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Mid IR pulsed light source for laser ultrasonic testing of carbon-fiber-reinforced plastic
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2015 J. Opt. 17 094011
(http://iopscience.iop.org/2040-8986/17/9/094011)
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Invited Article
Mid IR pulsed light source for laser
ultrasonic testing of carbon-fiber-reinforced
plastic
H Hatano1
, M Watanabe2
, K Kitamura1
, M Naito3
, H Yamawaki4
and
R Slater5
1
Optical & Electronic Materials Unit, National Institute for Materials Science (NIMS), Namiki 1-1,
Tsukuba, 305-0044, Japan
2
High Temperature Materials Unit, National Institute for Materials Science (NIMS), Sengen 1-2-1,
Tsukuba, 305-0047, Japan
3
Structural Materials Unit, National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, 305-
0044, Japan
4
Materials Reliability Unit, National Institute for Materials Science (NIMS), Sengen 1-2-1, Tsukuba, 305-
0047, Japan
5
RS Photonix LLC, 37 Wyman St. Waban, Massachusetts 02468-1516 USA
E-mail: HATANO.Hideki@nims.go.jp
Received 30 April 2015, revised 29 June 2015
Accepted for publication 29 June 2015
Published 3 September 2015
Abstract
A quasi-phase-matched (QPM) optical parametric oscillator (OPO) was developed using a
periodically poled Mg-doped stoichiometric LiTaO3 crystal to generate mid-IR light for excitation
of laser ultrasound in carbon fiber reinforced plastic (CFRP). The ultrasound generation efficiency
was measured at the three different wavelengths that emanate from the OPO: 1.064 μm, 1.59/
1.57 μm, and 3.23/3.30 μm. The measurements indicate that mid-IR 3.2–3.3 μm light generates
the most efficient ultrasonic waves in CFRP with the least laser damage. We used mid-IR light in
conjunction with a laser interferometer to demonstrate the detection of flaws/defects in CFRP
such as the existence of air gaps that mimic delamination and voids in CFRP, and the
inhomogeneous adhesion of CFRP material to a metal plate was also clearly detected.
Keywords: optical parametric oscillation, quasi-phase-matching frequency conversion, laser
ultrasonic testing, carbon fiber reinforced plastics, MID-IR light source
1. Introduction
Carbon-fiber reinforced plastic (CFRP) is a unique construc-
tion material possessing a strength-to-weight ratio forty times
that of iron. Its properties provide significant benefits to
energy-saving, low-environmental-impact, and reduced-car-
bon-footprint applications which are in great demand
worldwide. Moreover, its potential for a significant reduction
in fuel consumption has driven demand for CFRP as a
material for constructing major parts of aircraft, cars, boats,
and ships. In particular, the first CFRP automobile is now on
the market. In fields other than transportation, CFRP is being
applied to components such as compressed gas cylinders
(hydrogen tanks for fuel-cell vehicles and compressed natural
gas [CNG] tanks for CNG vehicles) and wind-turbine blades.
CFRP fabrication is a multi-step process and quite unlike
the fabrication of pure metal parts. There is a higher prob-
ability of a fabrication error in the making of CFRP. There-
fore, from the viewpoint of the manufacturers, priority must
Journal of Optics
J. Opt. 17 (2015) 094011 (8pp) doi:10.1088/2040-8978/17/9/094011
Content from this work may be used under the terms of the
Creative Commons Attribution 3.0 licence. Any further
distribution of this work must maintain attribution to the author(s) and the
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2040-8978/15/094011+08$33.00 © 2015 IOP Publishing Ltd Printed in the UK1
be given to assuring safety and reliability, while guaranteeing
the quality of CFRP products. Defects at joints composed of
similar CFRP/CFRP materials as well as joints between
dissimilar materials [such as CFRP/aluminum or CFRP/
titanium alloy] must be accurately detected so that reliability
can be assured and product quality guaranteed.
Aimed at satisfying these requirements, various non-
destructive evaluation technologies are being developed to
diagnose CFRP materials. Each technology has its advantages
and disadvantages, and the most suitable choice is based on
diverse factors like the shapes and locations of the CFRP
components, budget and delivery date, and required precision.
Among the various testing methods, a compact and robust
method that is contactless, non-destructive, and can be applied
remotely with sufficient spatial resolution would be very
desirable. In this paper, laser ultrasonic testing (LUT) as an
example of a non-destructive testing (NDT) method is being
investigated. LUT generates an ultrasound pulse by irradiating
the CFRP surface with a short pulse of laser radiation. The
radiation is rapidly absorbed and converted into heat, which
generates a pressure wave and an ultrasound pulse. For non-
contact inspection, the ultrasound is optically detected with an
interferometer; for contact inspection, a microphone could be
used [1]. LUT combines the high flaw detectability of ultra-
sound with the multiple degrees of freedom of an optical sys-
tem. When the region to be inspected is irradiated with a short-
pulse laser, expansions and contractions are locally generated
within the bulk of the material, and ultrasound waves propagate
both on the surface and inside the volume of the material. If
defects are present on the surface or inside the material, the
sound propagation properties change, leading to a variation in
the vibration amplitude and phase of the propagating waves. It
is possible to extract information regarding the interior of the
component if this change can be observed. Since LUT utilizes
an optical system, a laser interferometer can be used to establish
a completely contactless inspection system.
Current state-of-the-art LUT systems utilize legacy carbon-
dioxide (CO2) TEA (transverse excited, atmospheric pressure)
gas lasers to induce ultrasound in CFRP. These lasers emit at
10.6 micron wavelengths, and, most likely, this light is absor-
bed by weak molecular vibrations in the IR spectrum of the
epoxy matrix. These lasers can be difficult to maintain at their
optimum performance level because of the need for a high-
voltage excitation mechanism at high gas pressure and the
deleterious effects of the high-pressure discharge on the mole-
cular gas composition. These lasers are also large and heavy
and can be difficult to maneuver on the shop floor. It is desir-
able to develop alternative wavelength sources using modern
compact, reliable solid-state laser technology.
Recent work has shown that light with a wavelength in
the vicinity of 3.2 μm (namely, close to the strong carbon–
hydrogen stretching absorption band in epoxy resin) is sui-
table for ultrasound generation in various CFRP materials.
