELECTROLYTIC EXTRACTION OF LEAD AND ZINC FROM RED
SEA POLYMETAL ORE.
(1985) Journal of chemical technology and biotechnology. Chemical technology, 35 A (3), pp. 108-114. Cited 4 times.
6
Hampson, N., Brushrod, C.
(1971) Brit Corros J, 6, p. 129.

7
Volgina, V.A., Nechaev, E.A.
(1973) Sov Electrochem, 9, p. 984.

8
(1973) Sov Electrochem, 9, p. 1717.

9
Walker, R.
(1974) Int Metall Rev, 19, p. 1. Cited 2 times.

10
Narasimham, K.C., Sundararajan, S., Udupa, H.V.K.
(1965) Bull Acad Polon Ser Sci, 13, p. 619.

11
Madkour, L.H., Fouda, A.S.
Electrodeposition of titanium and its dioxide from ilmenite
(1986) Journal of Electroanalytical Chemistry, 199 (1), pp. 207-210. Cited 5 times.
doi: 10.1016/0022-0728(86)87053-X
 View at Publisher
12
Kenvert International Corporation, Brit Patent, 1,368,318 (1974)
 View on Web
13
Uence, A., Okubo, K., Kinzoku
(1964) Hyomen Gijutsu, 15, p. 216.

14
Seth, R.L.
(1972) Electroplat Metal Finish, 25, p. 5. Cited 2 times.

15
Nichkov, I.F., Paspopin, S.P., Devyakkin, V.I.
(1962) Tr Ural Pelitekh Inst, 121, p. 18. Cited 3 times.

16
Fouda, A.S., Elsemongy, M.M., Kenawy, I.M.
ELECTROLYTIC PRODUCTION OF TITANIUM AND ITS DIOXIDE.
(1982) Indian Journal of Technology, 20 (4), pp. 139-141. Cited 4 times.
17
Fouda, A.S., Elsemongy, M.M.
Cathodic deposition of thorium
(1981) Journal of Electroanalytical Chemistry, 124 (1-2), pp. 301-305. Cited 3 times.
18
Antropov, L.I.
(1972) Theoretical Electrochemistry, USSR, p. 477.
129820 Moscow 1-110, G-SP

19
Fouda, A.S.
Simple baths for the deposition of nickel oxides
(1980) Journal of Electroanalytical Chemistry, 114 (1), pp. 83-88. Cited 6 times.
doi: 10.1016/S0022-0728(80)80437-2
 View at Publisher
Madkour, L.H.; Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt
© Copyright 2004 Elsevier Science B.V., Amsterdam. All rights reserved.
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Title:
Electrodeposition of lead and its
dioxide from egyptial carbonate ore
residuum
Author / Creator:
Madkour, L. H. ; Society for the Advancement of Electrochemical Science
and Technology
In:
BULLETIN OF ELECTROCHEMISTRY; 12, 3//4; 234-236
Advances in electrochemical science and technology
International symposium; 5th, Advances in electrochemical science and
technology
Supplier: Central Electrochemical Research Institute , Karaikudi
Year of
publication:
1996
Size: 3 Pages
ISSN: 0256-1654
Type of media: Conference paper
Type of material: Print
Language: English
Keywords: electrochemical science, electrochemical technology
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Bulletin-Pb

