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Precise measurements on the light from distant quasars suggest that the value
        of the fine-structure constant may have changed over the history of the universe.
    If confirmed, the results will be of enormous significance for the foundations of physics



                Are the laws of nature
                 changing with time?
                                                          John Webb
WHAT do we mean by “the laws of na-                                                       What is the fine-structure constant?




                                                                                       NASA
ture”? The phrase evokes a set of divine                                                  Have the laws of nature remained the
and unchanging rules that transcend the                                                   same since the Big Bang some 13.5 bil-
“here and now” to apply everywhere                                                        lion years ago? Paul Dirac first posed
and at all times in the universe. The re-                                                 this question in 1937, and he was still
ality is not so grand. When we refer to                                                   interested in this idea when he visited
the laws of nature, what we are really                                                    the University of New South Wales
talking about is a particular set of ideas                                                (UNSW) in Sydney in 1975 – where I
that are striking in their simplicity, that                                               am now based. Dirac attempted to link
appear to be universal and have been                                                      the strength of gravity, which describes
verified by experiment. It is thus human                                                   the large-scale properties of the uni-
beings who declare that a scientific                                                       verse, with the various constants and
thory is a law of nature – and human                                                      numbers that characterize the small-
beings are quite often wrong.                                                             scale properties of the universe. In
  The development of a scientific the-                                                     doing so, he claimed that one of the
ory has always followed the need to                                                       constants of nature, the strength of
understand an observation for which Are the fundamental constants changing?               gravity, should change with time.
no satisfactory explanation previously Observations of light from distant quasars suggest    Although observations subsequently
existed. When developing new theories, that they might be.                                ruled out Dirac’s ideas, advances in
physicists tend to assume that funda-                                                     many areas of physics and astronomy
mental quantities such as the strength of gravity, the speed have resulted in a whole new set of opportunities for us to
of light in a vacuum or the charge on the electron are all search for any hint that the constants of nature might vary.
constant. And when these theories are found to predict the The particular question that I have been vigorously pursuing
results of new observations, our belief that these quantities with colleagues at UNSW and elsewhere can be stated as
are actually fundamental constants becomes even stronger.          follows: is the fine-structure constant really constant, or has
  Moreover, despite the rapid changes in technology in re- its value changed over the history of the universe?
cent decades, the timescale on which fundamental new dis-             The fine-structure constant, α, is a measure of the strength
coveries in physics are made is typically comparable to a of the electromagnetic interaction, and it quantifies the
human lifespan. This means that theories developed decades strength with which electrons bind within atoms and mole-
ago can appear as if they have been carved in granite.             cules. It is defined as α ≡ e 2/hc ≈ 1/137, where e is the charge
  The end result is a natural reluctance to change our under- on the electron, h is Planck’s constant divided by 2π, and c is
standing of the world. But it is vital to remember the limita- the speed of light in a vacuum. The fine-structure constant is
tions that have been involved in testing these assumptions. of particular interest because it is a dimensionless number.
Many of the experiments we carry out to test theories are This makes it even more fundamental than other constants
restricted to the here and now – to Earth-bound research labs such as the strength of gravity, the speed of light or the charge
or to the small part of the universe that we can observe with on the electron (see box on page 34).
telescopes. If we could somehow do our experiments in a dif-          There are theoretical reasons why α and other dimension-
ferent place or at a different time, we might well find that the less constants might vary with time. The holy grail of theoret-
results are different. Indeed, that is what appears to happen ical physics is to find a single unified theory that describes the
when we measure something called the fine-structure con- four fundamental forces: gravity, electromagnetism, and the
stant in the very distant past.                                    strong and weak nuclear forces. Although the strengths of

PHYSICS WORLD   APRIL 2003                                physicsweb.org                                                        33
1 Simulated quasar absorption spectrum                                                                        Constants with and without dimensions
                                                                                                              Nature presents us with various constants. Some of these
                                                            galaxy
                                                                     quasar
                                                                                                              constants, such as the fine-structure constant, are dimensionless
                            to Earth                                                                          and are not expressed in terms of units. However, other constants,
                                                                                                              such as the velocity of light or the mass of the proton, are
                                  hydrogen absorption                emission lines from the quasar           dimensional and their numerical values depend entirely on the units
                                  due to galaxy                      heavy-element absorption                 in which they are expressed. The laws of nature do not, of course,
 signal (arbitrary units)




                                                                     due to galaxy
                                                                                                              depend on a man-made system of units.
                                                                                                                 To put this another way, if we want to measure a dimensional
                                                                                                              constant, we need a “yardstick” to make the measurement. But if we
                                                                                                              obtained one value when we measured the speed of light on a
                                                                                                              Monday, say, and a different value when we measured it on a Friday,
                                                                                                              how would we know that our yardstick had not shrunk or expanded?
                                                                                                              We would not. Moreover, if we were to interpret our observations as
                               3500        4000       4500      5000        5500           6000               a change in the length of the yardstick, how could we verify it without
                                                    observed wavelength (Å)                                   reference to a second yardstick? Again, we could not. And so on.
Quasars are highly luminous objects that emit light over a wide range of                                         However, dimensionless constants are fundamental absolute
wavelengths (red line), with peaks at several wavelengths due to emission by
elements such as hydrogen, nitrogen, silicon, carbon and iron in the gas
                                                                                                              numbers, measured without reference to anything else. Therefore, if
around the quasar. When light from the quasar passes near a galaxy on its                                     we want to investigate if the laws of nature are changing we must
way to Earth, the gas around the galaxy causes a distinct pattern of                                          measure dimensionless quantities such as the fine-structure
absorption lines in the quasar spectrum (green line). By measuring the                                        constant or the ratio of the electron and proton masses.
wavelengths of the absorption lines due to heavy elements (on the right of
the figure) we can determine both the redshift of the gas and the value of the
fine-structure constant, α, at the time when the light from the quasar was
absorbed. Such observations suggest that the value of α was slightly smaller                                    There are several ways to measure possible changes in α
billions of years ago. The plethora of absorption features at the shorter
wavelengths on the left are due to hydrogen at different redshifts.
                                                                                                              with time. We can measure the absorption spectra of quasars
                                                                                                              at different redshifts, as we have done at UNSW. We can com-
                                                                                                              pare the “ticking rates” of atomic clocks made of different
these four forces differ, as do the distances over which they                                                 elements (see box on page 36). We can also study the cosmic
operate, most physicists believe that a unified theory will be                                                 microwave background or the creation of the elements in the
discovered. If such a theory is not found, a great deal of the                                                early universe. However, one of the first methods used to
elegance and beauty of fundamental physics will be lost.                                                      probe how α might have changed over the past two billion
   Einstein’s theory of gravity – the general theory of relativity                                            years relies on what must be one of the most unusual proces-
– only requires three spatial dimensions. However, the lead-                                                  ses ever studied by physicists – the so-called natural nuclear
ing contender for a unified theory requires extra dimensions                                                   reactor at Oklo in Central Africa.
beyond our familiar three. We do not know if these unified
theories are correct, but if extra dimensions do exist, they                                                  The strange story of the Oklo reactor
must be tiny compared with our ordinary spatial dimensions.                                                   Natural uranium contains two isotopes. Uranium-235, the
   The concept of attributing a “size” to a dimension may                                                     isotope that is useful for nuclear energy, is relatively rare and
seem strange but it is important. The current size of the uni-                                                accounts for just 0.7% of all natural uranium. Its less-radioact-
verse is determined by the distance that light has travelled                                                  ive sibling, uranium-238, makes up the other 99.3%. In 1972
since the Big Bang (i.e. about 13.5 billion light-years) and by                                               scientists from the French atomic energy commission noticed
the amount by which it has expanded since then. This means                                                    something mysterious in soil samples taken from a uranium
that the actual size of the universe is about 40 billion light-                                               mine in Gabon in Central Africa: the relative abundance of
years and rising.                                                                                             uranium-235 was a factor of two lower than expected.
   Are the extra dimensions predicted by unified theories also                                                    One possibility was that a band of hi-tech terrorists had
expanding at the same rate as the universe? The answer to                                                     been stealing and stockpiling the missing uranium for pur-
this question is no. If the tiny extra dimensions were expand-                                                poses even more evil than blowing up innocent atolls. How-
ing at this rate, then the strength of gravity would also be                                                  ever, isotopes of various other elements also appeared to be
changing very rapidly, and there is no evidence for this. How-                                                depleted in a pattern that was strikingly similar to that ob-
ever, it may be possible to infer the presence of these extra                                                 served among the waste products from modern nuclear re-
dimensions – if they exist – by detecting small changes in the                                                actors. The most plausible explanation is that there must once
strength of gravity or the other three forces.                                                                have been a “natural” nuclear reactor at Oklo. Although nat-
   It has been predicted, for instance, that “large” extra dimen-                                             ural nuclear reactors were predicted by Paul Kuroda of the
sions might cause small deviations in the inverse-square law                                                  University of Arkansas as long ago as 1956, Oklo is the only
of gravity over distances of less than 1 mm. However, recent                                                  known example (see photograph opposite).
measurements by John Price and co-workers at the Univer-                                                         What appears to have happened is that oxygenated water
sity of Colorado at Boulder have failed to find any evidence                                                   slowly dissolved the uranium-235 that was stored in surface
for this over distances of about 100 µm ( J C Long et al. 2003                                                rock about two billion years ago. Back then the natural con-
Nature 421 922). This is just one of many experiments that                                                    centration of uranium-235 would have been about 3% – it
have been set up to perform high-precision tests on constants,                                                is much lower now because uranium-235 decays about six
forces and fundamental symmetries in recent years.                                                            times faster than uranium-238. Over time the uranium-235

