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“We need, and are poised
for, a new industrial and
energy revolution”
Christiana Figueres,
Executive Secretary,
United Nations Framework
Convention on Climate Change

10th October 2011, London
• Founder Chairman Oxford Index

• Advisory Board Member of the UK High Temperature
  Innovation Centre

• Collaborating with the Stockholm Environment
  Institute on Carbon Foot printing

• Creator of a Carbon Neutral New Town proposal
  submitted to the UK Government
Why burn or hide the waste?
• New Waste Regulations 2011 support tyre pyrolysis
 • Legal requirement to employ the most environmentally responsible
   recycling or disposal route for any waste
 • Waste producers must observe ‘best’ process to deal with their wastes




DISPOSAL            RECOVERY            RECYCLING        PREPARING         PREVENTION
• the last resort   • reclaiming        • routing the    FOR RE-USE        • using best
  if no use can       some/all of         waste for      • routing the       efforts to
  be made of          the waste (e.g.     conversion       waste for         minimise the
  the waste           for energy)         into another     return to its     generation of
                                          product or       original          waste
                                          formulation      formulation
Utilising the rich, untapped resources of waste
tyres, PYReco is able to release the following
high quality ‘green’ products,

            • PYReco® Carbon Black
            • Oil
            • Gas
            • High Grade Steel
            • Electricity
 externally applying heat to tyres in
  a closed, oxygen free environment
 the tyres decompose, giving off
  gas then oil
 leaving a mix of char and steel
  which are then separated and
  further refined
Steel separation
                                     carbon black by
                                     electromagnets

WHOLE TYRE                           Carbon black
                                     refined to a
                                     commercial grade


        SHREDDER                     The Oil, a diesel
                                     equivalent



TYRE SHRED                           The Gas, calorific
                                     value similar to
                                     propane


                   CALCINER / KILN
• 45,000 tons Carbon Black
• 575,000 barrels of Oil & Gas
• 15,000 tons Steel
‘if its black it has carbon black in it’
• Reinforcing agent in tyres and rubber products




• Plastics




• Toners, Printing Inks and Electronic Components
The pyrolysing of just 50% of Europe’s annual rubber
waste would produce circa:

• 7,500,000 barrels of semi-refined diesel oil

• 7,500,000 barrels of oil equivalent of gas

• 1,000,000 tonnes of carbon black equivalent
  (saving circa 15,000,000 barrels of oil)

• 350,000 tonnes of high tensile steel
• Potential for over 500Mw of electricity
• 5,000,000 tonnes of CO2 emissions saved (Carbon
  Trust low estimate figures) but potentially
• 10,000,000 tonnes of CO2 saved according to
  projections from the Stockholm Environment
  Institute. Full research near completion
• For every 1 tonne of PYReco carbon black produced,
  2 tonnes of CO2 saved
• All achieved with zero waste
   1,000 tonnes of product into the process delivers
   1,000 tonnes of usable material
PYReco Science and Evaluation

              Process
     Properties & Performance
Mike Rowlinson
   MSc Polymer Engineering
        BSc Chemistry
     Rubber and Plastics

      Heading the PYReco
Research and Development Team
Method     Test Name Parameter      Unit     Run 8 NOV 11 Run 9 NOV 11 Run 10 NOV 11

  ASTM     Compressed
                          COAN      mL/100g       76           76.1         77.2
  D3493     Structure

  ASTM        Surface
                              NSA    m2/g        64.4          63.0         63.7
  D6556        Area

  ASTM        Sieve
                          325#       ppm          11            15           15
  D1514      Residue

                           PAH
            Total PAH^               ppm          94            9            28
                         content

^ Sum of 13 individual PAHs
PYReco carbon black
PYReco      References               Dispersion (x20)
Method   Test Name Parameter Unit
                                    9 NOV 12 N326 N660 N772
ASTM     ML(1+4)
                      ML     M.U.    39.1   42.6   38.5   32.9
D1646     100oC                                                  PYReco




                                                                 N326




                                                                 N660




                                                                 N772
PYReco Ref. Carbon Blacks
Method Parameter        Unit                                               Oven Aged Properties
                                 9 NOV 11 N326 N660 N772
 ASTM                                                                      % Original (24hrs 100oc)
          Hardness     Shore A      64     67    66     61
 D2240
                                                               140%
            M100        MPa        3.08   2.85   3.1    2.53
                                                               130%

 ASTM       M300        MPa        13.4   13.7 13.4     11.7   120%

 D412         EB         %         452    539    439    549    110%

                                                               100%
              TS        Mpa        21.4    26    19.8   23.6
                                                               90%
 ASTM
           Cres Tear   N/mm        92.8   155    96     96     80%
 D624
                                                               70%
  Compression Set
                         %         23.4   26.6 21.9     23.7
   (24hrs @ 70°C)                                              60%

Akron Abrasion (15o)                79    164    106    101    50%

                                                               40%




                                                                  PYReco
                                                                  N326
                                                                  N660
                                                                  N772
PYReco Carbon Black
• Consistent Production Quality
• Low PAH levels

