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ACID
RAIN
©
History
The term was coined in
1872 by the Scottish
chemist Robert Angus
Smith to describe the
acidic precipitation in
Manchester, England.
©
When is Acid Rain
ACID Rain?
When the pH of rain water is
<5.6, it is called Acid Rain.
©
When is Acid Rain
ACID Rain?
Acid Rain
pH < 5.6
Normal Rain
pH = 7
©
Adverse Effects at
what pH?
• Adverse Effects of Acid Rain
start only below pH 4.5
• North America, Central
Europe, Netherlands,
Sweden, USA and other
countries having acid rain
between 2.0 and 5.0.
©
Acid Rain in INDIA
Delhi, Uttar Pradesh,
Maharashtra, Madhya
Pradesh, Tamil Nadu and
even the Andaman Islands
have reported low levels of
pH.
©
ACID RAIN
formulas
©
Acid Rain Formulas
• CO2 + H2O =
• 2NO + O2 =
• 4NO2 + H20 + O2 =
• 2SO2 + O2 =
• SO3 + H2O =
• HCl gas Dissolved in
Water
H2CO3
2NO2
4HNO3
2SO3
H2SO4
HCl acid
©
Acid Rain Formulas
H2SO4 - 70% contribution to
Acid Rain
• 4HNO3 - 20% contribution to
Acid Rain
• 10% others ©
CAUSES
of
ACID RAIN
©
CAUSES of Acid Rain
• Mainly Air Pollution – by gases
like SOX and NOX released by
Natural Causes
&
Man-Made causes
©
CAUSES of Acid Rain
NATURAL
©
CAUSES of Acid Rain
1. Release of Gases through
Volcanic Eruptions.
©
CAUSES of Acid Rain
2. Release of Gases through
Ocean Sprays – Sea Salt Sprays.
©
CAUSES of Acid Rain
3. Decomposition of Organic
Matter
©
CAUSES of Acid Rain
4. NOX emitted from Lightening
Thunderstorms
©
CAUSES of Acid Rain
5. Natural Forest Fires
©
CAUSES of Acid Rain
6. Soil Organisms
©
CAUSES of Acid Rain
NATURAL Causes -
1/3rd of the Nitrogen
and Sulphur emissions
in the US.
©
CAUSES of Acid Rain
MAN-MADE
©
CAUSES of Acid Rain
1. Release of Gases through
Automobile Exhaust.
©
CAUSES of Acid Rain
2. Release of Gases through
Burning of Fossil Fuels like – Coal, Oil
and Natural Gas.
©
CAUSES of Acid Rain
3. Release of Gases through
Manufacturing, oil refineries and
other Industries.
©
EFFECTS
of
ACID RAIN
©
EFFECTS of Acid Rain
1. Effects on Humans
• Skin Irritation/Diseases
• Respiratory Problems – Chronic
Bronchitis, Asthma in children, ppl
over 65 years, pregnant women
and ppl with heart diseases.
(by breathing particulates of SOX and NOX.)
©
EFFECTS of Acid Rain
2. Effects on Animals
• Less Nutrients in animals who
feed on soil as ground nutrients
are leached/destroyed
by Acid Rain.
Calcium
Deficiency in
Snails.
©
EFFECTS of Acid Rain
3. Effects on Birds
• Death due to deceased
food supply in Acidic
wetlands – North American
Black Duck.
©
EFFECTS of Acid Rain
3. Effects on Birds
• Perishing of birds due to diet
on insects with less nutrients.
Birds that feed
on Snails.
©
EFFECTS of Acid Rain
SONGBIRD EGGS
The eggs they lay are defective — thin
and fragile. The chicks either do not
hatch or have bone malformations and
die. ©
EFFECTS of Acid Rain
3. Effects on Birds
• Loss of Habitat due to
destruction of Trees.
©
EFFECTS of Acid Rain
4. Effects on Trees / Vegetation
• Acid Rain decolourises
leaves.
©
EFFECTS of Acid Rain
5. Effects on Trees / Vegetation
• Reduction of Chlorophyll
content
©
EFFECTS of Acid Rain
5. Effects on Trees / Vegetation
• Forests exposed to heavy
industrialization are virtually
killed.
©
EFFECTS of Acid Rain
5. Effects on Trees / Vegetation
• Less Nutrients in the soil to
grow vegetation
©
EFFECTS of Acid Rain
6. Effects on Water Resources
• Acidification of water
resources - both surface and
underground
©
EFFECTS of Acid Rain
6. Effects on Water Resources
• Reduction of Aquatic Life.
