The document presents technologies from ARS Technologies for addressing complex environmental problems. It discusses ARS's proven experience developing technologies through university research programs. It also describes pneumatic fracturing and atomized liquid injection techniques for improving permeability and uniformly distributing chemicals. Finally, it outlines ARS's services including fracturing, chemical injection, advanced drilling, and chemical formulation assistance.

1. Practical Solutions
For
Complex Problems
Presented to

2. ARS TECHNOLOGIES FAMILY OF COMPANIES
Practical Solutions For
Complex Problems
Proven Experience
Better Amendment
Delivery
Safe, Knowledgeable &
Convenient Chemical
Services

3. PRESENTER
Robert Kelley, Ph.D.
Vice President of Technology Development
ARS Technologies, Inc
732-253-8131
bk@arstechnologies.com

4. PROVEN EXPERIENCE

5. PROVEN EXPERIENCE
Technologies Developed by
Prestigious University Research
Program
10 Ph.D.s
5 US Patents

6. PROVEN EXPERIENCE
Technologies Developed by
Prestigious University Research
Program
10 Ph.D.s
5 US Patents
Certified by USEPA Site Program

7. PROVEN EXPERIENCE
Technologies Developed by
Prestigious University Research
Program
10 Ph.D.s
5 US Patents
Certified by USEPA Site Program
300 + Sites

8. PROVEN EXPERIENCE
Technologies Developed by
Prestigious University Research
Program
10 Ph.D.s
5 US Patents
Certified by USEPA Site Program
300 + Sites
19 Years Commercial Experience

9. Safety Record
Full-Time Health and Safety Officer
“Stop-Job” Policy Empowers Any Worker
to Stop Operation on SIte If They Believe
the Site Unsafe
Zero Loss Time Cases
Zero Property Loss Claims

10. NATIONWIDE PRESENCE
New
Berkeley Chicago
Brunswick
Wilmington
Atlanta
Houston
Orlando

11. SERVICES

12. SERVICES

13. OUR TECHNOLOGIES
Pneumatic
Fracturing
Gas is injected into the
subsurface at pressures
exceeding the natural
in-situ pressures and at
flow rates that exceed
nature permeability

14. OUR TECHNOLOGIES
Pneumatic
Fracturing
Gas is injected into the
subsurface at pressures
exceeding the natural
in-situ pressures and at
flow rates that exceed
nature permeability

15. OUR TECHNOLOGIES
Pneumatic
Fracturing Soil Vapor
Gas is injected into the Extraction
subsurface at pressures
exceeding the natural
in-situ pressures and at
Pump and Treat
flow rates that exceed
nature permeability
Air Sparging

16. OUR TECHNOLOGIES
Pneumatic
Fracturing Soil Vapor
Gas is injected into the Extraction
subsurface at pressures
exceeding the natural
in-situ pressures and at
Pump and Treat
flow rates that exceed
nature permeability
Air Sparging
Atomized Liquid
Injection
Atomized Liquid
injection is a very
Injections effective method for
injecting liquids/
slurries/powder
uniformly within all
types of geology

17. OUR TECHNOLOGIES
Pneumatic
Fracturing Soil Vapor
Gas is injected into the Extraction
subsurface at pressures
exceeding the natural
in-situ pressures and at
Pump and Treat
flow rates that exceed
nature permeability
Air Sparging
Atomized Liquid
Injection
Atomized Liquid Ferox™ZVI
injection is a very
Injections effective method for
injecting liquids/
slurries/powder
Chemox
uniformly within all
types of geology
Bioaugmentation

