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p g . a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
a n i n t r o d u c t i o n t o
Nutrient management
NPAdapted from Richard Fawcett’s
“A Review of BMPs for Managing Crop Nutrients and
Conservation Tillage to Improve Water Quality”
For his editorial and technical assistance,
special thanks to Tim Smith, Cropsmith Inc.
For their review, our thanks to:
Julie French, Gordon  Associates
John Hassell, Agrotain International
Dr. Brad Joern, Purdue University
Dr. Eileen Kladivko, Purdue University
Dr. Harold Reetz, Foundation for Agronomic Research
Dan Towery, Ag Conservation Solutions
Mention of product, trade names, or equipment photos
does not constitute an endorsement by the Conservation
Technology Information Center.
Produced by the Conservation Technology Information Center
An Introduction to Nutrient Management
The Conservation Technology Information Center (CTIC) is a
national non-profit membership organization. CTIC promotes
environmentally responsible and economically viable decision-
making in agriculture. For information on other publications,
survey of tillage practices, CTIC membership, etc., visit us at
www.conservationinformation.org or contact us at:
CTIC
1220 Potter Drive
West Lafayette, Indiana 47906-1383
Phone (765) 494-9555
FAX: (765) 494-5969
E-mail: ctic@conservationinformation.org
CTIC is supported by a partnership of individuals,
corporations, governmental agencies, associations,
foundations, universities and media.
Table of Contents
Why Utilize a Nutrient Management Plan 	 2
Behavior of Nutrients in Soil and Water 	 3
Impact of Conservation Tillage on Nutrient Loss: Overview 	 11
Thinking About Livestock 	 16
Role of Nutrient Management in Larger Conservation Systems 	 18
A Summary of Nutrient BMPs 	 19
Works Referenced 	 23
a n i n t r o d u c t i o n t o
Nutrient management
This document is an introduction to two important nutrients, nitrogen and phosphorus,
and a look at some of the options for best management practices (BMPs) associated with them. The
following information should be helpful to ag producers, agricultural professionals advising farmers on
nutrient management practices and those writing farm-specific nutrient management plans. Included
at the conclusion of this paper is a summary of BMPs for each nutrient. For more information about
these management practices you can read the companion paper titled “A Review of BMPs for Man-
aging Crop Nutrients and Conservation Tillage to Improve Water Quality” which can be found at:
http://www.conservationinformation.org/?action=learningcenter_publications.
Every farm is different—soil types, topography, climate and the availability of water can change
dramatically within a county, to say nothing of the differences between the conditions of a Deep South
cotton farm and corn-bean rotation in the Midwest. Specific nutrient tests, application methods and
other practices must be calibrated to local conditions. There may be programs offered through county
or state agencies to assist with financing conservation efforts and location-specific regulations may
apply. Always consult with Extension, Soil and Water Conservation Districts, NRCS and other state and
local resources to find specific regulations and opportunities.
Nutrient management is matching
nutrient availability in the soil with a par-
ticular crop’s needs. Producers can do this
by increasing the efficiency of nutrient use
by fine-tuning application rates, timing and
placement of the right type of fertilizer to
match plant growth. Increased efficiency
results in reduced nutrient losses and, if
done properly, significant economic savings.
p g . a n i n t r o d u c t i o n t o
Nutrient management
introduction
Why utilize a nutrient
management plan?
Nutrients are essential for the growth of all liv-
ing organisms. Agriculture depends on nutrients
supplied by many sources, including the miner-
alization of soil organic matter, animal manure,
sewage sludge, commercial fertilizers, nitrogen
fixed by legumes, nitrogen contained in irrigation
water and atmospheric deposition. Research con-
ducted over many decades has aided farmers in
the efficient use of added nutrients through tech-
niques such as soil testing and nutrient place-
ment and timing. Until recently, most research
and education was aimed at helping farmers
determine economically optimal nutrient applica-
tion amounts and methods.
Today, we are more aware of the potential
off-site impacts that nutrients may have when
they leave agricultural fields with surface runoff
or leaching and enter surface or ground water in
excessive amounts. Nutrient losses may cause
impacts harmful to aquatic ecosystems, or harm-
ful to human health. Increased knowledge and
concern about the adverse impact of excessive
nutrients on water quality has led to a reex-
amination of agricultural nutrient management
practices and their impacts on water. New water
quality standards and regulations may be devel-
oped that may force changes in nutrient manage-
ment, especially in areas where waters have been
determined to be impaired by excessive nutrients.
As some proposed nutrient standards for surface
water are far lower than current nutrient levels,
agriculture faces a major challenge to reduce
nutrient losses. While there are no regulations as
of yet that hold farmers accountable for cropland
nutrient loss, today there are plenty of on-farm
reasons to have an efficient nutrient management
plan in place. Improving the financial position of
your operation is the primary reason to consider
developing a nutrient management plan.
Today there are plenty of on-farm reasons to
have an efficient nutrient management plan in
place. Improving the financial position of your
operation is the primary reason to consider
developing a nutrient management plan.
p g . a n i n t r o d u c t i o n t o
Nutrient management
why utililze a nutrient
management plan?
Behavior of Nutrients
in Soil and Water
The practices that control or change the way nutri-
ents are used are a function of the nutrients’ behav-
ior. Before any discussion of how nutrients can be
managed, it is important to understand how they
behave in the soil and water. Although they are
essential for plant growth, potassium and micronu-
trients will not be discussed, as they are not typi-
cally a part of a nutrient management plan.
Nitrogen
Nitrogen (N) is an essential nutrient for all plant
and animal life. It can follow many chemical path-
ways in soil and water, making it complex to trace.
Nitrogen is continually cycled among plants, soil
organisms, soil organic matter and the atmosphere.
Understanding the main processes in the nitrogen
cycle-mineralization, immobilization, nitrification,
denitrification, volatilization and leaching-can be
helpful in recognizing how BMPs can work to
improve water quality.
figure 1 Nitrogen Cycle (above) Adapted from
the University of Minnesota
At any given time, most of the N in the soil
is contained in soil organic matter and the soil
humus. N is slowly released as soil microbes
decompose or mineralize the organic matter.
Organic N occurs as particulate matter, in
living organisms, and as detritus (dissolved and
particulate dead organic matter). It occurs in dis-
solved form in compounds such as amino acids,
amines, purines and urea. Mineralization converts
organic N into ammonium (NH4
+
), which can be
taken up by plant roots. The ammonium ion is
positively charged and thus is held by negatively
charged clay particles and organic matter, pre-
venting it from leaching with percolating water.
In converse to mineralization, immobilization
includes processes by which ammonium (NH4
+
)
and nitrate (NO3
-
) are converted to organic N,
(AMMONIFICATION)
(NITRIFICATION)
Nitrogen Cycle
Legume Fixation
of Atmospheric N2
Fertilizer
Nitrogen
Removed by
Leaching
Removed by
Harvest
Ammonia
Loss Through
Leaves PLANT
UPTAKE
CROP
RESIDUES
Animal Manures
Nitrogen Fixation
by Lightning
SOIL ORGANIC
MATTER
NH4
AMMONIUM
Immobilization
NO3
NITRATE
Removed by
Dentrification
(Gaseous Loss
from Wet Soils)
Immobilization (by crop
residue
s)
( M I N E R ALIZATION
)
Nitrogen Cyclefigure 1
p g . a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
p g . a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
through uptake by plants and microorganisms,
and bound up in the soil. Adding carbon rich
crop residues to the soil causes temporary
immobilization of N, when bacteria take up
ammonium and nitrate as they decompose crop
residues. As crop residues decompose, nitrogen
is again released. The speed of release var-
ies with climate, with higher soil temperatures
speeding release.
figure 2 Mineralization and Immobilization
(above) Adapted from the University of Minnesota
An important part of the nitrogen cycle in
relation to water quality is nitrification. Nitrifica-
tion is the process by which two different bac-
teria convert ammonium (NH4
+
) in the soil to
nitrate (NO3
-
). Nitrosomonas bacteria mediate
the conversion of ammonium (NH4
+
) to nitrite
(NO2
-
), which is then quickly converted to nitrate
(NO3
-
) by Nitrobacter bacteria. Nitrate is readily
taken up by plant roots and is often the major
form of N utilized by crops.
figure 3 Nitrification (following page) Adapted from
the University of Minnesota
Nitrification rates depend upon soil tempera-
ture. Nitrification can occur rapidly in warm, moist,
well-aerated soils, changing the ammonium form of
N commonly found in many fertilizers to the nitrate
form within one to two weeks after application.
Because the ammonium form of N has a positive
charge, it is relatively immobile in the soil. Nitrate,
which results from nitrification, is negatively
charged; it enters the soil solution and is subject
to leaching. Nitrification significantly slows down at
temperatures below about 50 F. Thus, application
of ammonium fertilizers to soils below 50 F allows
the ammonium to remain in its positively charged,
immobile form until soil temperatures increase.
figure 4 Dentrification (following page) Adapted
from the University of Minnesota
There are two processes by which nitrogen
from the soil can return to the atmosphere. They
are denitrification and volatilization. Denitrifi-
cation is the bacterial conversion of nitrate to
elemental nitrogen (N2
) or nitrous oxide (N2
O)
gasses, which are lost to the atmosphere. These
forms of N are unavailable to plants. Denitrifi-
cation reduces nitrogen availability to crops
M I N E R A L I Z A T I O N
I M M O B I L I Z A T I O N
Soil
Organic
Matter
Manure
Rotting
Plant
Residues
NH3
Ammonia
NO2
Nitrate
NH4
+
Ammonium
NO3
+
Nitrate
Nitrosomonas
(DRY SOILS)
Nitrobacter
(DRY SOILS)
Soil Bacteria
(WET AND DRY SOILS)
Mineralization and Immobilizationfigure 2
p g . a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
NO2
Nitrate
NH4
+
Ammonium
Oxygen
Oxygen
NO3
+
Nitrate
Nitrification
Dentrification
S O I L S U R F A C E
E S C A P E S A S
G A S E S
N2
ONO2
NO3
+
Caused by soil organisms that live without air in a wet soil and get their oxygen (O) by taking
it from NO3
-. Warm wet soil with large amount of plant residues favor dentrification. (The soil
organisms that rot residues rapidly use up the free oxygen supply and then the denitrifying
organisms begin to multiply.)
NO N2
figure 3
figure 4
p g . a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
but does not threaten water quality. However,
because nitrous oxide is a greenhouse gas, deni-
trification has climate change implications.
Denitrification occurs in poorly aerated, water-
logged soils. This process is rapid, so that if water
stands on the soil for two to three days during the
growing season, much of the nitrate will be lost by
denitrification.
Volatilization losses of ammonia gas to the
atmosphere can occur when manure, urea fer-
tilizer or solutions containing urea are surface
applied and not incorporated into the soil. Vola-
tilization losses are greatest with high temper-
atures and lack of rain after application, and
where surface crop residue is present. Injection
of solutions containing ammonia and incorpora-
tion of manure and urea fertilizers greatly reduces
volatilization losses. Some ammonia lost to the
atmosphere returns to the soil through precipita-
tion. Precipitation also carries N from industrial
and automobile emissions and nitrate formed
by oxidation of nitrogen gas by lightning.
figure 5 Volatilization (above) Adapted from the
University of Minnesota
Symbiotic N fixation converts atmospheric
N into plant available N forms. Rhizobia bacte-
ria living in the roots of legumes like soybeans,
alfalfa and clovers make N available to their host
plants. As these crops decompose, N is made
available to succeeding crops. Small amounts of
N are also fixed by free living organisms in the
soil such as Azotobacter and blue-green algae.