©
pH range Effect on Fish
• 6.5–9 No effect
• 6.0–6.4 Unlikely to be harmful except when
carbon dioxide levels are very high (1,000 mg l−1)
• 5.0–5.9 Not especially harmful except when
carbon dioxide levels are high (20 mg I1) or ferric ions
are present
• 4.5–4.9 Harmful to the eggs of salmon and trout
species and to adult fish when levels of Ca2, Na+ and
Cl− are low
• 4.0–4.4 Harmful to adult fish of many types which
have not been progressively acclimated to low pH
• 3.5–3.9 Lethal to salmonids, although acclimated
roach can survive for longer
• 3.0–3.4 Most fish are killed within hours at these
levels
©
EFFECTS of Acid Rain
7. Effects on Environment
• Makes the weather smoggy.
©
EFFECTS of Acid Rain
7. Effects on Environment
• Reduction in Soil pH
©
EFFECTS of Acid Rain
8. Effects on Structure & Property
• Damage to Building Materials
like Plaster, Marble, Limestone
etc.
©
EFFECTS of Acid Rain
8. Effects on Structure & Property
• Corrosion of Reinforcement by
seepage through cracks.
©
EFFECTS of Acid Rain
9. Effects on Ecosystem
• Affects the food chain- less
nutrients & less food up the
chain.
©
PREVENTING
/CURE
of
ACID RAIN ©
CURE of Acid Rain
1. Decrease Emissions of SOX
and NOX.
©
2. Reduction of use of
Conventional Resources
©
CURE of Acid Rain
3. Treatment of Industrial Gases
before emissions
©
CURE of Acid Rain
CURE of Acid Rain
4. Alternate Energy Resources
©
CURE of Acid Rain
5. Considering Nuclear Energy
as an option for fuel
©
CURE of Acid Rain
6. Purification of Polluted Water
©
Let’s bring an end to
the Acid Rain
©
ASSIGNMENTS:
Q1 Write the Formulas for
the formation of Acid Rain.
Q2. What are the ill effects
of Acid Rain?
Q3. How to prevent Acid
Rain? ©

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Acid rain

  • 2. History The term was coined in 1872 by the Scottish chemist Robert Angus Smith to describe the acidic precipitation in Manchester, England. ©
  • 3. When is Acid Rain ACID Rain? When the pH of rain water is <5.6, it is called Acid Rain. ©
  • 4. When is Acid Rain ACID Rain? Acid Rain pH < 5.6 Normal Rain pH = 7 ©
  • 5. Adverse Effects at what pH? • Adverse Effects of Acid Rain start only below pH 4.5 • North America, Central Europe, Netherlands, Sweden, USA and other countries having acid rain between 2.0 and 5.0. ©
  • 6. Acid Rain in INDIA Delhi, Uttar Pradesh, Maharashtra, Madhya Pradesh, Tamil Nadu and even the Andaman Islands have reported low levels of pH. ©
  • 8. Acid Rain Formulas • CO2 + H2O = • 2NO + O2 = • 4NO2 + H20 + O2 = • 2SO2 + O2 = • SO3 + H2O = • HCl gas Dissolved in Water H2CO3 2NO2 4HNO3 2SO3 H2SO4 HCl acid ©
  • 9. Acid Rain Formulas H2SO4 - 70% contribution to Acid Rain • 4HNO3 - 20% contribution to Acid Rain • 10% others ©
  • 11. CAUSES of Acid Rain • Mainly Air Pollution – by gases like SOX and NOX released by Natural Causes & Man-Made causes ©
  • 12. CAUSES of Acid Rain NATURAL ©
  • 13. CAUSES of Acid Rain 1. Release of Gases through Volcanic Eruptions. ©
  • 14. CAUSES of Acid Rain 2. Release of Gases through Ocean Sprays – Sea Salt Sprays. ©
  • 15. CAUSES of Acid Rain 3. Decomposition of Organic Matter ©
  • 16. CAUSES of Acid Rain 4. NOX emitted from Lightening Thunderstorms ©
  • 17. CAUSES of Acid Rain 5. Natural Forest Fires ©
  • 18. CAUSES of Acid Rain 6. Soil Organisms ©
  • 19. CAUSES of Acid Rain NATURAL Causes - 1/3rd of the Nitrogen and Sulphur emissions in the US. ©
  • 20. CAUSES of Acid Rain MAN-MADE ©
  • 21. CAUSES of Acid Rain 1. Release of Gases through Automobile Exhaust. ©
