1. Thermoplastics Elastomer (TPE’s) With Their Uses And Features
Thermoplastic Elastomers or TPEs are a class of polymers that can be frequently stretched without
everlastingly deforming the shape of the part. Different from rubber like elastomers, TPEs do not need
vulcanization or curing because they are real thermoplastics. In addition, TPEs can be processed by
conventional thermoplastic techniques like injection molding, blow and extrusion molding. There are six
key thermoplastic elastomer groups found commercially:
Styrenic Block Copolymers
Polyolefin Blends (TPOs)
Elastomeric Alloys
Thermoplastic Polyurethanes (TPUs)
Thermoplastic Copolyesters
Thermoplastic Polyamides
Key Use(s)
TPE’s used in a wide range of applications that spans, right from bumpers to bellows, grommets,
vibrational dampers, to couplers. Thermoplastic Elastomers can also be used throughout the
automotive, aerospace industries, Gaskets, Over molding, Medical/Healthcare Applications, Consumer
Applications, Grommets and General Purpose.
Features
In almost all cases, the replacement of these materials for conventional thermosetting materials results
in such advantages as considerably increased production speeds and the ability to use again clean scrap
without any loss in physical properties. This results in a reduced part cost because of decreased scrap
loss. Some general properties of TPE’s are summarized below:
Good Processability
Good Colorability
Good UV Resistance
Good Chemical Resistance
2. Good Weather Resistance
Good Adhesion
Ozone Resistant
Block Copolymer
Recyclable Material
In addition, thermoplastic Elastomers are available in a wide range of durometers and colors and the
physical properties can be customized by adjusting the percentage of plastic segments in the copolymer
matrix. For instance, as styrene content is raised in polystyrene elastomer block copolymers, then they
change from weak rubber to strong elastomers, to tough materials to ultimately hard, glass-like products
with above 75 percent styrene content.
Limitations of TPE’s
The physical properties of TPE’s are very much dependent upon the properties of the plastic with
elastomeric regions of the copolymer. Thus, the behavior of the TPE changes as the temperature
changes. The high temperature limit is termed by the melting point of the plastic phase, over which the
material softens and starts to flow. On the other side, the low temperature limit is described by the glass
transition temperature (Tg) of the rubber phase, lower which the material is brittle. Tg is one of the most
vital properties of any epoxy (a plastic or other material made from a class of synthetic thermosetting
polymers having epoxide groups). Epoxy is the temperature region where the polymer transitions from a
solid, glassy material to a soft rubbery material. This results in lowering the overall heat resistance of the
copolymer.
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