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The syllabus is approved for use in England, Wales and Northern Ireland as a Cambridge International Level 1/Level 2 Certificate.
This document consists of 20 printed pages.
IB16 11_0620_21/6RP
© UCLES 2016 [Turn over
*6942475041*
Cambridge International Examinations
Cambridge International General Certificate of Secondary Education
CHEMISTRY 0620/21
Paper 2 Multiple Choice (Extended) October/November 2016
45 minutes
Additional Materials: Multiple Choice Answer Sheet
Soft clean eraser
Soft pencil (type B or HB is recommended)
READ THESE INSTRUCTIONS FIRST
Write in soft pencil.
Do not use staples, paper clips, glue or correction fluid.
Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless
this has been done for you.
DO NOT WRITE IN ANY BARCODES.
There are forty questions on this paper. Answer all questions. For each question there are four possible
answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet.
Read the instructions on the Answer Sheet very carefully.
Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is printed on page 20.
Electronic calculators may be used.
2
© UCLES 2016 0620/21/O/N/16
1 ‘Particles moving very slowly from an area of higher concentration to an area of lower
concentration.’
Which process is being described?
A a liquid being frozen
B a solid melting
C a substance diffusing through a liquid
D a substance diffusing through the air
2 A student mixes 25cm3
samples of dilute hydrochloric acid with different volumes of aqueous
sodium hydroxide.
In each case, the student measures the change in temperature to test if the reaction is
exothermic.
Which piece of apparatus is not needed?
burette clock pipette thermometer
A B C D
3
© UCLES 2016 0620/21/O/N/16 [Turn over
3 Information about the solubility of four solids, P, Q, R and S, is given in the table.
P Q R S
solubility in water dissolves insoluble insoluble dissolves
A student attempted to separate mixtures of these solids using the following method.
1 Add the mixture to a beaker of water and stir.
2 Filter the mixture.
3 Crystallise one of the solids from the filtrate.
Which of the following mixtures could not be separated by this method?
A a mixture of P and R
B a mixture of Q and P
C a mixture of Q and R
D a mixture of R and S
4 The table shows information about atoms of three different elements.
element
proton
number
nucleon
number
number of
protons
number of
neutrons
number of
electrons
chlorine 17 35 17 W 17
chlorine 17 X 17 19 17
argon Y 40 18 22 18
potassium 19 39 19 20 Z
What are the values of W, X, Y and Z?
W X Y Z
A 18 35 18 19
B 18 36 18 19
C 19 35 19 18
D 19 36 19 18
4
© UCLES 2016 0620/21/O/N/16
5 Metal P reacts with non-metal Q to form a compound.
Which process takes place and which type of compound is formed?
process type of compound
A electrons are transferred from P to Q covalent
B electrons are transferred from P to Q ionic
C electrons are transferred from Q to P covalent
D electrons are transferred from Q to P ionic
6 The structure of ethanoic acid is shown.
C
O
O H
H C
H
H
Which diagram shows the arrangement of outer shell electrons in a molecule of ethanoic acid?
C
H
H
H
O
O
H C
A
C
H
H
H
O
O
H C
B
C
H
H
H
O
O
H C
C
C
H
H
H
O
O
H C
D
5
© UCLES 2016 0620/21/O/N/16 [Turn over
7 X is a solid at room temperature.
X has a high melting point.
Solid X conducts electricity.
Which diagram shows how the particles are arranged in solid X?
+ +
+ +
+
+ + +
–
+
–
+
–
+
–
+
–
+
–
+
–
+
–
+
–
+
BA DC
–
–
–
–
– –
––
–
8 Benzene is a liquid with molecular formula C6H6.
Ethene is a gas with molecular formula C2H4.
Which statement is correct?
A 1 mole of benzene and 1 mole of ethene contain the same number of atoms.
B 1 mole of benzene and 1 mole of ethene both have a volume of 24dm3
at room temperature
and pressure.
C Both benzene and ethene have the same empirical formula.
D The number of carbon atoms in 0.5 moles of ethene is equal to the Avogadro constant.
9 Sodium hydrogencarbonate undergoes thermal decomposition as shown.
2NaHCO3 → Na2CO3 + CO2 + H2O
What is the maximum mass of sodium carbonate that can be made from 0.100 moles of
sodium hydrogencarbonate?
A 4.15g B 5.30g C 10.6g D 21.2g
6
© UCLES 2016 0620/21/O/N/16
10 Which apparatus could be used to electroplate an iron nail with copper?
+ –
A
+ –
B
+ –
C D
aqueous copper(II) sulfate
aqueous iron(II) sulfate
+ –
key
= copper sheet
= iron nail
7
© UCLES 2016 0620/21/O/N/16 [Turn over
11 The diagram shows a simple cell.
electrolyte
metal Ymetal X
voltmeter
V
Which two metals produce the highest reading on the voltmeter?
