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Product name
E-mail address SDS.Europe@Solutia.com
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1.4 Emergency telephone number
1.1 Product identifier
+44 (0) 1633 754280 (Europe)
1.3 Details of the supplier of the safety data sheet
1.2 Relevant identified uses of the substance or mixture and uses advised against
(National phone numbers)
Product code
Recommended Use Wetting agent
50032
SECTION 1: Identification of the substance/mixture and of the company/undertaking
For further information, please contact:
Uses advised against
Manufacturer
Performance Films
A wholly owned subsidiary of Solutia Inc.
4129 The Great Road, Fieldale, VA 24089, USA
Telephone(s): Emergency/Product Information
001-276-627-3000 (USA)
English
Supplier
Solutia Europe SPRL/BVBA
A subsidiary of Eastman Chemical Company
Corporate Village Aramis Building Leonardo Da Vincilaan 1,
B-1930 Zaventem - Belgium
Tel.: +32(0)2 746 50 00
Fax: +32(0)2 746 57 00
Safety Data Sheet (SDS) according to the Global Harmonized System
Version 1
____________________________________________________________________________________________________________________
Revision date 25-Jun-2013
SAFETY DATA SHEET
Page 1 / 12© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
____________________________________________________________________________________________________________________
Revision date 25-Jun-201350032 FILM ON
1 - 10 Not classified Not classified Not applicable
3.2 Mixtures
SECTION 3: Composition/information on ingredients
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]
ethoxy]-, hydrogen sulfate,
sodium salt
246-985-2 25446-78-0 1 - 5 Xi;R36, Xi;R41,
R52/53
Skin Irrit. Cat 2 -
H315
Serious Eye Dam.
Cat 1 - H318
Aquatic Chronic
Cat 3 - H412
Not applicable
Not Applicable
3.1 Substances
Chemical name EC-No
Note
CAS-No Weight %
For the full text of the R-phrases mentioned in this Section, see Section 16
Classification
(67/548/EEC)
Classification
(Reg. EU
1272/2008)
For the full text of the H-Statements mentioned in this Section, see Section 16
REACH
registration
number
Water 231-791-2 7732-18-5 85 - 95 Not classified Not classified Not applicable
Sorbitan,
monododecanoate,
poly(oxy-1,2-ethanediyl)
derivs.
Not applicable 9005-64-5
The preparation is non-dangerous in accordance with Directive 1999/45/EC.
S-phrase(s)
None
None
2.1 Classification of the substance or mixture
Hazard symbols
SECTION 2: Hazards identification
For the full text of the R-phrases mentioned in this Section, see Section 16
Chemical name Not applicable
None
Classification
2.3 Other hazards
____________________________________________________________________________________________________________________
R-phrase(s)
None
R-phrase(s)
None known
2.2 Label Elements
Page 2 / 12© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
____________________________________________________________________________________________________________________
50032 FILM ON Revision date 25-Jun-2013
5.2 Special hazards arising from the substance or mixture
Inhalation
Keep victim warm and quiet. Remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. Call
a physician. Get medical attention if symptoms occur.
General advice
When symptoms persist or in all cases of doubt seek medical advice. If unconscious, place in recovery position and get medical
attention immediately. Show this material safety data sheet to the doctor in attendance.
Notes to Physician
Treat symptomatically.
4.1 Description of first aid measures
Heating causes rise in pressure with risk of bursting.
Skin contact
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.
5.3 Advice for firefighters
SECTION 5: Firefighting measures
4.2 Most important symptoms and effects, both acute and delayed
Special protective equipment for fire-fighters
Positivepressureself-containedbreathingapparatus(SCBA)andstructuralfirefighters’protectiveclothingwillprovideadequate
protection.
5.1 Extinguishing media
Special protective actions for fire-fighters
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Prevent fire extinguishing water
from contaminating surface water or the ground water system. Collect contaminated fire extinguishing water separately. Do not
allow entering drains or surface water. Fire residues and contaminated fire extinguishing water must be disposed of in accordance
with local regulations. Move containers from fire area if you can do it without risk. Cool containers / tanks with water spray.