18. COMPLEX GEOLOGY PRESENTS
MAJOR CHALLENGES
Fractured Rock
Fine Sands
Heterogeneous
Clay

19. FRACTURING TECHNOLOGY
Permeability Enhancement

20. FRACTURING TECHNOLOGY
Permeability Enhancement

21. GAS FRACTURING CHARACTERIZED

22. GAS FRACTURING CHARACTERIZED
Relatively Low Pressure,
High Volume Process

23. GAS FRACTURING CHARACTERIZED
Relatively Low Pressure,
High Volume Process
15 second Injection Per
interval

24. GAS FRACTURING CHARACTERIZED
Relatively Low Pressure,
High Volume Process
15 second Injection Per
interval
1 meter packer interval

25. GAS FRACTURING CHARACTERIZED
Relatively Low Pressure,
High Volume Process
15 second Injection Per
interval
1 meter packer interval
Fracture ROI 15-70 ft

26. PNEUMATIC FRACTURING

27. OTHER FRACTURING METHODS

28. OTHER FRACTURING METHODS
Hydraulic Fracturing
Oil Field Use As Well As Development Tool
Well Drillers As Water Well Development Tool

29. OTHER FRACTURING METHODS
Hydraulic Fracturing
Oil Field Use As Well As Development Tool
Well Drillers As Water Well Development Tool
Blast Fracturing
Use Of Down-hole Explosives
Blast Fracturing Can Break Competent Rock

30. PNEUMATIC FRACTURE APPLICATION METHODS
“How Is Fracturing Applied”

31. PNEUMATIC FRACTURE APPLICATION METHODS
“How Is Fracturing Applied”

32. PNEUMATIC FRACTURE APPLICATION METHODS
“How Is Fracturing Applied”
Open Borehole (4in – 6in diameter)

33. PNEUMATIC FRACTURE APPLICATION METHODS
“How Is Fracturing Applied”
Open Borehole (4in – 6in diameter)
Cased Borehole

34. PNEUMATIC FRACTURE APPLICATION METHODS
“How Is Fracturing Applied”
Open Borehole (4in – 6in diameter)
Cased Borehole
Direct-Push-Drilling Methods
GeoProbe 5,6,7, Series —
Shallow Depth
GeoProbe 8040 —
Intermediate Depth/Difficult Conditions
Sonic —
Deep Depth/Difficult Conditions

35. PRESSURE — TIME HISTORY CURVES
Tells Us What’s Happening Below the Ground

36. PRESSURE — TIME HISTORY CURVES
Tells Us What’s Happening Below the Ground
150
Pressure (psig)
100
50
0
Culver City, California
0 10 20 30 (Clay)
Elapsed Time (s) Depth: 16 to 19 ft. bgs.

37. PRESSURE — TIME HISTORY CURVES
Tells Us What’s Happening Below the Ground
150
Pressure (psig)
100
50
0
Culver City, California
0 10 20 30 (Clay)
Elapsed Time (s) Depth: 16 to 19 ft. bgs.
20
Pressure (psig)
15
10
Auburn, Indiana
0 (sandy Silt)
0 5 10 15 Depth: 6-8 ft bgs.
Elapsed Time (s)

38. HOW WE MONITOR
PNEUMATIC FRACTURING

39. HOW WE MONITOR
PNEUMATIC FRACTURING
Down-Hole Pressure
Pressure-Time History Curves

40. HOW WE MONITOR
PNEUMATIC FRACTURING
Down-Hole Pressure
Pressure-Time History Curves
Pressure Influence
Pressure Gauges on Monitoring Wells

41. HOW WE MONITOR
PNEUMATIC FRACTURING
Down-Hole Pressure
Pressure-Time History Curves
Pressure Influence
Pressure Gauges on Monitoring Wells
Ground Surface Heave
Observe Small Ground Movement

42. WHAT WE CAN EXPECT FROM
PNEUMATIC FRACTURING

43. WHAT WE CAN EXPECT FROM
PNEUMATIC FRACTURING
Increased Radius of Influence (3-6
Times)

44. WHAT WE CAN EXPECT FROM
PNEUMATIC FRACTURING
Increased Radius of Influence (3-6
Times)
Increased Bulk Conductivity (1-4 OM)
•Reduction in Geologic Heterogeneity (less diffusion
limited zones)
•Uniform emplacement of Injected Substances
•Increased in Mass Removal
•Increased Dewaterability or airflow

