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Air Pollution Control

   Specific to Methane Digestion in the
    landfill
   Skill towards bioremediation for air
    pollution
   Engineering skills for Methane
    digester design
Study of Methane
Digestion in a Newly
 Designed Biofilter
Specific Objectives:

   To design a methane biofilter
   To find out the suitable material
    to maximize the bio-digestion
    of methane.
   To develop a relation between
    biomass growth and methane
    consumption efficiency.
Experimental setup for the methane
             biofilter
Another view of the experimental
             setup
a] Schematic diagram of the experimental
   Biofilter Column and [b] Top View
Different properties of filter materials

Parameter              Compost   Sawdust   Sand


Bulk Density (kg/m3)     568       168     1310


Water Content (%)        37        8.7     0.6


Ignition loss (%)        45        98       3


pH                       7.2       6.8     7.8
[a] Gas collection balloons, [b] Solution
extracted from compost, sawdust, and sand
[a] Gas Chromatograph, [b] GC
       Syringe opening
[a] Seeded BOD bottles, [b] DO
     and pH measurement
Chemical Oxygen Demand
       Analysis
[a] Centrifuge Tubes, [b] Bio-Rad
Bradford Kit, [c] Standard Cuvettes, [d]
          Sample Cuvettes
Methanotrophs Plate Count
        Analysis
Methanotrophs Plate Count
        Analysis
Initial experimental conditions of
        the selected three media
Description of parameters          Compost    Sawdust    Sand
Methane supply concentration (%)   2.70       2.70       2.70
Packed bed depth (cm)              50         50         50
Moisture content (cm3/cm3)         0.372      0.414      0.044
Biofilter volume (m3)              0.115      0.115      0.115
Bulk density of filter (kg/ m3)    568        183        1310
Methane mass flow rate (g/m3/hr)   3.4×10-3   3.4×10-3   3.4×10-3
COD status of filter (mg/L)        4842       3626       122
BOD status of filter (mg/L)        457        256        17
Biomass density (g/ m3)            876        408        32
Fig. 5.2: Specific capacity of methane digestion in different materials

                                  40.00

                                  35.00

                                  30.00

                                  25.00
Sp. methane digestion (g/m3/hr)




                                  20.00

                                  15.00
                                               Linear (Compost) y = -0.7886x + 33.03
                                  10.00
                                               Linear (Saw dust) y = -0.2992x + 21.43
                                   5.00        Linear (Sand)
                                                                 y = -0.2677x + 20.685
                                   0.00
                                          0        2                  4                  6           8             10   12
                                                                                Time period (week)
Fig. 5.3: Trends of temperature rise in different biofilters wrt inlet temperature

                    40


                                                                      TempCompost         TempSaw dust      TempSand
                    35


                    30
0 C)




                    25
Filter bed temp (




                    20


                    15


                    10


                    5


                    0
                         20.7    21.1     21.8     19      17.7      21.2        18.7   21.6      21     19.9    20.7
                                                                             0
                                                           Inlet temperature ( C)
Fig. 5.4: Relationship betw een methane digestion and temperature rise in different biofilters

                      1 20.0



                                                                                     DigestionCompost      DigestionSaw dust     DigestionSand
                      1 00.0
%)




                       80.0
Methane digestion (




                       60.0




                       40.0




                       20.0




                        0.0
                               25          29         27        25         22         24           22      23         21        20         21

                               28          30         31        25         24         28           24      24         22        22        22

                               27          35         36        27         26         30           26      26         24        24        23
                                                                                                   0C)
                                                                       Filter beds temperature (
Fig. 5.6: Methane digestion Vs moisture content in the Sawdust medium


                        80.00

                        70.00

                        60.00

                        50.00
Methane Digestion (%)




                        40.00
                                                           Poly. (Saw dust)   y = 233.15x2 - 140.78x + 75.629
                        30.00

                        20.00

                        10.00

                         0.00
                            0.360        0.380     0.400           0.420      0.440         0.460         0.480   0.500   0.520
                                                    Volumetric moisture content (m 3/m 3)
Fig. 5.8: Trends of biomass contents at different filter media


               1400

               1200                                                                          Compost
                                                                                             Saw dust
               1000                                                                          Sand
3)




               800
Biomass (g/m




               600

               400

               200

                 0
                      0   1        2        3        4        5          6      7        8             9   10