Main symptoms
May cause eye irritation with susceptible persons.
Ingestion
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Clean mouth with water and drink afterwards
plenty of water. Do NOT induce vomiting unless directed to do so by a physician. Get medical attention if symptoms occur.
____________________________________________________________________________________________________________________
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Extinguishing media which shall not be used for safety reasons
No information available.
Page 3 / 12
4.3 Indication of any immediate medical attention and special treatment needed
© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
SECTION 4: First aid measures
____________________________________________________________________________________________________________________
50032 FILM ON Revision date 25-Jun-2013
Use personal protection recommended in Section 8. See Section 13: DISPOSAL CONSIDERATIONS.
Packaging material
Keep/store only in original container
6.2 Environmental precautions
7.3 Specific end use(s)
SECTION 7: Handling and storage
Methods for containment
Prevent further leakage or spillage if safe to do so. Dike to collect large liquid spills.
No information available
7.1 Precautions for safe handling
Other guidelines
No information available.
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
Methods for cleaning up
Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place
in container for disposal according to local / national regulations (see Section 13).
SECTION 8: Exposure controls/personal protection
Prevent further leakage or spillage if safe to do so. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
Advices on general occupational hygiene
Handle in accordance with good industrial hygiene and safety practice. Ensure that eyewash stations and safety showers are close
to the workstation location. Use personal protection recommended in Section 8. It is a good industrial hygiene practice to minimize
skin contact. Do not eat, drink or smoke when using this product. Wash hands before breaks and at the end of workday. Remove
and wash contaminated clothing before re-use. Keep away from food, drink and animal feeding stuffs.
Advice for emergency responders
Use personal protective equipment. For personal protection see section 8.
8.1 Control parameters
____________________________________________________________________________________________________________________
7.2 Conditions for safe storage, including any incompatibilities
6.4 Reference to other sections
SECTION 6: Accidental release measures
Technical measures/Storage conditions
Keep only in the original container. Keep container tightly closed in a dry and well-ventilated place. Protect from direct sunlight.
Store away from incompatible materials. Keep away from food, drink and animal feeding stuffs. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage. Store in accordance with local regulations.
Page 4 / 12
6.3 Methods and materials for containment and cleaning up
© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
No action shall be taken involving any personal risk or without suitable training. Do not touch or walk through spilled material. Wear
personal protective equipment. Ensure adequate ventilation.
____________________________________________________________________________________________________________________
Revision date 25-Jun-201350032 FILM ON
Skin and body protection
Lightweight protective clothing.
Engineering measures
Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Eyewash stations.
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment, Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Exposure Limits
Environmental exposure controls
No information available.
Personal protective equipment
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Eye protection
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to
avoid exposure to liquid splashes, mists, gases or dusts.
Physical State Liquid
This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
Hand protection
For operations where prolonged or repeated skin contact may occur, impervious gloves should be worn: Polyvinylchloride,
Rubber gloves.
8.2 Exposure controls
7 - 8
Property
Flammability Limits in Air
Values
Appearance
Boiling point/boiling range
Not Applicable
~ 100 °C
Evaporation rate No information available
Upper flammability limit No information available
Color Colorless
Liquid
Remarks•Methods
Lower flammability limit No information available
Odor
Specific gravity 1.002
Melting point/freezing point ~ 0 °C
Odor threshold
____________________________________________________________________________________________________________________
Flash point No information available
No information available
Flammability (solid, gas) Not flammable
Odorless
pH
Page 5 / 12© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
Not applicable
____________________________________________________________________________________________________________________
Revision date 25-Jun-201350032 FILM ON
Hazardous polymerization
Hazardous polymerization does not occur.
Hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid
Do not freeze.
10.5 Incompatible Materials
SECTION 10: Stability and reactivity
No materials to be especially mentioned.
10.6 Hazardous decomposition products
10.1 Reactivity
Explosive properties
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Not explosive.
Stable under normal conditions.
SECTION 11: Toxicological information
Oxidizing properties Not oxidizing.