45. 18

46. 19

47. ATOMIZED LIQUID INJECTION

48. ATOMIZED LIQUID INJECTION

49. ATOMIZED LIQUID INJECTION
Ferox™ZVI
Chemox
Atomized Liquid
injection is a very
effective method for
injecting liquids/
slurries/powder
uniformly within all Bioaugmentation
types of geology

52. CONFIRMATORY SOIL SAMPLING
(85-88 ft. bgs. 17 ft)

53. CONFIRMATORY SOIL SAMPLING
(85-88 ft. bgs. 17 ft)
150
Pressure (psig)
100
50
0
0 10 20 30
Elapsed Time (s)

54. CONFIRMATORY SOIL SAMPLING
(85-88 ft. bgs. 17 ft)

55. CONFIRMATORY SOIL SAMPLING
(85-88 ft. bgs. 17 ft)
150
Pressure (psig)
100
50
0
0 10 20 30
Elapsed Time (s)

56. MATERIAL EMPLACEMENT THROUGH FLUIDIZATION
(77-80 ft bg, 17 ft from injection pt)

57. MATERIAL EMPLACEMENT THROUGH FLUIDIZATION
(77-80 ft bg, 17 ft from injection pt)
20
Pressure (psig)
15
10
0
0 5 10 15
Elapsed Time (s)

58. PRE AND POST INJECTION
ATOMIZED EMPLACEMENT

59. PRE AND POST INJECTION
ATOMIZED EMPLACEMENT

60. PRE AND POST INJECTION
ATOMIZED EMPLACEMENT

61. ENGINEERED APPROACH
Allows for Safe Injections Under Buildings/Structures

62. ENGINEERED APPROACH
Allows for Safe Injections Under Buildings/Structures

63. ARS ADVANCED DRILLING SERVICE

64. ARS ADVANCED DRILLING SERVICE
Geoprobe 8040 Offers Advanced Drilling
Methods

65. ARS ADVANCED DRILLING SERVICE
Geoprobe 8040 Offers Advanced Drilling
Methods
Cost-effective Alternative To Sonic
Drilling

66. ARS ADVANCED DRILLING SERVICE
Geoprobe 8040 Offers Advanced Drilling
Methods
Cost-effective Alternative To Sonic
Drilling
Site Investigation & Remediation

67. ARS ADVANCED DRILLING SERVICE
Geoprobe 8040 Offers Advanced Drilling
Methods
Cost-effective Alternative To Sonic
Drilling
Site Investigation & Remediation
Nationwide Service

68. INJECTION, SAMPLING,
WELL INSTALLATION

69. INJECTION, SAMPLING,
WELL INSTALLATION

70. INJECTION, SAMPLING,
WELL INSTALLATION
Direct Push

71. INJECTION, SAMPLING,
WELL INSTALLATION
Direct Push
Auger

72. INJECTION, SAMPLING,
WELL INSTALLATION
Direct Push
Auger
Air Rotary

73. INJECTION, SAMPLING,
WELL INSTALLATION
Direct Push
Auger
Air Rotary
Injection Pump
35 gpm
270 psi

74. INJECTION, SAMPLING,
WELL INSTALLATION

75. INJECTION, SAMPLING,
WELL INSTALLATION

76. INJECTION, SAMPLING,
WELL INSTALLATION
Turns Large Augers
Up to 8.5”

77. INJECTION, SAMPLING,
WELL INSTALLATION
Turns Large Augers
Up to 8.5”
Pushes Large Size
Rods
Up to 4.5”

78. INJECTION, SAMPLING,
WELL INSTALLATION
Turns Large Augers
Up to 8.5”
Pushes Large Size
Rods
Up to 4.5”
Pushes Rods Deeper
Up to 200’