X Y
A magnesium copper
B magnesium iron
C zinc copper
D zinc iron
12 When anhydrous copper(II) sulfate is added to water a solution is formed and heat is given out.
water
anhydrous
copper(II) sulfate
thermometer
Which row shows the temperature change and the type of reaction taking place?
temperature change type of reaction
A decrease endothermic
B decrease exothermic
C increase endothermic
D increase exothermic
8
© UCLES 2016 0620/21/O/N/16
13 The energy level diagram for a reaction is shown.
energy products
reactants
Ea
ΔH
Which statement is not correct for this energy level diagram?
A It could be the energy level diagram for the reaction when petrol is burnt.
B Less energy is released in bond forming than is needed for bond breaking.
C The activation energy, Ea, has a positive value.
D The energy change, ∆H, for the reaction is positive.
9
© UCLES 2016 0620/21/O/N/16 [Turn over
14 The rate of reaction between magnesium and excess dilute hydrochloric acid was followed by
measuring the mass of magnesium present at regular time intervals.
Two experiments were performed.
Both experiments used 0.1g of magnesium ribbon. The acid in experiment 1 was less
concentrated than in experiment 2.
Which graph shows the results of the experiments?
A
mass of
magnesium
time
C
mass of
magnesium
time
1
2
2
1
B
mass of
magnesium
time
D
0
0
0
0
0
0
0
0
mass of
magnesium
time
2
1
1
2
15 Which statement explains why coal dust forms an explosive mixture with air?
A Coal dust catalyses the explosion.
B Coal dust has a large surface area.
C Crushing coal increases the concentration of the coal.
D Crushing coal increases the temperature of the coal.
10
© UCLES 2016 0620/21/O/N/16
16 The following reversible reaction takes place in a closed vessel at constant temperature.
P(g) + Q(g) + R(g) S(g) + T(g)
When the system has reached equilibrium, more T is added.
After the addition of T, which substances increase in concentration?
A P, Q, R and S
B P and Q only
C P, Q and R only
D S only
17 Four ionic half-equations are shown.
1 Cu2+
(aq) + 2e–
→ Cu(s)
2 2I–
(aq) → I2(aq) + 2e–
3 Fe2+
(aq) → Fe3+
(aq) + e–
4 Cl2(g) + 2e–
→ 2Cl–
(aq)
Which statement is correct?
A In equation 1, copper(II) ions are oxidised to copper.
B In equation 2, iodide ions are reduced to iodine.
C In equation 3, iron(II) ions are oxidised to iron(III) ions.
D In equation 4, chlorine is oxidised to chloride ions.
18 Germanium oxide is a white powder.
Germanium oxide reacts with concentrated hydrochloric acid.
Germanium oxide reacts with concentrated aqueous sodium hydroxide.
Germanium oxide does not dissolve when added to water.
Which type of oxide is germanium oxide?
A acidic
B amphoteric
C basic
D neutral
11
© UCLES 2016 0620/21/O/N/16 [Turn over
19 Hydrogen chloride gas reacts with water to produce an acidic solution. The equation for the
reaction is shown.
HCl + H2O → Cl–
+ H3O+
Which statement describes what happens during the reaction?
A The chloride ion is formed by accepting an electron from the water.
B The hydrogen chloride loses an electron to form the chloride ion.
C The water accepts a proton from the hydrogen chloride.
D The water donates a proton to the hydrogen chloride.
20 The apparatus shown is used to prepare aqueous copper(II) sulfate.
Y
stirrer
solid X
aqueous
copper(II) sulfate
excess of solid X
filter paper
heat
What are X and Y?
X Y
A copper aqueous iron(II) sulfate
B copper(II) chloride sulfuric acid
C copper(II) oxide sulfuric acid
D sulfur aqueous copper(II) chloride
12
© UCLES 2016 0620/21/O/N/16
21 Information about some silver compounds is shown in the table.
compound formula solubility in water
silver carbonate Ag2CO3 insoluble
silver chloride AgCl insoluble
silver nitrate AgNO3 soluble
silver oxide Ag2O insoluble
Which equation shows a reaction which cannot be used to make a silver salt?
A AgNO3(aq) + HCl(aq) → AgCl(s) + HNO3(aq)
B Ag2O(s) + 2HNO3(aq) → 2AgNO3(aq) + H2O(l)
C Ag2CO3(s) + 2HNO3(aq) → 2AgNO3(aq) + H2O(l) + CO2(g)
D 2Ag(s) + 2HCl(aq) → 2AgCl(s) + H2(g)
22 What is not a property of Group I metals?
A They are soft and can be cut with a knife.