[2, 3] Moreover, the efficiency and damage thresholds of LUT
for CFRP have been reported [4]. A comparison of light
sources was carried out using mainly Nd:YAG and CO2 gas
lasers[4]. To the best of our knowledge, there is no com-
mercial pulsed solid-state light source in the vicinity of
3.0–3.5 μm that is suitable for applying LUT to CFRP. We
need a mid-IR laser with enough pulse energy (>10 mJ),
appropriate pulse width (10–35 ns), relatively high repetition
rate (>100 Hz), and portability, with easy handling. In other
words, we need a scalable, high average power mid-IR source
for LUT, and currently, we have assessed other solid state mid-
IR lasers and have determined that they are not sufficiently
mature to achieve these desired specifications in the near term.
At NIMS, we are developing a technology that incorpo-
rates an efficient wavelength conversion device for generating
mid-IR light by pumping an optical parametric oscillator (OPO)
using compact Nd:YAG solid-state lasers. These lasers are the
most reliable, most well-developed solid-state pump lasers
currently available and are ideally suited for LUT applications.
We have already produced quasi-phase matching (QPM)
wavelength-conversion devices fabricated from a ferroelectric
material, stoichiometric lithium tantalate (LiTaO3, hereafter
abbreviated as SLT), by means of the periodic poling (PP)
technique. The SLT coercive field (the external electric field
necessary for the polarization inversion) can be decreased by
more than one order of magnitude compared with conven-
tional LiTaO3 crystals by controlling the defect density during
crystal growth [5, 6]. This decrease in the coercive field has
made it possible to fabricate PPSLT devices [7–9] with
apertures as large as 5 mm×5 mm. PPSLT crystals are also
resistant to optical laser damage [10]. Both a wide aperture
and damage resistance are prerequisites for a wavelength
convertor in any mid-IR LUT application. Compact and
robust mid-infrared laser light sources in the vicinity of
3.2 μm can be realized by combining PPSLT convertor
technology with a solid-state Nd:YAG laser as a pump. The
reason why PPMgSLT was adopted as a nonlinear material
for the OPO laser instead of another periodically poled crystal
is based on the demonstrated large aperture capability (as
large as 5 mm×5 mm) needed for high energy per pulse
applications and the substantially high laser damage threshold
compared with PPLN,PPRTA, PPKTP, etc.
In this paper, we describe the system and performance of
a mid-IR PPSLT OPO as well as the results of LUT of CFRP
material using light generated by the OPO.
2. Experimental methods
2.1. Nonlinear optical material and device for OPO
Figure 1 shows a PPSLT OPO using periodically poled
MgSLT (1% MgO doped SLT) placed between two plano–
Figure 1. Schematic diagram of OPO system using a MgO doped
stoichiometric lithium tantalate QPM device with coated simple
plano–plano couplers.
2
J. Opt. 17 (2015) 094011 Invited Article
plano end mirrors. The QPM grating pitch was designed using
equations (1) and (2) below, which describe the energy con-
servation and phase matching conditions in a QPM parametric
convertor device:
1 1 1
1
p s i
( )
l l l
= +
n T n T n T1
2
p
p
s
s
i
i
( ) ( ) ( )
( )
l l lL
= - -
where ,pl ,sl ,il and L represent the pump wavelength, signal
wavelength, idler wavelength, and QPM grating pitch,
respectively. n T ,p ( ) n T ,s ( ) and n Ti ( ) represent the tempera-
ture-dependent refractive indices at the pump, signal, and
idler. Figure 2 shows the solutions to equations (1) and (2)
using the published Sellmeier dispersion equation for
SLT [11].
We designed and fabricated two QPM devices with
grating pitches of 30.9 μm and 31.1 μm, which correspond to
expected idler wavelengths of 3.30 μm and 3.23 μm at 30 °C.
The lengths and apertures of these devices were the same
(35 mm and 3 mm×3 mm).
2.2. OPO set-up
Figure 3 is a schematic diagram of the experimental OPO-
LUT system. Two Q-switched multimode Nd:YAG lasers
were used as the 1.064 μm pump source. A laser beam was
selected by using beam switching optics from either of two
laser systems: (a) Quantel/Centurion: designated as Laser-A
hereafter and (b) Quantel/Ultra: Laser-B, i.q. We used pump
laser pulses with a maximum energy of 40 mJ, a pulse length
of 7.8 ns (Laser-A)/9.0 ns (Laser-B) FWHM, and a repetition
rate of 20 Hz. The beam had a slightly elliptical top-hat shape
with a beam quality measure of M2
∼15. The pump energy
was controlled using a half-wave plate and polarizer, located
upstream of the OPO, so that the pulse profile remained
independent of the pump energy. The input pump wave was a
collimated beam with a diameter of ∼2.5 mm (1/e2
) at the
OPO resonator. The polarization of the pump laser was set
parallel to the z axis of the PPMgSLT device.
The OPO resonator was a linear cavity with a mirror
separation of 100–160 mm. The input and output couplers
were coated plane mirrors with the same dielectric coating:
high reflectivity at the signal wavelength (1.5–1.6 μm), high
transmission at the pump wavelength, and high transmission
at the idler wavelength (3.1–3.5 μm). When the signal
wavelength was required, the output coupler was replaced
with a mirror coated with R=95% at the signal wavelength.
The signal and idler waves were first separated from the
output light by using a pump-cut filter; then, the idler and
signal were separated from each other by a dichroic filter. The
idler and signal energy were measured using a power meter
with a thermal sensor (Ophir 3A-P). The idler wavelength was
measured with a spectrometer consisting of a grating and a
pyroelectric sensor array.
2.3. LUT experiments
The laser ultrasonic testing system (schematic layout in
figure 3) consisted of a pulsed laser for ultrasound generation,
a laser Doppler velocimeter (LDV) for ultrasonic measure-
ments, and a sample scanning XY stage.
Three light sources were used for ultrasound generation:
a Laser-B (Quantel/Ultra) Nd:YAG laser (1.064 μm), a
PPSLT OPO signal wave (1.59/1.57 μm) and a PPSLT OPO
idler wave (3.23/3.30 μm) . It should be noted that two OPO
outputs with different wavelength pairs (1.59 μm and 1.57 μm
for the signal wave, 3.23 μm and 3.30 μm for the idler wave)
were generated from two separate PPSLT QPM gratings
(31.1 μm and 30.9 μm, respectively, and at 30 °C). This small
wavelength difference has a negligible effect on the generated
LUT signals based on the relatively structureless, broad
CFRP absorption band. The laser pulse selected by the beam
switching device was directed to the surface of the CFRP
sample through a lens with a beam diameter of 1.0 mm. The
laser pulse interacted with the sample surface to induce an
ultrasonic pulse that propagated into the sample. Laminated
CFRP plates 1.1 mm thick (O-KEI Resin Co. Ltd, Japan)
were used for this investigation. It should be noted that
commercially available CFRP plates were produced based on
lamination of many thin prepreg sheets with thicknesses in the
range of 0.02–0.5 mm. These specially made CFRP plates
were carefully produced without any known defects, and,
therefore, our LUT was not affected by this process.
