This document discusses intermetallic materials, materials for cryogenic and space environments, and evaluation of materials for extreme conditions. It provides details on intermetallic compounds, including that they are generally hard and brittle but can have good high-temperature properties. Intermetallics exhibit a mix of metallic and ceramic properties and have applications in areas like batteries, superalloys, and microelectronics. The document also introduces materials for cryogenic use, extreme environments, and metallic foams, which have gas-filled pores and can be open-celled or closed-celled.
Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...
Materials for Extreme Environments & Intermetallics
1. Inter-Metallics,
Materials for cryogenic application,
Materials for space environment,
Evaluation of materials for extreme environment,
Introduction to metallic foams
2.
3. • An Intermetallic is a type of metallic alloy that forms an ordered solid-state
compound between two or more metallic elements.
• also called an Intermetallic compound, Intermetallic alloy, ordered Intermetallic
alloy, and a long-range-ordered alloy
• Intermetallic are generally hard and brittle, with good high-temperature
mechanical properties
They can be classified as
stoichiometric or nonstoichiometic
Intermetallic compounds
• Although the term "Intermetallic compounds", as it applies to solid phases, has
been in use for many years, its introduction was regretted, for example by Hume-
Rothery in 1955
Intermetallic compounds as solid phases containing
two or more metallic elements, with optionally one or
more non-metallic elements, whose crystal structure
differs from that of the other constituents
4. • Intermetallic compounds are generally brittle at room temperature and have high melting
points.
• Cleavage or intergranular fracture modes are typical of Intermetallic due to limited
independent slip systems required for plastic deformation.
• However, there are some examples of intermetallics with ductile fracture modes such as Nb–
15Al–40Ti. Other intermetallics can exhibit improved ductility by alloying with other
elements to increase grain boundary cohesion.
• Alloying of other materials such as boron to improve grain boundary cohesion can improve
ductility in many intermetallics.
• They often offer a compromise between ceramic and metallic properties when hardness
and/or resistance to high temperatures is important enough to sacrifice some toughness and
ease of processing.
• They can also display desirable magnetic, superconducting and chemical properties, due to
their strong internal order and mixed (metallic and covalent/ionic) bonding, respectively.
Intermetallics have given rise to various novel materials developments.
• Some examples include alnico and the hydrogen storage materials in nickel metal hydride
batteries. Ni3Al, which is the hardening phase in the familiar nickel-base super alloys, and
the various titanium aluminides have also attracted interest for turbine blade applications,
while the latter is also used in very small quantities for grain refinement of titanium alloys.
Silicides, inter-metallic involving silicon, are utilized as barrier and contact layers in
microelectronics.
10. Extreme Environments
Extremes in terms of what human life
cant exist in.
These can include temperature (high or
low), pressure, acid or alkali and high
salts.
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21. Introduction to metallic foams
• Metal foam is a cellular structure consisting of
a solid metal with gas-filled pores containing a
large volume fraction. There are two types of
metal foams: closed-cell foam and open-cell
foam depending on whether the pores are
sealed or interconnected
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