B They react when exposed to oxygen in the air.
C They produce an acidic solution when they react with water.
D They react rapidly with water producing hydrogen gas.
13
© UCLES 2016 0620/21/O/N/16 [Turn over
23 Four substances, P, Q, R and S, are tested as shown.
test
substance
P Q R S
dilute hydrochloric
acid added
gas given off
which ‘pops’ with
a lighted splint
gas given off
which turns
limewater milky
no reaction no reaction
dilute aqueous
sodium hydroxide
added and
warmed gently
no reaction no reaction
gas given off
which turns
damp, red litmus
paper blue
no reaction
What are P, Q, R and S?
P Q R S
A Mg Na2CO3 NH4Cl NaCl
B Mg NH4Cl Na2CO3 NaCl
C Mg Na2CO3 NaCl NH4Cl
D Na2CO3 Mg NaCl NH4Cl
24 Which statement about transition elements and their compounds is correct?
A All the transition elements have an oxidation state of +2 only.
B Aqueous solutions of the salts of transition elements are generally coloured.
C Transition elements change from metal to non-metal across the period.
D Transition elements can act as catalysts but their compounds cannot.
14
© UCLES 2016 0620/21/O/N/16
25 Impure iron from the blast furnace is converted to steel as shown.
oxygen
impure molten iron
Which statement about the process is correct?
A Acidic oxides are added to remove alkaline impurities.
B Coke is added as a reducing agent.
C Oxygen is blown in to oxidise the impure iron.
D The steel produced contains less carbon than the impure iron.
26 The ionic equations represent the reactions between four metals, P, Q, R and S, and solutions of
the salts of the same metals.
P + Q2+
→ no reaction
R + P2+
→ R2+
+ P
Q + S2+
→ Q2+
+ S
S + P2+
→ S2+
+ P
S + R2+
→ S2+
+ R
S + Q2+
→ no reaction
What is the correct order of reactivity of the metals?
most least
A P R S Q
B Q R S P
C Q S R P
D S Q P R
15
© UCLES 2016 0620/21/O/N/16 [Turn over
27 Aluminium is extracted by electrolysis.
From which ore is aluminium extracted and at which electrode is aluminium deposited during
electrolysis?
ore electrode
A bauxite negative
B bauxite positive
C cryolite negative
D cryolite positive
28 Zinc oxide can be reacted with carbon to produce zinc metal.
Which equation for this reaction is correct?
A 2ZnO + C → 2Zn + CO
B 2ZnO + 2C → 2Zn + 2CO2
C ZnO + C → Zn + CO
D ZnO + 2C → Zn + 2CO2
29 Air is a mixture of gases.
Which gas is present in the largest amount?
A argon
B carbon dioxide
C nitrogen
D oxygen
30 Which information about carbon dioxide and methane is correct?
carbon dioxide methane
A formed when vegetation decomposes   key
B greenhouse gas    = true
C present in unpolluted air    = false
D produced during respiration
16
© UCLES 2016 0620/21/O/N/16
31 Underwater steel pipes can be protected from corrosion by attaching magnesium blocks to them.
Which equation represents the reaction that prevents corrosion?
A Fe → Fe2+
+ 2e–
B Fe2+
→ Fe3+
+ e–
C Mg → Mg2+
+ 2e–
D Mg2+
+ 2e–
→ Mg
32 Ammonia is manufactured by the Haber process. The reaction is exothermic.
N2(g) + 3H2(g) 2NH3(g) ∆H = –92kJ/mol
Which statement about the Haber process is correct?
A The reaction is irreversible and produces only one product.
B The reaction is reversible and produces less ammonia at high pressure.
C The reaction is reversible and produces less ammonia at high temperature.
D The reaction is slow because a catalyst is not used in the Haber process.
33 Sulfuric acid is manufactured by the Contact process.
The most important reaction takes place in the presence of a catalyst.
What are the reactants and the catalyst for this reaction?
reactants catalyst
A sulfur and oxygen vanadium(V) oxide
B sulfur dioxide and oxygen vanadium(V) oxide
C sulfur dioxide and steam iron
D sulfur trioxide and water platinum
17
© UCLES 2016 0620/21/O/N/16 [Turn over
34 Which box corresponds to limestone?
Does limestone contain carbon?
yes no
yes no
Does limestone burn? Does limestone burn?
A B
yes no
C D
35 Petroleum is an important fossil fuel.
Which row correctly describes petroleum?
type of substance composition
A compound mainly hydrocarbons
B compound only hydrogen and carbon
C mixture mainly hydrocarbons
D mixture only hydrogen and carbon
36 Butane reacts as shown.
butane butene + hydrogen
catalyst
and heat
What is this type of reaction?