11.1 Information on toxicological effects
10.2 Chemical stability
Acute toxicity
Stable under normal conditions.
9.2 OTHER INFORMATION
10.3 Possibility of Hazardous Reactions
Solubility in other solvents
Viscosity, kinematic No information available
Autoignition temperature No information available
No information available.
Vapor pressure
Water solubility
Vapor density
Partition coefficient: n-octanol/waterNo information available
Viscosity, dynamic No information available
No information available
Decomposition temperature
____________________________________________________________________________________________________________________
Density 1002 kg/m³
No information available
Miscible with water
Page 6 / 12
No information available
© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
____________________________________________________________________________________________________________________
50032 FILM ON Revision date 25-Jun-2013
No data available
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information
available
No information
available
No information
available
No information
available
Not available.
No data available
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information
available
No information
available
No information
available
No information
available
Not available.
LD50 dermal: See table below
Conclusion Not sufficient for classification.
Component Information
Conclusion
See table below
Serious eye damage/eye irritation
Ingestion Not sufficient for classification
Product Information No information available.
Chemical name
Skin contact There is no data available for this product.
Chemical name Method Species Irritation score Exposure time Conclusion
LD50 Oral LD50 Dermal
Water No information
available
No information
available
No data available No data available Not available.
Inhalation
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information
available
No information
available
No data available No data available Not available.
There is no data available for this product.
LC50 Inhalation
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information
available
No information
available
No data available No data available Not available.
LC50 Inhalation:
Conclusion Not sufficient for classification.
Water
Irritation/Corrosion
90 mL/kg ( Rat ) No data available
Sensitization
Skin corrosion/irritation
No data available
See table below
Skin sensitization No information available.
LD50 oral:
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
Product Information No information available.
Respiratory sensitization No information available
> 33000 mg/kg b.w. ( Rat ) No data available
Chemical name Method Species Result
No data available
Water No information available No information available Not available.
Chemical name Method
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information available No information available Not available.
Species Irritation score Exposure time
____________________________________________________________________________________________________________________
Conclusion
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
Water No information
available
No information
available
No information
available
Page 7 / 12
No information
available
© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
Not available.
No data available
____________________________________________________________________________________________________________________
Revision date 25-Jun-201350032 FILM ON
Species Effect dose
Water No information available No information
available
No information
available
No information
available
No data
available
Not available.
Dose value
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information available No information
available
No information
available
No information
available
No data
available
Not available.
Water
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information available No information
available
No information
available
No information
available
No data
available
Not available.
No information available No information
available
No information
available
No information
available
Conclusion Not sufficient for classification.
No information
available
No data
available
Repeated dose toxicity
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information available
Germ cell mutagenicity
No information
available
No information
available
No information
available
No information
available
No data
available
No information available Not available.
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information available No information
available
Chemical name Test Method Test type Species Result
No information
available
No information
available
Water No information available No information available No information available Not available
No information
available
No data
available
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information available No information available No information available Not available
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information available No information available No information available Not available
Conclusion Not sufficient for classification.
Conclusion Not sufficient for classification.
Conclusion Not sufficient for classification.
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information available
Toxicity to Reproduction
Carcinogenicity
Effects on fertility
Chemical name Method
____________________________________________________________________________________________________________________
Test type Exposure
route
Chemical name Method Exposure
route
Species
Page 8 / 12
Effect dose
© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
Dose value Result
____________________________________________________________________________________________________________________
Revision date 25-Jun-201350032 FILM ON
Species Exposure route
Aspiration hazard
Dose value Conclusion
Chemical name Method
Not relevant for the product itself.
Water No information available No information
available
No information
available
Other adverse effects
No data available Not available.
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information available
No information available.
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information available No information
available
No information
available
No data available Not available.
No information
available
No information
available
SECTION 12: Ecological information
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information available No information
available
No information
available
12.1 Toxicity
No data available Not available.
No data available No information
available.
Acute aquatic toxicity
Product Information
Species Exposure route
Conclusion Not sufficient for classification.
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information available No information
available
No information
available
No data available No information
available.
