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SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 1. IDENTIFICATION
Product name : Zimmer Aufraumen Hand Rub
Manufacturer or supplier's details
Company name of supplier :: ZaGlobal India LLP
Address : Manufacturer:
ZAGlobal Chemical Lab (Batch ID starts with TN)
under license from ZAGlobal Chemical GmBH
Allotment 56/3, Nh38, Village Valasamidhiram,
Thoothukoodi, Tamilnadu, India 628002
Amba Chemoxie Enterprise (Batch ID with UK)
under license from ZAGlobal Chemical GmBH
Patta 102-105, Village Halduchaur Dauliya,
Haldwani, Uttaralkhand, India 263139
Recommended use of the chemical and restrictions on use
Recommended use :Hand Rub
Restrictions on use
This is a personal care or cosmetic product that is safe for
consumers and other users under normal and reasonably
foreseeable use. Cosmetics and consumer products, specifically
defined by regulations around the world, are exempt from the
requirement of an SDS for the consumer. While this material is
not considered hazardous, this SDS contains valuable information
critical to the safe handling and proper use of the product for
industrial workplace conditions as well as unusual and unintended
exposures such as large spills. This SDS should be retained and
available for employees and other users of this product. For
specific intended-use guidance, please refer to the information
provided on the package or instruction sheet
.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids : Category 3
Eye irritation : Category 2A
GHS Label element
Hazard pictograms :
Signal Word : Warning
Hazard Statements : H226 Flammable liquid and vapor.
H319 Causes serious eye irritation.
Precautionary Statements : Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. -
No smoking.
P233 Keep container tightly closed.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Other hazards
Vapors may form explosive mixture with air.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients
Chemical Name CAS-No. Concentration (%)
Ethanol 64-17-5 >= 0 - <60
Propan-2-ol 67-63-0 >= 15 - < 30
chlorhexidine gluconate 55-56-1 <1.0
SECTION 4. FIRST AID MEASURES
General advice : In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
If inhaled : If inhaled, remove to fresh air.
Get medical attention if symptoms occur.
In case of skin contact : Wash with water and soap as a precaution.
Get medical attention if symptoms occur.
In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention.
If swallowed : If swallowed, DO NOT induce vomiting.
Get medical attention if symptoms occur.
Rinse mouth thoroughly with water.
Most important symptoms
and effects, both acute
and delayed : Causes serious eye irritation.
Protection of first-aiders : First Aid responders should pay attention to self-protection,
and use the recommended personal protective equipment
when the potential for exposure exists.
Notes to physician : Treat symptomatically and supportively.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Water spray
Alcohol-resistant foam
Dry chemical
Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet
media
Specific hazards during fire : Do not use a solid water stream as it may scatter and spread
fighting fire.
Flash back possible over considerable distance.
Vapors may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Hazardous combustion prod- : Carbon oxides
ucts
Specific extinguishing : Use extinguishing measures that are appropriate to local
methods circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Remove all sources of ignition.
protective equipment and Use personal protective equipment.
emergency procedures Follow safe handling advice and personal protective
equipment recommendations.
Environmental precautions : Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil
barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for : Non-sparking tools should be used.
containment and cleaning up Soak up with inert absorbent material.
Suppress (knock down) gases/vapors/mists with a water spray
jet.
For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 7. HANDLING AND STORAGE
Technical measures : See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation : Use with local exhaust ventilation.
Use only in an area equipped with explosion proof exhaust
ventilation.
Advice on safe handling : Do not breathe vapors or spray mist.
Do not swallow.
Do not get in eyes.
Avoid prolonged or repeated contact with skin.
Handle in accordance with good industrial hygiene and safety
practice.
Non-sparking tools should be used.
Keep container tightly closed.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the
environment.
Conditions for safe storage : Keep in properly labeled containers.
Keep tightly closed.
Keep in a cool, well-ventilated place.
Store in accordance with the particular national regulations.
Keep away from heat and sources of ignition.