A combustion
B cracking
C polymerisation
D reduction
18
© UCLES 2016 0620/21/O/N/16
37 Substance Z has the following characteristics.
1 It burns in an excess of oxygen to form carbon dioxide and water.
2 It is oxidised by air to form a liquid smelling of vinegar.
3 It reacts with carboxylic acids to form esters.
What is substance Z?
A ethane
B ethanoic acid
C ethanol
D ethyl ethanoate
38 Ethanol is manufactured by the catalytic addition of steam to ethene and by fermentation.
Which row shows an advantage and a disadvantage of using the catalytic addition of steam to
ethene compared to fermentation?
advantage disadvantage
A fast the product is impure
B fast uses non-renewable materials
C the product is pure slow
D uses renewable materials slow
39 The partial structure of addition polymer X is shown.
C
CH3
H
C
H
CH3
C
CH3
H
C
H
CH3
Which monomer is used to form polymer X?
A CH2=CH2
B CH3CH=CH2
C CH3CH=CHCH3
D CH3CH2CH=CH2
19
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
International Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at
www.cie.org.uk after the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
© UCLES 2016 0620/21/O/N/16
40 The diagram shows the partial structure of Terylene.
C
O
C C
OO
O O O
From which pair of compounds is it made?
C
O
C
O
HO OHHO OH
+C
O
C
O
HO OH
C
O
C
O
HO OH C
O
C
O
HO OH
HO OHA
C
O
HO OH + C
O
HO OHB
+C
+D
20
© UCLES 2016 0620/21/O/N/16
Group
ThePeriodicTableofElements
1
H
hydrogen
1
2
He
helium
4
IIIIIIIVVVIVIIVIII
3
Li
lithium
7
4
Be
beryllium
9
atomicnumber
atomicsymbol
Key
name
relativeatomicmass
11
Na
sodium
23
12
Mg
magnesium
24
19
K
potassium
39
20
Ca
calcium
40
37
Rb
rubidium
85
38
Sr
strontium
88
55
Cs
caesium
133
56
Ba
barium
137
87
Fr
francium
–
88
Ra
radium
–
5
B
boron
11
13
Al
aluminium
27
31
Ga
gallium
70
49
In
indium
115
81
Tl
thallium
204
6
C
carbon
12
14
Si
silicon
28
32
Ge
germanium
73
50
Sn
tin
119
82
Pb
lead
207
22
Ti
titanium
48
40
Zr
zirconium
91
72
Hf
hafnium
178
104
Rf
rutherfordium
–
23
V
vanadium
51
41
Nb
niobium
93
73
Ta
tantalum
181
105
Db
dubnium
–
24
Cr
chromium
52
42
Mo
molybdenum
96
74
W
tungsten
184
106
Sg
seaborgium
–
25
Mn
manganese
55
43
Tc
technetium
–
75
Re
rhenium
186
107
Bh
bohrium
–
26
Fe
iron
56
44
Ru
ruthenium
101
76
Os
osmium
190
108
Hs
hassium
–
27
Co
cobalt
59
45
Rh
rhodium
103
77
Ir
iridium
192
109
Mt
meitnerium
–
28
Ni
nickel
59
46
Pd
palladium
106
78
Pt
platinum
195
110
Ds
darmstadtium
–
29
Cu
copper
64
47
Ag
silver
108
79
Au
gold
197
111
Rg
roentgenium
–
30
Zn
zinc
65
48
Cd
cadmium
112
80
Hg
mercury
201
112
Cn
copernicium
–
114
Fl
flerovium
–
116
Lv
livermorium
–
7
N
nitrogen
14
15
P
phosphorus
31
33
As
arsenic
75
51
Sb
antimony
122
83
Bi
bismuth
209
8
O
oxygen
16
16
S
sulfur
32
34
Se
selenium
79
52
Te
tellurium
128
84
Po
polonium
–
9
F
fluorine
19
17
Cl
chlorine
35.5
35
Br
bromine
80
53
I
iodine
127
85
At
astatine
–
10
Ne
neon
20
18
Ar
argon
40
36
Kr
krypton
84
54
Xe
xenon
131
86
Rn
radon
–
21
Sc
scandium
45
39
Y
yttrium
89
57–71
lanthanoids
89–103
actinoids
57
La
lanthanum
139
89
Ac
lanthanoids
actinoids
Thevolumeofonemoleofanygasis24dm3
atroomtemperatureandpressure(r.t.p.)