S O I L S U R F A C E
E S C A P E S A S
G A S E S
NH4
+
Ammonium
NH3
Ammonia
OH-
Hydroxide
Volatilizationfigure 5
p g . a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
NO3
-
Nitrate
NO3
-
Nitrate
NO3
-
Nitrate
S O I L S U R F A C E
W A T E R T A B L E
Leaching
Nitrogen and Water Quality
Most N reaching surface or ground water is in
the nitrate form because of its mobility. Because
ammonia is held by soil particles, little leaching
occurs, but erosion can carry ammonia to surface
water. Erosion and runoff can also carry organic
forms of N to lakes and streams where later con-
versions can release plant available N.
Leaching of nitrate to groundwater can occur
when nitrate in excess of crop needs is present
in the soil solution and water percolates through
the soil. Risk of leaching is greatest on coarse
textured soils, with shallow aquifers being most
vulnerable. High rainfall or irrigation in excess
of crop needs increases leaching risk.
figure 6 Leaching (above) Adapted from the Uni-
versity of Minnesota
Because nitrate is mobile, it readily moves into
the soil with rainfall or irrigation, rather than run-
ning off the surface of fields. In many settings,
surface runoff contains little nitrate. Exceptions
can occur, such as when fertilizers or manures are
applied to frozen soil, or heavy rains occur soon
after application. The way nitrate usually enters
streams and lakes is to first leach to shallow
groundwater and then move laterally with natural
subsurface flow or through drainage tiles. Areas
that have been extensively tiled often have greater
nitrate losses to surface water than untiled areas.
A 1995 study by Fausey, et al. estimated that 37
percent of Corn Belt and Great Lakes cropland is
artificially drained by surface channels, subterra-
nean tiles or a combination of the two. It is impor-
tant to be aware of the subsurface flow pathway
figure 6
p g . a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
of nitrate to surface water in selecting appropriate
BMPs. BMPs directed at surface water, for exam-
ple riparian buffer strips, would be ineffective if
nitrates are coming primarily from subsurface
pathways, such as through tile drainage.
figure 7 Surface and Subsurface Flow
(above) Adapted from Jim Baker, Iowa State University
As previously discussed, the ammonium and
nitrate forms of N are plant available. Which form
is preferred depends upon the plant species. The
primary N fertilizers used in the U.S. are anhy-
drous ammonia, urea, ammonium nitrate, and
urea-ammonium nitrate (UAN) solutions. Before
it can be utilized by plants, urea (CO(NH2
)2
)
first must be hydrolyzed, or decomposed, by the
enzyme urease to the ammonium (NH4
) form.
Ammonium is strongly held by soil particles, while
urea and nitrate are soluble and subject to leach-
ing. Ammonia (NH3
) is volatile and can be lost to
the atmosphere. Ammonia volatilization can be
significant with surface application of fertilizers
containing urea, especially when applied to large
amounts of crop residue. Ammonia losses also
may occur from surface manure applications,
or when application slots fail to close properly
behind anhydrous ammonia applicators.
figure 8 Side-Dress Applicator (following page)
Provided by Case IH
Soil
Moisture
Storage
SURFACE RUNOFF WATER
PLUS SEDIMENT
DeepPercolation
BASE FLOW AND/OR SUBSURFACE
(‘TILE’) DRAINAGE
RAIN FA LL
RAINFA LL
RUNOFF
(from thin
‘mixing’ zone)
-1 cm
INFILT RATION
(some through preferential flow paths
or ‘macropores’)
Surface and Subsurface Flowfigure 7
p g . a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
Side-Dress Applicator
Phosphorus
Phosphorus (P) undergoes many transformations
in the soil that affect its availability to crops
and its potential to be lost to water. Phospho-
rus exists in both organic and inorganic forms.
Organic P consists of undecomposed plant and
animal residues, microbes and organic matter in
the soil. Inorganic P is usually associated with
aluminum (Al), iron (Fe) and calcium (Ca) com-
pounds of varying solubility and availability to
plants. Phosphorus is added to soils so that there
are adequate levels for optimum crop growth.
However, P can be rapidly converted in the soil
to forms unavailable to plants. This “fixed” P can
be slowly converted to “labile” or available forms,
but this conversion is often too slow to meet crop
needs. Agronomic soil tests have been developed
to determine the amount of plant available P in
the soil and how much fertilizer or manure should
be added to meet desired crop yield goals.
There are over 200 forms of naturally occur-
ring P minerals in the soil. The most common
P minerals are: 1) apatite (calcium phosphate),
which is found in unweathered and moderately
weathered soils; and 2) iron and aluminum phos-
phates, which are found in highly weathered
soils. Commercial P fertilizer is apatite (calcium
phosphate) treated with sulfuric or phosphoric
acids to increase the solubility of P.
figure 8
p g . 10a n i n t r o d u c t i o n t o
Nutrient management
behavior of nutrients
in soil and water
Figure 9 (above) shows the phosphorus cycle.
In the soil solution, P is present as either H2
PO4
-1
in acid soils (monovalent) or HPO4
-2
in alkaline
soils (divalent). Phosphorus enters the soil solu-
tion by one of the following processes:
•	 Dissolution of primary minerals
•	 Dissolution of secondary minerals
•	 Desorption of P from clays, oxides and minerals
•	Biological conversion of organic
P to inorganic forms
figure 9 The Phosphorus Cycle (above)
Adapted from the International Plant Nutrition Institute
Phosphorus available for crop uptake (or avail-
able to aquatic organisms when P reaches water
bodies) is called bioavailable P and consists of
soluble P and a portion of P bound to soil parti-
cles that can subsequently be released into solu-
tion. Analyzing a soil for total P content is not
very useful from an agronomic standpoint, as it
does not determine how much P is available for
crops. Agronomic soil tests have been developed
over the years that extract all or a proportional
amount of plant available P from soils. By cor-
relating these soil tests with crop responses to P
additions to various soils in the field, recommen-
dations for needed amounts of P additions for
optimum crop production on various soils have
been developed. These agronomic P soil tests do
not necessarily predict P losses to water.
figure 10 Soil Testing (following page) Provided by
Dr. Harold Reetz, Foundation for Agronomic Research
Phosphorus and Water Quality
Phosphorus losses are often measured as total
P and soluble or dissolved P. Because soluble P
is available to aquatic organisms, it has the most
immediate impact on aquatic systems. Results of
P loss studies sometimes refer to bioavailable P
as algal available P.
figure 11 Heavy Rain on Conventional
Tillage (following page) Provided by NRCS
Sediment-bound P constitutes 60 percent
to 90 percent of P transported in runoff from
cultivated land. Runoff from grass, forest and
noncultivated land carries little sediment and is
usually dominated by soluble P. While most sedi-
ment-bound P is not readily available to aquatic
The Phosphorus Cycle
Animal
manures and
biosolids
Plant
residues
Atmospheric
deposition
Mineral
fertilizers
Component
Input to soil
Loss from soil
Crop harvest
Runoff and
erosion
Leaching
(usually minor)
Organic phosphorus
• Microbial
• Plant residue
• Humus
Soil solution
phosphorus
• HPO4
-2
• H2PO4
-1
Primary
minerals
(apatite)
Mineral
surfaces
(clays, Fe and
Al oxides,
carbonates)
Secondary compounds
(CaP, FeP, MnP, AIP)
PLANT UP TA KE
D ESORP TION
ADSORPTION
W
EATHERING
IMMOBILIZATION
MINERALIZATION
PR E C IP I TATI ON
DISS O LU TI ON
figure 9
organisms, sediment deposited in aquatic sys-
tems provides a long-term reservoir of P, as P
is slowly released. Because of the ability of lake
and stream sediments to provide a long-term
source of P even after inputs have been reduced,
beneficial impacts of P loss reductions are diffi-
cult to predict. Both total P and soluble P losses
are important. The relative importance of each
form may depend on local conditions.
Surface runoff and erosion are the primary
mechanisms that carry P to surface water in
most settings. Desorption of P from a thin layer
of surface soil and vegetation releases soluble P
carried in runoff water. Eroded sediment carries
adsorbed P and mineral and organic P sources.
Because of the rapid reactions by which P is
immobilized in soil, P leaching has until recently
been believed to be of minor importance. How-
ever, under some conditions soluble P and col-
loidal P can leach to natural subsurface flow or
drainage tiles to reach surface water in signifi-
cant amounts.
Impact of
Conservation
Tillage on Nutrient
Losses: Overview
Conservation tillage has unique interactions with
N and P. Conservation tillage systems impact both
soil erosion and water infiltration, which in turn
can affect the runoff or leaching of N and P. The
type of tillage system used also influences where
nutrients are found within the soil profile and their
vulnerability to loss. Conservation tillage systems,
utilizing some form of incorporation, allow more of
the applied fertilizers and manures to be removed
from the soil surface, placing them away from
overland drainage flow which could carry them to
surface water. Fertilizers and liquid manures can
be injected below the soil surface in any tillage
system, including no-till, protecting them from
runoff. Likewise, surface applied dry manure
would require incorporation to protect nutrients
from surface water flow.
Soil Testingfigure 10 figure 11 Heavy Rain on
Conventional Tillage
p g . 11a n i n t r o d u c t i o n t o
Nutrient management
impact of conservation
tillage on nutrient
losses: overview
Surface application of fertilizer or manure in
no-till systems results in a stratification of non-
mobile nutrients like P. Higher P concentrations
at the soil surface increase the availability of P for
runoff. The organic matter content of surface soils
also increases with no-till. This increased organic
matter could reduce runoff losses of some poten-
tial pollutants, like pesticides and P, by providing
more adsorption capacity and causing increased
infiltration, due to improved soil structure.
The ability of conservation tillage to reduce
erosion is well documented. Crop residue left on
the soil surface protects the soil from the erosive
impacts of rainfall and wind. Residue also slows
runoff and prevents sealing of the soil surface,
increasing infiltration of water. Reductions in ero-
sion are usually proportional to the percent of the
soil surface covered by crop residue.
Conservation tillage also often increases water
infiltration. Surface roughness and surface resi-
due are responsible for infiltration increases in
conservation tillage systems utilizing some form
of tillage. In no-till systems, improved soil struc-
ture and the presence of macropores consisting
of worm holes, cracks and root channels, allows
water to infiltrate rather than run off when rainfall
exceeds the capillary flow capacity of the soil.
Nitrogen
Conservation tillage can reduce overall nitrogen
loss by reducing ammonium nitrogen loss and
organic nitrogen loss with sediment; however it
may not reduce nitrogen leaching in the nitrate
form. Nitrate is soluble and quickly moves down
into the soil with rainfall or irrigation. Typically, lit-
tle nitrate is present in surface runoff. In contrast,
ammonium, which is held on soil particles, and
soil organic nitrogen can move off fields with soil
loss. Conservation tillage reduces runoff of these
forms of nitrogen. Baker and Laflen (1983) found
a 97 percent reduction of soil loss in no-till com-
pared to a moldboard plow system resulted in a
75 percent to 90 percent reduction in total N loss
for soybeans following corn and 50 percent to 73
percent reduction in total N loss for corn following
soybeans. Several other studies have documented
reductions in N losses with conservation tillage.
figure 12 Stream in Cropland (following page)
Provided by NRCS
Conservation tillage systems impact both soil
erosion and water infiltration, which in turn can
affect the runoff or leaching of N and P. The type of
tillage system used also influences where nutrients are found within the soil profile
and their vulnerability to loss. Conservation tillage systems, utilizing some form of
incorporation, allow more of the applied fertilizers and manures to be removed
from the soil surface, placing them away from overland drainage flow, which could
carry them to surface water.
p g . 12a n i n t r o d u c t i o n t o
Nutrient management
impact of conservation
tillage on nutrient
losses: overview
In most settings, nitrate reaches streams by
first infiltrating and then moving with subsurface
flow. Many researchers have investigated the
impact of no-till and other conservation tillage
systems on nitrate leaching. Most studies have
found little impact, with a few studies finding a
reduction or slight increase in nitrate leaching
with no-till.
figure 13 Tile Effluent from Soybean Field
(above) Provided by University of Michigan
Monitoring of drainage tile effluent has
proven useful in measuring tillage impacts on
nitrate leaching. A 1988 study by Kanwar et
al. monitored tile effluent from continuous corn
plots managed with no-till and conventional till-
age in Iowa. Nitrate concentrations were similar
between tillage systems in the first two years. By
the third year of the study, nitrate concentrations
were significantly lower in no-till plots. Kanwar
and Baker (1993) monitored these plots over
the next eight years and determined that nitrate
concentrations in tile effluent were consistently
lower with no-till than with conventional tillage.
