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Office: 33-313
Telephone: 880-7221
Email: espark@snu.ac.kr
Office hours: by appointment
2017 Spring
1
“Calculation and Applications Phase Equilibria”
Principles of Solidification
Eun Soo Park
03.06.2017
Text: “Principles of Solidification”,
BRUCE CHALMERS, John & Sons, Inc (1964)
References: 1) “Solidification Processing,” MERTON C. FLEMINGS,
McGraw-Hill Book Company, INC (1974)
2) “Fundamentals of Solidification,” W. KURZ,
TRANS TECH PUBLICATION (1984)
3) “Solidification and Casting,” G.J. DAVIES,
JOHN WILEY & SONS (1973)
Additional reading materials will be provided. 2
• Web lecture assistance: http://etl.snu.ac.kr
- All materials will be posted at the webpage.
- text message will be sent for the important and urgent notice.
• Hand out copied materials or scanned materials in website
Introduction
Course Goals
This course provides a critical review of the state of
knowledge and understanding of the process of
solidification, defined for this purpose as the discontinuous
change of state from liquid to crystalline solid. In particular,
this course is intended to provide an understanding of the
physical processes that relate to solidification and to show
how these processes combine to produce the phenomena
observed in practical situations. An essential aim of many
solidification processes is to obtain optimum properties in
the resultant material. This course can provide a working
knowledge of how the solidification principles can be
utilized to produce structures with improved mechanical or
physical properties, which then can be used to solve
problems involving materials and process design. By the
end of the semester, you will be able to understand key
concepts, experimental techniques, and open questions in
the solidification phenomena of various materials. 3
4
Contents in Phase Transformation
(Ch1) Thermodynamics and Phase Diagrams
(Ch2) Diffusion: Kinetics
(Ch3) Crystal Interface and Microstructure
(Ch4) Solidification: Liquid → Solid
(Ch5) Diffusional Transformations in Solid: Solid → Solid
(Ch6) Diffusionless Transformations: Solid → Solid
Background
to understand
phase
transformation
Representative
Phase
transformation
Schedule
week 1 Brief introduction : the relevant thermodynamic laws, properties,
and relationships
week 2 Solidification as an Atomic Process I
week 3 Solidification as an Atomic Process II
week 4 Nucleation I
week 5 Nucleation II
week 6 Microscopic Heat Flow Consideration I
week 7 Microscopic Heat Flow Consideration II
week 8 Reduction of Solute during solidification I
week 9 Reduction of Solute during solidification II
week 10 Polyphase Solidification I
week 11 Polyphase Solidification II
week 12 Macroscopic Heat Flow and Fluid Flow I
week 13 Macroscopic Heat Flow and Fluid Flow II
week 14 The Structure of Cast Metals I
week 15 The Structure of Cast Metals II 5
Components of Your Grade:
1) Exams (midterm: 30% + final: 35%)
There will be two exams, each of which will take 2-3 hours. I will not use class
time for the exams and instead will reserve separate time slots. The exams will
be conceptual and difficult.
2) Reports and Presentation (15%)
Assignments handed in after the start of class lose credit depending on the
timing. If you wish, you may work together on homework assignments. But, you
must hand in your own work, in your own words.
3) Quizzes (15%) and Attendance (5%)
There will be a few short quizzes between the major exams. These will take place
in class, at the beginning of class and will last for 20 minutes.
Remarks: The weight of each grade component may change up to 5%
depending on the student’s achievement.
6
Wednesday, Friday,
Wednesday, nothing thereafter.
7
Liquid Undercooled Liquid Solid
<Thermodynamic>
Solidification: Liquid Solid
• Interfacial energy ΔTN
Melting: Liquid Solid
• Interfacial energy
SV
LV
SL γ
γ
γ <
+
No superheating required!