actinium
–
58
Ce
cerium
140
90
Th
thorium
232
59
Pr
praseodymium
141
91
Pa
protactinium
231
60
Nd
neodymium
144
92
U
uranium
238
61
Pm
promethium
–
93
Np
neptunium
–
62
Sm
samarium
150
94
Pu
plutonium
–
63
Eu
europium
152
95
Am
americium
–
64
Gd
gadolinium
157
96
Cm
curium
–
65
Tb
terbium
159
97
Bk
berkelium
–
66
Dy
dysprosium
163
98
Cf
californium
–
67
Ho
holmium
165
99
Es
einsteinium
–
68
Er
erbium
167
100
Fm
fermium
–
69
Tm
thulium
169
101
Md
mendelevium
–
70
Yb
ytterbium
173
102
No
nobelium
–
71
Lu
lutetium
175
103
Lr
lawrencium
–

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0620 w16 qp_21

  • 1. The syllabus is approved for use in England, Wales and Northern Ireland as a Cambridge International Level 1/Level 2 Certificate. This document consists of 20 printed pages. IB16 11_0620_21/6RP © UCLES 2016 [Turn over *6942475041* Cambridge International Examinations Cambridge International General Certificate of Secondary Education CHEMISTRY 0620/21 Paper 2 Multiple Choice (Extended) October/November 2016 45 minutes Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended) READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. DO NOT WRITE IN ANY BARCODES. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 20. Electronic calculators may be used.
  • 2. 2 © UCLES 2016 0620/21/O/N/16 1 ‘Particles moving very slowly from an area of higher concentration to an area of lower concentration.’ Which process is being described? A a liquid being frozen B a solid melting C a substance diffusing through a liquid D a substance diffusing through the air 2 A student mixes 25cm3 samples of dilute hydrochloric acid with different volumes of aqueous sodium hydroxide. In each case, the student measures the change in temperature to test if the reaction is exothermic. Which piece of apparatus is not needed? burette clock pipette thermometer A B C D
  • 3. 3 © UCLES 2016 0620/21/O/N/16 [Turn over 3 Information about the solubility of four solids, P, Q, R and S, is given in the table. P Q R S solubility in water dissolves insoluble insoluble dissolves A student attempted to separate mixtures of these solids using the following method. 1 Add the mixture to a beaker of water and stir. 2 Filter the mixture. 3 Crystallise one of the solids from the filtrate. Which of the following mixtures could not be separated by this method? A a mixture of P and R B a mixture of Q and P C a mixture of Q and R D a mixture of R and S 4 The table shows information about atoms of three different elements. element proton number nucleon number number of protons number of neutrons number of electrons chlorine 17 35 17 W 17 chlorine 17 X 17 19 17 argon Y 40 18 22 18 potassium 19 39 19 20 Z What are the values of W, X, Y and Z? W X Y Z A 18 35 18 19 B 18 36 18 19 C 19 35 19 18 D 19 36 19 18
  • 4. 4 © UCLES 2016 0620/21/O/N/16 5 Metal P reacts with non-metal Q to form a compound. Which process takes place and which type of compound is formed? process type of compound A electrons are transferred from P to Q covalent B electrons are transferred from P to Q ionic C electrons are transferred from Q to P covalent D electrons are transferred from Q to P ionic 6 The structure of ethanoic acid is shown. C O O H H C H H Which diagram shows the arrangement of outer shell electrons in a molecule of ethanoic acid? C H H H O O H C A C H H H O O H C B C H H H O O H C C C H H H O O H C D
  • 5. 5 © UCLES 2016 0620/21/O/N/16 [Turn over 7 X is a solid at room temperature. X has a high melting point. Solid X conducts electricity. Which diagram shows how the particles are arranged in solid X? + + + + + + + + – + – + – + – + – + – + – + – + – + BA DC – – – – – – –– – 8 Benzene is a liquid with molecular formula C6H6. Ethene is a gas with molecular formula C2H4. Which statement is correct? A 1 mole of benzene and 1 mole of ethene contain the same number of atoms. B 1 mole of benzene and 1 mole of ethene both have a volume of 24dm3 at room temperature and pressure. C Both benzene and ethene have the same empirical formula. D The number of carbon atoms in 0.5 moles of ethene is equal to the Avogadro constant. 9 Sodium hydrogencarbonate undergoes thermal decomposition as shown. 2NaHCO3 → Na2CO3 + CO2 + H2O What is the maximum mass of sodium carbonate that can be made from 0.100 moles of sodium hydrogencarbonate? A 4.15g B 5.30g C 10.6g D 21.2g
  • 6. 6 © UCLES 2016 0620/21/O/N/16 10 Which apparatus could be used to electroplate an iron nail with copper? + – A + – B + – C D aqueous copper(II) sulfate aqueous iron(II) sulfate + – key = copper sheet = iron nail
  • 7. 7 © UCLES 2016 0620/21/O/N/16 [Turn over 11 The diagram shows a simple cell. electrolyte metal Ymetal X voltmeter V Which two metals produce the highest reading on the voltmeter? X Y A magnesium copper B magnesium iron C zinc copper D zinc iron 12 When anhydrous copper(II) sulfate is added to water a solution is formed and heat is given out. water anhydrous copper(II) sulfate thermometer Which row shows the temperature change and the type of reaction taking place? temperature change type of reaction A decrease endothermic B decrease exothermic C increase endothermic D increase exothermic
  • 8. 8 © UCLES 2016 0620/21/O/N/16 13 The energy level diagram for a reaction is shown. energy products reactants Ea ΔH Which statement is not correct for this energy level diagram? A It could be the energy level diagram for the reaction when petrol is burnt. B Less energy is released in bond forming than is needed for bond breaking. C The activation energy, Ea, has a positive value. D The energy change, ∆H, for the reaction is positive.