                                                    Time period (week)
Fig. 5.10: Relationship between biomass contents and methane digestion rates in sawdust filter
                       700
                                                                                                               Saw dust
                       600
                                                                                                               Pow er (Saw dust)
3)




                       500
                                                                                                           y = 631.31x-0.7693
                       400                                                                                    R2 = 0.8938
Biomass content (g/m




                       300

                       200

                       100

                        0
                             17.0    21.4      23.3     18.9      19.0      24.2     19.2      22.8     21.3       17.8         14.4
                                                                Methane digestion rate (g/m 3/hr)
Fig. 5.11: Relationship between biomass contents and methane digestion rates in sand filter
                       50
                       45                                                                                              Sand
                                                                                         y = 40.477x  -0.1626
                       40                                                                                              Pow er (Sand)
3)




                                                                                            R2 = 0.9088
                       35
                       30
                       25
Biomass content (g/m




                       20
                       15
                       10
                       5
                       0
                            19.9     21.2     21.8      19.5      18.9     19.7      17.3      18.9             19.5   21.1       14.9
                                                                Methane digestion rate (g/m 3/hr)
Fig. 5.13: Trends of BOD removal status in different filter media

                    500
                                                                                                      Compost
                    450
                                                                                                      Sawdust
                    400                                                                               Sand
                                                                                                      Power (Compost)
                    350
                                                                                                      Power (Sawdust)
                    300                                                                               Power (Sand)
BOD status (mg/L)




                    250

                    200

                    150

                    100

                    50

                     0
                          0   1          2        3         4        5      6        7        8       9         10

                                                      Time period (week)
Fig. 5.12: Trends of COD removal status in different filter media

                    6000
                                                                                                       Compost
                                                                                                       Sawdust
                    5000
                                                                                                       Sand
                                                                                                       Power (Compost)
                    4000                                                                               Power (Sawdust)
                                                                                                       Power (Sand)
COD status (mg/L)




                    3000



                    2000



                    1000



                      0
                           0   1         2        3        4        5         6      7        8         9        10

                                                         Time period (week)
Fig. 5.14: Trends of bacterial population at different filter media


                                                                                                                 Compost
                                                                                                                 Saw dust
                                                                                                                 Sand


                       250

                       200

                       150                                                                  0
              (10 4)
Bacterial population




                                                                                        1
                       100                                                          2       Time period (week)
                                                                                4
                       50                                                   5
                                                                        6
                                                                    7
                        0                                       8
                             Compost Saw dust      Sand     9
Conclusion
   The methane digestion efficiency in the sawdust
    medium was 60% with the biomass content of
    238 g/m3 while the compost medium had 86%
    with 539 g/m3 biomass.
   The overall results indicated that the sawdust
    material can be used for minimizing methane
    transfer rate from the landfill.
   The digestions efficiency in the sawdust could be
    accelerated by incorporating necessary nutrients
    in the beginning of the experiment.