34                                                                                                    physicsweb.org                                     PHYSICS WORLD    APRIL 2003
ANDREAS MITTLER
Natural wonder – measurements obtained at the natural nuclear reactor at Oklo in Central Africa can place limits on any possible change in the value of the
fine-structure constant over the past two billion years.

would have become concentrated in nearby algae mats,                              as it was just over eight minutes ago because that is how long
which acted as filters, and eventually enough of it would have                     it takes the light from the Sun to reach the Earth. Similarly,
collected to reach criticality and form a natural nuclear re-                     some quasars are so far away that we see them as they were
actor. This reactor would have “burned” the uranium-235,                          billions of years ago. Indeed, by observing quasars we can
thus explaining the low levels of the isotope found at Oklo.                      build up a continuous “universal history” that starts when the
   But what has this got to do with α? In 1976, four years after                  universe was only about one billion years old and continues
the Oklo reactor was discovered, Alexander Shlyakhter of                          up to the present day.
the Leningrad Nuclear Physics Institute made the connec-                             However, we cannot study α with any reasonable precision
tion. Samples from Oklo revealed a relative abundance of                          using the quasars themselves. Rather, we must examine what
samarium-149 that was a factor of 45 lower than other ter-                        happens when the radiation from a quasar passes through a
restrial samples and Shlyakhter showed that ambient neut-                         galaxy that lies between the Earth and the quasar. The quasar
rons could convert samarium-149 into samarium-150 if they                         emits light over a broad range of wavelengths (figure 1). How-
had exactly the right energy.                                                     ever, when this light passes through the gas around the galaxy,
   This resonance was due to a delicate balance between the                       a characteristic pattern of absorption lines will be super-
strong nuclear force and the repulsive electromagnetic force                      imposed on it.
in samarium. Moreover, the resonance energy depended on                              The presence of an absorption line at a particular wave-
α, so if the value of α was different two billion years ago, then                 length reveals that a specific element is present in the gas
the depletion of samarium-149 would also have been differ-                        cloud, and the width of each line shows the quantity of the
ent. The details of the calculation are complicated, but they                     element that is present. In addition to hydrogen, which is
show that any fractional change in the value of α since the                       ubiquitous in the universe, these “bar codes” reveal that the
time that Oklo was active cannot be greater than 10–7 (see                        gas clouds contain a range of other elements, including mag-
Olive et al. in further reading).                                                 nesium, iron, zinc, silicon, aluminium and chromium.
   Very recently a new geological measurement technique                              Moreover, the bar code reveals what was happening when
known as “rhenium dating” has produced potentially even                           the light passed through the cloud, which could have hap-
more stringent results. The ages of iron meteorites obtained                      pened as long ago as just one billion years after the Big Bang.
using rhenium dating are consistent with those found by                           Although the gas cloud would have evolved into something
other methods. From this we can show that the beta-decay                          quite different by today, its bar code provides us with a perma-
lifetime of rhenium cannot have changed by more than 0.5%                         nent imprint of its state in the distant past – including infor-
over the age of the solar system. This translates to an upper                     mation about the value of α at that time.
limit on any fractional change in the value of α of the order                        Therefore, if we compare the bar codes that we find in
10–7 over about 4.6 billion years.                                                quasar absorption spectra with the bar codes we measure for
   While 4.6 billion years is a long time, the universe itself is                 the same atoms and ions in the laboratory, we can find out if
about 13.5 billion years old. Is it possible to test for changes                  the physics that is responsible for the absorption of radiation
in the value of α even earlier in the history of the universe?                    by atoms has changed over the history of the universe. In
The answer is yes – with the help of quasars.                                     other words, we can find out if α has changed.

Using quasars to look at the fine-structure constant                               Back to the laboratory
Quasars are compact but highly luminous objects. Indeed,                          Back in 1998 I began collaborating with my colleagues Victor
they are so luminous that they can be studied in intricate                        Flambaum and Vladimir Dzuba at UNSW and John Bar-
detail using ground-based telescopes despite being vast dis-                      row, now at Cambridge University in the UK. Although both
tances away from us. We think that quasars contain black                          Victor and I worked in the same department, neither of us
holes at their centres and that the immense gravitational force                   had been aware of a common interest until he discovered that
exerted by the black hole is extremely efficient at converting                     I was looking for a student to help me in my efforts to use
matter in its vicinity into light.                                                quasars to explore whether α had been different in the past.
  Nature kindly co-operates by scattering quasars throughout                      The advantage of pooling his theoretical expertise with my
the universe. Since quasars are seen in all directions in the sky,                experimental work quickly became apparent as we realized
they provide a powerful way of charting almost the entire                         that we could improve the precision of the measurements of
universe. And, like any astronomical object, whenever we                          α by an order of magnitude by analysing existing astrophy-
look at a quasar we see it as it was in the past. We see the Sun                  sical data in a new way.