A commercial LDV system was used as an ultrasonic
wave sensor. The system consists of mainly two major parts:
(a) a sensor unit (Graphtec AT0023) which includes a helium
neon (HeNe) laser light source and a built-in autofocal lens,
and (b) an optical heterodyne interferometric signal demo-
dulation device (Thamway T1101077A). The HeNe probe
beam from the sensor unit was focused onto the CFRP sample
with a beam diameter of around 60 μm (1/e2
intensity). The
probe laser sensing beam and the ultrasound generation beam
were aligned to counterpropagate with respect to each other;
these two counterpropagating beams were then carefully
aligned to overlap each other on the target material. The probe
Figure 2. Calculated OPO emission wavelengths as a function of
PPSLT QPM period and crystal temperature.
3
J. Opt. 17 (2015) 094011 Invited Article
laser beam reflects off the CFRP surface, is modulated by the
ultrasonic soundwave and subsequently interferes with the
incident probe beam inside the sensing unit, producing an
optical heterodyne interferometric signal. The interferometric
signal was then processed and converted to an ultrasonic
velocity signal. The ultrasonic velocity signal was analyzed
using a 500 MHz oscilloscope (LeCroy). Signal averaging
was performed to reduce random noise. We used three
scanning methods:
(1) A-scan: The temporal response of the ultrasonic signal
at a fixed sample point.
(2) B-scan: Spatial one-dimensional scanning of the
temporal response graphically displayed on a 2D map.
(3) C-scan: Spatial two-dimensional scanning of ultrasonic
intensity graphically displayed on a 3D map.
3. Results and discussion
3.1. OPO performance
The OPO performance was usually obtained using Laser-A
(Quantel/Centurion) as a pump. We found no differences in
OPO performance when Laser-B (Quantel/Ultra) was used as
a pump. Figure 4 compares the theoretical and experimental
temperature dependences of the idler wavelength output from
the PPSLT OPO. The straight line and the dashed line
represent the theoretical results for QPM grating pitches of
30.9 μm and 31.1 μm, respectively. The squares and circles
represent the measured data for the samples with grating
pitches of 30.9 μm, and 31.1 μm, respectively, and it is clear
that they are in good agreement with theory.
The M2
of the idler light was estimated to be in the range
15–20 by measuring the propagation of the focused idler
beam using a Gaussian beam fitting routine. The idler M2
parameter is strongly dependent on the M2
of the pump wave.
figure 5 shows the dependence of the output energy for
the 3.23 μm and 3.30 μm idler waves (QPM grating pitches of
31.1 μm and 30.9 μm, respectively) on the input pump energy
(input–output property) measured at 30 °C. An OPO
Figure 3. Schematic diagram of experimental OPO-LUT system. A fundamental laser path is selected by switchable mirror (M4). The pump
beam is energy controlled using a half-wave (λ/2) plate and polarizer, then enters the OPO-resonator. Signal and idler beams are separated
from the OPO output by two filters. Lenses L1 and L2 adjust the beam waist at the PP-MgSLT crystal inside the resonator. Lenses L3, L4 and
L6 are used to focus the YAG fundamental beam, signal and idler beam onto the CFRP sample for ultrasound generation, respectively. The
LUT system consists of a sensor unit and an optical heterodyne interference signal demodulation device. Demodulated ultrasonic velocity
signal is observed by oscilloscope synchronizing with the laser repetition frequency.
Figure 4. Temperature dependence of idler wavelength: comparison
between design and experiment for QPM grating pitches of 30.9 μm
and 31.1 μm. The experimentally measured wavelength values show
good agreement with theory.
4
J. Opt. 17 (2015) 094011 Invited Article
threshold energy of ∼5 mJ and ∼5 mJ for the idler output was
obtained for a 35 mJ pump input.
Figure 6 shows the dependence of the output energy of
idler waves (QPM grating pitches of 31.1 μm) on the input
pump energy measured at 50, 100 and 150 °C.
3.2. LUT performance
As we previously explained, the LUT performance was
characterized using the OPO pumped by Laser-B (Quantel/
Ultra). Figure 7 illustrates a typical temporal ultrasonic
waveform (A-scan) measured on a CFRP sample excited by a
laser beam with a wavelength of 3.23 μm. The steep negative
peak appearing around 0.57 μs from the scale zero point of
the horizontal axis (which means the onset of the laser pulse)
corresponds to the ultrasonic velocity signal generated at a
point on one surface of the CFRP and that propagated on the
other surface.
To characterize the ultrasound intensity generated by
laser irradiation, we define a parameter (param1) by the fol-
lowing formula (3).
V t t T TParam1 d 3
T
T
2 1
1
2
( )( ) ( )ò= - -
Here, V t( ) represents the temporal ultrasonic velocity signal
shown in figure 7. T1 and T2 represent the integration interval
endpoints, and in this experiment, T1=0.5 μs and
T2=0.65 μs. Param1 represents the average voltage of the
ultrasonic velocity signal in the integration period.
2D maps of Param1 values were obtained by scanning an
area of 10 mm×10 mm of the sample using the ultrasound
generation laser at 3.30 μm. The resultant C-scan is shown in
figure 8; the bidirectional periodic structure with a cycle of
around 2 mm in either direction represents the bidirectional
weave of the carbon fibers inside the epoxy matrix (see
figure 9). Comparing the C-scan mapping and the CFRP
Figure 5. The dependence of the output energy as a function of the
input pump energy for the idler 3.23 μm and 3.3 μm waves. The
operation temperature is 30 °C.
Figure 6. An example of the temperature-dependent input–output
properties of the idler using a QPM grating period of 31.1 μm
Figure 7. Typical temporal ultrasonic waveform (A-scan) measured
in CFRP sample excited by a laser beam with a wavelength of
3.23 μm. A strong negative peak at 0.57 μs from the onset of the
exciting laser pulse corresponds to the ultrasonic velocity signal
generated at a point on one surface of the CFRP and that propagated
on the other surface.
Figure 8. Typical example of C-scan plot for CFRP sample.
5
J. Opt. 17 (2015) 094011 Invited Article
surface, we can see that more intense ultrasound is generated at
parts where the epoxy is exposed on the surface of the CFRP.