Monitoring of soil water at five depths from 3.9
feet to 11.8 feet (1.2 meters to 3.6 meters) also
showed that nitrate concentrations were lower at
all depths with no-till.
Nitrate concentrations in groundwater and
in drainage tile effluent have been consistently
lower under no-till management than with con-
ventional tillage. However, increased infiltration
from no-till may at least partially offset lower
concentrations of nitrates by increasing total
drainage through the soil. This increased infiltra-
tion of lower nitrate concentrations may result in
a total quantity of nitrate loss similar to conven-
tional tillage, leaching below fields to where it
may reach ground water or be carried by sub-
surface flow to surface water. To enhance the
effect of conservation tillage practices to reduce
nitrate losses to water, other BMPs will need to
be included in the management system.
Stream in Croplandfigure 12 Tile Effluent from
Soybean Field
figure 13
p g . 13a n i n t r o d u c t i o n t o
Nutrient management
impact of conservation
tillage on nutrient
losses: overview
Phosphorus
Phospohorus is lost from fields in two main ways:
attached to eroded sediment particles that end up
in streams and lakes and in the soluble P form that
is lost from fields when water flowing from fields
picks up P that is not adsorbed to soil particles.
figure 14 Algae from Excess Phosphorus
(above) Provided by NRCS
Because total P losses in runoff consist primar-
ily of insoluble P carried by eroded sediment par-
ticles, conservation tillage usually reduces total P
losses. As stated earlier, sediment-bound P often
represents 60 percent to 90 percent of the total
P load of row crop runoff. Conservation tillage has
been an important BMP recommended to farm-
ers to reduce P losses in specific watershed proj-
ects. For example, following wide-scale promotion
of conservation tillage to reduce P loading to the
Great Lakes, Baker (1993) concluded that the
downward trends in total and soluble P loads from
Lake Erie tributaries for the period from the late
1970s to 1993 indicated that agricultural BMPs,
including conservation tillage, were effective in
reducing total and soluble P export.
Controlled studies have documented the abil-
ity of various conservation tillage systems to
reduce P losses. For example, Baker and Laflen
found that when total P runoff losses were com-
pared between no-till and conventional tillage in
Iowa, the 97 percent reduction in erosion with
no-till resulted in an 80 percent to 91 percent
reduction in total P loss for soybeans following
corn. For corn following soybeans, the 86 per-
cent reduction in erosion led to a 66 percent to
77 percent reduction in P loss.
Barisas et al. (1978) compared runoff losses
of P in six tillage systems on three Iowa soils using
rainfall simulation techniques. They found that as
surface crop residue increased, soluble P losses
increased, but because erosion was reduced by
crop residue, total P losses decreased as residue
increased.
Seta et al. (1993) compared nutrient losses
with the moldboard plow, chisel plow and no-till
Algae from Excess Phosphorusfigure 14
p g . 14a n i n t r o d u c t i o n t o
Nutrient management
impact of conservation
tillage on nutrient
losses: overview
in Kentucky when fertilizer was applied before till-
age. Total losses of nitrate, ammonia and phos-
phate were in the order: moldboard plow  chisel
plow  no-till. However, nutrient concentrations
were higher with no-till.
figure 15 Nutrient Loss Comparison (above)
Adapted from Andraski et al. (1985)
The surface placement of fertilizer in no-
till systems may explain much of the tendency
for no-till systems to produce higher soluble P
concentrations in runoff in controlled studies
where P is surface applied (versus full width till-
age systems in which P is incorporated into the
soil). Application of P in a subsurface band in
no-till has prevented any increase in soluble P
loss compared to conventional tillage. Andraski
et al. (1985) compared runoff losses of P from
four tillage systems when fertilizer was subsur-
face banded in all systems. No-till, chisel plow
and ridge-till systems reduced total P losses by
81 percent, 70 percent, and 59 percent, respec-
tively, compared to the moldboard plow. Soluble
P losses also were reduced by no-till and the
chisel plow.
figure 16 Ridge Till (foilowing page)
Provided by NRCS
A M O U N T O F T O T A L P L O S T B Y T I L L A G E
Moldboard
Plow
No-Till
PercentofLoss
Chisel Plow Ridge-Till
0
20
40
60
80
100
120
Nutrient Loss Comparison When
Fertilizer was Applied Before Tillage
figure 15
p g . 15a n i n t r o d u c t i o n t o
Nutrient management
impact of conservation
tillage on nutrient
losses: overview
Kimmel et al. (2001) measured P runoff
losses as effected by tillage system and fertil-
izer placement in Kansas. A chisel plow-field
cultivator-disk system was compared to no-till
and ridge-till, with P fertilizer either broadcast
surface applied or knifed in prior to planting
sorghum. Losses of total P, soluble P and bio-
available P were measured. When the data are
averaged over two years of study, knifing in fertil-
izer reduced losses of total P, bioavailable P and
soluble P for all three tillage systems. Reductions
in P losses with knifing were most evident for
soluble P. Knifing reduced soluble P losses by
about 75 percent in no-till and ridge-till.
figure 17 Tillage and P Placement Effects
(following page) Adapted from Kimmell, R.J., G.M.
Pierzynski, K.A. Janssen, and P.L. Barnes. 2001.
J. Environ. Qual. 30:1324-1330.
Thinking About
Livestock
High livestock concentrations in some areas have
led to applications of manure as a source of nutri-
ents in excess of crop nutrient needs. If manure
applications are solely based on N content and
crop N needs, excessive amounts of P may be
applied. In the past, high P soil test levels were
not considered to cause environmental problems,
so manure was commonly applied based on N
needs without regard to the level of soil test P.
Such an application to a soil testing low in P
could be viewed as appropriate, as it would build
soil P toward optimum levels. But when excess
P applications are continued for many years, soil
tests reveal a rise to excessive levels of P and
the risk of water contamination is increased.
Ridge Tillfigure 16
p g . 16a n i n t r o d u c t i o n t o
Nutrient management
thinking about
livestiock
figure 18 Consider N and P content of
Manure (following page) Adapted from NRCS
Manure utilization has become a dilemma for
farmers in some areas, as more than twice as
many acres may be needed to apply manure based
on P levels as N levels. Transporting manure long
distances to land testing lower in P can be costly.
Once P soil test levels reach excessive lev-
els, it may take many years for P concentrations
to decrease, depending on the cropping system,
yield levels and soil characteristics. McCollum
(1991) estimated that without further P addi-
tions, 16 to 18 years of corn and soybean pro-
duction would be needed to deplete a soil test P
(Mehlich—3) in a Portsmouth fine sandy loam
from 100 ppm to the agronomic threshold of 20
ppm. It is important to manage current manure
and fertilizer applications to minimize both cur-
rent and future P loss risks.	
The presence of soils testing high in P may sim-
ply mean a crop farmer can forgo P fertilizer appli-
cations for some period of time. However, forgoing
P applications just compounds the problem for
livestock farmers in need of land to apply manure.
Regulations or required manure management plans
could limit manure applications to such land.
The future of manure management will be find-
ing ways to use it as a beneficial byproduct, not a
waste product. (Note: Partners magazine, the quar-
terly e-publication of CTIC, includes articles about
manure management in its 2007 issues. Partners:
www.conservationinformation.org/partners)
TILLAGE
SYSTEM
FERTILIZER
PLACEMENT
Annual P Runoff Loss Average of 2 Years Data
Soluble P
Bioavailable P
(g/ha)
Total P
Chisel-disk Surface 	 16.0 	 49.5 	 605.0
Chisel-disk Knifed-in 	 12.3 	 33.0 	 354.0
No-Till Surface 	 329.0 	 398.5 	 832.5
No-Till Knifed-in 	 73.5 	 123.5 	 479.5
Ridge-Till Surface 	 320.5 	 426.0 	 1122.5
Ridge-Till Knifed-in 	 77.5 	 121.5 	 675.5
Conservation tillage can be expected to consistently reduce runoff losses of total P. Losses of soluble P may be
higher with no-till if P fertilizers are surface applied to no-till compared to incorporated in other tillage systems.
However, subsurface banding of P fertilizer in no-till systems reduces losses of soluble P below loss levels for
conventionally tilled soils with the same fertilizer application method.
Tillage and P Placement Effects on Soluble, Bioavailable
and Total P Loss in Runoff Water from Sorghum Grown
on a Silt Loam Soil with 1.0 to 1.5 Percent Slopes
figure 17
p g . 17a n i n t r o d u c t i o n t o
Nutrient management
thinking about
livestiock
Role of nutrient
management in larger
conservation systems
Nutrient management by way of conservation till-
age is just one practice of conservation farming,
and is most effective when done in tandem with
other practices to create a whole farm conser-
vation system. For example, conservation till-
age may reduce P runoff, but won’t necessarily
reduce N leaching, so a producer would benefit
from precision application of N or growing cover
crops. A constructed wetland can dramatically
reduce N that has already reached a field’s tile
system, but does little to keep phosphorus in
place. It pays to come up with a farm-wide plan.
Always consult with state and local resources,
such as Extension, SWCD or NRCS offices, to
find out specific regulations and opportunities.
Some counties, especially those with impaired
waterways, may have cost-share opportunities to
help implement a nutrient management plan.
Consider N and P content of Manurefigure 18
p g . 18a n i n t r o d u c t i o n t o
Nutrient management
role of nutrient
management in larger
conservation systems
Ni t r oge n
Altered Drainage Tile Design
•	Controlled drainage-subirrigation systems recycle
nitrate leaching from the soil profile and reduce
nitrate lost in tile drainage.
•	Research is underway to alter tile installation
to favor denitrification before tiles intercept
drainage water.
application precision
•	New designs of manifolds may increase the
uniformity of anhydrous ammonia distribution
across applicators.
•	Experimental applicators, such as injectors
that form a compacted soil layer and surface
ridge, may reduce N losses in the future.
•	Variable rate applicators, combined with intensive
soil or crop sampling, can allow correct N rates
where fields vary in available N.
Breeding Crops for Efficient N Uptake
•	Certain crop varieties may be able to more
efficiently extract N from the soil.
•	Seed companies are developing varieties
that have improved nutrient uptake.
Conservation Buffers
•	Install buffers to trap sediment containing
ammonia and organic N.
•	Nitrate in subsurface flow is reduced through
denitrification enhanced by organic sources
placed in the subsoil by buffer plants.
•	Buffer plants take up nitrate and other nutrients,
preventing N loss to water.
•	Other conservation practices, such as terraces
and contouring, reduce total N losses due to
erosion reduction.