  • 1. Bulletin of Electrochemistry Volume 12, Issue 3-4, March 1996, Pages 234-236 Electrodeposition of lead and its dioxide from Egyptial carbonate ore residuum (Article) Madkour, L.H. Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt View references (19) Abstract Acid-leach residue resulting from the sulphate roasting of Zn-Pb Egyptial carbonate ore is used for the production of lead, after hydrometallurgical treatments. Studies to investigate various baths for the deposition of lead and lead dioxide have been carried out. The results showed a wide variety of electrolysis, either soluble simple salts, or those containing complex anions and in virtually all cases, very high current efficiencies are obtained. The effects of various factors on the electrodeposition of Pb and PbO2 are discussed. In commercial practice, the properties and service requirements dictate the precise electrolyte that should be used since the properties of electrodeposited lead vary with the baths. Mechanism of the electrolytic production of the element and its dioxide is discussed. The results spectrophotometric and chemical analyses revealed that the purity of the metal is > 99%. Author keywords Carbonate ore residuum; Hydrometallurgical treatments; Lead extraction ISSN: 02561654 CODEN: BUELESource Type: Journal Original language: English Document Type: Article View in search results format References (19) 1 Madkour, Loutfy H. THERMODYNAMIC STUDIES ON SULPHATE ROASTING FOR ZINC ELECTROWINNING FROM CARBONATE ORE. (1986) Journal of Chemical Technology and Biotechnology, 36 (5), pp. 197-211. Cited 2 times.  View at Publisher 2 Morris, J.A. ELECTROPLATING IN THE PLAIN BEARING INDUSTRY. (1973) Transactions of the Institute of Metal Finishing, 51 (Part 2 Conf), pp. 56-61. 3 Fraunhofer, J.A. (1976) Basic Metal Finishing Elek Science London 
  • 2. 4 Afifi, S.E., Taha, F., Madkour, L.H. (1984) Egypt J Chem, 27 (3), p. 275. Cited 3 times.  5 Madkour, Loutfy H. RECOMMENDED FLOWSHEETS FOR THE ELECTROLYTIC EXTRACTION OF LEAD AND ZINC FROM RED SEA POLYMETAL ORE. (1985) Journal of chemical technology and biotechnology. Chemical technology, 35 A (3), pp. 108-114. Cited 4 times. 6 Hampson, N., Brushrod, C. (1971) Brit Corros J, 6, p. 129.  7 Volgina, V.A., Nechaev, E.A. (1973) Sov Electrochem, 9, p. 984.  8 (1973) Sov Electrochem, 9, p. 1717.  9 Walker, R. (1974) Int Metall Rev, 19, p. 1. Cited 2 times.  10 Narasimham, K.C., Sundararajan, S., Udupa, H.V.K. (1965) Bull Acad Polon Ser Sci, 13, p. 619.  11 Madkour, L.H., Fouda, A.S. Electrodeposition of titanium and its dioxide from ilmenite (1986) Journal of Electroanalytical Chemistry, 199 (1), pp. 207-210. Cited 5 times. doi: 10.1016/0022-0728(86)87053-X  View at Publisher
  • 3. 12 Kenvert International Corporation, Brit Patent, 1,368,318 (1974)  View on Web 13 Uence, A., Okubo, K., Kinzoku (1964) Hyomen Gijutsu, 15, p. 216.  14 Seth, R.L. (1972) Electroplat Metal Finish, 25, p. 5. Cited 2 times.  15 Nichkov, I.F., Paspopin, S.P., Devyakkin, V.I. (1962) Tr Ural Pelitekh Inst, 121, p. 18. Cited 3 times.  16 Fouda, A.S., Elsemongy, M.M., Kenawy, I.M. ELECTROLYTIC PRODUCTION OF TITANIUM AND ITS DIOXIDE. (1982) Indian Journal of Technology, 20 (4), pp. 139-141. Cited 4 times. 17 Fouda, A.S., Elsemongy, M.M. Cathodic deposition of thorium (1981) Journal of Electroanalytical Chemistry, 124 (1-2), pp. 301-305. Cited 3 times. 18 Antropov, L.I. (1972) Theoretical Electrochemistry, USSR, p. 477. 129820 Moscow 1-110, G-SP  19 Fouda, A.S. Simple baths for the deposition of nickel oxides (1980) Journal of Electroanalytical Chemistry, 114 (1), pp. 83-88. Cited 6 times. doi: 10.1016/S0022-0728(80)80437-2  View at Publisher Madkour, L.H.; Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt © Copyright 2004 Elsevier Science B.V., Amsterdam. All rights reserved.
  • 4. GetInfo - Specialist Information on Science and Technology TIB - German National Library of Science and Technology ContactDeutsch Detail display Title: Electrodeposition of lead and its dioxide from egyptial carbonate ore residuum Author / Creator: Madkour, L. H. ; Society for the Advancement of Electrochemical Science and Technology In: BULLETIN OF ELECTROCHEMISTRY; 12, 3//4; 234-236 Advances in electrochemical science and technology International symposium; 5th, Advances in electrochemical science and technology Supplier: Central Electrochemical Research Institute , Karaikudi Year of publication: 1996 Size: 3 Pages ISSN: 0256-1654 Type of media: Conference paper Type of material: Print Language: English Keywords: electrochemical science, electrochemical technology © Metadata Copyright the British Library Board and other contributors. All rights reserved. Check availability in your Library: When choosing delivery via GetInfo by clicking "Order" Royalty mentioned below is applicable as part of the total price - 2005 commercial customers academic customers TIBsubito Library Service E-Mail Postal Fax E-Mail Postal Fax E-Mail Postal Fax (DEU) 2.52 Euro Royalty 5.50 EuroRoyalty 5.50 Euro Royalty
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