  • 9. 9 © UCLES 2016 0620/21/O/N/16 [Turn over 14 The rate of reaction between magnesium and excess dilute hydrochloric acid was followed by measuring the mass of magnesium present at regular time intervals. Two experiments were performed. Both experiments used 0.1g of magnesium ribbon. The acid in experiment 1 was less concentrated than in experiment 2. Which graph shows the results of the experiments? A mass of magnesium time C mass of magnesium time 1 2 2 1 B mass of magnesium time D 0 0 0 0 0 0 0 0 mass of magnesium time 2 1 1 2 15 Which statement explains why coal dust forms an explosive mixture with air? A Coal dust catalyses the explosion. B Coal dust has a large surface area. C Crushing coal increases the concentration of the coal. D Crushing coal increases the temperature of the coal.
  • 10. 10 © UCLES 2016 0620/21/O/N/16 16 The following reversible reaction takes place in a closed vessel at constant temperature. P(g) + Q(g) + R(g) S(g) + T(g) When the system has reached equilibrium, more T is added. After the addition of T, which substances increase in concentration? A P, Q, R and S B P and Q only C P, Q and R only D S only 17 Four ionic half-equations are shown. 1 Cu2+ (aq) + 2e– → Cu(s) 2 2I– (aq) → I2(aq) + 2e– 3 Fe2+ (aq) → Fe3+ (aq) + e– 4 Cl2(g) + 2e– → 2Cl– (aq) Which statement is correct? A In equation 1, copper(II) ions are oxidised to copper. B In equation 2, iodide ions are reduced to iodine. C In equation 3, iron(II) ions are oxidised to iron(III) ions. D In equation 4, chlorine is oxidised to chloride ions. 18 Germanium oxide is a white powder. Germanium oxide reacts with concentrated hydrochloric acid. Germanium oxide reacts with concentrated aqueous sodium hydroxide. Germanium oxide does not dissolve when added to water. Which type of oxide is germanium oxide? A acidic B amphoteric C basic D neutral
  • 11. 11 © UCLES 2016 0620/21/O/N/16 [Turn over 19 Hydrogen chloride gas reacts with water to produce an acidic solution. The equation for the reaction is shown. HCl + H2O → Cl– + H3O+ Which statement describes what happens during the reaction? A The chloride ion is formed by accepting an electron from the water. B The hydrogen chloride loses an electron to form the chloride ion. C The water accepts a proton from the hydrogen chloride. D The water donates a proton to the hydrogen chloride. 20 The apparatus shown is used to prepare aqueous copper(II) sulfate. Y stirrer solid X aqueous copper(II) sulfate excess of solid X filter paper heat What are X and Y? X Y A copper aqueous iron(II) sulfate B copper(II) chloride sulfuric acid C copper(II) oxide sulfuric acid D sulfur aqueous copper(II) chloride
  • 12. 12 © UCLES 2016 0620/21/O/N/16 21 Information about some silver compounds is shown in the table. compound formula solubility in water silver carbonate Ag2CO3 insoluble silver chloride AgCl insoluble silver nitrate AgNO3 soluble silver oxide Ag2O insoluble Which equation shows a reaction which cannot be used to make a silver salt? A AgNO3(aq) + HCl(aq) → AgCl(s) + HNO3(aq) B Ag2O(s) + 2HNO3(aq) → 2AgNO3(aq) + H2O(l) C Ag2CO3(s) + 2HNO3(aq) → 2AgNO3(aq) + H2O(l) + CO2(g) D 2Ag(s) + 2HCl(aq) → 2AgCl(s) + H2(g) 22 What is not a property of Group I metals? A They are soft and can be cut with a knife. B They react when exposed to oxygen in the air. C They produce an acidic solution when they react with water. D They react rapidly with water producing hydrogen gas.