PHYSICS WORLD     APRIL 2003                                            physicsweb.org                                                                        35
Searching for changes in the fine-structure constant using atomic clocks
                                 John Harrison would not have believed the                 corresponding increase in the precision of the clock.
                                 precision of the latest atomic clocks. Despite his           But what has this got to do with the fine-structure
                                 mechanical genius, a clock made out of atoms –            constant, α? It is not surprising to find that the
                                 rather than cogs and springs – would surely               resonance frequency relies on α. Moreover, if α is
                                 surprise him. The H4 clock with which Harrison            changing with time, clocks made from different
                                 eventually won the £20 000 prize offered by the           elements will “tick” at slightly different rates.
                                 Board of Longitude in 1714 for a solution to the          Therefore, by comparing the stability of two clocks
                                 problem of finding longitude at sea was accurate to       made of different elements it should be possible to
                                 39 seconds over 47 days, or 1 part in 105.                place an upper limit on any variation of α with time.
                                 However, the latest atomic clocks are accurate to         Unlike the quasar and Oklo results, experiments
                                 one second in 50 million years, or 1 part in 1015.        with atomic clocks probe the stability of α as it is
                                 This level of accuracy makes it possible to search        today rather than billions of years ago.
                                 for any variations in the fine-structure constant            A recent experiment by Harold Marion and co-
                                 over timescales of years.                                 workers at the Observatoire de Paris and the Ecole
                                    The world’s most precise atomic clocks are now         Normale Supérieure (ENS) compared the rates of
                                 made from “atomic fountains”. A gas of atoms              cesium and rubidium fountain clocks over a five-
                                 within a vacuum chamber is trapped by a set of            year period. If α is changing, the rate of change,
                                 intersecting laser beams and cooled to a                  1/α (dα/dt), must be less than –0.4 ± 16 × 10–16
                                 temperature close to absolute zero. The ball of           per year (see further reading). This is not in conflict
                                 atoms is then tossed vertically into the air by           with the Oklo or quasar results.
                                 changing the frequency of the lasers and it passes           The European Space Agency has plans to fly an
                                 through a microwave cavity on its way up and also         atomic-clock experiment – called the Atomic Clock
                                 on its way down as it falls under gravity. The whole      Ensemble in Space (ACES) – on the International
                                 process is then repeated.                                 Space Station. In addition to various tests of
                                    Another laser beam is used to make the atoms           general relativity, ACES will be 100 times more
                                 fluoresce, and the amount of fluorescence is              sensitive to changes in α than terrestrial
                                 measured as a function of the microwave                   experiments. ACES will comprise two atomic clocks:
                                 frequency to plot a “resonance curve”. An                 a cesium clock called PHARAO (see photograph)
                                 ultra-precise measurement of time can be made             built by a team led by Christophe Salomon of the
                                 by measuring the frequency of the peak in this            ENS and Andre Clairon of the Observatoire de Paris,
                                 resonance curve (see “Atomic clocks” by                   and a hydrogen maser built by Alain Jornod of the
                                 Pierre Lemonde in Physics World January 2001              Observatoire Cantonal de Neuchâtel in Switzerland.
                                 pp39–44).                                                    The ACES experiment is particularly exciting for
                                    It turns out that the width of the resonance curve     my colleagues and me because it might be able to
                                 is inversely proportional to the time that it takes for   detect a drift in the value of α, which would confirm
                                 the atoms to pass through the microwave cavity, so        our quasar results. On the other hand, ACES may
                                 the curve becomes narrower as the atoms spend             find no change. However, this will not show that the
                                 longer in the cavity. This allows the position of the     quasar results are wrong because the two
                                 peak to be determined more precisely, which               experiments probe vastly different times and α
                                 means that the clock becomes more accurate.               could be changing at very different rates in these
                                 This is why physicists are keen to place an atomic        different epochs. Moreover, the rate of change
                                 fountain in space: “micro-gravity” conditions will        may also depend on other factors, such as the
                                 extend the time by a factor of 10, with a                 local gravitational potential.


  Prior to our work, α had been measured by looking at                 shift of the gas: λobs = (1 + z)λ, where z is the redshift and λ is
“alkali doublet” lines in systems such as singly ionized mag-          the original wavelength.
nesium (Mg II). This ion has a single electron in its outer shell         The change in the absorption spectrum caused by the red-
and its first excited energy level is split into a doublet as a         shift and that caused by any change in α are different and
result of interactions between the orbital and spin angular            can be separated out. Whereas the effect of the redshift is to
momenta of the electron. The energy difference between the             multiply the wavelength of every line in the spectrum by the
two states in the doublet is proportional to α2. Indeed, “fine          name number, 1 + z, any variation in α only changes the rel-
structure” is defined as the splitting of energy levels due to          ative separation between the lines in the doublet.
interactions between the orbital and spin angular momenta.                However, the alkali-doublet approach fails to take advant-
  This fine-structure splitting means that Mg II absorbs light          age of one crucial physical aspect. When an atom or ion is in
at two slightly different frequencies when it is excited from its      its ground state, the electrons spend a lot more time close to
ground state to the first excited state. In the laboratory these        the nucleus than they do when the atom is in an excited state.
wavelengths are 2796 Å and 2803 Å. The expansion of the                Since α essentially defines the strength of the interaction be-
universe means that the wavelengths observed in quasar                 tween the nucleus and the electrons, any change in α will have
spectra, λobs, are longer by a factor that depends on the red-         a greater impact on the atom or ion when in its ground state.

36                                                            physicsweb.org                                         PHYSICS WORLD    APRIL 2003
2 How spectral lines shift                                                        What could produce a spurious signal in the data?
                      AIII SiII                                                   We have spent a great deal of time and effort trying to answer this
              SiII FeII NiII AI III Zn II Cr II   Fe II   Fe II   Mg II Mg I      question and make sure that the results we have seen are due to a
         0
                                                                                  change in the value of α and not something else. We have even
                                                                                  written an entire paper summarising all the possible sources of error
                                                                                  and quantifying them one by one (see Murphy et al. in further
                                                                                  reading). After an exhaustive study we came up with only two possible
                                                                                  experimental effects that could significantly influence the results.
∆α/α




