Which of the following pairs are expected to have an unexpectedly low.docx

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The document discusses which pairs of compounds are expected to have unexpectedly low or high boiling temperatures. It analyzes four pairs - n-butane/2-methylpentane, acetone/dimethylamine, water/n-butane, and acetonitrile/benzene - based on the number of carbons and whether attractions like hydrogen bonding, polarity differences, or ionic interactions exist between the compounds. It determines that water and n-butane would have the lowest boiling point due to hydrogen bonding being the only interaction, while n-butane and 2-methylpentane would have the highest since there is no attraction between the nonpolar compounds.

Which of the following pairs are expected to have an unexpectedly low boiling temperature?
Which are expected to have an unexpectedly high or low boiling temperature?
- n-butane / 2-methylpentane
- acetone / dimethylamine
- water / n-butane
- acetonitrile / benzene
Solution
1) n-butane+ 2-methylpentane.. not attracted (nopolairty in any compound) (no.of carbon
=8)
2) acetone+ dimethylamine .. attracted due to H-bonding and dipole diff. (no. of carbons
=5)
3) water + n-butane .. only H-bionding (no.of carbon 3)
4) acetonitrile +benzene .. only ionic diff. (no. of carbon 6)
so boiling point= 3<2<4<1

Which of the following pairs are expected to have an unexpectedly low.docx

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