A Summary of Nutrient BMPs
The following is a limited collection of Best Management Practices, divided into
sections on N and P, that runs the breadth of nutrient management. Farmers can con-
sider these BMPs as they develop the most appropriate system of conservation practices for
their operations. A brief overview of manure, pasture and hayland management is included.
Remember that a whole-farm plan must be specific to the conditions of the area in which the
plan will be applied. What is best here is not necessarily best there—talk to an expert about
what practices are appropriate for your area.
p g . 19a n i n t r o d u c t i o n t o
Nutrient management
a summary
of nutrient bmps
Conservation Tillage
•	Conservation tillage reduces total N losses
because it reduces sediment loss.
•	Leaching losses of nitrate are not consistently
affected by conservation tillage.
Constructed Wetlands
•	Constructed wetlands placed to process tile efflu-
ent reduce nitrate loads to surface water through
denitrification.
•	Constructed wetlands may be more effective in
reducing nitrate when coupled with buffer strips.
Cover Crops
•	Cover crops grown between the time annual crops
are harvested and when successive crops are
planted can scavenge N and other nutrients and
prevent leaching.
•	Cover crops can prevent soil erosion and improve
water infiltration where N is surface applied.
Crop Rotation
•	Legumes and other crops not needing supple-
mental N can utilize N remaining in the soil
from previous N-fertilized crops, reducing nitrate
leaching risk.
•	Alfalfa can remove nitrate from the soil below
the rooting depth of most annual crops.
Crop Testing
•	Leaf tissue tests can identify N deficiencies.
•	Variations in chlorophyll content are being evalu-
ated as a potential tool to facilitate variable rate
N applications in-season.
•	Post-black-layer corn stalk nitrate tests help to
determine if N rates were low, optimal or exces-
sive, so that management changes can be made
in following years.
Fertilizer Application Method and Placement
•	Injection or incorporation of urea or
N solutions reduces volatility losses.
•	In ridged crops, placing N fertilizers in a band
in ridges makes N less susceptible to leaching.
•	Controlled release N fertilizers can help
improve crop uptake.
Inhibitors
•	Nitrification inhibitors maintain applied anhy-
drous ammonia in the ammonium form longer,
reducing leaching and denitrification losses.
•	Where fall N applications are appropriate, nitrifi-
cation inhibitors reduce risk of leaching loss.
•	Urease inhibitors temporarily block the function
of the urease enzyme, maintaining urea-based
fertilizers in the non-volatile urea form, and reduce
losses when these fertilizers are surface applied
in high residue, conservation tillage systems.
Nitrogen Application Rates
•	Include N applied as manure, in irrigation
water and fixed by legumes as part of the
total N application rate.
•	Use appropriate soil tests to determine
residual N.
•	Increase plant populations in soils with
greater potential to release mineralized N.
•	Nitrogen credits for legumes, such as alfalfa,
can provide significant amounts of N to crops
grown in rotation and need to be subtracted
from total N required.
•	Manure credits should be taken into account
when determining crop N needs.
•	Use a reasonable method to determine
expected yields if N rates are based on yield.
N i t r o g e n , continued
p g . 20a n i n t r o d u c t i o n t o
Nutrient management
a summary
of nutrient bmps
Pest Management
•	Proper pest management allows crops to attain
their potential yields, utilizing applied N and
reducing the amount of excess N available to loss.
•	Bt corn prevents European corn borer feeding and
associated stalk rots, which can cause corn to die
early and leave excess N in the soil.
•	Rootworm resistant corn may allow better root
growth and improved N uptake from the soil.
Timing of N Applications
•	Applying N sources close to when crops can
utilize N reduces N loss risk.
•	Side-dress application, usually made four to six
weeks after planting crops, provides N just prior
to the time of most rapid N uptake, and reduces
risk of leaching and denitrification losses.
•	Split applications, involving preplant and side-
dress applications, allow efficient use of applied
N and reduce risk of yield reductions, should
side-dress applications be delayed.
•	Fall application of N may be discouraged in
some areas. In regions where anhydrous ammo-
nia can be suitably applied in the fall, soil tem-
peratures should be below 50 F before applying.
Soil Testing
•	Preplant soil tests are useful in drier climates.
•	In areas where significant spring nitrate losses may
occur due to leaching and/or denitrification, late
spring or pre-side-dress N tests can determine if
and how much additional N is needed.
•	New soil test procedures, such as amino sugar
tests, may be useful in determining potential N
release from the soil.
P ho s p horu s
Application Rates for Phosphorus
•	Use soil tests to determine agronomic rates.
•	P rates may need to be reduced for environmental
reasons in high-risk areas.
•	Environmental P thresholds are being developed
by states to determine P rates protective of water
resources.
•	Consider P content of manure rather than solely
N content.
Application Timing for Phosphorus
•	Avoid fertilizer and manure application
to frozen soil.
•	Incorporate fall-applied P fertilizers
and manure to reduce runoff.
•	Avoid fertilizer and manure applications
to wet soils.
Conservation Buffers
•	Buffers trap sediment and adsorbed P.
•	Construct and maintain buffers to encourage
sheet flow of runoff over the buffer.
•	As sediment accumulates in buffers, changing
their profile, sediment should be removed, or
buffers reshaped.
•	Select buffer species based on adaptation to
local conditions and other desired benefits of
buffers, such as wildlife habitat.
•	Other soil conservation practices, such as
terraces and contour planting, reduce total
P losses due to reduced erosion.
Conservation Tillage
•	Conservation tillage consistently reduces runoff
losses of total P.
•	Runoff losses of soluble P can be higher with
no-till if fertilizers or manures are surface
applied. Incorporating or injecting P sources
below the soil surface reduces total and soluble
P losses in all systems.
N i t r o g e n , continued
p g . 21a n i n t r o d u c t i o n t o
Nutrient management
a summary
of nutrient bmps
Constructed Wetlands
•	Wetlands have potential to reduce total P loads
from surface runoff.
•	Wetland results have been variable in removing
soluble P.
Cover Crops
•	Plant cover crops to reduce erosion between
when annual crops are harvested and the follow-
ing crop covers the ground, thus reducing runoff
of sediment-adsorbed P.
•	Achieving phosphorus reduction depends on
good cover crop stand management.
Fertilizer and Manure Placement
•	Incorporation or injection of P sources reduces
runoff losses.
•	Starter applications can usually supply all of
the maintenance P requirements for row crops.
•	Variable rate application, combined with intensive
soil sampling, can reduce fertilizer inputs and
avoid over-fertilizing high-testing areas
of fields.
•	Banded applications may increase yield when
P is stratified and soil tests below 15 cm (6 in.)
reveal low levels of P.
Irrigation Management
•	Surface crop residue, in furrow irrigated crops,
reduces sediment and P losses.
•	Polyacrylamide (PAM) applied with furrow irriga-
tion greatly reduces sediment, P and organic
material losses.
Livestock Feed Management
•	Carefully balance livestock rations so that
supplemental P is not excessive.
•	Feed low-phytate corn varieties, in nonruminant
rations to reduce the P content of manure.
•	Supplementing nonruminant feed rations with the
phytase enzyme, reduces the need for supplemen-
tal P and reduces P content of manure.
Phosphorus Index
•	A coalition of U.S. scientists has developed a
field-based planning tool that assesses the risk
of P movement from soil to water. States are
modifying the index to match local conditions.
M a nur e , Pa s t ur e a nd
H ay l a nd M a n a ge me n t
Manure
•	Determine nutrient content of manure to calculate
appropriate application rates.
•	Consider both P and N content of manure when
determining rates.
•	Fields testing low in P benefit most from manure
applications.
•	Consider risk factors such as nearness to streams
and slopes, the presence of wells, sinkholes,
surface tile inlets, and residences when selecting
fields for manure applications.
•	Inject manure or use limited incorporation to
reduce runoff risk.
•	Avoid manure application to frozen soil.
•	Manure amendments such as alum may reduce
soluble P losses in runoff.
Pasture and Hayland
•	Use shallow tillage tools, such as harrows or
“aerators” on pastures, that may increase infil-
tration and reduce runoff of manure or fertilizer.
•	Rotational grazing reduces compaction,
overgrazing and nutrient runoff.
•	Exclude livestock from access to streams.
•	Make maintenance P fertilizer applications
to forage legumes after the first cutting, when
runoff losses are lower.
•	Cut hay higher to leave more stubble that
may significantly reduces P runoff.
p h o s p h o r u s , continued
p g . 22a n i n t r o d u c t i o n t o
Nutrient management
a summary
of nutrient bmps
W or k s R e f e r e n ce d
Andraski, B.J., D.H. Mueller, and T.C. Daniel. 1985.
Phosphorus losses in runoff as affected by tillage. Soil
Sci. Soc. Amer. J. 49:1523-1527.
Baker, J.L. and J.M. Laflen. 1983. Water quality con-
sequences of conservation tillage. J. Soil and Water
Cons. 38:186-193.
Baker, D.B. 1993. The Lake Erie agroecosystem pro-
gram: water quality assessments. Agriculture, Ecosys-
tems and Environment 46:197-215.
Barisas, S.G., J.L. Baker, H.P. Johnson, and J.M.
Laflen. 1978. Effect of tillage system on runoff losses
of nutrients, a rainfall simulation study. Trans. ASAE
21:893-897.
Bouman, G.A., A.M. Blackmer, J.M. Bremner. 1980.
Effects of different nitrogen and fertilizer on emission
of nitrous oxide from soil. Geophys. Res. Let. 7:85-88.
Bundy, L.G. 1985. Understanding plant nutrients: soil
and applied nitrogen. Univ. WI Coop. Ext. Serv. Bull.
No. A2519.
Erbach, D.C. 1982. Tillage for continuous corn and
corn-soybean rotation. Trans ASAE 25:906-922.
Fausey, N.R., L.C. Brown, H.W. Belcher, and R.S.
Kanwar. 1995. Drainage and water quality in the
Great Lakes and Cornbelt states. J. Irrig. Drain. Eng.
121:283-288.
Fawcett, R.S. and S. Caruana. 2002. Better soil bet-
ter yields: a guidebook to improving soil organic mat-
ter and infiltration with continuous no-till. CTIC, West
Lafayette, IN. 17 pp.
Gray, C.B.J. and R.A. Kirkland. 1986. Suspended
sediment phosphorus composition in tributaries of the
Okanagen Lakes, B.C. Water Res. 20:1193-1196.
Johnson, A.H.; Baker, J.L.; Shrader, W.D.; Laflen, J.M.
1979.Tillage system effect on sediment and nutrients
in runoff from small watersheds. Trans. ASEA 22-
1.110-1.114.
Kanwar, R.S., J.L. Baker, and D.G. Baker. 1988. Till-
age and split N-fertilization effects on subsurface
drainage water quality and crop yields. Trans ASAE
31:453-461.
Kanwar, R.S. and J.L. Baker. 1993. Tillage and chemi-
cal management effects on groundwater quality. In:
Proceedings of the National Conference on Agricul-
tural Research to Protect Water Quality. SCS Ankena
IA, pp. 490-493.
Kimmell, R.J., G.M. Pierzynski, K.A. Janssen, and
P.L. Barnes. 2001. Effects of tillage and phosphorus
placement on phosphorus losses in a grain sorghum-
soybean rotation. J. Environ. Qual. 30:1324-1330.
Logan, T.J. 1987. An assessment of Great Lakes till-
age practices and their potential impact on water
quality. In T.J. Logan, J.M. Davidson, J.L. Baker, and
M.R. Overcash, eds. Effects of Conservation Tillage on
Groundwater Quality. Lewis Pub., Chelsea, MI. Pages
271-276.