  • 22. CAUSES of Acid Rain 2. Release of Gases through Burning of Fossil Fuels like – Coal, Oil and Natural Gas. ©
  • 23. CAUSES of Acid Rain 3. Release of Gases through Manufacturing, oil refineries and other Industries. ©
  • 25. EFFECTS of Acid Rain 1. Effects on Humans • Skin Irritation/Diseases • Respiratory Problems – Chronic Bronchitis, Asthma in children, ppl over 65 years, pregnant women and ppl with heart diseases. (by breathing particulates of SOX and NOX.) ©
  • 26. EFFECTS of Acid Rain 2. Effects on Animals • Less Nutrients in animals who feed on soil as ground nutrients are leached/destroyed by Acid Rain. Calcium Deficiency in Snails. ©
  • 27. EFFECTS of Acid Rain 3. Effects on Birds • Death due to deceased food supply in Acidic wetlands – North American Black Duck. ©
  • 28. EFFECTS of Acid Rain 3. Effects on Birds • Perishing of birds due to diet on insects with less nutrients. Birds that feed on Snails. ©
  • 29. EFFECTS of Acid Rain SONGBIRD EGGS The eggs they lay are defective — thin and fragile. The chicks either do not hatch or have bone malformations and die. ©
  • 30. EFFECTS of Acid Rain 3. Effects on Birds • Loss of Habitat due to destruction of Trees. ©
  • 31. EFFECTS of Acid Rain 4. Effects on Trees / Vegetation • Acid Rain decolourises leaves. ©
  • 32. EFFECTS of Acid Rain 5. Effects on Trees / Vegetation • Reduction of Chlorophyll content ©
  • 33. EFFECTS of Acid Rain 5. Effects on Trees / Vegetation • Forests exposed to heavy industrialization are virtually killed. ©
  • 34. EFFECTS of Acid Rain 5. Effects on Trees / Vegetation • Less Nutrients in the soil to grow vegetation ©
  • 35. EFFECTS of Acid Rain 6. Effects on Water Resources • Acidification of water resources - both surface and underground ©
  • 36. EFFECTS of Acid Rain 6. Effects on Water Resources • Reduction of Aquatic Life. ©
  • 37. pH range Effect on Fish • 6.5–9 No effect • 6.0–6.4 Unlikely to be harmful except when carbon dioxide levels are very high (1,000 mg l−1) • 5.0–5.9 Not especially harmful except when carbon dioxide levels are high (20 mg I1) or ferric ions are present • 4.5–4.9 Harmful to the eggs of salmon and trout species and to adult fish when levels of Ca2, Na+ and Cl− are low • 4.0–4.4 Harmful to adult fish of many types which have not been progressively acclimated to low pH • 3.5–3.9 Lethal to salmonids, although acclimated roach can survive for longer • 3.0–3.4 Most fish are killed within hours at these levels ©
  • 38. EFFECTS of Acid Rain 7. Effects on Environment • Makes the weather smoggy. ©
  • 39. EFFECTS of Acid Rain 7. Effects on Environment • Reduction in Soil pH ©
  • 40. EFFECTS of Acid Rain 8. Effects on Structure & Property • Damage to Building Materials like Plaster, Marble, Limestone etc. ©
  • 41. EFFECTS of Acid Rain 8. Effects on Structure & Property • Corrosion of Reinforcement by seepage through cracks. ©
  • 42. EFFECTS of Acid Rain 9. Effects on Ecosystem • Affects the food chain- less nutrients & less food up the chain. ©
  • 44. CURE of Acid Rain 1. Decrease Emissions of SOX and NOX. ©
  • 45. 2. Reduction of use of Conventional Resources © CURE of Acid Rain
  • 46. 3. Treatment of Industrial Gases before emissions © CURE of Acid Rain
  • 47. CURE of Acid Rain 4. Alternate Energy Resources ©
  • 48. CURE of Acid Rain 5. Considering Nuclear Energy as an option for fuel ©
  • 49. CURE of Acid Rain 6. Purification of Polluted Water ©
  • 50. Let’s bring an end to the Acid Rain ©
  • 51. ASSIGNMENTS: Q1 Write the Formulas for the formation of Acid Rain. Q2. What are the ill effects of Acid Rain? Q3. How to prevent Acid Rain? ©