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MethaneDigester Design

  • 1. Air Pollution Control  Specific to Methane Digestion in the landfill  Skill towards bioremediation for air pollution  Engineering skills for Methane digester design
  • 2. Study of Methane Digestion in a Newly Designed Biofilter
  • 3. Specific Objectives:  To design a methane biofilter  To find out the suitable material to maximize the bio-digestion of methane.  To develop a relation between biomass growth and methane consumption efficiency.
  • 4. Experimental setup for the methane biofilter
  • 5. Another view of the experimental setup
  • 6. a] Schematic diagram of the experimental Biofilter Column and [b] Top View
  • 7. Different properties of filter materials Parameter Compost Sawdust Sand Bulk Density (kg/m3) 568 168 1310 Water Content (%) 37 8.7 0.6 Ignition loss (%) 45 98 3 pH 7.2 6.8 7.8
  • 8. [a] Gas collection balloons, [b] Solution extracted from compost, sawdust, and sand
  • 9. [a] Gas Chromatograph, [b] GC Syringe opening
  • 10. [a] Seeded BOD bottles, [b] DO and pH measurement
  • 12. [a] Centrifuge Tubes, [b] Bio-Rad Bradford Kit, [c] Standard Cuvettes, [d] Sample Cuvettes
  • 15. Initial experimental conditions of the selected three media Description of parameters Compost Sawdust Sand Methane supply concentration (%) 2.70 2.70 2.70 Packed bed depth (cm) 50 50 50 Moisture content (cm3/cm3) 0.372 0.414 0.044 Biofilter volume (m3) 0.115 0.115 0.115 Bulk density of filter (kg/ m3) 568 183 1310 Methane mass flow rate (g/m3/hr) 3.4×10-3 3.4×10-3 3.4×10-3 COD status of filter (mg/L) 4842 3626 122 BOD status of filter (mg/L) 457 256 17 Biomass density (g/ m3) 876 408 32
  • 16. Fig. 5.2: Specific capacity of methane digestion in different materials 40.00 35.00 30.00 25.00 Sp. methane digestion (g/m3/hr) 20.00 15.00 Linear (Compost) y = -0.7886x + 33.03 10.00 Linear (Saw dust) y = -0.2992x + 21.43 5.00 Linear (Sand) y = -0.2677x + 20.685 0.00 0 2 4 6 8 10 12 Time period (week)
  • 17. Fig. 5.3: Trends of temperature rise in different biofilters wrt inlet temperature 40 TempCompost TempSaw dust TempSand 35 30 0 C) 25 Filter bed temp ( 20 15 10 5 0 20.7 21.1 21.8 19 17.7 21.2 18.7 21.6 21 19.9 20.7 0 Inlet temperature ( C)
  • 18. Fig. 5.4: Relationship betw een methane digestion and temperature rise in different biofilters 1 20.0 DigestionCompost DigestionSaw dust DigestionSand 1 00.0 %) 80.0 Methane digestion ( 60.0 40.0 20.0 0.0 25 29 27 25 22 24 22 23 21 20 21 28 30 31 25 24 28 24 24 22 22 22 27 35 36 27 26 30 26 26 24 24 23 0C) Filter beds temperature (
  • 19. Fig. 5.6: Methane digestion Vs moisture content in the Sawdust medium 80.00 70.00 60.00 50.00 Methane Digestion (%) 40.00 Poly. (Saw dust) y = 233.15x2 - 140.78x + 75.629 30.00 20.00 10.00 0.00 0.360 0.380 0.400 0.420 0.440 0.460 0.480 0.500 0.520 Volumetric moisture content (m 3/m 3)
  • 20. Fig. 5.8: Trends of biomass contents at different filter media 1400 1200 Compost Saw dust 1000 Sand 3) 800 Biomass (g/m 600 400 200 0 0 1 2 3 4 5 6 7 8 9 10 Time period (week)
  • 21. Fig. 5.10: Relationship between biomass contents and methane digestion rates in sawdust filter 700 Saw dust 600 Pow er (Saw dust) 3) 500 y = 631.31x-0.7693 400 R2 = 0.8938 Biomass content (g/m 300 200 100 0 17.0 21.4 23.3 18.9 19.0 24.2 19.2 22.8 21.3 17.8 14.4 Methane digestion rate (g/m 3/hr)
  • 22. Fig. 5.11: Relationship between biomass contents and methane digestion rates in sand filter 50 45 Sand y = 40.477x -0.1626 40 Pow er (Sand) 3) R2 = 0.9088 35 30 25 Biomass content (g/m 20 15 10 5 0 19.9 21.2 21.8 19.5 18.9 19.7 17.3 18.9 19.5 21.1 14.9 Methane digestion rate (g/m 3/hr)
  • 23. Fig. 5.13: Trends of BOD removal status in different filter media 500 Compost 450 Sawdust 400 Sand Power (Compost) 350 Power (Sawdust) 300 Power (Sand) BOD status (mg/L) 250 200 150 100 50 0 0 1 2 3 4 5 6 7 8 9 10 Time period (week)
  • 24. Fig. 5.12: Trends of COD removal status in different filter media 6000 Compost Sawdust 5000 Sand Power (Compost) 4000 Power (Sawdust) Power (Sand) COD status (mg/L) 3000 2000 1000 0 0 1 2 3 4 5 6 7 8 9 10 Time period (week)
  • 25. Fig. 5.14: Trends of bacterial population at different filter media Compost Saw dust Sand 250 200 150 0 (10 4) Bacterial population 1 100 2 Time period (week) 4 50 5 6 7 0 8 Compost Saw dust Sand 9
  • 26. Conclusion  The methane digestion efficiency in the sawdust medium was 60% with the biomass content of 238 g/m3 while the compost medium had 86% with 539 g/m3 biomass.  The overall results indicated that the sawdust material can be used for minimizing methane transfer rate from the landfill.  The digestions efficiency in the sawdust could be accelerated by incorporating necessary nutrients in the beginning of the experiment.

Editor's Notes

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