Materials to avoid : Do not store with the following product types:
Strong oxidizing agents
Organic peroxides
Flammable solids
Pyrophoric liquids
Pyrophoric solids
Self-heating substances and mixtures
Substances and mixtures which in contact with water emit
flammable gases
Explosives
Gases
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Ingredients CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Ethanol 64-17-5 TWA 1,000 ppm NIOSH REL
1,900 mg/m3
TWA 1,000 ppm OSHA Z-1
1,900 mg/m3
STEL 1,000 ppm ACGIH
Propan-2-ol 67-63-0 TWA 200 ppm ACGIH
STEL 400 ppm ACGIH
TWA 400 ppm NIOSH REL
980 mg/m3
ST 500 ppm NIOSH REL
1,225 mg/m3
TWA 400 ppm OSHA Z-1
980 mg/m3
Biological occupational exposure limits
Ingredients CAS-No. Control Biological Sam- Permissible Basis
parameters specimen pling concentratio
time n
Propan-2-ol 67-63-0 Acetone Urine End of 40 mg/l ACGIH
shift at BEI
end of
work-
week
Engineering measures : Minimize workplace exposure concentrations.
Use only in an area equipped with explosion proof exhaust
ventilation.
Use with local exhaust ventilation.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
Personal protective equipment
Respiratory protection : General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.
Hand protection
Material : Impervious gloves
Material : Flame retardant gloves
Remarks : Choose gloves to protect hands against chemicals depending
on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection : Wear the following personal protective equipment:
Safety goggles
Skin and body protection : Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Wear the following personal protective equipment:
Flame retardant antistatic protective clothing.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures : Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : clear, Colorless to pale yellow
Odor : citrus
Odor Threshold : No data available
pH : 6.5 - 8.5
Melting point/freezing point : No data available
Initial boiling point and boiling : 70 °C
range
Flash point : 25 °C
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Density : 0.8750 g/cm3
Solubility(ies)
Water solubility : soluble
Partition coefficient: n- : Not applicable
octanol/water
Autoignition temperature : No data available
Decomposition temperature : The substance or mixture is not classified self-reactive.
Viscosity
Viscosity, kinematic : 3,500 - 23,000 mm2/s (20 °C)
Explosive properties : Not explosive
Oxidizing properties : The substance or mixture is not classified as oxidizing.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Not classified as a reactivity hazard.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : Flammable liquid and vapor.
tions Vapors may form explosive mixture with air.
Can react with strong oxidizing agents.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method
Ingredients:
Ethanol:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Propan-2-ol:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation
Not classified based on available information.
Product:
Result: No skin irritation
Ingredients:
Ethanol:
Species: Rabbit
Method: OECD Test Guideline 404
Result: No skin irritation
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
Propan-2-ol:
Species: Rabbit
Result: No skin irritation
Serious eye damage/eye irritation
Causes serious eye irritation.
Ingredients:
Ethanol:
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Method: OECD Test Guideline 405
Propan-2-ol:
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Respiratory or skin sensitization
Skin sensitization: Not classified based on available information.
Respiratory sensitization: Not classified based on available information.
Product:
Assessment: Does not cause skin sensitization.
Ingredients:
Ethanol:
Test Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse
Result: negative
Propan-2-ol:
Test Type: Buehler Test
Routes of exposure: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406
Result: negative
Germ cell mutagenicity
Not classified based on available information.
Ingredients:
Ethanol:
Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test
Result: negative
Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo)
Species: Mouse
Application Route: Ingestion
Result: negative
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
Propan-2-ol:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: Intraperitoneal injection
Result: negative
Carcinogenicity
Not classified based on available information.
Ingredients:
Propan-2-ol:
Species: Rat
Application Route: inhalation (vapor)
Exposure time: 104 weeks
Method: OECD Test Guideline 451
Result: negative
IARC No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcino-
gen by OSHA.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Reproductive toxicity
Not classified based on available information.
Ingredients:
Ethanol:
Effects on fertility : Test Type: Two-generation reproduction toxicity study
Species: Mouse
Application Route: Ingestion
Method: OECD Test Guideline 416
Result: negative
Propan-2-ol:
Effects on fertility : Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion
Result: negative
Effects on fetal development : Test Type: Embryo-fetal development
Species: Rat
Application Route: Ingestion
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
Result: negative
STOT-single exposure
Not classified based on available information.
Ingredients:
Propan-2-ol:
Assessment: May cause drowsiness or dizziness.
STOT-repeated exposure
Not classified based on available information.
Repeated dose toxicity
Ingredients:
Ethanol:
Species: Rat
NOAEL: 2,400 mg/kg
Application Route: Ingestion
Exposure time: 2 y
Propan-2-ol:
Species: Rat
NOAEL: 5000 ppm
Application Route: inhalation (vapor)
Exposure time: 104 w
Method: OECD Test Guideline 413
Aspiration toxicity
Not classified based on available information.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Ethanol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Toxicity to daphnia and
other aquatic invertebrates
(Chronic toxicity)
: NOEC (Daphnia magna (Water flea)): 9.6 mg/l
Exposure time: 9 d
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l
Exposure time: 0.25 h
Propan-2-ol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l
aquatic invertebrates Exposure time: 24 h
Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800
mg/l
Exposure time: 8 d
Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l
Exposure time: 16 h
Persistence and degradability
Ingredients:
Ethanol:
Biodegradability : Result: Readily biodegradable.
