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Acid rain
1.
ACID RAIN ©
2.
History The term was
coined in 1872 by the Scottish chemist Robert Angus Smith to describe the acidic precipitation in Manchester, England. ©
3.
When is Acid
Rain ACID Rain? When the pH of rain water is <5.6, it is called Acid Rain. ©
4.
When is Acid
Rain ACID Rain? Acid Rain pH < 5.6 Normal Rain pH = 7 ©
5.
Adverse Effects at what
pH? • Adverse Effects of Acid Rain start only below pH 4.5 • North America, Central Europe, Netherlands, Sweden, USA and other countries having acid rain between 2.0 and 5.0. ©
6.
Acid Rain in
INDIA Delhi, Uttar Pradesh, Maharashtra, Madhya Pradesh, Tamil Nadu and even the Andaman Islands have reported low levels of pH. ©
7.
ACID RAIN formulas ©
8.
Acid Rain Formulas •
CO2 + H2O = • 2NO + O2 = • 4NO2 + H20 + O2 = • 2SO2 + O2 = • SO3 + H2O = • HCl gas Dissolved in Water H2CO3 2NO2 4HNO3 2SO3 H2SO4 HCl acid ©
9.
Acid Rain Formulas H2SO4
- 70% contribution to Acid Rain • 4HNO3 - 20% contribution to Acid Rain • 10% others ©
10.
CAUSES of ACID RAIN ©
11.
CAUSES of Acid
Rain • Mainly Air Pollution – by gases like SOX and NOX released by Natural Causes & Man-Made causes ©
12.
CAUSES of Acid
Rain NATURAL ©
13.
CAUSES of Acid
Rain 1. Release of Gases through Volcanic Eruptions. ©
14.
CAUSES of Acid
Rain 2. Release of Gases through Ocean Sprays – Sea Salt Sprays. ©
15.
CAUSES of Acid
Rain 3. Decomposition of Organic Matter ©
16.
CAUSES of Acid
Rain 4. NOX emitted from Lightening Thunderstorms ©
17.
CAUSES of Acid
Rain 5. Natural Forest Fires ©
18.
CAUSES of Acid
Rain 6. Soil Organisms ©
19.
CAUSES of Acid
Rain NATURAL Causes - 1/3rd of the Nitrogen and Sulphur emissions in the US. ©
20.
CAUSES of Acid
Rain MAN-MADE ©
21.
CAUSES of Acid
Rain 1. Release of Gases through Automobile Exhaust. ©
22.
CAUSES of Acid
Rain 2. Release of Gases through Burning of Fossil Fuels like – Coal, Oil and Natural Gas. ©
23.
CAUSES of Acid
Rain 3. Release of Gases through Manufacturing, oil refineries and other Industries. ©
24.
EFFECTS of ACID RAIN ©
25.
EFFECTS of Acid
Rain 1. Effects on Humans • Skin Irritation/Diseases • Respiratory Problems – Chronic Bronchitis, Asthma in children, ppl over 65 years, pregnant women and ppl with heart diseases. (by breathing particulates of SOX and NOX.) ©
26.
EFFECTS of Acid
Rain 2. Effects on Animals • Less Nutrients in animals who feed on soil as ground nutrients are leached/destroyed by Acid Rain. Calcium Deficiency in Snails. ©
27.
EFFECTS of Acid
Rain 3. Effects on Birds • Death due to deceased food supply in Acidic wetlands – North American Black Duck. ©
28.
EFFECTS of Acid
Rain 3. Effects on Birds • Perishing of birds due to diet on insects with less nutrients. Birds that feed on Snails. ©
29.
EFFECTS of Acid
Rain SONGBIRD EGGS The eggs they lay are defective — thin and fragile. The chicks either do not hatch or have bone malformations and die. ©
30.
EFFECTS of Acid
Rain 3. Effects on Birds • Loss of Habitat due to destruction of Trees. ©
31.
EFFECTS of Acid
Rain 4. Effects on Trees / Vegetation • Acid Rain decolourises leaves. ©
32.
EFFECTS of Acid
Rain 5. Effects on Trees / Vegetation • Reduction of Chlorophyll content ©
33.
EFFECTS of Acid
Rain 5. Effects on Trees / Vegetation • Forests exposed to heavy industrialization are virtually killed. ©
34.
EFFECTS of Acid
Rain 5. Effects on Trees / Vegetation • Less Nutrients in the soil to grow vegetation ©
35.
EFFECTS of Acid
Rain 6. Effects on Water Resources • Acidification of water resources - both surface and underground ©
36.
EFFECTS of Acid
Rain 6. Effects on Water Resources • Reduction of Aquatic Life. ©
37.
pH range Effect
on Fish • 6.5–9 No effect • 6.0–6.4 Unlikely to be harmful except when carbon dioxide levels are very high (1,000 mg l−1) • 5.0–5.9 Not especially harmful except when carbon dioxide levels are high (20 mg I1) or ferric ions are present • 4.5–4.9 Harmful to the eggs of salmon and trout species and to adult fish when levels of Ca2, Na+ and Cl− are low • 4.0–4.4 Harmful to adult fish of many types which have not been progressively acclimated to low pH • 3.5–3.9 Lethal to salmonids, although acclimated roach can survive for longer • 3.0–3.4 Most fish are killed within hours at these levels ©
38.
EFFECTS of Acid
Rain 7. Effects on Environment • Makes the weather smoggy. ©
39.
EFFECTS of Acid
Rain 7. Effects on Environment • Reduction in Soil pH ©
40.
EFFECTS of Acid
Rain 8. Effects on Structure & Property • Damage to Building Materials like Plaster, Marble, Limestone etc. ©
41.
EFFECTS of Acid
Rain 8. Effects on Structure & Property • Corrosion of Reinforcement by seepage through cracks. ©
42.
EFFECTS of Acid
Rain 9. Effects on Ecosystem • Affects the food chain- less nutrients & less food up the chain. ©
43.
PREVENTING /CURE of ACID RAIN ©
44.
CURE of Acid
Rain 1. Decrease Emissions of SOX and NOX. ©
45.
2. Reduction of
use of Conventional Resources © CURE of Acid Rain
46.
3. Treatment of
Industrial Gases before emissions © CURE of Acid Rain
47.
CURE of Acid
Rain 4. Alternate Energy Resources ©
48.
CURE of Acid
Rain 5. Considering Nuclear Energy as an option for fuel ©
49.
CURE of Acid
Rain 6. Purification of Polluted Water ©
50.
Let’s bring an
end to the Acid Rain ©
51.
ASSIGNMENTS: Q1 Write the
Formulas for the formation of Acid Rain. Q2. What are the ill effects of Acid Rain? Q3. How to prevent Acid Rain? ©
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