Specific target organ toxicity (single exposure)
Dose value Effects on
fertility
Conclusion Not relevant for the product itself.
Developmental toxicity
Water No information available
Specific target organ toxicity (repeated exposure)
No information
available
No information
available
Conclusion Not relevant for the product itself.
No data available No information
available.
Chemical name Test Method
No information available
96-hour LC50 - Fish
Species
72-hour EC50 - Algae/aquatic plants
48-hour EC50 - Aquatic invertebrates
____________________________________________________________________________________________________________________
Result
No data available
No data available
No data available
No information available
Page 9 / 12
Property
© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
No information available
____________________________________________________________________________________________________________________
50032 FILM ON Revision date 25-Jun-2013
Water No information available No information available
Not available
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No information available No information available
Not available
12.2 Persistence and degradability
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No information available No information available
Not available
Chemical name
Water
Conclusion Not sufficient for classification.
Product Information
12.3 Bioaccumulative potential
Not available
No information available.
Not available
Chronic aquatic toxicity
Component Information
Not available
Chemical name Bioconcentration factor (BCF) log Pow
Toxicity to fish
Water No data available No data available
Component Information No information available
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
No data available No data available
Toxicity to daphnia and other
aquatic invertebrates
Component Information
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
No data available No data available
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
Chemical name Method Biodegradability
Not available
Water
Conclusion Not sufficient for classification.
Not available No information available.
Not available
12.4 Mobility in soil
Sorbitan, monododecanoate,
poly(oxy-1,2-ethanediyl) derivs.
Not available No information available.
Not available
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
Mobility No information available.
Not available No information available.
Toxicity to algae
____________________________________________________________________________________________________________________
Conclusion Not sufficient for classification.
Component Information
Chemical name Aquatic half-life
Page 10 / 12
Temperature
© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
Ethanol,
2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-,
hydrogen sulfate, sodium salt
____________________________________________________________________________________________________________________
Revision date 25-Jun-201350032 FILM ON
14.4 Packing group Not applicable
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
14.5 Environmental Hazard Not applicable
12.6 Other adverse effects.
14.6 Special precautions for user No information available.
Section 13: Disposal considerations
Additional Information
Disposal considerations
Do not flush into surface water or sanitary sewer system.
This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT)
This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB)
IMDG Not regulated
14.1 UN/ID no Not applicable
OTHER INFORMATION
No information available.
14.2 Proper shipping name Not applicable
13.1 Waste treatment methods
14.3 Hazard Class Not applicable
14.4 Packing group Not applicable
No information available
SECTION 14: Transport information
14.5 Environmental Hazard Not applicable
14.6 Special precautions for user No information available
14.7 Transport in bulk according to
MARPOL 73/78 and the IBC Code
Not applicable
12.5 Results of PBT and vPvB assessment
General advice
The generation of waste should be avoided or minimized wherever possible.
IATA Not regulated
14.1 UN/ID no Not applicable
ADR/RID Not regulated
14.2 Proper shipping name Not applicable
14.1 UN/ID no
____________________________________________________________________________________________________________________
Not applicable
Waste from residues / unused products
Dispose of in accordance with local regulations. Should not be released into the environment.
14.2 Proper shipping name Not applicable
Page 11 / 12
14.3 Hazard Class
© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
Not applicable
____________________________________________________________________________________________________________________
50032 FILM ON Revision date 25-Jun-2013
14.3 Hazard Class Not applicable
IECSC (China) Complies
International Inventories
AICS (Australia) Complies
KECL (Korea) Complies
NZIoC (New Zealand) Complies
14.5 Environmental Hazard Not applicable
Legend
TSCA (US) Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
14.4 Packing group
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
EINECS/ELINCS (EU) Complies
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
Not applicable
Section 15: Regulatory information
PICCS - Philippines Inventory of Chemicals and Chemical Substances
DSL/NDSL (Canada) Complies
ENCS - Japan Existing and New Chemical Substances
14.6 Special precautions for user No information available
IECSC - China Inventory of Existing Chemical Substances
PICCS (Philippines) Complies
AICS - Australian Inventory of Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
ENCS (Japan) -
NZIoC - New Zealand Inventory of Chemicals
End of Safety Data Sheet
SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3
H315 - Causes skin irritation
H318 - Causes serious eye damage
H412 - Harmful to aquatic life with long lasting effects
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Revision Note Not applicable.