McCollum, R.E. 1991. Buildup and decline in soil
phosphorus: 30-year trends on a Typic Umprabuult.
Agron. J. 83:77-85.
McDowell, R., A. Sharpley, and G. Folmar. 2001.
Phosphorus export from an agricultural watershed:
linking source and transport mechanisms. J. Environ.
Qual. 30:1587-1595.
Randall, G.W., and T.K. Iragavarapu. 1995. Impact of
long-term tillage systems for continuous corn on nitrate
leaching to tile drainage. J. Environ. Qual. 24:360-366.
Reicosky, D.C., W.D. Kemper, G.W. Langdale, C.L.
Douglas, Jr., and P.E. Rasmussen. 1995. Soil organic
matter changes resulting from tillage and biomass
production. J. Soil and Water Cons. 50:253-261.
Seta, A.K., R.L. Blevins, W.W. Frye, and B.J. Barfield.
1993. Reducing soil erosion and agricultural chemi-
cal losses with conservation tillage. J. Environ. Qual.
22:661-665.
Sharpley, A.N., S.S. Smith, O.R. Jones, 1992. The
transport of bioavailable phosphorus in agricultural
runoff. J. Environ. Qual. 21:30-35.
Young, T.C. and J.V. DePinto. 1982. Algal-availability of
particulate phosphorus from diffuse and point sources
in the lower Great Lakes basin. Hydrobiologia 91:111-
119.
p g . 23a n i n t r o d u c t i o n t o
Nutrient management
works referenced

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Nutrient management

  • 1. p g . a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water a n i n t r o d u c t i o n t o Nutrient management NPAdapted from Richard Fawcett’s “A Review of BMPs for Managing Crop Nutrients and Conservation Tillage to Improve Water Quality”
  • 2. For his editorial and technical assistance, special thanks to Tim Smith, Cropsmith Inc. For their review, our thanks to: Julie French, Gordon Associates John Hassell, Agrotain International Dr. Brad Joern, Purdue University Dr. Eileen Kladivko, Purdue University Dr. Harold Reetz, Foundation for Agronomic Research Dan Towery, Ag Conservation Solutions Mention of product, trade names, or equipment photos does not constitute an endorsement by the Conservation Technology Information Center. Produced by the Conservation Technology Information Center An Introduction to Nutrient Management The Conservation Technology Information Center (CTIC) is a national non-profit membership organization. CTIC promotes environmentally responsible and economically viable decision- making in agriculture. For information on other publications, survey of tillage practices, CTIC membership, etc., visit us at www.conservationinformation.org or contact us at: CTIC 1220 Potter Drive West Lafayette, Indiana 47906-1383 Phone (765) 494-9555 FAX: (765) 494-5969 E-mail: ctic@conservationinformation.org CTIC is supported by a partnership of individuals, corporations, governmental agencies, associations, foundations, universities and media.
  • 3. Table of Contents Why Utilize a Nutrient Management Plan 2 Behavior of Nutrients in Soil and Water 3 Impact of Conservation Tillage on Nutrient Loss: Overview 11 Thinking About Livestock 16 Role of Nutrient Management in Larger Conservation Systems 18 A Summary of Nutrient BMPs 19 Works Referenced 23 a n i n t r o d u c t i o n t o Nutrient management
  • 4. This document is an introduction to two important nutrients, nitrogen and phosphorus, and a look at some of the options for best management practices (BMPs) associated with them. The following information should be helpful to ag producers, agricultural professionals advising farmers on nutrient management practices and those writing farm-specific nutrient management plans. Included at the conclusion of this paper is a summary of BMPs for each nutrient. For more information about these management practices you can read the companion paper titled “A Review of BMPs for Man- aging Crop Nutrients and Conservation Tillage to Improve Water Quality” which can be found at: http://www.conservationinformation.org/?action=learningcenter_publications. Every farm is different—soil types, topography, climate and the availability of water can change dramatically within a county, to say nothing of the differences between the conditions of a Deep South cotton farm and corn-bean rotation in the Midwest. Specific nutrient tests, application methods and other practices must be calibrated to local conditions. There may be programs offered through county or state agencies to assist with financing conservation efforts and location-specific regulations may apply. Always consult with Extension, Soil and Water Conservation Districts, NRCS and other state and local resources to find specific regulations and opportunities. Nutrient management is matching nutrient availability in the soil with a par- ticular crop’s needs. Producers can do this by increasing the efficiency of nutrient use by fine-tuning application rates, timing and placement of the right type of fertilizer to match plant growth. Increased efficiency results in reduced nutrient losses and, if done properly, significant economic savings. p g . a n i n t r o d u c t i o n t o Nutrient management introduction
  • 5. Why utilize a nutrient management plan? Nutrients are essential for the growth of all liv- ing organisms. Agriculture depends on nutrients supplied by many sources, including the miner- alization of soil organic matter, animal manure, sewage sludge, commercial fertilizers, nitrogen fixed by legumes, nitrogen contained in irrigation water and atmospheric deposition. Research con- ducted over many decades has aided farmers in the efficient use of added nutrients through tech- niques such as soil testing and nutrient place- ment and timing. Until recently, most research and education was aimed at helping farmers determine economically optimal nutrient applica- tion amounts and methods. Today, we are more aware of the potential off-site impacts that nutrients may have when they leave agricultural fields with surface runoff or leaching and enter surface or ground water in excessive amounts. Nutrient losses may cause impacts harmful to aquatic ecosystems, or harm- ful to human health. Increased knowledge and concern about the adverse impact of excessive nutrients on water quality has led to a reex- amination of agricultural nutrient management practices and their impacts on water. New water quality standards and regulations may be devel- oped that may force changes in nutrient manage- ment, especially in areas where waters have been determined to be impaired by excessive nutrients. As some proposed nutrient standards for surface water are far lower than current nutrient levels, agriculture faces a major challenge to reduce nutrient losses. While there are no regulations as of yet that hold farmers accountable for cropland nutrient loss, today there are plenty of on-farm reasons to have an efficient nutrient management plan in place. Improving the financial position of your operation is the primary reason to consider developing a nutrient management plan. Today there are plenty of on-farm reasons to have an efficient nutrient management plan in place. Improving the financial position of your operation is the primary reason to consider developing a nutrient management plan. p g . a n i n t r o d u c t i o n t o Nutrient management why utililze a nutrient management plan?
  • 6. Behavior of Nutrients in Soil and Water The practices that control or change the way nutri- ents are used are a function of the nutrients’ behav- ior. Before any discussion of how nutrients can be managed, it is important to understand how they behave in the soil and water. Although they are essential for plant growth, potassium and micronu- trients will not be discussed, as they are not typi- cally a part of a nutrient management plan. Nitrogen Nitrogen (N) is an essential nutrient for all plant and animal life. It can follow many chemical path- ways in soil and water, making it complex to trace. Nitrogen is continually cycled among plants, soil organisms, soil organic matter and the atmosphere. Understanding the main processes in the nitrogen cycle-mineralization, immobilization, nitrification, denitrification, volatilization and leaching-can be helpful in recognizing how BMPs can work to improve water quality. figure 1 Nitrogen Cycle (above) Adapted from the University of Minnesota At any given time, most of the N in the soil is contained in soil organic matter and the soil humus. N is slowly released as soil microbes decompose or mineralize the organic matter. Organic N occurs as particulate matter, in living organisms, and as detritus (dissolved and particulate dead organic matter). It occurs in dis- solved form in compounds such as amino acids, amines, purines and urea. Mineralization converts organic N into ammonium (NH4 + ), which can be taken up by plant roots. The ammonium ion is positively charged and thus is held by negatively charged clay particles and organic matter, pre- venting it from leaching with percolating water. In converse to mineralization, immobilization includes processes by which ammonium (NH4 + ) and nitrate (NO3 - ) are converted to organic N, (AMMONIFICATION) (NITRIFICATION) Nitrogen Cycle Legume Fixation of Atmospheric N2 Fertilizer Nitrogen Removed by Leaching Removed by Harvest Ammonia Loss Through Leaves PLANT UPTAKE CROP RESIDUES Animal Manures Nitrogen Fixation by Lightning SOIL ORGANIC MATTER NH4 AMMONIUM Immobilization NO3 NITRATE Removed by Dentrification (Gaseous Loss from Wet Soils) Immobilization (by crop residue s) ( M I N E R ALIZATION ) Nitrogen Cyclefigure 1 p g . a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water
  • 7. p g . a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water through uptake by plants and microorganisms, and bound up in the soil. Adding carbon rich crop residues to the soil causes temporary immobilization of N, when bacteria take up ammonium and nitrate as they decompose crop residues. As crop residues decompose, nitrogen is again released. The speed of release var- ies with climate, with higher soil temperatures speeding release. figure 2 Mineralization and Immobilization (above) Adapted from the University of Minnesota An important part of the nitrogen cycle in relation to water quality is nitrification. Nitrifica- tion is the process by which two different bac- teria convert ammonium (NH4 + ) in the soil to nitrate (NO3 - ). Nitrosomonas bacteria mediate the conversion of ammonium (NH4 + ) to nitrite (NO2 - ), which is then quickly converted to nitrate (NO3 - ) by Nitrobacter bacteria. Nitrate is readily taken up by plant roots and is often the major form of N utilized by crops. figure 3 Nitrification (following page) Adapted from the University of Minnesota Nitrification rates depend upon soil tempera- ture. Nitrification can occur rapidly in warm, moist, well-aerated soils, changing the ammonium form of N commonly found in many fertilizers to the nitrate form within one to two weeks after application. Because the ammonium form of N has a positive charge, it is relatively immobile in the soil. Nitrate, which results from nitrification, is negatively charged; it enters the soil solution and is subject to leaching. Nitrification significantly slows down at temperatures below about 50 F. Thus, application of ammonium fertilizers to soils below 50 F allows the ammonium to remain in its positively charged, immobile form until soil temperatures increase. figure 4 Dentrification (following page) Adapted from the University of Minnesota There are two processes by which nitrogen from the soil can return to the atmosphere. They are denitrification and volatilization. Denitrifi- cation is the bacterial conversion of nitrate to elemental nitrogen (N2 ) or nitrous oxide (N2 O) gasses, which are lost to the atmosphere. These forms of N are unavailable to plants. Denitrifi- cation reduces nitrogen availability to crops M I N E R A L I Z A T I O N I M M O B I L I Z A T I O N Soil Organic Matter Manure Rotting Plant Residues NH3 Ammonia NO2 Nitrate NH4 + Ammonium NO3 + Nitrate Nitrosomonas (DRY SOILS) Nitrobacter (DRY SOILS) Soil Bacteria (WET AND DRY SOILS) Mineralization and Immobilizationfigure 2
  • 8. p g . a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water NO2 Nitrate NH4 + Ammonium Oxygen Oxygen NO3 + Nitrate Nitrification Dentrification S O I L S U R F A C E E S C A P E S A S G A S E S N2 ONO2 NO3 + Caused by soil organisms that live without air in a wet soil and get their oxygen (O) by taking it from NO3 -. Warm wet soil with large amount of plant residues favor dentrification. (The soil organisms that rot residues rapidly use up the free oxygen supply and then the denitrifying organisms begin to multiply.) NO N2 figure 3 figure 4