This result is consistent with the fact that the mid-infrared
light is strongly absorbed by the C-H stretching vibration in
the –CH2–(O–CH2)– linkage of the epoxy polymer [12].
The thermal expansion of the epoxy resin is considerably
larger [13] than the thermal expansion of the carbon fiber,
which is close to zero or slightly negative [14]. As a result, very
little ultrasound was generated where the carbon fibers were
exposed on the surface. Note that the enhancement of ultra-
sound generation in the epoxy layer was simulated in [15].
Next, we measured the laser wavelength dependence of
the ultrasound generation efficiency in CFRP. To reduce the
influence of the structure-dependent generation described
above, the ultrasound was generated by scanning a 20 mm
length with a pitch of 0.2 mm (B-scan), and the ultrasound
parameters (param1) were then averaged over the entire
region. The comparison was done using the same area of
CFRP. For each wavelength, the laser pulse energy and the
beam diameter were held constant at 0.2 mJ and 1.0 mm,
respectively. Figure 10 shows the variation of the peak
ultrasound intensity along the scanning distance with wave-
length as a parameter. The figure shows that 3.23 μm wave-
length light has a stronger capability of ultrasonic generation
than 1.064 μm (pump) light and 1.57 μm (signal) light.
A laser scanning experiment was carried out in order to
assess the laser’s damage to a rough CFRP surface. The
ultrasound generating laser was scanned in an area measuring
3 mm×3 mm with a step of 0.5 mm (total of 7×7 spots).
The irradiation time for each spot was 10 s. The laser energy
in the irradiated areas was varied from 0.8 mJ to 2.4 mJ.
Figure 11(a) shows photographs of the CFRP sample surface
after laser irradiation. Figure 11(b) shows microscope images
of the damaged areas. These images were taken at the center
of a 2 mm×2 mm area of the CFRP surface. Most of the
laser damage occurred in areas where the carbon fibers were
exposed on the surface.
We can see that the tolerance to damage is highest with
the mid-infrared laser at a 3.3 μm wavelength. In particular,
this wavelength produces no obvious damage at 0.8 mJ and
clearly less damage at higher intensities such as 2.4 mJ. A
possible explanation for the reason why tolerance to damage
is highest with the mid-infrared laser may come from its
lowest photon energy. Irradiation of higher photon energy
tends to shift to ablation mode easily.
3.3. LUT applications for CFRP
The above results confirm the potential for mid-infrared laser
induced ultrasound generation in CFRP. Next, we demon-
strate two applications of mid-infrared lasers to LUT detec-
tion of flaws in CFRP. The first application is detection of
voids. We fabricated a sample of CFRP with a void inside it
by bonding two CFRP plates with a thickness of 1.1 mm and
with an un-bonded area of 7 mm diameter, as illustrated in
figure 12(a). The results of the LUT C-scan are shown in
figure 12(b). A nearly null signal can be clearly seen, and it
corresponds to the location and size of the void.
Figure 13 shows a second application of an LUT C-scan
for detecting inhomogeneous adhesion between CFRP and an
aluminum plate. Figure 13(a) shows a photograph displaying
the inhomogeneous distribution of an adhesive bond (glue) on
top of a CFRP plate to which an aluminum plate was bonded.
The region where the adhesive bond is missing corresponds to
the blue-colored region with a near null signal in the C-scan
shown in figure 13(b).
Figure 9. (a) Cross section of CFRP sample showing a woven
structure of carbon-fiber (CF) bunches. CF bunches and epoxy resin
are exposed alternately on the surface. (b) A thin section of CFRP
sample with a thickness of 40 μm under an optical microscope.
Figure 10. The peak ultrasound intensity variation along the
scanning distance with the parameter of exciting laser wavelength.
The periodic structure of each curve corresponds to the woven
structure of carbon-fiber bunches shown in figure 9(a).
6
J. Opt. 17 (2015) 094011 Invited Article
Here, the He-Ne laser sensing beam and the ultrasound
generation beam were aligned to counter-propagate with
respect to each other. Therefore, the existence of air-gaps,
mimicking delamination and voids where the ultrasound
cannot penetrate, can be clearly detected.
4. Summary
A QPM OPO using periodically poled MgSLT (MgO 1%
doped near-stoichiometric LiTaO3) was demonstrated. The
OPO, pumped by a 1.064 μm Q-switched Nd:YAG laser, was
tuned to the wavelength region 3.2–3.3 μm. This is the most
promising regime for LUT of CFRP. An experiment was
conducted to evaluate the ultrasound generation efficiencies
of laser pulses at three different wavelengths (1.064 μm,
1.59/1.57 μm, and 3.23/3.30 μm) that are emitted from the
OPO system. We found that the mid-IR laser at a 3.2–3.3 μm
wavelength generated the most efficient and least damaging
ultrasonic waves in CFRP.
We used mid-IR light in conjunction with a laser inter-
ferometer to demonstrate the detection of flaws/defects in
CFRP such as the existence of air-gaps that mimic delami-
nation and voids in CFRP, and the inhomogeneous adhesion
of CFRP material to a metal plate was also clearly detected.
Acknowledgements
A part of this research was supported by the ‘Cross-minis-
terial Strategic Innovation Promotion Program (SIP), Struc-
tural Materials for Innovation’ of Japan Science and
Technology Agency, JST. We wish to thank S Takekawa and
Y Furukawa of OXIDE Corporation for optical crystal fab-
rication, Y Fujii of NIMS for CFRP sample preparation, and
K Oguchi and M Enoki of the University of Tokyo for
valuable discussion about ultrasonic wave propagation.
References
[1] Green R Jr (ed) 1997 See for example papers, Proc. of the
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[2] Dubois M, Lorraine P W, Filkins R J and Drake T E 2001
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[3] Dubois M, Lorraine P W, Filkins R J, Drake T E,
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Figure 11. (a) Macroscopic photographs of the CFRP sample
surfaces after laser irradiation. The dashed square shows the area of
scanned irradiation. (b) Microscopic photographs of laser irradiated
Figure 12. Results of LUT C-scan of CFRP including void inside: (a)
illustration of sample preparation, (b) ultrasound intensity distribu-
tion for the CFRP sample.
Figure 13. (a) Photograph showing the distribution of adhesive bond
(glue) on top of a CFRP plate. An aluminum plate was overlapping
on this CFRP plate. (b) C-scan plot for the partially-bonded sample
shown above.