____________________________________________________________________________________________________________________
Full text of R-phrases referred to under sections 2 and 3
R38 - Irritating to skin
R41 - Risk of serious damage to eyes
Disclaimer
The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.
Revision date
Page 12 / 12© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
25-Jun-2013

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  • 1. None known Product name E-mail address SDS.Europe@Solutia.com FILM ON 1.4 Emergency telephone number 1.1 Product identifier +44 (0) 1633 754280 (Europe) 1.3 Details of the supplier of the safety data sheet 1.2 Relevant identified uses of the substance or mixture and uses advised against (National phone numbers) Product code Recommended Use Wetting agent 50032 SECTION 1: Identification of the substance/mixture and of the company/undertaking For further information, please contact: Uses advised against Manufacturer Performance Films A wholly owned subsidiary of Solutia Inc. 4129 The Great Road, Fieldale, VA 24089, USA Telephone(s): Emergency/Product Information 001-276-627-3000 (USA) English Supplier Solutia Europe SPRL/BVBA A subsidiary of Eastman Chemical Company Corporate Village Aramis Building Leonardo Da Vincilaan 1, B-1930 Zaventem - Belgium Tel.: +32(0)2 746 50 00 Fax: +32(0)2 746 57 00 Safety Data Sheet (SDS) according to the Global Harmonized System Version 1 ____________________________________________________________________________________________________________________ Revision date 25-Jun-2013 SAFETY DATA SHEET Page 1 / 12© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
  • 2. ____________________________________________________________________________________________________________________ Revision date 25-Jun-201350032 FILM ON 1 - 10 Not classified Not classified Not applicable 3.2 Mixtures SECTION 3: Composition/information on ingredients Ethanol, 2-[2-[2-(tridecyloxy)ethoxy] ethoxy]-, hydrogen sulfate, sodium salt 246-985-2 25446-78-0 1 - 5 Xi;R36, Xi;R41, R52/53 Skin Irrit. Cat 2 - H315 Serious Eye Dam. Cat 1 - H318 Aquatic Chronic Cat 3 - H412 Not applicable Not Applicable 3.1 Substances Chemical name EC-No Note CAS-No Weight % For the full text of the R-phrases mentioned in this Section, see Section 16 Classification (67/548/EEC) Classification (Reg. EU 1272/2008) For the full text of the H-Statements mentioned in this Section, see Section 16 REACH registration number Water 231-791-2 7732-18-5 85 - 95 Not classified Not classified Not applicable Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. Not applicable 9005-64-5 The preparation is non-dangerous in accordance with Directive 1999/45/EC. S-phrase(s) None None 2.1 Classification of the substance or mixture Hazard symbols SECTION 2: Hazards identification For the full text of the R-phrases mentioned in this Section, see Section 16 Chemical name Not applicable None Classification 2.3 Other hazards ____________________________________________________________________________________________________________________ R-phrase(s) None R-phrase(s) None known 2.2 Label Elements Page 2 / 12© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
  • 3. ____________________________________________________________________________________________________________________ 50032 FILM ON Revision date 25-Jun-2013 5.2 Special hazards arising from the substance or mixture Inhalation Keep victim warm and quiet. Remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Get medical attention if symptoms occur. General advice When symptoms persist or in all cases of doubt seek medical advice. If unconscious, place in recovery position and get medical attention immediately. Show this material safety data sheet to the doctor in attendance. Notes to Physician Treat symptomatically. 4.1 Description of first aid measures Heating causes rise in pressure with risk of bursting. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. 5.3 Advice for firefighters SECTION 5: Firefighting measures 4.2 Most important symptoms and effects, both acute and delayed Special protective equipment for fire-fighters Positivepressureself-containedbreathingapparatus(SCBA)andstructuralfirefighters’protectiveclothingwillprovideadequate protection. 5.1 Extinguishing media Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Prevent fire extinguishing water from contaminating surface water or the ground water system. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Move containers from fire area if you can do it without risk. Cool containers / tanks with water spray. Main symptoms May cause eye irritation with susceptible persons. Ingestion Remove victim to fresh air and keep at rest in a position comfortable for breathing. Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting unless directed to do so by a physician. Get medical attention if symptoms occur. ____________________________________________________________________________________________________________________ Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Extinguishing media which shall not be used for safety reasons No information available. Page 3 / 12 4.3 Indication of any immediate medical attention and special treatment needed © COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY SECTION 4: First aid measures