  • 13. 13 © UCLES 2016 0620/21/O/N/16 [Turn over 23 Four substances, P, Q, R and S, are tested as shown. test substance P Q R S dilute hydrochloric acid added gas given off which ‘pops’ with a lighted splint gas given off which turns limewater milky no reaction no reaction dilute aqueous sodium hydroxide added and warmed gently no reaction no reaction gas given off which turns damp, red litmus paper blue no reaction What are P, Q, R and S? P Q R S A Mg Na2CO3 NH4Cl NaCl B Mg NH4Cl Na2CO3 NaCl C Mg Na2CO3 NaCl NH4Cl D Na2CO3 Mg NaCl NH4Cl 24 Which statement about transition elements and their compounds is correct? A All the transition elements have an oxidation state of +2 only. B Aqueous solutions of the salts of transition elements are generally coloured. C Transition elements change from metal to non-metal across the period. D Transition elements can act as catalysts but their compounds cannot.
  • 14. 14 © UCLES 2016 0620/21/O/N/16 25 Impure iron from the blast furnace is converted to steel as shown. oxygen impure molten iron Which statement about the process is correct? A Acidic oxides are added to remove alkaline impurities. B Coke is added as a reducing agent. C Oxygen is blown in to oxidise the impure iron. D The steel produced contains less carbon than the impure iron. 26 The ionic equations represent the reactions between four metals, P, Q, R and S, and solutions of the salts of the same metals. P + Q2+ → no reaction R + P2+ → R2+ + P Q + S2+ → Q2+ + S S + P2+ → S2+ + P S + R2+ → S2+ + R S + Q2+ → no reaction What is the correct order of reactivity of the metals? most least A P R S Q B Q R S P C Q S R P D S Q P R
  • 15. 15 © UCLES 2016 0620/21/O/N/16 [Turn over 27 Aluminium is extracted by electrolysis. From which ore is aluminium extracted and at which electrode is aluminium deposited during electrolysis? ore electrode A bauxite negative B bauxite positive C cryolite negative D cryolite positive 28 Zinc oxide can be reacted with carbon to produce zinc metal. Which equation for this reaction is correct? A 2ZnO + C → 2Zn + CO B 2ZnO + 2C → 2Zn + 2CO2 C ZnO + C → Zn + CO D ZnO + 2C → Zn + 2CO2 29 Air is a mixture of gases. Which gas is present in the largest amount? A argon B carbon dioxide C nitrogen D oxygen 30 Which information about carbon dioxide and methane is correct? carbon dioxide methane A formed when vegetation decomposes key B greenhouse gas = true C present in unpolluted air = false D produced during respiration
  • 16. 16 © UCLES 2016 0620/21/O/N/16 31 Underwater steel pipes can be protected from corrosion by attaching magnesium blocks to them. Which equation represents the reaction that prevents corrosion? A Fe → Fe2+ + 2e– B Fe2+ → Fe3+ + e– C Mg → Mg2+ + 2e– D Mg2+ + 2e– → Mg 32 Ammonia is manufactured by the Haber process. The reaction is exothermic. N2(g) + 3H2(g) 2NH3(g) ∆H = –92kJ/mol Which statement about the Haber process is correct? A The reaction is irreversible and produces only one product. B The reaction is reversible and produces less ammonia at high pressure. C The reaction is reversible and produces less ammonia at high temperature. D The reaction is slow because a catalyst is not used in the Haber process. 33 Sulfuric acid is manufactured by the Contact process. The most important reaction takes place in the presence of a catalyst. What are the reactants and the catalyst for this reaction? reactants catalyst A sulfur and oxygen vanadium(V) oxide B sulfur dioxide and oxygen vanadium(V) oxide C sulfur dioxide and steam iron D sulfur trioxide and water platinum
  • 17. 17 © UCLES 2016 0620/21/O/N/16 [Turn over 34 Which box corresponds to limestone? Does limestone contain carbon? yes no yes no Does limestone burn? Does limestone burn? A B yes no C D 35 Petroleum is an important fossil fuel. Which row correctly describes petroleum? type of substance composition A compound mainly hydrocarbons B compound only hydrogen and carbon C mixture mainly hydrocarbons D mixture only hydrogen and carbon 36 Butane reacts as shown. butane butene + hydrogen catalyst and heat What is this type of reaction? A combustion B cracking C polymerisation D reduction