7
J. Opt. 17 (2015) 094011 Invited Article
[4] Edwards C, Stratoudaki T, Dixon S and Palmer S 2001 IEEE
Proc.-Sci. Meas. Technol. 148 139
[5] Kitamura K, Furukawa Y, Niwa K, Gopalan V and
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[14] see www.christinedemerchant.com/carboncharacteristics.html
[15] Dubois M, Enguehard F and Bertrand L 1995 Review of
Progress in Quantitative Nondestructive Evaluation (New
York: Plenum Press) pp 529
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J. Opt. 17 (2015) 094011 Invited Article

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hatano article

  • 1. This content has been downloaded from IOPscience. Please scroll down to see the full text. Download details: IP Address: 50.177.130.15 This content was downloaded on 08/09/2015 at 17:17 Please note that terms and conditions apply. Mid IR pulsed light source for laser ultrasonic testing of carbon-fiber-reinforced plastic View the table of contents for this issue, or go to the journal homepage for more 2015 J. Opt. 17 094011 (http://iopscience.iop.org/2040-8986/17/9/094011) Home Search Collections Journals About Contact us My IOPscience
  • 2. Invited Article Mid IR pulsed light source for laser ultrasonic testing of carbon-fiber-reinforced plastic H Hatano1 , M Watanabe2 , K Kitamura1 , M Naito3 , H Yamawaki4 and R Slater5 1 Optical & Electronic Materials Unit, National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, 305-0044, Japan 2 High Temperature Materials Unit, National Institute for Materials Science (NIMS), Sengen 1-2-1, Tsukuba, 305-0047, Japan 3 Structural Materials Unit, National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, 305- 0044, Japan 4 Materials Reliability Unit, National Institute for Materials Science (NIMS), Sengen 1-2-1, Tsukuba, 305- 0047, Japan 5 RS Photonix LLC, 37 Wyman St. Waban, Massachusetts 02468-1516 USA E-mail: HATANO.Hideki@nims.go.jp Received 30 April 2015, revised 29 June 2015 Accepted for publication 29 June 2015 Published 3 September 2015 Abstract A quasi-phase-matched (QPM) optical parametric oscillator (OPO) was developed using a periodically poled Mg-doped stoichiometric LiTaO3 crystal to generate mid-IR light for excitation of laser ultrasound in carbon fiber reinforced plastic (CFRP). The ultrasound generation efficiency was measured at the three different wavelengths that emanate from the OPO: 1.064 μm, 1.59/ 1.57 μm, and 3.23/3.30 μm. The measurements indicate that mid-IR 3.2–3.3 μm light generates the most efficient ultrasonic waves in CFRP with the least laser damage. We used mid-IR light in conjunction with a laser interferometer to demonstrate the detection of flaws/defects in CFRP such as the existence of air gaps that mimic delamination and voids in CFRP, and the inhomogeneous adhesion of CFRP material to a metal plate was also clearly detected. Keywords: optical parametric oscillation, quasi-phase-matching frequency conversion, laser ultrasonic testing, carbon fiber reinforced plastics, MID-IR light source 1. Introduction Carbon-fiber reinforced plastic (CFRP) is a unique construc- tion material possessing a strength-to-weight ratio forty times that of iron. Its properties provide significant benefits to energy-saving, low-environmental-impact, and reduced-car- bon-footprint applications which are in great demand worldwide. Moreover, its potential for a significant reduction in fuel consumption has driven demand for CFRP as a material for constructing major parts of aircraft, cars, boats, and ships. In particular, the first CFRP automobile is now on the market. In fields other than transportation, CFRP is being applied to components such as compressed gas cylinders (hydrogen tanks for fuel-cell vehicles and compressed natural gas [CNG] tanks for CNG vehicles) and wind-turbine blades. CFRP fabrication is a multi-step process and quite unlike the fabrication of pure metal parts. There is a higher prob- ability of a fabrication error in the making of CFRP. There- fore, from the viewpoint of the manufacturers, priority must Journal of Optics J. Opt. 17 (2015) 094011 (8pp) doi:10.1088/2040-8978/17/9/094011 Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. 2040-8978/15/094011+08$33.00 © 2015 IOP Publishing Ltd Printed in the UK1
  • 3. be given to assuring safety and reliability, while guaranteeing the quality of CFRP products. Defects at joints composed of similar CFRP/CFRP materials as well as joints between dissimilar materials [such as CFRP/aluminum or CFRP/ titanium alloy] must be accurately detected so that reliability can be assured and product quality guaranteed. Aimed at satisfying these requirements, various non- destructive evaluation technologies are being developed to diagnose CFRP materials. Each technology has its advantages and disadvantages, and the most suitable choice is based on diverse factors like the shapes and locations of the CFRP components, budget and delivery date, and required precision. Among the various testing methods, a compact and robust method that is contactless, non-destructive, and can be applied remotely with sufficient spatial resolution would be very desirable. In this paper, laser ultrasonic testing (LUT) as an example of a non-destructive testing (NDT) method is being investigated. LUT generates an ultrasound pulse by irradiating the CFRP surface with a short pulse of laser radiation. The radiation is rapidly absorbed and converted into heat, which generates a pressure wave and an ultrasound pulse. For non- contact inspection, the ultrasound is optically detected with an interferometer; for contact inspection, a microphone could be used [1]. LUT combines the high flaw detectability of ultra- sound with the multiple degrees of freedom of an optical sys- tem. When the region to be inspected is irradiated with a short- pulse laser, expansions and contractions are locally generated within the bulk of the material, and ultrasound waves propagate both on the surface and inside the volume of the material. If defects are present on the surface or inside the material, the sound propagation properties change, leading to a variation in the vibration amplitude and phase of the propagating waves. It is possible to extract information regarding the interior of the component if this change can be observed. Since LUT utilizes an optical system, a laser interferometer can be used to establish a completely contactless inspection system. Current state-of-the-art LUT systems utilize legacy carbon- dioxide (CO2) TEA (transverse excited, atmospheric pressure) gas lasers to induce ultrasound in CFRP. These lasers emit at 10.6 micron wavelengths, and, most likely, this light is absor- bed by weak molecular vibrations in the IR spectrum of the epoxy matrix. These lasers can be difficult to maintain at their optimum performance level because of the need for a high- voltage excitation mechanism at high gas pressure and the deleterious