  • 9. p g . a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water but does not threaten water quality. However, because nitrous oxide is a greenhouse gas, deni- trification has climate change implications. Denitrification occurs in poorly aerated, water- logged soils. This process is rapid, so that if water stands on the soil for two to three days during the growing season, much of the nitrate will be lost by denitrification. Volatilization losses of ammonia gas to the atmosphere can occur when manure, urea fer- tilizer or solutions containing urea are surface applied and not incorporated into the soil. Vola- tilization losses are greatest with high temper- atures and lack of rain after application, and where surface crop residue is present. Injection of solutions containing ammonia and incorpora- tion of manure and urea fertilizers greatly reduces volatilization losses. Some ammonia lost to the atmosphere returns to the soil through precipita- tion. Precipitation also carries N from industrial and automobile emissions and nitrate formed by oxidation of nitrogen gas by lightning. figure 5 Volatilization (above) Adapted from the University of Minnesota Symbiotic N fixation converts atmospheric N into plant available N forms. Rhizobia bacte- ria living in the roots of legumes like soybeans, alfalfa and clovers make N available to their host plants. As these crops decompose, N is made available to succeeding crops. Small amounts of N are also fixed by free living organisms in the soil such as Azotobacter and blue-green algae. S O I L S U R F A C E E S C A P E S A S G A S E S NH4 + Ammonium NH3 Ammonia OH- Hydroxide Volatilizationfigure 5
  • 10. p g . a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water NO3 - Nitrate NO3 - Nitrate NO3 - Nitrate S O I L S U R F A C E W A T E R T A B L E Leaching Nitrogen and Water Quality Most N reaching surface or ground water is in the nitrate form because of its mobility. Because ammonia is held by soil particles, little leaching occurs, but erosion can carry ammonia to surface water. Erosion and runoff can also carry organic forms of N to lakes and streams where later con- versions can release plant available N. Leaching of nitrate to groundwater can occur when nitrate in excess of crop needs is present in the soil solution and water percolates through the soil. Risk of leaching is greatest on coarse textured soils, with shallow aquifers being most vulnerable. High rainfall or irrigation in excess of crop needs increases leaching risk. figure 6 Leaching (above) Adapted from the Uni- versity of Minnesota Because nitrate is mobile, it readily moves into the soil with rainfall or irrigation, rather than run- ning off the surface of fields. In many settings, surface runoff contains little nitrate. Exceptions can occur, such as when fertilizers or manures are applied to frozen soil, or heavy rains occur soon after application. The way nitrate usually enters streams and lakes is to first leach to shallow groundwater and then move laterally with natural subsurface flow or through drainage tiles. Areas that have been extensively tiled often have greater nitrate losses to surface water than untiled areas. A 1995 study by Fausey, et al. estimated that 37 percent of Corn Belt and Great Lakes cropland is artificially drained by surface channels, subterra- nean tiles or a combination of the two. It is impor- tant to be aware of the subsurface flow pathway figure 6
  • 11. p g . a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water of nitrate to surface water in selecting appropriate BMPs. BMPs directed at surface water, for exam- ple riparian buffer strips, would be ineffective if nitrates are coming primarily from subsurface pathways, such as through tile drainage. figure 7 Surface and Subsurface Flow (above) Adapted from Jim Baker, Iowa State University As previously discussed, the ammonium and nitrate forms of N are plant available. Which form is preferred depends upon the plant species. The primary N fertilizers used in the U.S. are anhy- drous ammonia, urea, ammonium nitrate, and urea-ammonium nitrate (UAN) solutions. Before it can be utilized by plants, urea (CO(NH2 )2 ) first must be hydrolyzed, or decomposed, by the enzyme urease to the ammonium (NH4 ) form. Ammonium is strongly held by soil particles, while urea and nitrate are soluble and subject to leach- ing. Ammonia (NH3 ) is volatile and can be lost to the atmosphere. Ammonia volatilization can be significant with surface application of fertilizers containing urea, especially when applied to large amounts of crop residue. Ammonia losses also may occur from surface manure applications, or when application slots fail to close properly behind anhydrous ammonia applicators. figure 8 Side-Dress Applicator (following page) Provided by Case IH Soil Moisture Storage SURFACE RUNOFF WATER PLUS SEDIMENT DeepPercolation BASE FLOW AND/OR SUBSURFACE (‘TILE’) DRAINAGE RAIN FA LL RAINFA LL RUNOFF (from thin ‘mixing’ zone) -1 cm INFILT RATION (some through preferential flow paths or ‘macropores’) Surface and Subsurface Flowfigure 7
  • 12. p g . a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water Side-Dress Applicator Phosphorus Phosphorus (P) undergoes many transformations in the soil that affect its availability to crops and its potential to be lost to water. Phospho- rus exists in both organic and inorganic forms. Organic P consists of undecomposed plant and animal residues, microbes and organic matter in the soil. Inorganic P is usually associated with aluminum (Al), iron (Fe) and calcium (Ca) com- pounds of varying solubility and availability to plants. Phosphorus is added to soils so that there are adequate levels for optimum crop growth. However, P can be rapidly converted in the soil to forms unavailable to plants. This “fixed” P can be slowly converted to “labile” or available forms, but this conversion is often too slow to meet crop needs. Agronomic soil tests have been developed to determine the amount of plant available P in the soil and how much fertilizer or manure should be added to meet desired crop yield goals. There are over 200 forms of naturally occur- ring P minerals in the soil. The most common P minerals are: 1) apatite (calcium phosphate), which is found in unweathered and moderately weathered soils; and 2) iron and aluminum phos- phates, which are found in highly weathered soils. Commercial P fertilizer is apatite (calcium phosphate) treated with sulfuric or phosphoric acids to increase the solubility of P. figure 8
  • 13. p g . 10a n i n t r o d u c t i o n t o Nutrient management behavior of nutrients in soil and water Figure 9 (above) shows the phosphorus cycle. In the soil solution, P is present as either H2 PO4 -1 in acid soils (monovalent) or HPO4 -2 in alkaline soils (divalent). Phosphorus enters the soil solu- tion by one of the following processes: • Dissolution of primary minerals • Dissolution of secondary minerals • Desorption of P from clays, oxides and minerals • Biological conversion of organic P to inorganic forms figure 9 The Phosphorus Cycle (above) Adapted from the International Plant Nutrition Institute Phosphorus available for crop uptake (or avail- able to aquatic organisms when P reaches water bodies) is called bioavailable P and consists of soluble P and a portion of P bound to soil parti- cles that can subsequently be released into solu- tion. Analyzing a soil for total P content is not very useful from an agronomic standpoint, as it does not determine how much P is available for crops. Agronomic soil tests have been developed over the years that extract all or a proportional amount of plant available P from soils. By cor- relating these soil tests with crop responses to P additions to various soils in the field, recommen- dations for needed amounts of P additions for optimum crop production on various soils have been developed. These agronomic P soil tests do not necessarily predict P losses to water. figure 10 Soil Testing (following page) Provided by Dr. Harold Reetz, Foundation for Agronomic Research Phosphorus and Water Quality Phosphorus losses are often measured as total P and soluble or dissolved P. Because soluble P is available to aquatic organisms, it has the most immediate impact on aquatic systems. Results of P loss studies sometimes refer to bioavailable P as algal available P. figure 11 Heavy Rain on Conventional Tillage (following page) Provided by NRCS Sediment-bound P constitutes 60 percent to 90 percent of P transported in runoff from cultivated land. Runoff from grass, forest and noncultivated land carries little sediment and is usually dominated by soluble P. While most sedi- ment-bound P is not readily available to aquatic The Phosphorus Cycle Animal manures and biosolids Plant residues Atmospheric deposition Mineral fertilizers Component Input to soil Loss from soil Crop harvest Runoff and erosion Leaching (usually minor) Organic phosphorus • Microbial • Plant residue • Humus Soil solution phosphorus • HPO4 -2 • H2PO4 -1 Primary minerals (apatite) Mineral surfaces (clays, Fe and Al oxides, carbonates) Secondary compounds (CaP, FeP, MnP, AIP) PLANT UP TA KE D ESORP TION ADSORPTION W EATHERING IMMOBILIZATION MINERALIZATION PR E C IP I TATI ON DISS O LU TI ON figure 9
  • 14. organisms, sediment deposited in aquatic sys- tems provides a long-term reservoir of P, as P is slowly released. Because of the ability of lake and stream sediments to provide a long-term source of P even after inputs have been reduced, beneficial impacts of P loss reductions are diffi- cult to predict. Both total P and soluble P losses are important. The relative importance of each form may depend on local conditions. Surface runoff and erosion are the primary mechanisms that carry P to surface water in most settings. Desorption of P from a thin layer of surface soil and vegetation releases soluble P carried in runoff water. Eroded sediment carries adsorbed P and mineral and organic P sources. Because of the rapid reactions by which P is immobilized in soil, P leaching has until recently been believed to be of minor importance. How- ever, under some conditions soluble P and col- loidal P can leach to natural subsurface flow or drainage tiles to reach surface water in signifi- cant amounts. Impact of Conservation Tillage on Nutrient Losses: Overview Conservation tillage has unique interactions with N and P. Conservation tillage systems impact both soil erosion and water infiltration, which in turn can affect the runoff or leaching of N and P. The type of tillage system used also influences where nutrients are found within the soil profile and their vulnerability to loss. Conservation tillage systems, utilizing some form of incorporation, allow more of the applied fertilizers and manures to be removed from the soil surface, placing them away from overland drainage flow which could carry them to surface water. Fertilizers and liquid manures can be injected below the soil surface in any tillage system, including no-till, protecting them from runoff. Likewise, surface applied dry manure would require incorporation to protect nutrients from surface water flow. Soil Testingfigure 10 figure 11 Heavy Rain on Conventional Tillage p g . 11a n i n t r o d u c t i o n t o Nutrient management impact of conservation tillage on nutrient losses: overview
  • 15. Surface application of fertilizer or manure in no-till systems results in a stratification of non- mobile nutrients like P. Higher P concentrations at the soil surface increase the availability of P for runoff. The organic matter content of surface soils also increases with no-till. This increased organic matter could reduce runoff losses of some poten- tial pollutants, like pesticides and P, by providing more adsorption capacity and causing increased infiltration, due to improved soil structure. The ability of conservation tillage to reduce erosion is well documented. Crop residue left on the soil surface protects the soil from the erosive impacts of rainfall and wind. Residue also slows runoff and prevents sealing of the soil surface, increasing infiltration of water. Reductions in ero- sion are usually proportional to the percent of the soil surface covered by crop residue. Conservation tillage also often increases water infiltration. Surface roughness and surface resi- due are responsible for infiltration increases in conservation tillage systems utilizing some form of tillage. In no-till systems, improved soil struc- ture and the presence of macropores consisting of worm holes, cracks and root channels, allows water to infiltrate rather than run off when rainfall exceeds the capillary flow capacity of the soil. Nitrogen Conservation tillage can reduce overall nitrogen loss by reducing ammonium nitrogen loss and organic nitrogen loss with sediment; however it may not reduce nitrogen leaching in the nitrate form. Nitrate is soluble and quickly moves down into the soil with rainfall or irrigation. Typically, lit- tle nitrate is present in surface runoff. In contrast, ammonium, which is held on soil particles, and soil organic nitrogen can move off fields with soil loss. Conservation tillage reduces runoff of these forms of nitrogen. Baker and Laflen (1983) found a 97 percent reduction of soil loss in no-till com- pared to a moldboard plow system resulted in a 75 percent to 90 percent reduction in total N loss for soybeans following corn and 50 percent to 73 percent reduction in total N loss for corn following soybeans. Several other studies have documented reductions in N losses with conservation tillage. figure 12 Stream in Cropland (following page) Provided by NRCS Conservation tillage systems impact both soil erosion and water infiltration, which in turn can affect the runoff or leaching of N and P. The type of tillage system used also influences where nutrients are found within the soil profile and their vulnerability to loss. Conservation tillage systems, utilizing some form of incorporation, allow more of the applied fertilizers and manures to be removed from the soil surface, placing them away from overland drainage flow, which could carry them to surface water. p g . 12a n i n t r o d u c t i o n t o Nutrient management impact of conservation tillage on nutrient losses: overview