79. INJECTION, SAMPLING,
WELL INSTALLATION

80. INJECTION, SAMPLING,
WELL INSTALLATION

81. INJECTION, SAMPLING,
WELL INSTALLATION
Install 2” Monitoring
Wells with no
cuttings

82. INJECTION, SAMPLING,
WELL INSTALLATION
Install 2” Monitoring
Wells with no
cuttings
Quick and Easy to
Convert from DPT to
Rotary

83. INJECTION, SAMPLING,
WELL INSTALLATION
Install 2” Monitoring
Wells with no
cuttings
Quick and Easy to
Convert from DPT to
Rotary
Track Mounted
Access

84. INJECTION, SAMPLING,
WELL INSTALLATION
Install 2” Monitoring
Wells with no
cuttings
Quick and Easy to
Convert from DPT to
Rotary
Track Mounted
Access
ARS Tech’s Highly
Experienced Crew
Provide Safe Efficient
Operations

85. ARS SERVICES

86. ARS SERVICES
Pneumatic Fracturing

87. ARS SERVICES
Pneumatic Fracturing
Liquid Atomized Injection

88. ARS SERVICES
Pneumatic Fracturing
Liquid Atomized Injection
Ferox (Zero Valent Iron)

89. ARS SERVICES
Pneumatic Fracturing
Liquid Atomized Injection
Ferox (Zero Valent Iron)
Chemical Oxidation

90. ARS SERVICES
Pneumatic Fracturing
Liquid Atomized Injection
Ferox (Zero Valent Iron)
Chemical Oxidation
Advanced Drilling Services

91. CHEMICALS & FORMULATION SERVICES

92. HEPURE SERVICES

93. HEPURE SERVICES

94. HEPURE SERVICES
 Site Ready Materials and Chemicals
– ZVI powders - H-200 Plus, HC-15
– Permanganate - NaMn04 , KMnO4
– Peroxygens
– Bioaugmentation & BioStimulation
• EVO, Microbes

95. Cost to Time Relationship
Peroxygens Expensive, But Fast Expensive and Slow
COST $
Inexpensive, and Fast Inexpensive, But Slow
TIME

96. Cost to Time Relationship
Peroxygens Expensive, But Fast Expensive and Slow
COST $
Inexpensive, and Fast Inexpensive, But Slow
TIME

97. Cost to Time Relationship
Peroxygens Expensive, But Fast Expensive and Slow
COST $
Inexpensive, and Fast Inexpensive, But Slow
TIME

98. Cost to Time Relationship
Peroxygens Expensive, But Fast Expensive and Slow
COST $
Inexpensive, and Fast Inexpensive, But Slow
TIME

99. Cost to Time Relationship
Peroxygens Expensive, But Fast Expensive and Slow
COST $
Inexpensive, and Fast Inexpensive, But Slow
TIME

100. Cost to Time Relationship
Expensive, But Fast Expensive and Slow
Permanganate
Peroxygens
COST $
Inexpensive, and Fast Inexpensive, But Slow
TIME

101. Cost to Time Relationship
Expensive, But Fast Expensive and Slow
Permanganate
Peroxygens
COST $
Inexpensive, and Fast Inexpensive, But Slow
TIME

102. Cost to Time Relationship
Expensive, But Fast Expensive and Slow
Permanganate
Peroxygens
COST $
Catalyzed Iron
Ferox(tm)
Inexpensive, and Fast Inexpensive, But Slow
TIME

103. Cost to Time Relationship
Expensive, But Fast Expensive and Slow
Permanganate
Peroxygens
COST $
Catalyzed Iron
Ferox(tm)
Inexpensive, and Fast Inexpensive, But Slow
TIME

104. Cost to Time Relationship
Expensive, But Fast Expensive and Slow
Permanganate
Peroxygens
COST $
Catalyzed Iron
Ferox(tm)
Bioremediation
Inexpensive, and Fast Inexpensive, But Slow
TIME