effects of the high-pressure discharge on the mole- cular gas composition. These lasers are also large and heavy and can be difficult to maneuver on the shop floor. It is desir- able to develop alternative wavelength sources using modern compact, reliable solid-state laser technology. Recent work has shown that light with a wavelength in the vicinity of 3.2 μm (namely, close to the strong carbon– hydrogen stretching absorption band in epoxy resin) is sui- table for ultrasound generation in various CFRP materials. [2, 3] Moreover, the efficiency and damage thresholds of LUT for CFRP have been reported [4]. A comparison of light sources was carried out using mainly Nd:YAG and CO2 gas lasers[4]. To the best of our knowledge, there is no com- mercial pulsed solid-state light source in the vicinity of 3.0–3.5 μm that is suitable for applying LUT to CFRP. We need a mid-IR laser with enough pulse energy (>10 mJ), appropriate pulse width (10–35 ns), relatively high repetition rate (>100 Hz), and portability, with easy handling. In other words, we need a scalable, high average power mid-IR source for LUT, and currently, we have assessed other solid state mid- IR lasers and have determined that they are not sufficiently mature to achieve these desired specifications in the near term. At NIMS, we are developing a technology that incorpo- rates an efficient wavelength conversion device for generating mid-IR light by pumping an optical parametric oscillator (OPO) using compact Nd:YAG solid-state lasers. These lasers are the most reliable, most well-developed solid-state pump lasers currently available and are ideally suited for LUT applications. We have already produced quasi-phase matching (QPM) wavelength-conversion devices fabricated from a ferroelectric material, stoichiometric lithium tantalate (LiTaO3, hereafter abbreviated as SLT), by means of the periodic poling (PP) technique. The SLT coercive field (the external electric field necessary for the polarization inversion) can be decreased by more than one order of magnitude compared with conven- tional LiTaO3 crystals by controlling the defect density during crystal growth [5, 6]. This decrease in the coercive field has made it possible to fabricate PPSLT devices [7–9] with apertures as large as 5 mm×5 mm. PPSLT crystals are also resistant to optical laser damage [10]. Both a wide aperture and damage resistance are prerequisites for a wavelength convertor in any mid-IR LUT application. Compact and robust mid-infrared laser light sources in the vicinity of 3.2 μm can be realized by combining PPSLT convertor technology with a solid-state Nd:YAG laser as a pump. The reason why PPMgSLT was adopted as a nonlinear material for the OPO laser instead of another periodically poled crystal is based on the demonstrated large aperture capability (as large as 5 mm×5 mm) needed for high energy per pulse applications and the substantially high laser damage threshold compared with PPLN,PPRTA, PPKTP, etc. In this paper, we describe the system and performance of a mid-IR PPSLT OPO as well as the results of LUT of CFRP material using light generated by the OPO. 2. Experimental methods 2.1. Nonlinear optical material and device for OPO Figure 1 shows a PPSLT OPO using periodically poled MgSLT (1% MgO doped SLT) placed between two plano– Figure 1. Schematic diagram of OPO system using a MgO doped stoichiometric lithium tantalate QPM device with coated simple plano–plano couplers. 2 J. Opt. 17 (2015) 094011 Invited Article
  • 4. plano end mirrors. The QPM grating pitch was designed using equations (1) and (2) below, which describe the energy con- servation and phase matching conditions in a QPM parametric convertor device: 1 1 1 1 p s i ( ) l l l = + n T n T n T1 2 p p s s i i ( ) ( ) ( ) ( ) l l lL = - - where ,pl ,sl ,il and L represent the pump wavelength, signal wavelength, idler wavelength, and QPM grating pitch, respectively. n T ,p ( ) n T ,s ( ) and n Ti ( ) represent the tempera- ture-dependent refractive indices at the pump, signal, and idler. Figure 2 shows the solutions to equations (1) and (2) using the published Sellmeier dispersion equation for SLT [11]. We designed and fabricated two QPM devices with grating pitches of 30.9 μm and 31.1 μm, which correspond to expected idler wavelengths of 3.30 μm and 3.23 μm at 30 °C. The lengths and apertures of these devices were the same (35 mm and 3 mm×3 mm). 2.2. OPO set-up Figure 3 is a schematic diagram of the experimental OPO- LUT system. Two Q-switched multimode Nd:YAG lasers were used as the 1.064 μm pump source. A laser beam was selected by using beam switching optics from either of two laser systems: (a) Quantel/Centurion: designated as Laser-A hereafter and (b) Quantel/Ultra: Laser-B, i.q. We used pump laser pulses with a maximum energy of 40 mJ, a pulse length of 7.8 ns (Laser-A)/9.0 ns (Laser-B) FWHM, and a repetition rate of 20 Hz. The beam had a slightly elliptical top-hat shape with a beam quality measure of M2 ∼15. The pump energy was controlled using a half-wave plate and polarizer, located upstream of the OPO, so that the pulse profile remained independent of the pump energy. The input pump wave was a collimated beam with a diameter of ∼2.5 mm (1/e2 ) at the OPO resonator. The polarization of the pump laser was set parallel to the z axis of the PPMgSLT device. The OPO resonator was a linear cavity with a mirror separation of 100–160 mm. The input and output couplers were coated plane mirrors with the same dielectric coating: high reflectivity at the signal wavelength (1.5–1.6 μm), high transmission at the pump wavelength, and high transmission at the idler wavelength (3.1–3.5 μm). When the signal wavelength was required, the output coupler was replaced with a mirror coated with R=95% at the signal wavelength. The signal and idler waves were first separated from the output light by using a pump-cut filter; then, the idler and signal were separated from each other by a dichroic filter. The idler and signal energy were measured using a power meter with a thermal sensor (Ophir 3A-P). The idler wavelength was measured with a spectrometer consisting of a grating and a pyroelectric sensor array. 