       –0.5                                                                          One concerned the dispersion of light from the quasar as it
                                                                                  passed through the Earth’s atmosphere. Light at each end of the
                                                                                  optical spectrum is dispersed by a different amount, since the
                                                                                  refractive index of any medium depends on frequency.
                                                                                   A sophisticated application of what is high-school physics allows us
                                                                                  to compute the importance of this effect, with the conclusion that it
       1.0
                                                                                  is unable to explain the results we find.
             1500               2000                    2500              3000       A second and more subtle effect concerns the relative amounts of
                                    rest wavelength (Å)                           different isotopes of the same elements in the quasar spectra and
To check if the value of the fine-structure constant, α, has changed over the     the laboratory spectra. Terrestrial samples of magnesium, for
history of the universe it is necessary to compare the wavelength of various
absorption lines in quasar spectra, after redshift effects have been removed,     example, contain 79% magnesium-24, 10% magnesium-25 and
with the corresponding wavelengths as measured in the laboratory. The top         11% of magnesium-26. What if the gas clouds contain different
(green) line in this figure shows the position of various absorption lines in     relative abundances of these isotopes? Again, we have looked at
atoms and ions of silicon (Si), iron (Fe), aluminium (Al), zinc (Zn), chromium    this effect in detail and it is unable to explain the quasar results. In
(Cr) and magnesium (Mg) as measured in the laboratory. Mg I is neutral
magnesium, Mg II is singly ionized magnesium (i.e. a Mg+ ion) and so on. The      fact, averaged over the whole quasar sample, we find that any
wavelengths of these lines depend on α in different ways, and the coloured        attempt to include these effects in our interpretation of the quasar
lines show where the absorption lines would be if α was smaller in the past       data is likely to make the results even more statistically significant.
than it is today. The red line corresponds to a value of α that is 90% of the
current value (i.e. ∆α/α = –0.1), green corresponds to 80%, and so on. Notice
how some atoms hardly change as α varies (e.g. silicon), whereas others shift
towards longer wavelengths (e.g. iron) or shorter wavelengths (zinc). This        laboratory experiments to re-measure the wavelengths of all
observation is important because it means that it would be hard for effects       the absorption lines seen in the quasar spectra. Much of this
other than a variation in α to mimic this pattern.
                                                                                  experimental work was carried out by Anne Thorne and
                                                                                  Juliet Pickering at Imperial College in London and the data
But the alkali-doublet method uses just a single atomic spe-                      are now so accurate that there is no longer a significant error
cies, so it measures change relative to the same ground state                     due to laboratory measurements in the quasar results.
and so misses out on this advantage.                                                 The observations have been carried out by many astron-
  For these reasons, Victor, Vladimir Dzuba and I developed                       omers, including Chris Churchill of Penn State University,
a method to use different sets of atomic absorption lines and                     Jason Prochaska and Michael Rauch of the Carnegie Ob-
compare wavelengths relative to different ground states. After                    servatories in Pasadena, Art Wolfe of the University of Ca-
we realized that comparing laboratory and quasar observa-                         lifornia at San Diego, and Tom Barlow, Rob Simcoe and Wal
tions in this way would provide a huge increase in sensitivity,                   Sargent at the California Institute of Technology, while John
the challenge was to compute to a reasonable precision how                        Barrow at Cambridge has also been very active in the the-
the energy of an electron in its ground state changed for a                       oretical interpretation of the results. A great deal of work has
given change in α. Once we had that information, we could                         been done by Michael Murphy, who recently completed his
then translate any differences between the laboratory and                         PhD with me at UNSW and is now at Cambridge. Stephen
quasar measurements into a value for, or a upper limit on, any                    Curran and, very recently, Panayiotis Tzanivaris have also
possible change in the value of α.                                                joined the project at UNSW.
  A further advantage of this “many-multiplet” approach is                           Since the project started in 1998 we have measured 75
that light elements, such as magnesium, do not react strongly                     quasars at distances out to 13 billion light-years with the
to a change in α, whereas heavier elements such as iron do.                       10 metre Keck 1 telescope on Hawaii. The results from the
This means that the light elements can be used as “anchors”                       Keck 1 data are astonishing. There is statistically significant
against which we can measure changes in heavier elements                          evidence that α may have been very slightly smaller in the
(figure 2).                                                                        past, but only by about 1 part in 105 (see figure 3). We have ex-
  However, when we first tried to apply the many-multiplet                         plored many different possible sources of errors but they can-
approach to real astrophysical data we got a big shock. The                       not explain what we find (see box on page 37).
high-resolution spectrographs on the world’s largest tele-                           We are aware, however, that all our data come from the
scopes were able to measure wavelengths in quasar spectra                         same instrument, the HIRES spectrograph on Keck 1, and
more accurately than they had ever been measured in the                           we are therefore keen to analyse data from other instruments
laboratory. In other words, we knew more about the fine                            and telescopes, such as the European Southern Observatory’s
structure of atoms 12 billion years ago than we did today, and                    magnificent Very Large Telescope (VLT). New quasar data
our efforts to look for changes in α were immediately limited                     are beginning to flow from the VLT – a set of four 8 metre
by the old experimental data.                                                     telescopes in Chile – and we should soon be able to tell whe-
  It was therefore necessary to begin a series of brand new                       ther the same signal appears in those data.

PHYSICS WORLD           APRIL 2003                                        physicsweb.org                                                               37
3 Results from quasar spectra                                                         What does it all mean?
                                                                                      It should be noted that the present status of all these ex-
                                                                                      periments is one of consistency. For example, the geological
       0                                                                              results do not conflict with the quasar results or the atomic-
                                                                                      clock experiments because they probe very different epochs
∆α/α




       –1
                                                                                      in the history of the universe. It is possible that the value of α
                                                                                      was changing relatively rapidly (by 1 part in 105) in the first
                                                                                      few billion years after the Big Bang, and that the fractional
       –2                                                                             change has been 100 times smaller since the time of the Oklo
         0                    1                          2                        3
                                         redshift                                     reactor about two billion years ago. We cannot repeat the
When the fractional change in the fine-structure constant, ∆α/α, is plotted           Oklo “experiment” but the results from the quasar observa-
as a function of redshift, we find that the value of α appears to have been           tions and the atomic-clock experiments will become increas-
slightly smaller (by about 1 part in 105) in the past than it is now. Each of
the green data points in the figure corresponds to an average of about
                                                                                      ingly accurate over the next few years.
10 independent quasar measurements, and the redshifts range from z = 0.55                Confirmation that α is changing would have profound im-
(about 5.6 billion years ago) to z = 3 (about 12.6 billion years ago). If α was not   plications for physics. For instance, the equivalence principle –
changing over the history of the universe then the data points would be               one of the cornerstones of relativity – states that in freely fal-
scattered about the horizontal dashed line (see Webb et al. in further reading).
                                                                                      ling reference frames, the outcome of any non-gravitational
                                                                                      experiment is independent of when and where it is carried out.
  Other groups are also joining the hunt. John Bahcall of the                            Changes in the value of α would constitute a violation of
Institute for Advanced Studies in Princeton and colleagues                            the equivalence principle. However, this is not necessarily bad
have just completed an exceptionally thorough analysis based                          news because many of the theories that seek to unify the four
on a new approach in which they studied oxygen emission lines                         fundamental forces of nature also violate the equivalence prin-
from distant galaxies. Although Bahcall and co-workers took                           ciple. The varying speed of light (VSL) theories, first proposed
enormous care to select only the highest quality data for their                       by John Moffat of the University of Toronto and developed in
analysis, the precision they finally reach is about an order of                        recent years by João Magueijo of Imperial College, John Bar-
magnitude less than we obtained using the many-multiplet                              row and others as an alternative to inflationary models in cos-
methods on quasar absorption spectra. This means that they                            mology, could also lead to changes in the value of α in the early
have not yet been able to provide a test of our results (see                          universe. Inflation and VSL theories are both attempts to ex-
further reading).                                                                     plain various features of the universe – such as its apparent flat-
  If the new data do not confirm the results so far, the com-                          ness – that cannot be explained by the Big Bang theory alone.
bined data from Keck 1 and the VLT will nevertheless place                               If the quasar results are eventually confirmed, our concepts
the most stringent constraints so far on the form that new uni-                       of space and time are sure to undergo radical transforma-
fied theories of the fundamental forces must take. And if the                          tions. Who knows how this will change our fundamental un-
new data support a changing α, we may eventually have to re-                          derstanding of the universe?
write significant portions of modern physics.
                                                                                      Further reading
The early universe                                                                    J N Bahcall, C L Steinhardt and D Schlegel 2003 Does the fine-structure
We can also search for variations in α at even earlier times                          constant vary with cosmological epoch? arXiv.org/abs/astro-ph/0301507
in the history of the universe. If we change α, we change the                         J Barrow 2002 The Constants of Nature (Jonathan Cape, London)
temperature at which electrons and protons recombined in                              J D Bekenstein 2003 Fine-structure constant variability: surprises for
the early universe to form neutral hydrogen atoms: this is the                        laboratory atomic spectroscopy and cosmological evolution of quasar spectra
process that defines the formation of the cosmic microwave                             arXiv.org/abs/astro-ph/0301566
background about 380 000 years after the Big Bang (see                                L Bergström, S Iguri and H Rubinstein 1999 Constraints on the variation of the
“The cosmic microwave background” by Pedro G Ferreira                                 fine-structure constant from big bang nucleosynthesis Phys. Rev. D 60 045005
on page 27 and Martins et al. in further reading). A change in                        C J A P Martins et al. 2003 WMAP constraints on varying α and the promise of
α would change the time at which recombination occurred,                              reionization arXiv.org/abs/astro-ph/0302295
and this could be detected by satellite measurements of the                           H Marion et al. 2003 A search for variations of fundamental constants using
cosmic background.                                                                    atomic fountain clocks arXiv.org/abs/physics/0212112
  The formation of light elements such as helium, deuterium                           M T Murphy et al. 2002 Does the fine-structure constant vary? A detailed
and lithium in the first few minutes after the Big Bang would                          investigation into systematic effects arXiv.org/abs/astro-ph/0210532
also be affected if α was changing over time. The equations                           K A Olive et al. 2002 Constraints on the variations of the fundamental
that define the rate at which the light elements are formed are                        couplings arXiv.org/abs/hep-ph/0205269
modified in different ways if α varies over time. This means                           J-P Uzan 2002 The fundamental constants and their variation: observational
that accurate measurements of the relative abundances of                              status and theoretical motivations arXiv.org/abs/hep-ph/0205340
these elements can also be used to constrain any change in α                          J K Webb et al. 2001 Further evidence for cosmological evolution of the
over almost the entire history of the universe – from the first                        fine-structure constant Phys. Rev. Lett. 87 091301
few minutes after the Big Bang until today (see Bergström et al.                      J K Webb et al. 2002 Does the fine-structure constant vary? A third quasar
in further reading).                                                                  absorption sample consistent with varying alpha arXiv.org/abs/
  Both of these methods are not yet very accurate. Neverthe-                          astro-ph/0210531
less they provide important complementary constraints on
any variations of α and show that it cannot have changed by                           John Webb is in the School of Physics, University of New South Wales, Sydney,
much more than 10% in either case.                                                    NSW 2052, Australia, e-mail jkw@bat.phys.unsw.edu.au