  • 4. ____________________________________________________________________________________________________________________ 50032 FILM ON Revision date 25-Jun-2013 Use personal protection recommended in Section 8. See Section 13: DISPOSAL CONSIDERATIONS. Packaging material Keep/store only in original container 6.2 Environmental precautions 7.3 Specific end use(s) SECTION 7: Handling and storage Methods for containment Prevent further leakage or spillage if safe to do so. Dike to collect large liquid spills. No information available 7.1 Precautions for safe handling Other guidelines No information available. 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel Methods for cleaning up Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). SECTION 8: Exposure controls/personal protection Prevent further leakage or spillage if safe to do so. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Advices on general occupational hygiene Handle in accordance with good industrial hygiene and safety practice. Ensure that eyewash stations and safety showers are close to the workstation location. Use personal protection recommended in Section 8. It is a good industrial hygiene practice to minimize skin contact. Do not eat, drink or smoke when using this product. Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. Keep away from food, drink and animal feeding stuffs. Advice for emergency responders Use personal protective equipment. For personal protection see section 8. 8.1 Control parameters ____________________________________________________________________________________________________________________ 7.2 Conditions for safe storage, including any incompatibilities 6.4 Reference to other sections SECTION 6: Accidental release measures Technical measures/Storage conditions Keep only in the original container. Keep container tightly closed in a dry and well-ventilated place. Protect from direct sunlight. Store away from incompatible materials. Keep away from food, drink and animal feeding stuffs. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Store in accordance with local regulations. Page 4 / 12 6.3 Methods and materials for containment and cleaning up © COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY No action shall be taken involving any personal risk or without suitable training. Do not touch or walk through spilled material. Wear personal protective equipment. Ensure adequate ventilation.
  • 5. ____________________________________________________________________________________________________________________ Revision date 25-Jun-201350032 FILM ON Skin and body protection Lightweight protective clothing. Engineering measures Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Eyewash stations. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment, Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Exposure Limits Environmental exposure controls No information available. Personal protective equipment SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Eye protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Physical State Liquid This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Hand protection For operations where prolonged or repeated skin contact may occur, impervious gloves should be worn: Polyvinylchloride, Rubber gloves. 8.2 Exposure controls 7 - 8 Property Flammability Limits in Air Values Appearance Boiling point/boiling range Not Applicable ~ 100 °C Evaporation rate No information available Upper flammability limit No information available Color Colorless Liquid Remarks•Methods Lower flammability limit No information available Odor Specific gravity 1.002 Melting point/freezing point ~ 0 °C Odor threshold ____________________________________________________________________________________________________________________ Flash point No information available No information available Flammability (solid, gas) Not flammable Odorless pH Page 5 / 12© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY Not applicable
  • 6. ____________________________________________________________________________________________________________________ Revision date 25-Jun-201350032 FILM ON Hazardous polymerization Hazardous polymerization does not occur. Hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to avoid Do not freeze. 10.5 Incompatible Materials SECTION 10: Stability and reactivity No materials to be especially mentioned. 10.6 Hazardous decomposition products 10.1 Reactivity Explosive properties Under normal conditions of storage and use, hazardous decomposition products should not be produced. Not explosive. Stable under normal conditions. SECTION 11: Toxicological information Oxidizing properties Not oxidizing. 11.1 Information on toxicological effects 10.2 Chemical stability Acute toxicity Stable under normal conditions. 9.2 OTHER INFORMATION 10.3 Possibility of Hazardous Reactions Solubility in other solvents Viscosity, kinematic No information available Autoignition temperature No information available No information available. Vapor pressure Water solubility Vapor density Partition coefficient: n-octanol/waterNo information available Viscosity, dynamic No information available No information available Decomposition temperature ____________________________________________________________________________________________________________________ Density 1002 kg/m³ No information available Miscible with water Page 6 / 12 No information available © COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY
  • 7. ____________________________________________________________________________________________________________________ 50032 FILM ON Revision date 25-Jun-2013 No data available Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available No information available No information available No information available Not available. No data available Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available No information available No information available No information available Not available. LD50 dermal: See table below Conclusion Not sufficient for classification. Component Information Conclusion See table below Serious eye damage/eye irritation Ingestion Not sufficient for classification Product Information No information available. Chemical name Skin contact There is no data available for this product. Chemical name Method Species Irritation score Exposure time Conclusion LD50 Oral LD50 Dermal Water No information available No information available No data available No data available Not available. Inhalation Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available No information available No data available No data available Not available. There is no data available for this product. LC50 Inhalation Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available No information available No data available No data available Not available. LC50 Inhalation: Conclusion Not sufficient for classification. Water Irritation/Corrosion 90 mL/kg ( Rat ) No data available Sensitization Skin corrosion/irritation No data available See table below Skin sensitization No information available. LD50 oral: Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. Product Information No information available. Respiratory sensitization No information available > 33000 mg/kg b.w. ( Rat ) No data available Chemical name Method Species Result No data available Water No information available No information available Not available. Chemical name Method Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available No information available Not available. Species Irritation score Exposure time ____________________________________________________________________________________________________________________ Conclusion Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt Water No information available No information available No information available Page 7 / 12 No information available © COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY Not available. No data available
  • 8. ____________________________________________________________________________________________________________________ Revision date 25-Jun-201350032 FILM ON Species Effect dose Water No information available No information available No information available No information available No data available Not available. Dose value Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available No information available No information available No information available No data available Not available. Water Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available No information available No information available No information available No data available Not available. No information available No information available No information available No information available Conclusion Not sufficient for classification. No information available No data available Repeated dose toxicity Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available Germ cell mutagenicity No information available No information available No information available No information available No data available No information available Not available. Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available No information available Chemical name Test Method Test type Species Result No information available No information available Water No information available No information available No information available Not available No information available No data available Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available No information available No information available Not available Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available No information available No information available Not available Conclusion Not sufficient for classification. Conclusion Not sufficient for classification. Conclusion Not sufficient for classification. Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available Toxicity to Reproduction Carcinogenicity Effects on fertility Chemical name Method ____________________________________________________________________________________________________________________ Test type Exposure route Chemical name Method Exposure route Species Page 8 / 12 Effect dose © COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY Dose value Result
  • 9. ____________________________________________________________________________________________________________________ Revision date 25-Jun-201350032 FILM ON Species Exposure route Aspiration hazard Dose value Conclusion Chemical name Method Not relevant for the product itself. Water No information available No information available No information available Other adverse effects No data available Not available. Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available No information available. Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available No information available No information available No data available Not available. No information available No information available SECTION 12: Ecological information Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available No information available No information available 12.1 Toxicity No data available Not available. No data available No information available. Acute aquatic toxicity Product Information Species Exposure route Conclusion Not sufficient for classification. Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available No information available No information available No data available No information available. Specific target organ toxicity (single exposure) Dose value Effects on fertility Conclusion Not relevant for the product itself. Developmental toxicity Water No information available Specific target organ toxicity (repeated exposure) No information available No information available Conclusion Not relevant for the product itself. No data available No information available. Chemical name Test Method No information available 96-hour LC50 - Fish Species 72-hour EC50 - Algae/aquatic plants 48-hour EC50 - Aquatic invertebrates ____________________________________________________________________________________________________________________ Result No data available No data available No data available No information available Page 9 / 12 Property © COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY No information available