No ΔTN
Tm
vapor
Melting and Crystallization are Thermodynamic Transitions
Incentive Homework 1:
Example of Superheating (PPT 3 pages)
Chapter 1 Introduction of Solidification

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1_Solidification 030617.pdf

  • 1. Office: 33-313 Telephone: 880-7221 Email: espark@snu.ac.kr Office hours: by appointment 2017 Spring 1 “Calculation and Applications Phase Equilibria” Principles of Solidification Eun Soo Park 03.06.2017
  • 2. Text: “Principles of Solidification”, BRUCE CHALMERS, John & Sons, Inc (1964) References: 1) “Solidification Processing,” MERTON C. FLEMINGS, McGraw-Hill Book Company, INC (1974) 2) “Fundamentals of Solidification,” W. KURZ, TRANS TECH PUBLICATION (1984) 3) “Solidification and Casting,” G.J. DAVIES, JOHN WILEY & SONS (1973) Additional reading materials will be provided. 2 • Web lecture assistance: http://etl.snu.ac.kr - All materials will be posted at the webpage. - text message will be sent for the important and urgent notice. • Hand out copied materials or scanned materials in website Introduction
  • 3. Course Goals This course provides a critical review of the state of knowledge and understanding of the process of solidification, defined for this purpose as the discontinuous change of state from liquid to crystalline solid. In particular, this course is intended to provide an understanding of the physical processes that relate to solidification and to show how these processes combine to produce the phenomena observed in practical situations. An essential aim of many solidification processes is to obtain optimum properties in the resultant material. This course can provide a working knowledge of how the solidification principles can be utilized to produce structures with improved mechanical or physical properties, which then can be used to solve problems involving materials and process design. By the end of the semester, you will be able to understand key concepts, experimental techniques, and open questions in the solidification phenomena of various materials. 3
  • 4. 4 Contents in Phase Transformation (Ch1) Thermodynamics and Phase Diagrams (Ch2) Diffusion: Kinetics (Ch3) Crystal Interface and Microstructure (Ch4) Solidification: Liquid → Solid (Ch5) Diffusional Transformations in Solid: Solid → Solid (Ch6) Diffusionless Transformations: Solid → Solid Background to understand phase transformation Representative Phase transformation
  • 5. Schedule week 1 Brief introduction : the relevant thermodynamic laws, properties, and relationships week 2 Solidification as an Atomic Process I week 3 Solidification as an Atomic Process II week 4 Nucleation I week 5 Nucleation II week 6 Microscopic Heat Flow Consideration I week 7 Microscopic Heat Flow Consideration II week 8 Reduction of Solute during solidification I week 9 Reduction of Solute during solidification II week 10 Polyphase Solidification I week 11 Polyphase Solidification II week 12 Macroscopic Heat Flow and Fluid Flow I week 13 Macroscopic Heat Flow and Fluid Flow II week 14 The Structure of Cast Metals I week 15 The Structure of Cast Metals II 5
  • 6. Components of Your Grade: 1) Exams (midterm: 30% + final: 35%) There will be two exams, each of which will take 2-3 hours. I will not use class time for the exams and instead will reserve separate time slots. The exams will be conceptual and difficult. 2) Reports and Presentation (15%) Assignments handed in after the start of class lose credit depending on the timing. If you wish, you may work together on homework assignments. But, you must hand in your own work, in your own words. 3) Quizzes (15%) and Attendance (5%) There will be a few short quizzes between the major exams. These will take place in class, at the beginning of class and will last for 20 minutes. Remarks: The weight of each grade component may change up to 5% depending on the student’s achievement. 6
  • 8. Liquid Undercooled Liquid Solid <Thermodynamic> Solidification: Liquid Solid • Interfacial energy ΔTN Melting: Liquid Solid • Interfacial energy SV LV SL γ γ γ < + No superheating required! No ΔTN Tm vapor Melting and Crystallization are Thermodynamic Transitions Incentive Homework 1: Example of Superheating (PPT 3 pages) Chapter 1 Introduction of Solidification