38                                                                          physicsweb.org                                           PHYSICS WORLD      APRIL 2003

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Precise measurements of distant quasars suggest the fine-structure constant may have changed

  • 1. Precise measurements on the light from distant quasars suggest that the value of the fine-structure constant may have changed over the history of the universe. If confirmed, the results will be of enormous significance for the foundations of physics Are the laws of nature changing with time? John Webb WHAT do we mean by “the laws of na- What is the fine-structure constant? NASA ture”? The phrase evokes a set of divine Have the laws of nature remained the and unchanging rules that transcend the same since the Big Bang some 13.5 bil- “here and now” to apply everywhere lion years ago? Paul Dirac first posed and at all times in the universe. The re- this question in 1937, and he was still ality is not so grand. When we refer to interested in this idea when he visited the laws of nature, what we are really the University of New South Wales talking about is a particular set of ideas (UNSW) in Sydney in 1975 – where I that are striking in their simplicity, that am now based. Dirac attempted to link appear to be universal and have been the strength of gravity, which describes verified by experiment. It is thus human the large-scale properties of the uni- beings who declare that a scientific verse, with the various constants and thory is a law of nature – and human numbers that characterize the small- beings are quite often wrong. scale properties of the universe. In The development of a scientific the- doing so, he claimed that one of the ory has always followed the need to constants of nature, the strength of understand an observation for which Are the fundamental constants changing? gravity, should change with time. no satisfactory explanation previously Observations of light from distant quasars suggest Although observations subsequently existed. When developing new theories, that they might be. ruled out Dirac’s ideas, advances in physicists tend to assume that funda- many areas of physics and astronomy mental quantities such as the strength of gravity, the speed have resulted in a whole new set of opportunities for us to of light in a vacuum or the charge on the electron are all search for any hint that the constants of nature might vary. constant. And when these theories are found to predict the The particular question that I have been vigorously pursuing results of new observations, our belief that these quantities with colleagues at UNSW and elsewhere can be stated as are actually fundamental constants becomes even stronger. follows: is the fine-structure constant really constant, or has Moreover, despite the rapid changes in technology in re- its value changed over the history of the universe? cent decades, the timescale on which fundamental new dis- The fine-structure constant, α, is a measure of the strength coveries in physics are made is typically comparable to a of the electromagnetic interaction, and it quantifies the human lifespan. This means that theories developed decades strength with which electrons bind within atoms and mole- ago can appear as if they have been carved in granite. cules. It is defined as α ≡ e 2/hc ≈ 1/137, where e is the charge The end result is a natural reluctance to change our under- on the electron, h is Planck’s constant divided by 2π, and c is standing of the world. But it is vital to remember the limita- the speed of light in a vacuum. The fine-structure constant is tions that have been involved in testing these assumptions. of particular interest because it is a dimensionless number. Many of the experiments we carry out to test theories are This makes it even more fundamental than other constants restricted to the here and now – to Earth-bound research labs such as the strength of gravity, the speed of light or the charge or to the small part of the universe that we can observe with on the electron (see box on page 34). telescopes. If we could somehow do our experiments in a dif- There are theoretical reasons why α and other dimension- ferent place or at a different time, we might well find that the less constants might vary with time. The holy grail of theoret- results are different. Indeed, that is what appears to happen ical physics is to find a single unified theory that describes the when we measure something called the fine-structure con- four fundamental forces: gravity, electromagnetism, and the stant in the very distant past. strong and weak nuclear forces. Although the strengths of PHYSICS WORLD APRIL 2003 physicsweb.org 33
  • 2. 1 Simulated quasar absorption spectrum Constants with and without dimensions Nature presents us with various constants. Some of these galaxy quasar constants, such as the fine-structure constant, are dimensionless to Earth and are not expressed in terms of units. However, other constants, such as the velocity of light or the mass of the proton, are hydrogen absorption emission lines from the quasar dimensional and their numerical values depend entirely on the units due to galaxy heavy-element absorption in which they are expressed. The laws of nature do not, of course, signal (arbitrary units) due to galaxy depend on a man-made system of units. To put this another way, if we want to measure a dimensional constant, we need a “yardstick” to make the measurement. But if we obtained one value when we measured the speed of light on a Monday, say, and a different value when we measured it on a Friday, how would we know that our yardstick had not shrunk or expanded? We would not. Moreover, if we were to interpret our observations as 3500 4000 4500 5000 5500 6000 a change in the length of the yardstick, how could we verify it without observed wavelength (Å) reference to a second yardstick? Again, we could not. And so on. Quasars are highly luminous objects that emit light over a wide range of However, dimensionless constants are fundamental absolute wavelengths (red line), with peaks at several wavelengths due to emission by elements such as hydrogen, nitrogen, silicon, carbon and iron in the gas numbers, measured without reference to anything else. Therefore, if around the quasar. When light from the quasar passes near a galaxy on its we want to investigate if the laws of nature are changing we must way to Earth, the gas around the galaxy causes a distinct pattern of measure dimensionless quantities such as the fine-structure absorption lines in the quasar spectrum (green line). By measuring the constant or the ratio of the electron and proton masses. wavelengths of the absorption lines due to heavy elements (on the right of the figure) we can determine both the redshift of the gas and the value of the fine-structure constant, α, at the time when the light from the quasar was absorbed. Such observations suggest that the value of α was slightly smaller There are several ways to measure possible changes in α billions of years ago. The plethora of absorption features at the shorter wavelengths on the left are due to hydrogen at different redshifts. with time. We can measure the absorption spectra of quasars at different redshifts, as we have done at UNSW. We can com- pare the “ticking rates” of atomic clocks made of different these four forces differ, as do the distances over which they elements (see box on page 36). We can also study the cosmic operate, most physicists believe that a unified theory will be microwave background or the creation of the elements in the discovered. If such a theory is not found, a great deal of the early universe. However, one of the first methods used to elegance and beauty of fundamental physics will be lost. probe how α might have changed over the past two billion Einstein’s theory of gravity – the general theory of relativity years relies on what must be one of the most unusual proces- – only requires three spatial dimensions. However, the lead- ses ever studied by physicists – the so-called natural nuclear ing contender for a unified theory requires extra dimensions reactor at Oklo in Central Africa. beyond our familiar three. We do not know if these unified theories are correct, but if extra dimensions do exist, they The strange story of the Oklo reactor must be tiny compared with our ordinary spatial dimensions. Natural uranium contains two isotopes. Uranium-235, the The concept of attributing a “size” to a dimension may isotope that is useful for nuclear energy, is relatively rare and seem strange but it is important. The current size of the uni- accounts for just 0.7% of all natural uranium. Its less-radioact- verse is determined by the distance that light has travelled ive sibling, uranium-238, makes up the other 99.3%. In 1972 since the Big Bang (i.e. about 13.5 billion light-years) and by scientists from the French atomic energy commission noticed the amount by which it has expanded since then. This means