  • 16. In most settings, nitrate reaches streams by first infiltrating and then moving with subsurface flow. Many researchers have investigated the impact of no-till and other conservation tillage systems on nitrate leaching. Most studies have found little impact, with a few studies finding a reduction or slight increase in nitrate leaching with no-till. figure 13 Tile Effluent from Soybean Field (above) Provided by University of Michigan Monitoring of drainage tile effluent has proven useful in measuring tillage impacts on nitrate leaching. A 1988 study by Kanwar et al. monitored tile effluent from continuous corn plots managed with no-till and conventional till- age in Iowa. Nitrate concentrations were similar between tillage systems in the first two years. By the third year of the study, nitrate concentrations were significantly lower in no-till plots. Kanwar and Baker (1993) monitored these plots over the next eight years and determined that nitrate concentrations in tile effluent were consistently lower with no-till than with conventional tillage. Monitoring of soil water at five depths from 3.9 feet to 11.8 feet (1.2 meters to 3.6 meters) also showed that nitrate concentrations were lower at all depths with no-till. Nitrate concentrations in groundwater and in drainage tile effluent have been consistently lower under no-till management than with con- ventional tillage. However, increased infiltration from no-till may at least partially offset lower concentrations of nitrates by increasing total drainage through the soil. This increased infiltra- tion of lower nitrate concentrations may result in a total quantity of nitrate loss similar to conven- tional tillage, leaching below fields to where it may reach ground water or be carried by sub- surface flow to surface water. To enhance the effect of conservation tillage practices to reduce nitrate losses to water, other BMPs will need to be included in the management system. Stream in Croplandfigure 12 Tile Effluent from Soybean Field figure 13 p g . 13a n i n t r o d u c t i o n t o Nutrient management impact of conservation tillage on nutrient losses: overview
  • 17. Phosphorus Phospohorus is lost from fields in two main ways: attached to eroded sediment particles that end up in streams and lakes and in the soluble P form that is lost from fields when water flowing from fields picks up P that is not adsorbed to soil particles. figure 14 Algae from Excess Phosphorus (above) Provided by NRCS Because total P losses in runoff consist primar- ily of insoluble P carried by eroded sediment par- ticles, conservation tillage usually reduces total P losses. As stated earlier, sediment-bound P often represents 60 percent to 90 percent of the total P load of row crop runoff. Conservation tillage has been an important BMP recommended to farm- ers to reduce P losses in specific watershed proj- ects. For example, following wide-scale promotion of conservation tillage to reduce P loading to the Great Lakes, Baker (1993) concluded that the downward trends in total and soluble P loads from Lake Erie tributaries for the period from the late 1970s to 1993 indicated that agricultural BMPs, including conservation tillage, were effective in reducing total and soluble P export. Controlled studies have documented the abil- ity of various conservation tillage systems to reduce P losses. For example, Baker and Laflen found that when total P runoff losses were com- pared between no-till and conventional tillage in Iowa, the 97 percent reduction in erosion with no-till resulted in an 80 percent to 91 percent reduction in total P loss for soybeans following corn. For corn following soybeans, the 86 per- cent reduction in erosion led to a 66 percent to 77 percent reduction in P loss. Barisas et al. (1978) compared runoff losses of P in six tillage systems on three Iowa soils using rainfall simulation techniques. They found that as surface crop residue increased, soluble P losses increased, but because erosion was reduced by crop residue, total P losses decreased as residue increased. Seta et al. (1993) compared nutrient losses with the moldboard plow, chisel plow and no-till Algae from Excess Phosphorusfigure 14 p g . 14a n i n t r o d u c t i o n t o Nutrient management impact of conservation tillage on nutrient losses: overview
  • 18. in Kentucky when fertilizer was applied before till- age. Total losses of nitrate, ammonia and phos- phate were in the order: moldboard plow chisel plow no-till. However, nutrient concentrations were higher with no-till. figure 15 Nutrient Loss Comparison (above) Adapted from Andraski et al. (1985) The surface placement of fertilizer in no- till systems may explain much of the tendency for no-till systems to produce higher soluble P concentrations in runoff in controlled studies where P is surface applied (versus full width till- age systems in which P is incorporated into the soil). Application of P in a subsurface band in no-till has prevented any increase in soluble P loss compared to conventional tillage. Andraski et al. (1985) compared runoff losses of P from four tillage systems when fertilizer was subsur- face banded in all systems. No-till, chisel plow and ridge-till systems reduced total P losses by 81 percent, 70 percent, and 59 percent, respec- tively, compared to the moldboard plow. Soluble P losses also were reduced by no-till and the chisel plow. figure 16 Ridge Till (foilowing page) Provided by NRCS A M O U N T O F T O T A L P L O S T B Y T I L L A G E Moldboard Plow No-Till PercentofLoss Chisel Plow Ridge-Till 0 20 40 60 80 100 120 Nutrient Loss Comparison When Fertilizer was Applied Before Tillage figure 15 p g . 15a n i n t r o d u c t i o n t o Nutrient management impact of conservation tillage on nutrient losses: overview
  • 19. Kimmel et al. (2001) measured P runoff losses as effected by tillage system and fertil- izer placement in Kansas. A chisel plow-field cultivator-disk system was compared to no-till and ridge-till, with P fertilizer either broadcast surface applied or knifed in prior to planting sorghum. Losses of total P, soluble P and bio- available P were measured. When the data are averaged over two years of study, knifing in fertil- izer reduced losses of total P, bioavailable P and soluble P for all three tillage systems. Reductions in P losses with knifing were most evident for soluble P. Knifing reduced soluble P losses by about 75 percent in no-till and ridge-till. figure 17 Tillage and P Placement Effects (following page) Adapted from Kimmell, R.J., G.M. Pierzynski, K.A. Janssen, and P.L. Barnes. 2001. J. Environ. Qual. 30:1324-1330. Thinking About Livestock High livestock concentrations in some areas have led to applications of manure as a source of nutri- ents in excess of crop nutrient needs. If manure applications are solely based on N content and crop N needs, excessive amounts of P may be applied. In the past, high P soil test levels were not considered to cause environmental problems, so manure was commonly applied based on N needs without regard to the level of soil test P. Such an application to a soil testing low in P could be viewed as appropriate, as it would build soil P toward optimum levels. But when excess P applications are continued for many years, soil tests reveal a rise to excessive levels of P and the risk of water contamination is increased. Ridge Tillfigure 16 p g . 16a n i n t r o d u c t i o n t o Nutrient management thinking about livestiock
  • 20. figure 18 Consider N and P content of Manure (following page) Adapted from NRCS Manure utilization has become a dilemma for farmers in some areas, as more than twice as many acres may be needed to apply manure based on P levels as N levels. Transporting manure long distances to land testing lower in P can be costly. Once P soil test levels reach excessive lev- els, it may take many years for P concentrations to decrease, depending on the cropping system, yield levels and soil characteristics. McCollum (1991) estimated that without further P addi- tions, 16 to 18 years of corn and soybean pro- duction would be needed to deplete a soil test P (Mehlich—3) in a Portsmouth fine sandy loam from 100 ppm to the agronomic threshold of 20 ppm. It is important to manage current manure and fertilizer applications to minimize both cur- rent and future P loss risks. The presence of soils testing high in P may sim- ply mean a crop farmer can forgo P fertilizer appli- cations for some period of time. However, forgoing P applications just compounds the problem for livestock farmers in need of land to apply manure. Regulations or required manure management plans could limit manure applications to such land. The future of manure management will be find- ing ways to use it as a beneficial byproduct, not a waste product. (Note: Partners magazine, the quar- terly e-publication of CTIC, includes articles about manure management in its 2007 issues. Partners: www.conservationinformation.org/partners) TILLAGE SYSTEM FERTILIZER PLACEMENT Annual P Runoff Loss Average of 2 Years Data Soluble P Bioavailable P (g/ha) Total P Chisel-disk Surface 16.0 49.5 605.0 Chisel-disk Knifed-in 12.3 33.0 354.0 No-Till Surface 329.0 398.5 832.5 No-Till Knifed-in 73.5 123.5 479.5 Ridge-Till Surface 320.5 426.0 1122.5 Ridge-Till Knifed-in 77.5 121.5 675.5 Conservation tillage can be expected to consistently reduce runoff losses of total P. Losses of soluble P may be higher with no-till if P fertilizers are surface applied to no-till compared to incorporated in other tillage systems. However, subsurface banding of P fertilizer in no-till systems reduces losses of soluble P below loss levels for conventionally tilled soils with the same fertilizer application method. Tillage and P Placement Effects on Soluble, Bioavailable and Total P Loss in Runoff Water from Sorghum Grown on a Silt Loam Soil with 1.0 to 1.5 Percent Slopes figure 17 p g . 17a n i n t r o d u c t i o n t o Nutrient management thinking about livestiock
  • 21. Role of nutrient management in larger conservation systems Nutrient management by way of conservation till- age is just one practice of conservation farming, and is most effective when done in tandem with other practices to create a whole farm conser- vation system. For example, conservation till- age may reduce P runoff, but won’t necessarily reduce N leaching, so a producer would benefit from precision application of N or growing cover crops. A constructed wetland can dramatically reduce N that has already reached a field’s tile system, but does little to keep phosphorus in place. It pays to come up with a farm-wide plan. Always consult with state and local resources, such as Extension, SWCD or NRCS offices, to find out specific regulations and opportunities. Some counties, especially those with impaired waterways, may have cost-share opportunities to help implement a nutrient management plan. Consider N and P content of Manurefigure 18 p g . 18a n i n t r o d u c t i o n t o Nutrient management role of nutrient management in larger conservation systems
  • 22. Ni t r oge n Altered Drainage Tile Design • Controlled drainage-subirrigation systems recycle nitrate leaching from the soil profile and reduce nitrate lost in tile drainage. • Research is underway to alter tile installation to favor denitrification before tiles intercept drainage water. application precision • New designs of manifolds may increase the uniformity of anhydrous ammonia distribution across applicators. • Experimental applicators, such as injectors that form a compacted soil layer and surface ridge, may reduce N losses in the future. • Variable rate applicators, combined with intensive soil or crop sampling, can allow correct N rates where fields vary in available N. Breeding Crops for Efficient N Uptake • Certain crop varieties may be able to more efficiently extract N from the soil. • Seed companies are developing varieties that have improved nutrient uptake. Conservation Buffers • Install buffers to trap sediment containing ammonia and organic N. • Nitrate in subsurface flow is reduced through denitrification enhanced by organic sources placed in the subsoil by buffer plants. • Buffer plants take up nitrate and other nutrients, preventing N loss to water. • Other conservation practices, such as terraces and contouring, reduce total N losses due to erosion reduction. A Summary of Nutrient BMPs The following is a limited collection of Best Management Practices, divided into sections on N and P, that runs the breadth of nutrient management. Farmers can con- sider these BMPs as they develop the most appropriate system of conservation practices for their operations. A brief overview of manure, pasture and hayland management is included. Remember that a whole-farm plan must be specific to the conditions of the area in which the plan will be applied. What is best here is not necessarily best there—talk to an expert about what practices are appropriate for your area. p g . 19a n i n t r o d u c t i o n t o Nutrient management a summary of nutrient bmps