  • 10. ____________________________________________________________________________________________________________________ 50032 FILM ON Revision date 25-Jun-2013 Water No information available No information available Not available Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No information available No information available Not available 12.2 Persistence and degradability Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No information available No information available Not available Chemical name Water Conclusion Not sufficient for classification. Product Information 12.3 Bioaccumulative potential Not available No information available. Not available Chronic aquatic toxicity Component Information Not available Chemical name Bioconcentration factor (BCF) log Pow Toxicity to fish Water No data available No data available Component Information No information available Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. No data available No data available Toxicity to daphnia and other aquatic invertebrates Component Information Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt No data available No data available Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. Chemical name Method Biodegradability Not available Water Conclusion Not sufficient for classification. Not available No information available. Not available 12.4 Mobility in soil Sorbitan, monododecanoate, poly(oxy-1,2-ethanediyl) derivs. Not available No information available. Not available Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt Mobility No information available. Not available No information available. Toxicity to algae ____________________________________________________________________________________________________________________ Conclusion Not sufficient for classification. Component Information Chemical name Aquatic half-life Page 10 / 12 Temperature © COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY Ethanol, 2-[2-[2-(tridecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt
  • 11. ____________________________________________________________________________________________________________________ Revision date 25-Jun-201350032 FILM ON 14.4 Packing group Not applicable Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14.5 Environmental Hazard Not applicable 12.6 Other adverse effects. 14.6 Special precautions for user No information available. Section 13: Disposal considerations Additional Information Disposal considerations Do not flush into surface water or sanitary sewer system. This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT) This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB) IMDG Not regulated 14.1 UN/ID no Not applicable OTHER INFORMATION No information available. 14.2 Proper shipping name Not applicable 13.1 Waste treatment methods 14.3 Hazard Class Not applicable 14.4 Packing group Not applicable No information available SECTION 14: Transport information 14.5 Environmental Hazard Not applicable 14.6 Special precautions for user No information available 14.7 Transport in bulk according to MARPOL 73/78 and the IBC Code Not applicable 12.5 Results of PBT and vPvB assessment General advice The generation of waste should be avoided or minimized wherever possible. IATA Not regulated 14.1 UN/ID no Not applicable ADR/RID Not regulated 14.2 Proper shipping name Not applicable 14.1 UN/ID no ____________________________________________________________________________________________________________________ Not applicable Waste from residues / unused products Dispose of in accordance with local regulations. Should not be released into the environment. 14.2 Proper shipping name Not applicable Page 11 / 12 14.3 Hazard Class © COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY Not applicable
  • 12. ____________________________________________________________________________________________________________________ 50032 FILM ON Revision date 25-Jun-2013 14.3 Hazard Class Not applicable IECSC (China) Complies International Inventories AICS (Australia) Complies KECL (Korea) Complies NZIoC (New Zealand) Complies 14.5 Environmental Hazard Not applicable Legend TSCA (US) Complies TSCA - United States Toxic Substances Control Act Section 8(b) Inventory 14.4 Packing group EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances EINECS/ELINCS (EU) Complies DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Not applicable Section 15: Regulatory information PICCS - Philippines Inventory of Chemicals and Chemical Substances DSL/NDSL (Canada) Complies ENCS - Japan Existing and New Chemical Substances 14.6 Special precautions for user No information available IECSC - China Inventory of Existing Chemical Substances PICCS (Philippines) Complies AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances ENCS (Japan) - NZIoC - New Zealand Inventory of Chemicals End of Safety Data Sheet SECTION 16: Other information Full text of H-Statements referred to under sections 2 and 3 H315 - Causes skin irritation H318 - Causes serious eye damage H412 - Harmful to aquatic life with long lasting effects R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Revision Note Not applicable. ____________________________________________________________________________________________________________________ Full text of R-phrases referred to under sections 2 and 3 R38 - Irritating to skin R41 - Risk of serious damage to eyes Disclaimer The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. Revision date Page 12 / 12© COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY 25-Jun-2013