something mysterious in soil samples taken from a uranium that the actual size of the universe is about 40 billion light- mine in Gabon in Central Africa: the relative abundance of years and rising. uranium-235 was a factor of two lower than expected. Are the extra dimensions predicted by unified theories also One possibility was that a band of hi-tech terrorists had expanding at the same rate as the universe? The answer to been stealing and stockpiling the missing uranium for pur- this question is no. If the tiny extra dimensions were expand- poses even more evil than blowing up innocent atolls. How- ing at this rate, then the strength of gravity would also be ever, isotopes of various other elements also appeared to be changing very rapidly, and there is no evidence for this. How- depleted in a pattern that was strikingly similar to that ob- ever, it may be possible to infer the presence of these extra served among the waste products from modern nuclear re- dimensions – if they exist – by detecting small changes in the actors. The most plausible explanation is that there must once strength of gravity or the other three forces. have been a “natural” nuclear reactor at Oklo. Although nat- It has been predicted, for instance, that “large” extra dimen- ural nuclear reactors were predicted by Paul Kuroda of the sions might cause small deviations in the inverse-square law University of Arkansas as long ago as 1956, Oklo is the only of gravity over distances of less than 1 mm. However, recent known example (see photograph opposite). measurements by John Price and co-workers at the Univer- What appears to have happened is that oxygenated water sity of Colorado at Boulder have failed to find any evidence slowly dissolved the uranium-235 that was stored in surface for this over distances of about 100 µm ( J C Long et al. 2003 rock about two billion years ago. Back then the natural con- Nature 421 922). This is just one of many experiments that centration of uranium-235 would have been about 3% – it have been set up to perform high-precision tests on constants, is much lower now because uranium-235 decays about six forces and fundamental symmetries in recent years. times faster than uranium-238. Over time the uranium-235 34 physicsweb.org PHYSICS WORLD APRIL 2003
  • 3. ANDREAS MITTLER Natural wonder – measurements obtained at the natural nuclear reactor at Oklo in Central Africa can place limits on any possible change in the value of the fine-structure constant over the past two billion years. would have become concentrated in nearby algae mats, as it was just over eight minutes ago because that is how long which acted as filters, and eventually enough of it would have it takes the light from the Sun to reach the Earth. Similarly, collected to reach criticality and form a natural nuclear re- some quasars are so far away that we see them as they were actor. This reactor would have “burned” the uranium-235, billions of years ago. Indeed, by observing quasars we can thus explaining the low levels of the isotope found at Oklo. build up a continuous “universal history” that starts when the But what has this got to do with α? In 1976, four years after universe was only about one billion years old and continues the Oklo reactor was discovered, Alexander Shlyakhter of up to the present day. the Leningrad Nuclear Physics Institute made the connec- However, we cannot study α with any reasonable precision tion. Samples from Oklo revealed a relative abundance of using the quasars themselves. Rather, we must examine what samarium-149 that was a factor of 45 lower than other ter- happens when the radiation from a quasar passes through a restrial samples and Shlyakhter showed that ambient neut- galaxy that lies between the Earth and the quasar. The quasar rons could convert samarium-149 into samarium-150 if they emits light over a broad range of wavelengths (figure 1). How- had exactly the right energy. ever, when this light passes through the gas around the galaxy, This resonance was due to a delicate balance between the a characteristic pattern of absorption lines will be super- strong nuclear force and the repulsive electromagnetic force imposed on it. in samarium. Moreover, the resonance energy depended on The presence of an absorption line at a particular wave- α, so if the value of α was different two billion years ago, then length reveals that a specific element is present in the gas the depletion of samarium-149 would also have been differ- cloud, and the width of each line shows the quantity of the ent. The details of the calculation are complicated, but they element that is present. In addition to hydrogen, which is show that any fractional change in the value of α since the ubiquitous in the universe, these “bar codes” reveal that the time that Oklo was active cannot be greater than 10–7 (see gas clouds contain a range of other elements, including mag- Olive et al. in further reading). nesium, iron, zinc, silicon, aluminium and chromium. Very recently a new geological measurement technique Moreover, the bar code reveals what was happening when known as “rhenium dating” has produced potentially even the light passed through the cloud, which could have hap- more stringent results. The ages of iron meteorites obtained pened as long ago as just one billion years after the Big Bang. using rhenium dating are consistent with those found by Although the gas cloud would have evolved into something other methods. From this we can show that the beta-decay quite different by today, its bar code provides us with a perma- lifetime of rhenium cannot have changed by more than 0.5% nent imprint of its state in the distant past – including infor- over the age of the solar system. This translates to an upper mation about the value of α at that time. limit on any fractional change in the value of α of the order Therefore, if we compare the bar codes that we find in 10–7 over about 4.6 billion years. quasar absorption spectra with the bar codes we measure for While 4.6 billion years is a long time, the universe itself is the same atoms and ions in the laboratory, we can find out if about 13.5 billion years old. Is it possible to test for changes the physics that is responsible for the absorption of radiation in the value of α even earlier in the history of the universe? by atoms has changed over the history of the universe. In The answer is yes – with the help of quasars. other words, we can find out if α has changed. Using quasars to look at the fine-structure constant Back to the laboratory Quasars are compact but highly luminous objects. Indeed, Back in 1998 I began collaborating with my colleagues Victor they are so luminous that they can be studied in intricate Flambaum and Vladimir Dzuba at UNSW and John Bar- detail using ground-based telescopes despite being vast dis- row, now at Cambridge University in the UK. Although both tances away from us. We think that quasars contain black Victor and I worked in the same department, neither of us holes at their centres and that the immense gravitational force had been aware of a common interest until he discovered that exerted by the black hole is extremely efficient at converting I was looking for a student to help me in my efforts to use matter in its vicinity into light. quasars to explore whether α had been different in the past. Nature kindly co-operates by scattering quasars throughout The advantage of pooling his theoretical expertise with my the universe. Since quasars are seen in all directions in the sky, experimental work quickly became apparent as we realized they provide a powerful way of charting almost the entire that we could improve the precision of the measurements of universe. And, like any astronomical object, whenever we α by an order of magnitude by analysing existing astrophy- look at a quasar we see it as it was in the past. We see the Sun sical data in a new way. PHYSICS WORLD APRIL 2003 physicsweb.org 35