  • 23. Conservation Tillage • Conservation tillage reduces total N losses because it reduces sediment loss. • Leaching losses of nitrate are not consistently affected by conservation tillage. Constructed Wetlands • Constructed wetlands placed to process tile efflu- ent reduce nitrate loads to surface water through denitrification. • Constructed wetlands may be more effective in reducing nitrate when coupled with buffer strips. Cover Crops • Cover crops grown between the time annual crops are harvested and when successive crops are planted can scavenge N and other nutrients and prevent leaching. • Cover crops can prevent soil erosion and improve water infiltration where N is surface applied. Crop Rotation • Legumes and other crops not needing supple- mental N can utilize N remaining in the soil from previous N-fertilized crops, reducing nitrate leaching risk. • Alfalfa can remove nitrate from the soil below the rooting depth of most annual crops. Crop Testing • Leaf tissue tests can identify N deficiencies. • Variations in chlorophyll content are being evalu- ated as a potential tool to facilitate variable rate N applications in-season. • Post-black-layer corn stalk nitrate tests help to determine if N rates were low, optimal or exces- sive, so that management changes can be made in following years. Fertilizer Application Method and Placement • Injection or incorporation of urea or N solutions reduces volatility losses. • In ridged crops, placing N fertilizers in a band in ridges makes N less susceptible to leaching. • Controlled release N fertilizers can help improve crop uptake. Inhibitors • Nitrification inhibitors maintain applied anhy- drous ammonia in the ammonium form longer, reducing leaching and denitrification losses. • Where fall N applications are appropriate, nitrifi- cation inhibitors reduce risk of leaching loss. • Urease inhibitors temporarily block the function of the urease enzyme, maintaining urea-based fertilizers in the non-volatile urea form, and reduce losses when these fertilizers are surface applied in high residue, conservation tillage systems. Nitrogen Application Rates • Include N applied as manure, in irrigation water and fixed by legumes as part of the total N application rate. • Use appropriate soil tests to determine residual N. • Increase plant populations in soils with greater potential to release mineralized N. • Nitrogen credits for legumes, such as alfalfa, can provide significant amounts of N to crops grown in rotation and need to be subtracted from total N required. • Manure credits should be taken into account when determining crop N needs. • Use a reasonable method to determine expected yields if N rates are based on yield. N i t r o g e n , continued p g . 20a n i n t r o d u c t i o n t o Nutrient management a summary of nutrient bmps
  • 24. Pest Management • Proper pest management allows crops to attain their potential yields, utilizing applied N and reducing the amount of excess N available to loss. • Bt corn prevents European corn borer feeding and associated stalk rots, which can cause corn to die early and leave excess N in the soil. • Rootworm resistant corn may allow better root growth and improved N uptake from the soil. Timing of N Applications • Applying N sources close to when crops can utilize N reduces N loss risk. • Side-dress application, usually made four to six weeks after planting crops, provides N just prior to the time of most rapid N uptake, and reduces risk of leaching and denitrification losses. • Split applications, involving preplant and side- dress applications, allow efficient use of applied N and reduce risk of yield reductions, should side-dress applications be delayed. • Fall application of N may be discouraged in some areas. In regions where anhydrous ammo- nia can be suitably applied in the fall, soil tem- peratures should be below 50 F before applying. Soil Testing • Preplant soil tests are useful in drier climates. • In areas where significant spring nitrate losses may occur due to leaching and/or denitrification, late spring or pre-side-dress N tests can determine if and how much additional N is needed. • New soil test procedures, such as amino sugar tests, may be useful in determining potential N release from the soil. P ho s p horu s Application Rates for Phosphorus • Use soil tests to determine agronomic rates. • P rates may need to be reduced for environmental reasons in high-risk areas. • Environmental P thresholds are being developed by states to determine P rates protective of water resources. • Consider P content of manure rather than solely N content. Application Timing for Phosphorus • Avoid fertilizer and manure application to frozen soil. • Incorporate fall-applied P fertilizers and manure to reduce runoff. • Avoid fertilizer and manure applications to wet soils. Conservation Buffers • Buffers trap sediment and adsorbed P. • Construct and maintain buffers to encourage sheet flow of runoff over the buffer. • As sediment accumulates in buffers, changing their profile, sediment should be removed, or buffers reshaped. • Select buffer species based on adaptation to local conditions and other desired benefits of buffers, such as wildlife habitat. • Other soil conservation practices, such as terraces and contour planting, reduce total P losses due to reduced erosion. Conservation Tillage • Conservation tillage consistently reduces runoff losses of total P. • Runoff losses of soluble P can be higher with no-till if fertilizers or manures are surface applied. Incorporating or injecting P sources below the soil surface reduces total and soluble P losses in all systems. N i t r o g e n , continued p g . 21a n i n t r o d u c t i o n t o Nutrient management a summary of nutrient bmps
  • 25. Constructed Wetlands • Wetlands have potential to reduce total P loads from surface runoff. • Wetland results have been variable in removing soluble P. Cover Crops • Plant cover crops to reduce erosion between when annual crops are harvested and the follow- ing crop covers the ground, thus reducing runoff of sediment-adsorbed P. • Achieving phosphorus reduction depends on good cover crop stand management. Fertilizer and Manure Placement • Incorporation or injection of P sources reduces runoff losses. • Starter applications can usually supply all of the maintenance P requirements for row crops. • Variable rate application, combined with intensive soil sampling, can reduce fertilizer inputs and avoid over-fertilizing high-testing areas of fields. • Banded applications may increase yield when P is stratified and soil tests below 15 cm (6 in.) reveal low levels of P. Irrigation Management • Surface crop residue, in furrow irrigated crops, reduces sediment and P losses. • Polyacrylamide (PAM) applied with furrow irriga- tion greatly reduces sediment, P and organic material losses. Livestock Feed Management • Carefully balance livestock rations so that supplemental P is not excessive. • Feed low-phytate corn varieties, in nonruminant rations to reduce the P content of manure. • Supplementing nonruminant feed rations with the phytase enzyme, reduces the need for supplemen- tal P and reduces P content of manure. Phosphorus Index • A coalition of U.S. scientists has developed a field-based planning tool that assesses the risk of P movement from soil to water. States are modifying the index to match local conditions. M a nur e , Pa s t ur e a nd H ay l a nd M a n a ge me n t Manure • Determine nutrient content of manure to calculate appropriate application rates. • Consider both P and N content of manure when determining rates. • Fields testing low in P benefit most from manure applications. • Consider risk factors such as nearness to streams and slopes, the presence of wells, sinkholes, surface tile inlets, and residences when selecting fields for manure applications. • Inject manure or use limited incorporation to reduce runoff risk. • Avoid manure application to frozen soil. • Manure amendments such as alum may reduce soluble P losses in runoff. Pasture and Hayland • Use shallow tillage tools, such as harrows or “aerators” on pastures, that may increase infil- tration and reduce runoff of manure or fertilizer. • Rotational grazing reduces compaction, overgrazing and nutrient runoff. • Exclude livestock from access to streams. • Make maintenance P fertilizer applications to forage legumes after the first cutting, when runoff losses are lower. • Cut hay higher to leave more stubble that may significantly reduces P runoff. p h o s p h o r u s , continued p g . 22a n i n t r o d u c t i o n t o Nutrient management a summary of nutrient bmps
  • 26. W or k s R e f e r e n ce d Andraski, B.J., D.H. Mueller, and T.C. Daniel. 1985. Phosphorus losses in runoff as affected by tillage. Soil Sci. Soc. Amer. J. 49:1523-1527. Baker, J.L. and J.M. Laflen. 1983. Water quality con- sequences of conservation tillage. J. Soil and Water Cons. 38:186-193. Baker, D.B. 1993. The Lake Erie agroecosystem pro- gram: water quality assessments. Agriculture, Ecosys- tems and Environment 46:197-215. Barisas, S.G., J.L. Baker, H.P. Johnson, and J.M. Laflen. 1978. Effect of tillage system on runoff losses of nutrients, a rainfall simulation study. Trans. ASAE 21:893-897. Bouman, G.A., A.M. Blackmer, J.M. Bremner. 1980. Effects of different nitrogen and fertilizer on emission of nitrous oxide from soil. Geophys. Res. Let. 7:85-88. Bundy, L.G. 1985. Understanding plant nutrients: soil and applied nitrogen. Univ. WI Coop. Ext. Serv. Bull. No. A2519. Erbach, D.C. 1982. Tillage for continuous corn and corn-soybean rotation. Trans ASAE 25:906-922. Fausey, N.R., L.C. Brown, H.W. Belcher, and R.S. Kanwar. 1995. Drainage and water quality in the Great Lakes and Cornbelt states. J. Irrig. Drain. Eng. 121:283-288. Fawcett, R.S. and S. Caruana. 2002. Better soil bet- ter yields: a guidebook to improving soil organic mat- ter and infiltration with continuous no-till. CTIC, West Lafayette, IN. 17 pp. Gray, C.B.J. and R.A. Kirkland. 1986. Suspended sediment phosphorus composition in tributaries of the Okanagen Lakes, B.C. Water Res. 20:1193-1196. Johnson, A.H.; Baker, J.L.; Shrader, W.D.; Laflen, J.M. 1979.Tillage system effect on sediment and nutrients in runoff from small watersheds. Trans. ASEA 22- 1.110-1.114. Kanwar, R.S., J.L. Baker, and D.G. Baker. 1988. Till- age and split N-fertilization effects on subsurface drainage water quality and crop yields. Trans ASAE 31:453-461. Kanwar, R.S. and J.L. Baker. 1993. Tillage and chemi- cal management effects on groundwater quality. In: Proceedings of the National Conference on Agricul- tural Research to Protect Water Quality. SCS Ankena IA, pp. 490-493. Kimmell, R.J., G.M. Pierzynski, K.A. Janssen, and P.L. Barnes. 2001. Effects of tillage and phosphorus placement on phosphorus losses in a grain sorghum- soybean rotation. J. Environ. Qual. 30:1324-1330. Logan, T.J. 1987. An assessment of Great Lakes till- age practices and their potential impact on water quality. In T.J. Logan, J.M. Davidson, J.L. Baker, and M.R. Overcash, eds. Effects of Conservation Tillage on Groundwater Quality. Lewis Pub., Chelsea, MI. Pages 271-276. McCollum, R.E. 1991. Buildup and decline in soil phosphorus: 30-year trends on a Typic Umprabuult. Agron. J. 83:77-85. McDowell, R., A. Sharpley, and G. Folmar. 2001. Phosphorus export from an agricultural watershed: linking source and transport mechanisms. J. Environ. Qual. 30:1587-1595. Randall, G.W., and T.K. Iragavarapu. 1995. Impact of long-term tillage systems for continuous corn on nitrate leaching to tile drainage. J. Environ. Qual. 24:360-366. Reicosky, D.C., W.D. Kemper, G.W. Langdale, C.L. Douglas, Jr., and P.E. Rasmussen. 1995. Soil organic matter changes resulting from tillage and biomass production. J. Soil and Water Cons. 50:253-261. Seta, A.K., R.L. Blevins, W.W. Frye, and B.J. Barfield. 1993. Reducing soil erosion and agricultural chemi- cal losses with conservation tillage. J. Environ. Qual. 22:661-665. Sharpley, A.N., S.S. Smith, O.R. Jones, 1992. The transport of bioavailable phosphorus in agricultural runoff. J. Environ. Qual. 21:30-35. Young, T.C. and J.V. DePinto. 1982. Algal-availability of particulate phosphorus from diffuse and point sources in the lower Great Lakes basin. Hydrobiologia 91:111- 119. p g . 23a n i n t r o d u c t i o n t o Nutrient management works referenced