105. Cost to Time Relationship
Expensive, But Fast Expensive and Slow
? nZVI ?
Permanganate
Peroxygens
COST $
Catalyzed Iron
Ferox(tm)
Bioremediation
Inexpensive, and Fast Inexpensive, But Slow
TIME

106. ZVI IRON POWDERS

107. ZVI IRON POWDERS

108. ZVI IRON POWDERS
 Micron Scale Zero Valent Iron Powder

109. ZVI IRON POWDERS
 Micron Scale Zero Valent Iron Powder
 Emulsified Zero Valent Iron Powder

110. ZVI IRON POWDERS
 Micron Scale Zero Valent Iron Powder
 Emulsified Zero Valent Iron Powder
 Nanoscale Zero Valent Iron Powder

111. 38

112. Iron Quality Matters
Competitor’s Product
Hepure’s Product
39

113. ZVI IRON POWDERS
Brand Characteristics
• Pure Feedstock
• Reactive Alternative to Scrap
HCA Filings
• 3 Grades (Course, Fine and
Ultrafine)
• Atomized Powder
HC-15 • Catalytic Iron--Very High
Reactivity
• 2 Grades (Fine and Ultrafine)
• Successor to Most Widely Used ZVI
H200 Plus •Application Specific Blend
40

114. 41

115. “EVERYTHING BUT BOOTS
ON THE GROUND”

116. “EVERYTHING BUT BOOTS
ON THE GROUND”

117. “EVERYTHING BUT BOOTS
ON THE GROUND”
 Just In Time Tanker Delivery

118. “EVERYTHING BUT BOOTS
ON THE GROUND”
 Just In Time Tanker Delivery
 Totes, Drums, Pails

119. “EVERYTHING BUT BOOTS
ON THE GROUND”
 Just In Time Tanker Delivery
 Totes, Drums, Pails
 Dosatrons, Flowmeters

120. “EVERYTHING BUT BOOTS
ON THE GROUND”
 Just In Time Tanker Delivery
 Totes, Drums, Pails
 Dosatrons, Flowmeters
 Manifold Setups

121. “EVERYTHING BUT BOOTS
ON THE GROUND”
 Just In Time Tanker Delivery
 Totes, Drums, Pails
 Dosatrons, Flowmeters
 Manifold Setups
 Pumps, Hosing

122. “EVERYTHING BUT BOOTS
ON THE GROUND”
 Just In Time Tanker Delivery
 Totes, Drums, Pails
 Dosatrons, Flowmeters
 Manifold Setups
 Pumps, Hosing
 Tankage

123. HOW ARE YOU DOING YOUR
ON-SITE CHEMOX MIXING?

124. HOW ARE YOU DOING YOUR
ON-SITE CHEMOX MIXING?
OR

125. HOW ARE YOU DOING YOUR
ON-SITE CHEMOX MIXING?
OR

126. 44

127. CUSTOM BLENDING & SITE DELIVERY

128. CUSTOM BLENDING & SITE DELIVERY

129. CUSTOM BLENDING & SITE DELIVERY
 Cost-effective Nationwide Service

130. CUSTOM BLENDING & SITE DELIVERY
 Cost-effective Nationwide Service
 NaMnO , KMnO , Emulsified Vegetable
4 4
Oil, Sodium Lactate

131. CUSTOM BLENDING & SITE DELIVERY
 Cost-effective Nationwide Service
 NaMnO , KMnO , Emulsified Vegetable
4 4
Oil, Sodium Lactate
 “Just In Time” Site-ready Delivery

132. CUSTOM BLENDING & SITE DELIVERY
 Cost-effective Nationwide Service
 NaMnO , KMnO , Emulsified Vegetable
4 4
Oil, Sodium Lactate
 “Just In Time” Site-ready Delivery
 Eliminates Mixing-related
Health And Safety Issues

