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Vertical movement of dispersed oil from the
Deepwater Horizon spill, Gulf of Mexico
Rachel Beavins
AP Photo
Motivation
NOAA, 2010Revised: 16% chemically dispersed
Hopkinson et al, 2010
Where did the dispersed oil go?
• When will it surface (if ever)?
• How long will it take for microbes to consume it?
Stokes’ Ascent
Stokes’
settling
ws
(velocity upward, drag
downward)
Stokes’ ascent
ws
Fd ,
Fg
Newton’s 2nd Law
Archimedes’ Principle
Stokes’ Law
ws =
−2R2
g(ρd − ρs)
9µ
ws =
Fd
6πµR
Fd = −Fg = − 4
3
πR3
g(ρd − ρs)
Hindered Ascent
http://www.filtration-and-separation.com/thickener/sld005.htm
Critical concentration
m ~ 5 (Richardson and Zaki, 1954)
Particle size
Stokes' ascent
(m/s)
Time to
surface
Hindered
ascent (m/s)
Time to
surface
100 µm 0.0018 9.61 days 2.0968 x 10-4 2.76 months
50 µm 4.5177 x 10-4 38.43 days 5.2419 x 10-5 11.04 months
10 µm 1.81 x 10-5 2.67 years 2.0968 x 10-6 23 years
w =
−2R2
g(ρd − ρs )
9µ
(1−
c
cs
)m
Viscosity Effects
Quantified how high concentration of small spheres
affect the viscosity of the solution:
Concentration of small spheres
Particle
size
Hindered
ascent (m/s)
Time to
surface
Velocity (m/s)
5% by volume
Time to
surface
Velocity (m/s)
10% by
volume
Time to
surface
100 µm 2.0968 x 10-4 2.76 months 1.86 x 10-4 3.12 months 1.67 x 10-4 3.45 months
50 µm 5.2419 x 10-5 11.04 months 4.66 x 10-5 12.42 months 4.19 x 10-5 13.8 months
μ solution = μ solvent (1+2.5Φ)
w =
−2R2
g(ρd − ρs )
9[µ(1+ 2.5φ)]
(1−
c
cs
)m
Biodegradation
Hazen et al 2010
Aim: Find equation for z(t) given that z(R(t))
1. Find dR/dt
2. Use ws (dz/dt) and dR/dt to find z(t)
dm
dt
=
dm
dR
×
dR
dt
dR
dt
=
dm dt
dm dR
m = 4
3
πρd R3 dm
dR
= 4πρd R2
dm
dt
= f (R,ρd ,b)
dm
dt
= R2
b
dR
dt
= −
R2
b
4ρd πR2
= −
b
4ρd π
BiodegradationAim: Find equation for z(t) given that z(R(t))
1. Find dR/dt
2. Use ws (dz/dt) and dR/dt to find z(t)
Integrate dR/dt: Substitute R into above:
Integrate twice:
R = −
b
4ρd π
+ R0
d2
z
dt2
= A− Bt
z = At2
− 1
6
Bt3
+ ws0
t + z0
Model results
Biodegradation Rate (kg m-2 s-1 )
100 μm
Total consumption time Position above ocean floor (m) Time to surface
5.74 x 10-10 61.5 years surface 9.61 days
5.74 x 10-9 6.15 years surface 9.65 days
5.74 x 10-8 7.38 months surface 10.05 days
5.98 x 10-7 21.26 days 1106 n/a
Biodegradation Rate (kg m-2 s-1 )
50 μm
Total consumption time Position above ocean floor (m) Time to surface
5.74 x 10-10 30.76 years surface 38.55 days
5.74 x 10-9 3.08 years surface 39.84 days
5.74 x 10-8 3.69 months 1441 n/a
5.98 x 10-7 10.63 days 138.3 n/a
Biodegradation Rate (kg m-2 s-
1 )
10 μm
Total consumption time Position above ocean floor (m) Time to surface
5.74 x 10-10 6.15 years 1153 n/a
5.74 x 10-9 7.38 months 115.3 n/a
5.74 x 10-8 22.15 days 11.53 n/a
5.98 x 10-7 2.13 days 1.12 n/a
Implications
• Large particles biodegrade slowly and surface quickly
• Small particles biodegrade quickly and mostly remain in
the fluid column
• Many factors will contribute to the ultimate fate of the oil
• Oil will likely persist for months, if not years
5.74 x 10-8 (kg m-2 s-1 ) 5.74 x 10-9 (kg m-2 s-1 )
Joye 2010
Questions?
AP Photo
References
Atlas, R.M. (1981), Microbial degradation of petroleum hydrocarbons: an environmental perspective, Microbiological Reviews, 45,
180-209.
Bartha, R. (1986), Biotechnology of petroleum pollutant biodegradation, Microb. Ecol., 12, 155-172.
Einstein, A. (1911), A new determination of molecular dimensions, Annals of Physics, 19, 289-306.
Hopkinson, C., Brandes, J., Joye, S., Lee, R., and M. Sun., 2010, Outcome/guidance form Georgia Sea Grant Program: current status
of BP oil spill, Georgia Sea Grant.
Joye, S. (2010), Gulf oil blog, University of Georgia, September 5.
Lubchenco, J., McNutt, M., Lehr, B., Sogge, M., Miller, M., Hammond, S., and W. Conner (2010), Deepwater Horizon/BP oil budget:
what happened to the oil?, NOAA.
Richardson, J.F., and Zaki, W.N. (1954), Sedimentation and fluidisation: Part I, Trans. Inst. Chem. Eng., 32, 35-53.

