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Aquifer Recharge
– Drinking Water Considerations –
Washington Department of Health
June 19, 2013 Webinar
Chris PitreRebekah Weston
Managed Aquifer Recharge
– the Right Tool in the Right Place –
• A water resource management tool.
• Used around the world.
• Ecology endorses ASR
• Proponents are lining up in Washington.
WA DOH’s Role:
 Ensure protection of public health
 Facilitate between project proponents and Ecology
Why ASR in the PNW
• Water Availability
– Water rights & winter water
• Financial
– Capital infrastructure (storage) investment
• System reliability
– Distribution of sources
• Environmental conditions
– Climate change, fish 
DOH Interests in ASR
• Protect public health.
• Interact constructively with:
– Ecology
• Water rights review
• Policy/program development
– Project proponents
• Show understanding of program components
• Provide guidance
Walla Walla ASR Wellhead
Clogging
• System scale is a common concern.
• Mitigate with pre‐recharge flushing of 
distribution system.
• Biofouling 
controlled by 
disinfection
• Filtered water 
(low TSS)  usually 
needed (though 
Walla Walla uses 
unfiltered water)
• Some clogging easily reversed by back flushing 
of well.
DISINFECTION BYPRODUCTS 
(DBPs)
• Disinfection needed to 
control biofouling, clogging.
• Inconsistency in regulations:
– Drinking water standards(protection of public health, WAC 246‐290):
• Chloroform (TTHM) – 80 ppb
• HAAs(5) – 60 ppb
– Groundwater protection standards (WAC 173‐200):
• Chloroform – 7 ppb
0.0
0.5
1.0
1.5
2.0
2.5
0
5
10
15
20
25
11/17/2000 12/2/2000 12/17/2000 1/1/2001 1/16/2001 1/31/2001 2/15/2001 3/2/2001
ResidualChlorine(mg/L)
ChloroformandTotalTHM(g/L)
Date
Chloroform
Residual Chlorine
STORAGE
(2 months)
RECHARGE
(1 month)
RECOVERY
(1.5 months)
RecoveredVolume
=Recharged
Chloroform WAC 173-200 Criteria (7 g/L)
Chlorination Disinfection Byproducts (DBPs)
80 Residual Cl 
gone
Natural Attenuation
DBPs form while
Residual Cl is present
Drinking 
water 
standard
Yakima 
ASR Test
DBPs remain within safe drinking limits and 
naturally attenuate during storage
Protection of Groundwater Quality
• Status Quo (Antidegradation Rule, WAC 173‐200)
– Passed in early days of environmental regulation development 
(~1980s)
– Stricter than drinking water standards
• Approaches to allow groundwater recharge :
– Variance (needs renewal every 5‐year = project uncertainty)
Overriding Public Interest (OPI)
– Groundwater Management Area (GWMA)
– Legislative fix
Oregon
• Allows 50% of MCLs allowed (100% of SMCLs & DBPs)
• Agency discretion reserved
Burden on regulatory 
staffing resources.
Recommended
Source Approval for ASR is Different From 
Conventional Supply
Individual sources are generally stable.
• Source (surface) water for recharge.
• Groundwater storage.
Mixing of sources can be dynamic.
• e.g., Redox reactions (e.g., oxidation of aquifer materials).
• Address with geochemical modeling, monitoring.
Reactions in the Aquifer
• Oxygenated recharge water
+ reduced aquifer minerals
= Oxidation of sulfide minerals?
• Potential release of trace elements(e.g., As)
• Has happened in other areas (e.g., FL [Arsenic], WI [Cobalt])
• Mineral has to be accessible to recharged water
(e.g., minerals locked in aquifer matrix is of less concern).
• Has not happened yet in the PNW.
Golder Associates ASR Projects
Various Stages of Operational Development
Studies
Portland
Tigard
TVWD
Clackamas
Salem
Dallas
Yakima
Kennewick
Walla Walla
Pendleton
Extents of
Columbia River Basalt
Groundwater Reactions
Recharge 
“bubble”
Reactions can:
• Occur within bubble.
• At interface (mixing zone).
• Take time (kinetics).
Water Quality in Recovery
Break Through Theory
0.0
0.2
0.4
0.6
0.8
1.0
0.0 0.1 1.0 10.0
C/Co
Volume Recovered/Volume Injected (-)Native Water
Recharged
Water
• Dispersivity (mixing) 
affects recovered 
water quality.
• Intrinsic to aquifer 
fabric
Sand
Fractured rock
0.0
0.2
0.4
0.6
0.8
1.0
0.0 0.1 1.0 10.0
C/Co
Volume Recovered/Volume Injected (-)
Fractured Chalk
Sandstone/
Claystone
Fractured Sandstone
Sand & Gravel
Basalt
Native Water
Recharged Water
Water Quality in Recovery
Mixing Examples
Basalt
Ellensburg Fm.
Data sets are from different projects and are affected by:  duration of storage; number of 
recharge/recovery cycles; and, other variables.  Examples illustrate the range of water quality 
distributions as a function of different aquifer fabrics.
Evaluation of Pilot Test Data – Yakima Example
C/C0 = 0.5
SO4
Tracers
Storage Recovery
NO3
18O
D
CFC‐12
Naturally occurring tracer data are used to evaluate the degree of mixing and 
hydrogeological characteristics (porous/fracture flow).
Example of Silica Dissolution Kinetics 
During Storage
Kennewick Willowbrook Well 
– Theoretical Pyrite Oxidation Simulation
O2
Fe
SO4
pH
Geochemical modeling is used to evaluate 
geochemical reactions during storage.
Testing the Waters
Monitor water quality through full recharge/recovery cycle 
to evaluate potential reactions:
1. Recharge (characterize input/baseline).
2. Storage – long enough to see reactions (e.g., 2 mos).
3. Recovery – to get break through curve (e.g. 2 x recharge vol.)
• Analytical suite should include:
– extended IOCs 
– DBPs 
– physical parameters
• Project specific considerations:
– VOCs/SOCs
– Radionuclides
– Tracers
ASR & Operations
(e.g., for Yakima)
 Storage needed for fire flow
 Conventional new storage:
 ~$2M
 ASR (per well):
 ~$2M (1,000’ deep,
3,000 gpm)
 ~400 million gallons
ASR Costs
• Conventional water costs:
– Water right: $1,000-$10,000/afy (water market)
– Seasonal storage: $5,000/af (Black Rock)
– Infrastructure storage: $2M (2 MG)
 ASR costs:
– Water right: Zero (using existing city rights)
– Seasonal storage: Zero (using Mother Nature’s aquifer)
– Infrastructure storage: $2M (per well)
Misconceptions About ASR
• How do we stop other people from taking the 
water we recharged? – CONTROLLED BY 
WATER RIGHTS – not an issue.
• The same molecule of water recharged has to 
be recovered. – NOT TRUE – Recovery is based 
on water balance accounting
ASR Water Quality Recap
Pre‐test analysis:
• Mineralogical analysis.
• Analysis of source and aquifer waters.
• Geochemical modeling.
Recharge and recovery cycle analysis:
• Sufficiently long storage period (e.g., 2 months).
• Obtain breakthrough curve (e.g., 2 x recharge volume).
Aquifer Recharge
– Drinking Water Considerations –
Washington Department of Health
June 19, 2013 Webinar
Chris PitreRebekah Weston
Thank you!

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Bonn_Water_Declaration_final
 

WADOH Webinar 2013-06-19