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
Atmospheric Layers

Ozone is the only major atmospheric constituent that absorbs
significantly between 210 and 290 nm.
Without it life would have remained underwater
The ozone layer is a consequence of oxygen-only chemistry. It
formed once photosynthetic marine organisms (cyanobacteria)
began “polluting” the atmosphere with oxygen.
Ozone Layer: Function

 The Chapman Cycle explains how the ozone layer is formed and
maintained.
 Four chemical reactions
 Initiation O2 + light  2O (120 – 210 nm)
 Propagation (cycling)
O + O2 + M  O3 + M* (generates heat)
O3 + light  O2 + O (220 – 320 nm)
 Termination O3 + O  2O2
The Chapman Cycle

The Chapman Cycle
OhO2
O
10-4 - 10 s
O3
60 - 3 min
O2
h
O2

Ozone Depleting Substances

EFFECTS
 On health of humans
 Eyes
 Skin
 Immunity
 On plants
 On marine ecosystem
 Effect on biogeochemical cycles

 Protection against cancer and cataract
 Protection of environment and ecosystem
ADVANTAGES

 Ozone is continuously depleting and is the highly
alarming situation.
 Chlorofluorocarbons are the major cause of ozone
depletion.
 Montreal protocol of 1987 – agreeing to reduce CFC
production by atleast 50%.
Conclusion


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Ozone depletion

  • 1.
  • 3.  Ozone is the only major atmospheric constituent that absorbs significantly between 210 and 290 nm. Without it life would have remained underwater The ozone layer is a consequence of oxygen-only chemistry. It formed once photosynthetic marine organisms (cyanobacteria) began “polluting” the atmosphere with oxygen. Ozone Layer: Function
  • 4.   The Chapman Cycle explains how the ozone layer is formed and maintained.  Four chemical reactions  Initiation O2 + light  2O (120 – 210 nm)  Propagation (cycling) O + O2 + M  O3 + M* (generates heat) O3 + light  O2 + O (220 – 320 nm)  Termination O3 + O  2O2 The Chapman Cycle
  • 5.  The Chapman Cycle OhO2 O 10-4 - 10 s O3 60 - 3 min O2 h O2
  • 7.  EFFECTS  On health of humans  Eyes  Skin  Immunity  On plants  On marine ecosystem  Effect on biogeochemical cycles
  • 8.   Protection against cancer and cataract  Protection of environment and ecosystem ADVANTAGES
  • 9.   Ozone is continuously depleting and is the highly alarming situation.  Chlorofluorocarbons are the major cause of ozone depletion.  Montreal protocol of 1987 – agreeing to reduce CFC production by atleast 50%. Conclusion
  • 10.