  • 4. Searching for changes in the fine-structure constant using atomic clocks John Harrison would not have believed the corresponding increase in the precision of the clock. precision of the latest atomic clocks. Despite his But what has this got to do with the fine-structure mechanical genius, a clock made out of atoms – constant, α? It is not surprising to find that the rather than cogs and springs – would surely resonance frequency relies on α. Moreover, if α is surprise him. The H4 clock with which Harrison changing with time, clocks made from different eventually won the £20 000 prize offered by the elements will “tick” at slightly different rates. Board of Longitude in 1714 for a solution to the Therefore, by comparing the stability of two clocks problem of finding longitude at sea was accurate to made of different elements it should be possible to 39 seconds over 47 days, or 1 part in 105. place an upper limit on any variation of α with time. However, the latest atomic clocks are accurate to Unlike the quasar and Oklo results, experiments one second in 50 million years, or 1 part in 1015. with atomic clocks probe the stability of α as it is This level of accuracy makes it possible to search today rather than billions of years ago. for any variations in the fine-structure constant A recent experiment by Harold Marion and co- over timescales of years. workers at the Observatoire de Paris and the Ecole The world’s most precise atomic clocks are now Normale Supérieure (ENS) compared the rates of made from “atomic fountains”. A gas of atoms cesium and rubidium fountain clocks over a five- within a vacuum chamber is trapped by a set of year period. If α is changing, the rate of change, intersecting laser beams and cooled to a 1/α (dα/dt), must be less than –0.4 ± 16 × 10–16 temperature close to absolute zero. The ball of per year (see further reading). This is not in conflict atoms is then tossed vertically into the air by with the Oklo or quasar results. changing the frequency of the lasers and it passes The European Space Agency has plans to fly an through a microwave cavity on its way up and also atomic-clock experiment – called the Atomic Clock on its way down as it falls under gravity. The whole Ensemble in Space (ACES) – on the International process is then repeated. Space Station. In addition to various tests of Another laser beam is used to make the atoms general relativity, ACES will be 100 times more fluoresce, and the amount of fluorescence is sensitive to changes in α than terrestrial measured as a function of the microwave experiments. ACES will comprise two atomic clocks: frequency to plot a “resonance curve”. An a cesium clock called PHARAO (see photograph) ultra-precise measurement of time can be made built by a team led by Christophe Salomon of the by measuring the frequency of the peak in this ENS and Andre Clairon of the Observatoire de Paris, resonance curve (see “Atomic clocks” by and a hydrogen maser built by Alain Jornod of the Pierre Lemonde in Physics World January 2001 Observatoire Cantonal de Neuchâtel in Switzerland. pp39–44). The ACES experiment is particularly exciting for It turns out that the width of the resonance curve my colleagues and me because it might be able to is inversely proportional to the time that it takes for detect a drift in the value of α, which would confirm the atoms to pass through the microwave cavity, so our quasar results. On the other hand, ACES may the curve becomes narrower as the atoms spend find no change. However, this will not show that the longer in the cavity. This allows the position of the quasar results are wrong because the two peak to be determined more precisely, which experiments probe vastly different times and α means that the clock becomes more accurate. could be changing at very different rates in these This is why physicists are keen to place an atomic different epochs. Moreover, the rate of change fountain in space: “micro-gravity” conditions will may also depend on other factors, such as the extend the time by a factor of 10, with a local gravitational potential. Prior to our work, α had been measured by looking at shift of the gas: λobs = (1 + z)λ, where z is the redshift and λ is “alkali doublet” lines in systems such as singly ionized mag- the original wavelength. nesium (Mg II). This ion has a single electron in its outer shell The change in the absorption spectrum caused by the red- and its first excited energy level is split into a doublet as a shift and that caused by any change in α are different and result of interactions between the orbital and spin angular can be separated out. Whereas the effect of the redshift is to momenta of the electron. The energy difference between the multiply the wavelength of every line in the spectrum by the two states in the doublet is proportional to α2. Indeed, “fine name number, 1 + z, any variation in α only changes the rel- structure” is defined as the splitting of energy levels due to ative separation between the lines in the doublet. interactions between the orbital and spin angular momenta. However, the alkali-doublet approach fails to take advant- This fine-structure splitting means that Mg II absorbs light age of one crucial physical aspect. When an atom or ion is in at two slightly different frequencies when it is excited from its its ground state, the electrons spend a lot more time close to ground state to the first excited state. In the laboratory these the nucleus than they do when the atom is in an excited state. wavelengths are 2796 Å and 2803 Å. The expansion of the Since α essentially defines the strength of the interaction be- universe means that the wavelengths observed in quasar tween the nucleus and the electrons, any change in α will have spectra, λobs, are longer by a factor that depends on the red- a greater impact on the atom or ion when in its ground state. 36 physicsweb.org PHYSICS WORLD APRIL 2003
  • 5. 2 How spectral lines shift What could produce a spurious signal in the data? AIII SiII We have spent a great deal of time and effort trying to answer this SiII FeII NiII AI III Zn II Cr II Fe II Fe II Mg II Mg I question and make sure that the results we have seen are due to a 0 change in the value of α and not something else. We have even written an entire paper summarising all the possible sources of error and quantifying them one by one (see Murphy et al. in further reading). After an exhaustive study we came up with only two possible experimental effects that could significantly influence the results. ∆α/α –0.5 One concerned the dispersion of light from the quasar as it passed through the Earth’s atmosphere. Light at each end of the optical spectrum is dispersed by a different amount, since the refractive index of any medium depends on frequency. A sophisticated application of what is high-school physics allows us to compute the importance of this effect, with the conclusion that it 1.0 is unable to explain the results we find. 1500 2000 2500 3000 A second and more subtle effect concerns the relative amounts of rest wavelength (Å) different isotopes of the same elements in the quasar spectra and To check if the value of the fine-structure constant, α, has changed over the the laboratory spectra. Terrestrial samples of magnesium, for history of the universe it is necessary to compare the wavelength of various absorption lines in quasar spectra, after redshift effects have been removed, example, contain 79% magnesium-24, 10% magnesium-25 and with the corresponding wavelengths as measured in the laboratory. The top 11% of magnesium-26. What if the gas clouds contain different (green) line in this figure shows the position of various absorption lines in relative abundances of these isotopes? Again, we have looked at atoms and ions of silicon (Si), iron (Fe), aluminium (Al), zinc (Zn), chromium this effect in detail and it is unable to explain the quasar results. In (Cr) and magnesium (Mg) as measured in the laboratory. Mg I is neutral magnesium, Mg II is singly ionized magnesium (i.e. a Mg+ ion) and so on. The fact, averaged over the whole quasar sample, we find that any wavelengths of these lines depend on α in different ways, and the coloured attempt to include these effects in our interpretation of the quasar lines show where the absorption lines would be if α was smaller in the past data is likely to make the results even more statistically significant. than it is today. The red line corresponds to a value of α that is 90% of the current value (i.e. ∆α/α = –0.1), green corresponds to 80%, and so on. Notice how some atoms hardly change as α varies (e.g. silicon), whereas others shift towards longer wavelengths (e.g. iron) or shorter wavelengths (zinc). This laboratory experiments to re-measure the wavelengths of all observation is important because it means that it would be hard for effects the absorption lines seen in the quasar spectra. Much of this other than a variation in α to mimic this pattern. experimental work was carried out by Anne Thorne and Juliet Pickering at Imperial College in London and the data But the alkali-doublet method uses just a single atomic spe- are now so accurate that there is no longer a significant error cies, so it measures change relative to the same ground state due to laboratory measurements in the quasar results. and so misses out on this advantage. The observations have been carried out by many astron- For these reasons, Victor, Vladimir Dzuba and I developed omers, including Chris Churchill of Penn State University, a method to use different sets of atomic absorption lines and Jason Prochaska and Michael Rauch of the Carnegie Ob- compare wavelengths relative to different ground states. After servatories in Pasadena, Art Wolfe of the University of Ca- we realized that comparing laboratory and quasar observa- lifornia at San Diego, and Tom Barlow, Rob Simcoe and Wal tions in this way would provide a huge increase in sensitivity, Sargent at the California Institute of Technology, while John the challenge was to compute to a reasonable precision how Barrow at Cambridge has also been very active in the the- the