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Deepwater modeling

  • 1. Vertical movement of dispersed oil from the Deepwater Horizon spill, Gulf of Mexico Rachel Beavins AP Photo
  • 2. Motivation NOAA, 2010Revised: 16% chemically dispersed Hopkinson et al, 2010 Where did the dispersed oil go? • When will it surface (if ever)? • How long will it take for microbes to consume it?
  • 3. Stokes’ Ascent Stokes’ settling ws (velocity upward, drag downward) Stokes’ ascent ws Fd , Fg Newton’s 2nd Law Archimedes’ Principle Stokes’ Law ws = −2R2 g(ρd − ρs) 9µ ws = Fd 6πµR Fd = −Fg = − 4 3 πR3 g(ρd − ρs)
  • 4. Hindered Ascent http://www.filtration-and-separation.com/thickener/sld005.htm Critical concentration m ~ 5 (Richardson and Zaki, 1954) Particle size Stokes' ascent (m/s) Time to surface Hindered ascent (m/s) Time to surface 100 µm 0.0018 9.61 days 2.0968 x 10-4 2.76 months 50 µm 4.5177 x 10-4 38.43 days 5.2419 x 10-5 11.04 months 10 µm 1.81 x 10-5 2.67 years 2.0968 x 10-6 23 years w = −2R2 g(ρd − ρs ) 9µ (1− c cs )m
  • 5. Viscosity Effects Quantified how high concentration of small spheres affect the viscosity of the solution: Concentration of small spheres Particle size Hindered ascent (m/s) Time to surface Velocity (m/s) 5% by volume Time to surface Velocity (m/s) 10% by volume Time to surface 100 µm 2.0968 x 10-4 2.76 months 1.86 x 10-4 3.12 months 1.67 x 10-4 3.45 months 50 µm 5.2419 x 10-5 11.04 months 4.66 x 10-5 12.42 months 4.19 x 10-5 13.8 months μ solution = μ solvent (1+2.5Φ) w = −2R2 g(ρd − ρs ) 9[µ(1+ 2.5φ)] (1− c cs )m
  • 6. Biodegradation Hazen et al 2010 Aim: Find equation for z(t) given that z(R(t)) 1. Find dR/dt 2. Use ws (dz/dt) and dR/dt to find z(t) dm dt = dm dR × dR dt dR dt = dm dt dm dR m = 4 3 πρd R3 dm dR = 4πρd R2 dm dt = f (R,ρd ,b) dm dt = R2 b dR dt = − R2 b 4ρd πR2 = − b 4ρd π
  • 7. BiodegradationAim: Find equation for z(t) given that z(R(t)) 1. Find dR/dt 2. Use ws (dz/dt) and dR/dt to find z(t) Integrate dR/dt: Substitute R into above: Integrate twice: R = − b 4ρd π + R0 d2 z dt2 = A− Bt z = At2 − 1 6 Bt3 + ws0 t + z0
  • 8. Model results Biodegradation Rate (kg m-2 s-1 ) 100 μm Total consumption time Position above ocean floor (m) Time to surface 5.74 x 10-10 61.5 years surface 9.61 days 5.74 x 10-9 6.15 years surface 9.65 days 5.74 x 10-8 7.38 months surface 10.05 days 5.98 x 10-7 21.26 days 1106 n/a Biodegradation Rate (kg m-2 s-1 ) 50 μm Total consumption time Position above ocean floor (m) Time to surface 5.74 x 10-10 30.76 years surface 38.55 days 5.74 x 10-9 3.08 years surface 39.84 days 5.74 x 10-8 3.69 months 1441 n/a 5.98 x 10-7 10.63 days 138.3 n/a Biodegradation Rate (kg m-2 s- 1 ) 10 μm Total consumption time Position above ocean floor (m) Time to surface 5.74 x 10-10 6.15 years 1153 n/a 5.74 x 10-9 7.38 months 115.3 n/a 5.74 x 10-8 22.15 days 11.53 n/a 5.98 x 10-7 2.13 days 1.12 n/a
  • 9. Implications • Large particles biodegrade slowly and surface quickly • Small particles biodegrade quickly and mostly remain in the fluid column • Many factors will contribute to the ultimate fate of the oil • Oil will likely persist for months, if not years 5.74 x 10-8 (kg m-2 s-1 ) 5.74 x 10-9 (kg m-2 s-1 ) Joye 2010
  • 10. Questions? AP Photo References Atlas, R.M. (1981), Microbial degradation of petroleum hydrocarbons: an environmental perspective, Microbiological Reviews, 45, 180-209. Bartha, R. (1986), Biotechnology of petroleum pollutant biodegradation, Microb. Ecol., 12, 155-172. Einstein, A. (1911), A new determination of molecular dimensions, Annals of Physics, 19, 289-306. Hopkinson, C., Brandes, J., Joye, S., Lee, R., and M. Sun., 2010, Outcome/guidance form Georgia Sea Grant Program: current status of BP oil spill, Georgia Sea Grant. Joye, S. (2010), Gulf oil blog, University of Georgia, September 5. Lubchenco, J., McNutt, M., Lehr, B., Sogge, M., Miller, M., Hammond, S., and W. Conner (2010), Deepwater Horizon/BP oil budget: what happened to the oil?, NOAA. Richardson, J.F., and Zaki, W.N. (1954), Sedimentation and fluidisation: Part I, Trans. Inst. Chem. Eng., 32, 35-53.