Biodegradation: 84 %
Exposure time: 20 d
Propan-2-ol:
Biodegradability : Result: rapidly degradable
Bioaccumulative potential
Ingredients:
Ethanol:
Partition coefficient: n- : log Pow: -0.35
octanol/water
Propan-2-ol:
Partition coefficient: n- : log Pow: 0.05
octanol/water
Mobility in soil
No data available
Other adverse effects
No data available
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product.
Empty containers should be taken to an approved
waste handling site for recycling or disposal.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG
UN number : UN 1987
Proper shipping name : ALCOHOLS, N.O.S.
(Ethanol, Propan-2-ol)
Class : 3
Packing group : III
Labels : 3
IATA-DGR
UN/ID No. : UN 1987
Proper shipping name : Alcohols, n.o.s.
(Ethanol, Propan-2-ol)
Class : 3
Packing group : III
Labels : Flammable Liquids
Packing instruction (cargo : 366
aircraft)
Packing instruction : 355
(passenger aircraft)
IMDG-Code
UN number : UN 1987
Proper shipping name : ALCOHOLS, N.O.S.
(Ethanol, Propan-2-ol)
Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-D
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC
Code Not applicable for product as supplied.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Fire Hazard
Acute Health Hazard
SARA 302 : No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313 : The following components are subject to reporting levels
established by SARA Title III, Section 313:
Propan-2-ol 67-63-0 3.4086 %
The ingredients of this product are reported in the following inventories:
AICS : All ingredients listed or exempt.
SAFETY DATA SHEET
Hand Rub (72% Alcohol)
Version Revision Date: MSDS Number: Date of last issue: 12/06/2019
1.2 - 54756-00002 Date of first issue: 10/06/2019
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III:
Flammability
Health
3
2 0
Special hazard.
Instability
HEALTH 2
FLAMMABILITY 3
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Full text of other abbreviations
ACGIH
ACGIH BEI
NIOSH REL
OSHA Z-1
ACGIH / TWA
ACGIH / STEL
NIOSH REL / TWA
NIOSH REL / ST
OSHA Z-1 / TWA
Sources of key data used to
compile the Material Safety
Data Sheet
Revision Date
: USA. ACGIH Threshold Limit Values (TLV)
: ACGIH - Biological Exposure Indices (BEI)
: USA. NIOSH Recommended Exposure Limits
: USA. Occupational Exposure Limits (OSHA) - Table Z-1
Lim-its for Air Contaminants
: 8-hour, time-weighted average
: Short-term exposure limit
: Time-weighted average concentration for up to a 10-
hour workday during a 40-hour workweek
: STEL - 15-minute TWA exposure that should not be
exceeded at any time during a workday
: 8-hour time weighted average
: Internal technical data, data from raw material SDSs, OECD
eChem Portal search results and European Chemicals
Agen-cy, http://echa.europa.eu/
: 1st 12/12/2019
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-
formation and belief at the date of its publication. The information is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provid-
ed relates only to the specific material identified at the top of this SDS and may not be valid
when the SDS material is used in combination with any other materials or in any process, un-
less specified in the text. Material users should review the information and recommendations
in the specific context of their intended manner of handling, use, processing and storage, in-
cluding an assessment of the appropriateness of the SDS material in the user’s end product,
if applicable.

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  • 1. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 1. IDENTIFICATION Product name : Zimmer Aufraumen Hand Rub Manufacturer or supplier's details Company name of supplier :: ZaGlobal India LLP Address : Manufacturer: ZAGlobal Chemical Lab (Batch ID starts with TN) under license from ZAGlobal Chemical GmBH Allotment 56/3, Nh38, Village Valasamidhiram, Thoothukoodi, Tamilnadu, India 628002 Amba Chemoxie Enterprise (Batch ID with UK) under license from ZAGlobal Chemical GmBH Patta 102-105, Village Halduchaur Dauliya, Haldwani, Uttaralkhand, India 263139 Recommended use of the chemical and restrictions on use Recommended use :Hand Rub Restrictions on use This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet .
  • 2. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal Word : Warning Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation. Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air.
  • 3. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration (%) Ethanol 64-17-5 >= 0 - <60 Propan-2-ol 67-63-0 >= 15 - < 30 chlorhexidine gluconate 55-56-1 <1.0 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. Most important symptoms and effects, both acute and delayed : Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat symptomatically and supportively.
  • 4. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing : High volume water jet media Specific hazards during fire : Do not use a solid water stream as it may scatter and spread fighting fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- : Carbon oxides ucts Specific extinguishing : Use extinguishing measures that are appropriate to local methods circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for fire-fighters Use personal protective equipment.
  • 5. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, : Remove all sources of ignition. protective equipment and Use personal protective equipment. emergency procedures Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for : Non-sparking tools should be used. containment and cleaning up Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
  • 6. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases
  • 7. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type Control Basis (Form of parameters / exposure) Permissible concentration Ethanol 64-17-5 TWA 1,000 ppm NIOSH REL 1,900 mg/m3 TWA 1,000 ppm OSHA Z-1 1,900 mg/m3 STEL 1,000 ppm ACGIH Propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm NIOSH REL 980 mg/m3 ST 500 ppm NIOSH REL 1,225 mg/m3 TWA 400 ppm OSHA Z-1 980 mg/m3 Biological occupational exposure limits Ingredients CAS-No. Control Biological Sam- Permissible Basis parameters specimen pling concentratio time n Propan-2-ol 67-63-0 Acetone Urine End of 40 mg/l ACGIH shift at BEI end of work- week Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation.
  • 8. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety goggles Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
  • 9. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : clear, Colorless to pale yellow Odor : citrus Odor Threshold : No data available pH : 6.5 - 8.5 Melting point/freezing point : No data available Initial boiling point and boiling : 70 °C range Flash point : 25 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 0.8750 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- : Not applicable octanol/water Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 3,500 - 23,000 mm2/s (20 °C) Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing.
  • 10. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- : Flammable liquid and vapor. tions Vapors may form explosive mixture with air. Can react with strong oxidizing agents.
  • 11. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Propan-2-ol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation
  • 12. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 Propan-2-ol: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Ingredients: Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Propan-2-ol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Propan-2-ol: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative
  • 13. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 Propan-2-ol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative Carcinogenicity Not classified based on available information. Ingredients: Propan-2-ol: Species: Rat Application Route: inhalation (vapor) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Propan-2-ol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion
  • 14. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 Result: negative STOT-single exposure Not classified based on available information. Ingredients: Propan-2-ol: Assessment: May cause drowsiness or dizziness. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Propan-2-ol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapor) Exposure time: 104 w Method: OECD Test Guideline 413 Aspiration toxicity Not classified based on available information.
  • 15. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d
  • 16. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Propan-2-ol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l aquatic invertebrates Exposure time: 24 h Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800 mg/l Exposure time: 8 d Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Propan-2-ol: Biodegradability : Result: rapidly degradable Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: n- : log Pow: -0.35 octanol/water Propan-2-ol: Partition coefficient: n- : log Pow: 0.05 octanol/water Mobility in soil No data available Other adverse effects No data available
  • 17. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulation UNRTDG UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 IATA-DGR UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo : 366 aircraft) Packing instruction : 355 (passenger aircraft) IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
  • 18. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: Propan-2-ol 67-63-0 3.4086 % The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt.
  • 19. SAFETY DATA SHEET Hand Rub (72% Alcohol) Version Revision Date: MSDS Number: Date of last issue: 12/06/2019 1.2 - 54756-00002 Date of first issue: 10/06/2019 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Flammability Health 3 2 0 Special hazard. Instability HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Full text of other abbreviations ACGIH ACGIH BEI NIOSH REL OSHA Z-1 ACGIH / TWA ACGIH / STEL NIOSH REL / TWA NIOSH REL / ST OSHA Z-1 / TWA Sources of key data used to compile the Material Safety Data Sheet Revision Date : USA. ACGIH Threshold Limit Values (TLV) : ACGIH - Biological Exposure Indices (BEI) : USA. NIOSH Recommended Exposure Limits : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-its for Air Contaminants : 8-hour, time-weighted average : Short-term exposure limit : Time-weighted average concentration for up to a 10- hour workday during a 40-hour workweek : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday : 8-hour time weighted average : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen-cy, http://echa.europa.eu/ : 1st 12/12/2019 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid- ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.