2.3. LUT experiments The laser ultrasonic testing system (schematic layout in figure 3) consisted of a pulsed laser for ultrasound generation, a laser Doppler velocimeter (LDV) for ultrasonic measure- ments, and a sample scanning XY stage. Three light sources were used for ultrasound generation: a Laser-B (Quantel/Ultra) Nd:YAG laser (1.064 μm), a PPSLT OPO signal wave (1.59/1.57 μm) and a PPSLT OPO idler wave (3.23/3.30 μm) . It should be noted that two OPO outputs with different wavelength pairs (1.59 μm and 1.57 μm for the signal wave, 3.23 μm and 3.30 μm for the idler wave) were generated from two separate PPSLT QPM gratings (31.1 μm and 30.9 μm, respectively, and at 30 °C). This small wavelength difference has a negligible effect on the generated LUT signals based on the relatively structureless, broad CFRP absorption band. The laser pulse selected by the beam switching device was directed to the surface of the CFRP sample through a lens with a beam diameter of 1.0 mm. The laser pulse interacted with the sample surface to induce an ultrasonic pulse that propagated into the sample. Laminated CFRP plates 1.1 mm thick (O-KEI Resin Co. Ltd, Japan) were used for this investigation. It should be noted that commercially available CFRP plates were produced based on lamination of many thin prepreg sheets with thicknesses in the range of 0.02–0.5 mm. These specially made CFRP plates were carefully produced without any known defects, and, therefore, our LUT was not affected by this process. A commercial LDV system was used as an ultrasonic wave sensor. The system consists of mainly two major parts: (a) a sensor unit (Graphtec AT0023) which includes a helium neon (HeNe) laser light source and a built-in autofocal lens, and (b) an optical heterodyne interferometric signal demo- dulation device (Thamway T1101077A). The HeNe probe beam from the sensor unit was focused onto the CFRP sample with a beam diameter of around 60 μm (1/e2 intensity). The probe laser sensing beam and the ultrasound generation beam were aligned to counterpropagate with respect to each other; these two counterpropagating beams were then carefully aligned to overlap each other on the target material. The probe Figure 2. Calculated OPO emission wavelengths as a function of PPSLT QPM period and crystal temperature. 3 J. Opt. 17 (2015) 094011 Invited Article
  • 5. laser beam reflects off the CFRP surface, is modulated by the ultrasonic soundwave and subsequently interferes with the incident probe beam inside the sensing unit, producing an optical heterodyne interferometric signal. The interferometric signal was then processed and converted to an ultrasonic velocity signal. The ultrasonic velocity signal was analyzed using a 500 MHz oscilloscope (LeCroy). Signal averaging was performed to reduce random noise. We used three scanning methods: (1) A-scan: The temporal response of the ultrasonic signal at a fixed sample point. (2) B-scan: Spatial one-dimensional scanning of the temporal response graphically displayed on a 2D map. (3) C-scan: Spatial two-dimensional scanning of ultrasonic intensity graphically displayed on a 3D map. 3. Results and discussion 3.1. OPO performance The OPO performance was usually obtained using Laser-A (Quantel/Centurion) as a pump. We found no differences in OPO performance when Laser-B (Quantel/Ultra) was used as a pump. Figure 4 compares the theoretical and experimental temperature dependences of the idler wavelength output from the PPSLT OPO. The straight line and the dashed line represent the theoretical results for QPM grating pitches of 30.9 μm and 31.1 μm, respectively. The squares and circles represent the measured data for the samples with grating pitches of 30.9 μm, and 31.1 μm, respectively, and it is clear that they are in good agreement with theory. The M2 of the idler light was estimated to be in the range 15–20 by measuring the propagation of the focused idler beam using a Gaussian beam fitting routine. The idler M2 parameter is strongly dependent on the M2 of the pump wave. figure 5 shows the dependence of the output energy for the 3.23 μm and 3.30 μm idler waves (QPM grating pitches of 31.1 μm and 30.9 μm, respectively) on the input pump energy (input–output property) measured at 30 °C. An OPO Figure 3. Schematic diagram of experimental OPO-LUT system. A fundamental laser path is selected by switchable mirror (M4). The pump beam is energy controlled using a half-wave (λ/2) plate and polarizer, then enters the OPO-resonator. Signal and idler beams are separated from the OPO output by two filters. Lenses L1 and L2 adjust the beam waist at the PP-MgSLT crystal inside the resonator. Lenses L3, L4 and L6 are used to focus the YAG fundamental beam, signal and idler beam onto the CFRP sample for ultrasound generation, respectively. The LUT system consists of a sensor unit and an optical heterodyne interference signal demodulation device. Demodulated ultrasonic velocity signal is observed by oscilloscope synchronizing with the laser repetition frequency. Figure 4. Temperature dependence of idler wavelength: comparison between design and experiment for QPM grating pitches of 30.9 μm and 31.1 μm. The experimentally measured wavelength values show good agreement with theory. 4 J. Opt. 17 (2015) 094011 Invited Article
  • 6. threshold energy of ∼5 mJ and ∼5 mJ for the idler output was obtained for a 35 mJ pump input. Figure 6 shows the dependence of the output energy of idler waves (QPM grating pitches of 31.1 μm) on the input pump energy measured at 50, 100 and 150 °C. 3.2. LUT performance As we previously explained, the LUT performance was characterized using the OPO pumped by Laser-B (Quantel/ Ultra). Figure 7 illustrates a typical temporal ultrasonic waveform (A-scan) measured on a CFRP sample excited by a laser beam with a wavelength of 3.23 μm. The steep negative peak appearing around 0.57 μs from the scale zero point of the horizontal axis (which means the onset of the laser pulse) corresponds to the ultrasonic velocity signal generated at a point on one surface of the CFRP and that propagated on the other surface. To characterize the ultrasound intensity generated by laser irradiation, we define a parameter (param1) by the fol- lowing formula (3). V t t T TParam1 d 3 T T 2 1 1 2 ( )( ) ( )ò= - - Here, V t( ) represents the temporal ultrasonic velocity signal shown in figure 7. T1 and T2 represent the integration interval endpoints, and in this experiment, T1=0.5 μs and T2=0.65 μs. Param1 represents the average voltage of the ultrasonic velocity signal in the integration period. 2D maps of Param1 values were obtained by scanning an area of 10 mm×10 mm of the sample using the ultrasound generation laser at 3.30 μm. The resultant C-scan is shown in figure 8; the bidirectional periodic structure with a cycle of around 2 mm in either direction represents the bidirectional weave of the carbon fibers inside the epoxy matrix (see figure 9). Comparing the C-scan mapping and the CFRP Figure 5. The dependence of the output energy as a function of the input pump energy for the idler 3.23 μm and 3.3 μm waves. The operation temperature is 30 °C. Figure 6. An example of the temperature-dependent input–output properties of the idler using a QPM grating period of 31.1 μm Figure 7. Typical temporal ultrasonic waveform (A-scan) measured in CFRP sample excited by a laser beam with a wavelength of 3.23 μm. A strong negative peak at 0.57 μs from the onset of the exciting laser pulse corresponds to the ultrasonic velocity signal generated at a point on one surface of the CFRP and that propagated on the other surface. Figure 8. Typical example of C-scan plot for CFRP sample. 5 J. Opt. 17 (2015) 094011 Invited Article