Meets current quality demands for:
• Processing
• Surface appearance
• Reinforcement
   • Static
   • Dynamic

science@pyreco.com
Samples available
We do not inherit the
       Earth
from our ancestors,
    we borrow it
 from our children

        Native American Proverb

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PYReco present at Cologne Expo Cologne 14 16th Feb 2012 = Final

  • 1.
  • 2. “We need, and are poised for, a new industrial and energy revolution” Christiana Figueres, Executive Secretary, United Nations Framework Convention on Climate Change 10th October 2011, London
  • 3. • Founder Chairman Oxford Index • Advisory Board Member of the UK High Temperature Innovation Centre • Collaborating with the Stockholm Environment Institute on Carbon Foot printing • Creator of a Carbon Neutral New Town proposal submitted to the UK Government
  • 4. Why burn or hide the waste?
  • 5. • New Waste Regulations 2011 support tyre pyrolysis • Legal requirement to employ the most environmentally responsible recycling or disposal route for any waste • Waste producers must observe ‘best’ process to deal with their wastes DISPOSAL RECOVERY RECYCLING PREPARING PREVENTION • the last resort • reclaiming • routing the FOR RE-USE • using best if no use can some/all of waste for • routing the efforts to be made of the waste (e.g. conversion waste for minimise the the waste for energy) into another return to its generation of product or original waste formulation formulation
  • 6.
  • 7.
  • 8. Utilising the rich, untapped resources of waste tyres, PYReco is able to release the following high quality ‘green’ products, • PYReco® Carbon Black • Oil • Gas • High Grade Steel • Electricity
  • 9.  externally applying heat to tyres in a closed, oxygen free environment  the tyres decompose, giving off gas then oil  leaving a mix of char and steel which are then separated and further refined
  • 10. Steel separation carbon black by electromagnets WHOLE TYRE Carbon black refined to a commercial grade SHREDDER The Oil, a diesel equivalent TYRE SHRED The Gas, calorific value similar to propane CALCINER / KILN
  • 11. • 45,000 tons Carbon Black • 575,000 barrels of Oil & Gas • 15,000 tons Steel
  • 12. ‘if its black it has carbon black in it’ • Reinforcing agent in tyres and rubber products • Plastics • Toners, Printing Inks and Electronic Components
  • 13. The pyrolysing of just 50% of Europe’s annual rubber waste would produce circa: • 7,500,000 barrels of semi-refined diesel oil • 7,500,000 barrels of oil equivalent of gas • 1,000,000 tonnes of carbon black equivalent (saving circa 15,000,000 barrels of oil) • 350,000 tonnes of high tensile steel
  • 14. • Potential for over 500Mw of electricity • 5,000,000 tonnes of CO2 emissions saved (Carbon Trust low estimate figures) but potentially • 10,000,000 tonnes of CO2 saved according to projections from the Stockholm Environment Institute. Full research near completion • For every 1 tonne of PYReco carbon black produced, 2 tonnes of CO2 saved • All achieved with zero waste 1,000 tonnes of product into the process delivers 1,000 tonnes of usable material
  • 15.
  • 16. PYReco Science and Evaluation Process Properties & Performance
  • 17. Mike Rowlinson MSc Polymer Engineering BSc Chemistry Rubber and Plastics Heading the PYReco Research and Development Team
  • 18. Method Test Name Parameter Unit Run 8 NOV 11 Run 9 NOV 11 Run 10 NOV 11 ASTM Compressed COAN mL/100g 76 76.1 77.2 D3493 Structure ASTM Surface NSA m2/g 64.4 63.0 63.7 D6556 Area ASTM Sieve 325# ppm 11 15 15 D1514 Residue PAH Total PAH^ ppm 94 9 28 content ^ Sum of 13 individual PAHs
  • 20. PYReco References Dispersion (x20) Method Test Name Parameter Unit 9 NOV 12 N326 N660 N772 ASTM ML(1+4) ML M.U. 39.1 42.6 38.5 32.9 D1646 100oC PYReco N326 N660 N772
  • 21. PYReco Ref. Carbon Blacks Method Parameter Unit Oven Aged Properties 9 NOV 11 N326 N660 N772 ASTM % Original (24hrs 100oc) Hardness Shore A 64 67 66 61 D2240 140% M100 MPa 3.08 2.85 3.1 2.53 130% ASTM M300 MPa 13.4 13.7 13.4 11.7 120% D412 EB % 452 539 439 549 110% 100% TS Mpa 21.4 26 19.8 23.6 90% ASTM Cres Tear N/mm 92.8 155 96 96 80% D624 70% Compression Set % 23.4 26.6 21.9 23.7 (24hrs @ 70°C) 60% Akron Abrasion (15o) 79 164 106 101 50% 40% PYReco N326 N660 N772
  • 22. PYReco Carbon Black • Consistent Production Quality • Low PAH levels Meets current quality demands for: • Processing • Surface appearance • Reinforcement • Static • Dynamic science@pyreco.com Samples available
  • 23. We do not inherit the Earth from our ancestors, we borrow it from our children Native American Proverb