Carboranes
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Carboranes
- 1. Presentation by Primary Information Services www.primaryinfo.com mailto:primaryinfo@gmail.com
- 4. Carboranes are a class of boron cluster compounds with one or more polyhedral. boron vertices replaced by carbon which have been known since the 1960s.' These. electron-deficient neutral compounds are classified as closo-, nido-, arachno-, and. hyp ho-, etc} according to the number of skeletal electrons. Carborane is a class of thermally stable compounds with the formula BnC2Hn+2. The carboranes have polyhedral molecular structures based on networks of boron and carbon atoms, in which the carbon atoms occupy adjacent positions. Currently, many thousands of carboranes have been prepared, and they have been combined with transition metals to yield derivatives called metallacarboranes, some of which show catalytic activity.
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