energy of an electron in its ground state changed for a oretical interpretation of the results. A great deal of work has given change in α. Once we had that information, we could been done by Michael Murphy, who recently completed his then translate any differences between the laboratory and PhD with me at UNSW and is now at Cambridge. Stephen quasar measurements into a value for, or a upper limit on, any Curran and, very recently, Panayiotis Tzanivaris have also possible change in the value of α. joined the project at UNSW. A further advantage of this “many-multiplet” approach is Since the project started in 1998 we have measured 75 that light elements, such as magnesium, do not react strongly quasars at distances out to 13 billion light-years with the to a change in α, whereas heavier elements such as iron do. 10 metre Keck 1 telescope on Hawaii. The results from the This means that the light elements can be used as “anchors” Keck 1 data are astonishing. There is statistically significant against which we can measure changes in heavier elements evidence that α may have been very slightly smaller in the (figure 2). past, but only by about 1 part in 105 (see figure 3). We have ex- However, when we first tried to apply the many-multiplet plored many different possible sources of errors but they can- approach to real astrophysical data we got a big shock. The not explain what we find (see box on page 37). high-resolution spectrographs on the world’s largest tele- We are aware, however, that all our data come from the scopes were able to measure wavelengths in quasar spectra same instrument, the HIRES spectrograph on Keck 1, and more accurately than they had ever been measured in the we are therefore keen to analyse data from other instruments laboratory. In other words, we knew more about the fine and telescopes, such as the European Southern Observatory’s structure of atoms 12 billion years ago than we did today, and magnificent Very Large Telescope (VLT). New quasar data our efforts to look for changes in α were immediately limited are beginning to flow from the VLT – a set of four 8 metre by the old experimental data. telescopes in Chile – and we should soon be able to tell whe- It was therefore necessary to begin a series of brand new ther the same signal appears in those data. PHYSICS WORLD APRIL 2003 physicsweb.org 37
  • 6. 3 Results from quasar spectra What does it all mean? It should be noted that the present status of all these ex- periments is one of consistency. For example, the geological 0 results do not conflict with the quasar results or the atomic- clock experiments because they probe very different epochs ∆α/α –1 in the history of the universe. It is possible that the value of α was changing relatively rapidly (by 1 part in 105) in the first few billion years after the Big Bang, and that the fractional –2 change has been 100 times smaller since the time of the Oklo 0 1 2 3 redshift reactor about two billion years ago. We cannot repeat the When the fractional change in the fine-structure constant, ∆α/α, is plotted Oklo “experiment” but the results from the quasar observa- as a function of redshift, we find that the value of α appears to have been tions and the atomic-clock experiments will become increas- slightly smaller (by about 1 part in 105) in the past than it is now. Each of the green data points in the figure corresponds to an average of about ingly accurate over the next few years. 10 independent quasar measurements, and the redshifts range from z = 0.55 Confirmation that α is changing would have profound im- (about 5.6 billion years ago) to z = 3 (about 12.6 billion years ago). If α was not plications for physics. For instance, the equivalence principle – changing over the history of the universe then the data points would be one of the cornerstones of relativity – states that in freely fal- scattered about the horizontal dashed line (see Webb et al. in further reading). ling reference frames, the outcome of any non-gravitational experiment is independent of when and where it is carried out. Other groups are also joining the hunt. John Bahcall of the Changes in the value of α would constitute a violation of Institute for Advanced Studies in Princeton and colleagues the equivalence principle. However, this is not necessarily bad have just completed an exceptionally thorough analysis based news because many of the theories that seek to unify the four on a new approach in which they studied oxygen emission lines fundamental forces of nature also violate the equivalence prin- from distant galaxies. Although Bahcall and co-workers took ciple. The varying speed of light (VSL) theories, first proposed enormous care to select only the highest quality data for their by John Moffat of the University of Toronto and developed in analysis, the precision they finally reach is about an order of recent years by João Magueijo of Imperial College, John Bar- magnitude less than we obtained using the many-multiplet row and others as an alternative to inflationary models in cos- methods on quasar absorption spectra. This means that they mology, could also lead to changes in the value of α in the early have not yet been able to provide a test of our results (see universe. Inflation and VSL theories are both attempts to ex- further reading). plain various features of the universe – such as its apparent flat- If the new data do not confirm the results so far, the com- ness – that cannot be explained by the Big Bang theory alone. bined data from Keck 1 and the VLT will nevertheless place If the quasar results are eventually confirmed, our concepts the most stringent constraints so far on the form that new uni- of space and time are sure to undergo radical transforma- fied theories of the fundamental forces must take. And if the tions. Who knows how this will change our fundamental un- new data support a changing α, we may eventually have to re- derstanding of the universe? write significant portions of modern physics. Further reading The early universe J N Bahcall, C L Steinhardt and D Schlegel 2003 Does the fine-structure We can also search for variations in α at even earlier times constant vary with cosmological epoch? arXiv.org/abs/astro-ph/0301507 in the history of the universe. If we change α, we change the J Barrow 2002 The Constants of Nature (Jonathan Cape, London) temperature at which electrons and protons recombined in J D Bekenstein 2003 Fine-structure constant variability: surprises for the early universe to form neutral hydrogen atoms: this is the laboratory atomic spectroscopy and cosmological evolution of quasar spectra process that defines the formation of the cosmic microwave arXiv.org/abs/astro-ph/0301566 background about 380 000 years after the Big Bang (see L Bergström, S Iguri and H Rubinstein 1999 Constraints on the variation of the “The cosmic microwave background” by Pedro G Ferreira fine-structure constant from big bang nucleosynthesis Phys. Rev. D 60 045005 on page 27 and Martins et al. in further reading). A change in C J A P Martins et al. 2003 WMAP constraints on varying α and the promise of α would change the time at which recombination occurred, reionization arXiv.org/abs/astro-ph/0302295 and this could be detected by satellite measurements of the H Marion et al. 2003 A search for variations of fundamental constants using cosmic background. atomic fountain clocks arXiv.org/abs/physics/0212112 The formation of light elements such as helium, deuterium M T Murphy et al. 2002 Does the fine-structure constant vary? A detailed and lithium in the first few minutes after the Big Bang would investigation into systematic effects arXiv.org/abs/astro-ph/0210532 also be affected if α was changing over time. The equations K A Olive et al. 2002 Constraints on the variations of the fundamental that define the rate at which the light elements are formed are couplings arXiv.org/abs/hep-ph/0205269 modified in different ways if α varies over time. This means J-P Uzan 2002 The fundamental constants and their variation: observational that accurate measurements of the relative abundances of status and theoretical motivations arXiv.org/abs/hep-ph/0205340 these elements can also be used to constrain any change in α J K Webb et al. 2001 Further evidence for cosmological evolution of the over almost the entire history of the universe – from the first fine-structure constant Phys. Rev. Lett. 87 091301 few minutes after the Big Bang until today (see Bergström et al. J K Webb et al. 2002 Does the fine-structure constant vary? A third quasar in further reading). absorption sample consistent with varying alpha arXiv.org/abs/ Both of these methods are not yet very accurate. Neverthe- astro-ph/0210531 less they provide important complementary constraints on any variations of α and show that it cannot have changed by John Webb is in the School of Physics, University of New South Wales, Sydney, much more than 10% in either case. NSW 2052, Australia, e-mail jkw@bat.phys.unsw.edu.au 38 physicsweb.org PHYSICS WORLD APRIL 2003