  • 18. 18 © UCLES 2016 0620/21/O/N/16 37 Substance Z has the following characteristics. 1 It burns in an excess of oxygen to form carbon dioxide and water. 2 It is oxidised by air to form a liquid smelling of vinegar. 3 It reacts with carboxylic acids to form esters. What is substance Z? A ethane B ethanoic acid C ethanol D ethyl ethanoate 38 Ethanol is manufactured by the catalytic addition of steam to ethene and by fermentation. Which row shows an advantage and a disadvantage of using the catalytic addition of steam to ethene compared to fermentation? advantage disadvantage A fast the product is impure B fast uses non-renewable materials C the product is pure slow D uses renewable materials slow 39 The partial structure of addition polymer X is shown. C CH3 H C H CH3 C CH3 H C H CH3 Which monomer is used to form polymer X? A CH2=CH2 B CH3CH=CH2 C CH3CH=CHCH3 D CH3CH2CH=CH2
  • 19. 19 Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after the live examination series. Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge. © UCLES 2016 0620/21/O/N/16 40 The diagram shows the partial structure of Terylene. C O C C OO O O O From which pair of compounds is it made? C O C O HO OHHO OH +C O C O HO OH C O C O HO OH C O C O HO OH HO OHA C O HO OH + C O HO OHB +C +D
  • 20. 20 © UCLES 2016 0620/21/O/N/16 Group ThePeriodicTableofElements 1 H hydrogen 1 2 He helium 4 IIIIIIIVVVIVIIVIII 3 Li lithium 7 4 Be beryllium 9 atomicnumber atomicsymbol Key name relativeatomicmass 11 Na sodium 23 12 Mg magnesium 24 19 K potassium 39 20 Ca calcium 40 37 Rb rubidium 85 38 Sr strontium 88 55 Cs caesium 133 56 Ba barium 137 87 Fr francium – 88 Ra radium – 5 B boron 11 13 Al aluminium 27 31 Ga gallium 70 49 In indium 115 81 Tl thallium 204 6 C carbon 12 14 Si silicon 28 32 Ge germanium 73 50 Sn tin 119 82 Pb lead 207 22 Ti titanium 48 40 Zr zirconium 91 72 Hf hafnium 178 104 Rf rutherfordium – 23 V vanadium 51 41 Nb niobium 93 73 Ta tantalum 181 105 Db dubnium – 24 Cr chromium 52 42 Mo molybdenum 96 74 W tungsten 184 106 Sg seaborgium – 25 Mn manganese 55 43 Tc technetium – 75 Re rhenium 186 107 Bh bohrium – 26 Fe iron 56 44 Ru ruthenium 101 76 Os osmium 190 108 Hs hassium – 27 Co cobalt 59 45 Rh rhodium 103 77 Ir iridium 192 109 Mt meitnerium – 28 Ni nickel 59 46 Pd palladium 106 78 Pt platinum 195 110 Ds darmstadtium – 29 Cu copper 64 47 Ag silver 108 79 Au gold 197 111 Rg roentgenium – 30 Zn zinc 65 48 Cd cadmium 112 80 Hg mercury 201 112 Cn copernicium – 114 Fl flerovium – 116 Lv livermorium – 7 N nitrogen 14 15 P phosphorus 31 33 As arsenic 75 51 Sb antimony 122 83 Bi bismuth 209 8 O oxygen 16 16 S sulfur 32 34 Se selenium 79 52 Te tellurium 128 84 Po polonium – 9 F fluorine 19 17 Cl chlorine 35.5 35 Br bromine 80 53 I iodine 127 85 At astatine – 10 Ne neon 20 18 Ar argon 40 36 Kr krypton 84 54 Xe xenon 131 86 Rn radon – 21 Sc scandium 45 39 Y yttrium 89 57–71 lanthanoids 89–103 actinoids 57 La lanthanum 139 89 Ac lanthanoids actinoids Thevolumeofonemoleofanygasis24dm3 atroomtemperatureandpressure(r.t.p.) actinium – 58 Ce cerium 140 90 Th thorium 232 59 Pr praseodymium 141 91 Pa protactinium 231 60 Nd neodymium 144 92 U uranium 238 61 Pm promethium – 93 Np neptunium – 62 Sm samarium 150 94 Pu plutonium – 63 Eu europium 152 95 Am americium – 64 Gd gadolinium 157 96 Cm curium – 65 Tb terbium 159 97 Bk berkelium – 66 Dy dysprosium 163 98 Cf californium – 67 Ho holmium 165 99 Es einsteinium – 68 Er erbium 167 100 Fm fermium – 69 Tm thulium 169 101 Md mendelevium – 70 Yb ytterbium 173 102 No nobelium – 71 Lu lutetium 175 103 Lr lawrencium –