133. CUSTOM BLENDING & SITE DELIVERY
 Cost-effective Nationwide Service
 NaMnO , KMnO , Emulsified Vegetable
4 4
Oil, Sodium Lactate
 “Just In Time” Site-ready Delivery
 Eliminates Mixing-related
Health And Safety Issues
 Resolves QA/QC Concerns

134. SODIUM PERMANGANATE (NaMnO4)

135. SODIUM PERMANGANATE (NaMnO4)
 High Purity Standard For Insitu Injection

136. SODIUM PERMANGANATE (NaMnO4)
 High Purity Standard For Insitu Injection
 Available In “Site Ready” 2,000 – 5,000
Gal. Bulk Tanker Trucks

137. SODIUM PERMANGANATE (NaMnO4)
 High Purity Standard For Insitu Injection
 Available In “Site Ready” 2,000 – 5,000
Gal. Bulk Tanker Trucks
 Available In (10-40%) Concentration

138. POTASSIUM PERMANGANATE (KMnO4)

139. POTASSIUM PERMANGANATE (KMnO4)
 Tech Grade Chemicals

140. POTASSIUM PERMANGANATE (KMnO4)
 Tech Grade Chemicals
 Available As Dry Or “Site Ready” 1,000 –
5,000 Gal. Blended Bulk Tanker Trucks

141. POTASSIUM PERMANGANATE (KMnO4)
 Tech Grade Chemicals
 Available As Dry Or “Site Ready” 1,000 –
5,000 Gal. Blended Bulk Tanker Trucks
 Blended Available In (1-7%)
Concentration

142. POTASSIUM PERMANGANATE (KMnO4)
 Tech Grade Chemicals
 Available As Dry Or “Site Ready” 1,000 –
5,000 Gal. Blended Bulk Tanker Trucks
 Blended Available In (1-7%)
Concentration
 Established Product QA/QC Program

143. POTASSIUM PERMANGANATE (KMnO4)
 Tech Grade Chemicals
 Available As Dry Or “Site Ready” 1,000 –
5,000 Gal. Blended Bulk Tanker Trucks
 Blended Available In (1-7%)
Concentration
 Established Product QA/QC Program
 Avoid Homeland Security’s 300+ List

144. BIOREMEDIATION PRODUCTS

145. BIOREMEDIATION PRODUCTS
 H60 - Emusified Vegetable Oil Substrate
(SRS)

146. BIOREMEDIATION PRODUCTS
 H60 - Emusified Vegetable Oil Substrate
(SRS)
 H45 - Emulsified Vegetable Oil Substrate
(QRS)

147. BIOREMEDIATION PRODUCTS
 H60 - Emusified Vegetable Oil Substrate
(SRS)
 H45 - Emulsified Vegetable Oil Substrate
(QRS)
 HSL - Sodium Lactate Substrate

148. BIOREMEDIATION PRODUCTS
 H60 - Emusified Vegetable Oil Substrate
(SRS)
 H45 - Emulsified Vegetable Oil Substrate
(QRS)
 HSL - Sodium Lactate Substrate
 EZVI – Emulsified Zero Valent Iron

149. BIOREMEDIATION PRODUCTS
 H60 - Emusified Vegetable Oil Substrate
(SRS)
 H45 - Emulsified Vegetable Oil Substrate
(QRS)
 HSL - Sodium Lactate Substrate
 EZVI – Emulsified Zero Valent Iron
 Microbial Culture

150. ARS TECHNOLOGIES FAMILY OF COMPANIES
Practical Solutions For
Complex Problems
Proven Experience
Better Amendment
Delivery
Safe, Knowledgeable &
Convenient Chemical
Services

151. FOR MORE INFORMATION
Websites
www.arstechnologies.com
www.hepure.com
www.pressure_grouting.com
ftp site
www.onlinefilefolder.com
User: arsfiles
Password: arspublic