  • 7. surface, we can see that more intense ultrasound is generated at parts where the epoxy is exposed on the surface of the CFRP. This result is consistent with the fact that the mid-infrared light is strongly absorbed by the C-H stretching vibration in the –CH2–(O–CH2)– linkage of the epoxy polymer [12]. The thermal expansion of the epoxy resin is considerably larger [13] than the thermal expansion of the carbon fiber, which is close to zero or slightly negative [14]. As a result, very little ultrasound was generated where the carbon fibers were exposed on the surface. Note that the enhancement of ultra- sound generation in the epoxy layer was simulated in [15]. Next, we measured the laser wavelength dependence of the ultrasound generation efficiency in CFRP. To reduce the influence of the structure-dependent generation described above, the ultrasound was generated by scanning a 20 mm length with a pitch of 0.2 mm (B-scan), and the ultrasound parameters (param1) were then averaged over the entire region. The comparison was done using the same area of CFRP. For each wavelength, the laser pulse energy and the beam diameter were held constant at 0.2 mJ and 1.0 mm, respectively. Figure 10 shows the variation of the peak ultrasound intensity along the scanning distance with wave- length as a parameter. The figure shows that 3.23 μm wave- length light has a stronger capability of ultrasonic generation than 1.064 μm (pump) light and 1.57 μm (signal) light. A laser scanning experiment was carried out in order to assess the laser’s damage to a rough CFRP surface. The ultrasound generating laser was scanned in an area measuring 3 mm×3 mm with a step of 0.5 mm (total of 7×7 spots). The irradiation time for each spot was 10 s. The laser energy in the irradiated areas was varied from 0.8 mJ to 2.4 mJ. Figure 11(a) shows photographs of the CFRP sample surface after laser irradiation. Figure 11(b) shows microscope images of the damaged areas. These images were taken at the center of a 2 mm×2 mm area of the CFRP surface. Most of the laser damage occurred in areas where the carbon fibers were exposed on the surface. We can see that the tolerance to damage is highest with the mid-infrared laser at a 3.3 μm wavelength. In particular, this wavelength produces no obvious damage at 0.8 mJ and clearly less damage at higher intensities such as 2.4 mJ. A possible explanation for the reason why tolerance to damage is highest with the mid-infrared laser may come from its lowest photon energy. Irradiation of higher photon energy tends to shift to ablation mode easily. 3.3. LUT applications for CFRP The above results confirm the potential for mid-infrared laser induced ultrasound generation in CFRP. Next, we demon- strate two applications of mid-infrared lasers to LUT detec- tion of flaws in CFRP. The first application is detection of voids. We fabricated a sample of CFRP with a void inside it by bonding two CFRP plates with a thickness of 1.1 mm and with an un-bonded area of 7 mm diameter, as illustrated in figure 12(a). The results of the LUT C-scan are shown in figure 12(b). A nearly null signal can be clearly seen, and it corresponds to the location and size of the void. Figure 13 shows a second application of an LUT C-scan for detecting inhomogeneous adhesion between CFRP and an aluminum plate. Figure 13(a) shows a photograph displaying the inhomogeneous distribution of an adhesive bond (glue) on top of a CFRP plate to which an aluminum plate was bonded. The region where the adhesive bond is missing corresponds to the blue-colored region with a near null signal in the C-scan shown in figure 13(b). Figure 9. (a) Cross section of CFRP sample showing a woven structure of carbon-fiber (CF) bunches. CF bunches and epoxy resin are exposed alternately on the surface. (b) A thin section of CFRP sample with a thickness of 40 μm under an optical microscope. Figure 10. The peak ultrasound intensity variation along the scanning distance with the parameter of exciting laser wavelength. The periodic structure of each curve corresponds to the woven structure of carbon-fiber bunches shown in figure 9(a). 6 J. Opt. 17 (2015) 094011 Invited Article
  • 8. Here, the He-Ne laser sensing beam and the ultrasound generation beam were aligned to counter-propagate with respect to each other. Therefore, the existence of air-gaps, mimicking delamination and voids where the ultrasound cannot penetrate, can be clearly detected. 4. Summary A QPM OPO using periodically poled MgSLT (MgO 1% doped near-stoichiometric LiTaO3) was demonstrated. The OPO, pumped by a 1.064 μm Q-switched Nd:YAG laser, was tuned to the wavelength region 3.2–3.3 μm. This is the most promising regime for LUT of CFRP. An experiment was conducted to evaluate the ultrasound generation efficiencies of laser pulses at three different wavelengths (1.064 μm, 1.59/1.57 μm, and 3.23/3.30 μm) that are emitted from the OPO system. We found that the mid-IR laser at a 3.2–3.3 μm wavelength generated the most efficient and least damaging ultrasonic waves in CFRP. We used mid-IR light in conjunction with a laser inter- ferometer to demonstrate the detection of flaws/defects in CFRP such as the existence of air-gaps that mimic delami- nation and voids in CFRP, and the inhomogeneous adhesion of CFRP material to a metal plate was also clearly detected. Acknowledgements A part of this research was supported by the ‘Cross-minis- terial Strategic Innovation Promotion Program (SIP), Struc- tural Materials for Innovation’ of Japan Science and Technology Agency, JST. We wish to thank S Takekawa and Y Furukawa of OXIDE Corporation for optical crystal fab- rication, Y Fujii of NIMS for CFRP sample preparation, and K Oguchi and M Enoki of the University of Tokyo for valuable discussion about ultrasonic wave propagation. References [1] Green R Jr (ed) 1997 See for example papers, Proc. of the Eighth Int. Symp. on Nondestructive Characterization of Materials: Nondestructive characterization of materials VIII (Boulder, Colorado, June) [2] Dubois M, Lorraine P W, Filkins R J and Drake T E 2001 Appl. Phys. Lett. 79 1813 [3] Dubois M, Lorraine P W, Filkins R J, Drake T E, Yawn K R and Chuang S-Y 2002 Ultrasonics 40 809 Figure 11. (a) Macroscopic photographs of the CFRP sample surfaces after laser irradiation. The dashed square shows the area of scanned irradiation. (b) Microscopic photographs of laser irradiated Figure 12. Results of LUT C-scan of CFRP including void inside: (a) illustration of sample preparation, (b) ultrasound intensity distribu- tion for the CFRP sample. Figure 13. (a) Photograph showing the distribution of adhesive bond (glue) on top of a CFRP plate. An aluminum plate was overlapping on this CFRP plate. (b) C-scan plot for the partially-bonded sample shown above. 7 J. Opt. 17 (2015) 094011 Invited Article
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