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Material Safety Data Sheet
CMC
Revision date May 2005 Page 1/4
1. IDENTIFICATION OF THE SUBSTANCES/PREPARATION AND THE COMPANY UNDERTAKING
Product Name CMC HVT, HVS, HVP // CMC LVT, LVS, LVP
Application Filtrate reducer for drilling fluids
Supplier Ava S.p.A.
via Salaria 1313/C
00138 ROMA
Italy
Emergency telephone number Off.: +39 06 885611324; +39 06 885611326; +39 06 885611373
Mob.: +39 3355897280; +39 3355234619; +39 3355710385
Telefax +39-06-8889363
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical description Carboxymethylcellulose High/Low viscosity.
Technical/Semi pure/Pure grade
Hazardous Impurities This product doesn't contain relevant concentrations of compounds
classified as hazardous according to EC regulation
EINECS-No.
CAS-No. CMC, sodium salt: 9004-32-4
Sodium chloride: 7647-14-5
3. HAZARD IDENTIFICATION
Inhalation Repeated or prolonged exposure may irritate the respiratory tract.
Avoid generating dusts
Skin contact May cause irritation with prolonged contact. Avoid contact with skin
Eye contact May cause mild irritation
Ingestion Do not take internally. Ingestion of product may cause the formation
of a jelly-like mass which may result in a intestinal obstruction
Human health hazards - Chronic No adverse effects expected
Environmental hazards No adverse effects expected. Do not contaminate water courses
Physical and chemical hazards Wet floor on which this powder is split may become very slippery.
This powder, when dispersed in air, represents an explosion hazard
4. FIRST AID MEASURES
Inhalation Remove to fresh air. Obtain medical attention
Skin contact Remove contaminating clothing. Wash off affected area with plenty
of water
Eye contact Gently irrigate with water for at least 15’. Obtain medical attention
Ingestion Rinse mouth immediately and repeatedly with water. Obtain medical
attention
Material Safety Data Sheet
CMC
Revision date May 2005 Page 2/4
Other information
5. FIRE FIGHTING MEASURES
Extinguishing media In case of fire use water spray, foam, powder, carbon dioxide
Unsuitable extinguishing media None
Fire and explosion hazard Powder when dispersed in air represents an explosive hazard
Protective equipment In case of fire wear a full face positive pressure self contained
breathing apparatus and protective suit
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Do not breathe powders. Avoid the contact with eyes and skin
Environmental precautions No adverse effects expected
Methods for cleaning up Remove as much as possible with broom, scoop or vacuum, as the
addition of water causes slippery floor conditions. System should be
earthed to avoid risk of ignition by static electricity. The product
makes the ground slippery when wet.
7. HANDLING AND STORAGE
Handling Avoid dust formation, maintain good ventilation and a clean area
Storage conditions Keep product dry. Store under cover
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering measures General ventilation is recommended
Exposure limits (ACGIH 2004) Nuisance dust (inhalable fraction):
TLV-TWA = 10 mg/m³ lung
Personal protection equipment
Respiratory protection Dust mask (when required by use conditions)
Hand/skin protection Impervious gloves. Standard protective clothing
Eye protection Safety glasses
Hygiene measures Eye-wash fountain near-by
9. PHYSICAL AND CHEMICAL PROPERTIES
Form Hygroscopic free flowing powder
Colour Whitish - Yellowish
Odour None
Boiling point N/A
Melting point N/A
Flash point - (PMCC) None
Material Safety Data Sheet
CMC
Revision date May 2005 Page 3/4
Auto ignition > 280 °C
Explosion limits N/E
Vapour pressure Negligible
Relative density N/A
Solubility in water Soluble
pH (2 % sol.) 6.5 - 10.5
Viscosity @ 25 °C (2 % sol.) 5 - 15.000 mPa⋅s
Bulk density 0.5 - 0.8
Freezing point N/A
Pour point N/A
Abbreviations: N/A = Not Applicable - N/E = Not Evaluated
10. STABILITY AND REACTIVITY
Stability Stable under normal usage conditions
Conditions to avoid Moisture
Materials to avoid None know
Hazardous decomposition products CO, CO2 (if involved in fire)
11. TOXICOLOGICAL INFORMATION
Acute toxicity LD50 (oral rat) > 5g/kg
Primary irritation skin/eye Can cause mild irritation
Sensitization No adverse effects expected
Chronic toxicity data No adverse effects expected
12. ECOLOGICAL INFORMATION
Persistency and degradation Completely soluble
Mobility and Bioaccumulation Solubility and mobility: high.
Bioaccumulation: no adverse effects expected
Ecotoxicological effects LC50 (Rainbow trout, 96h) > 100 ppm
LC50 (Bluegill Sunfish, 96h) > 100 ppm
13. DISPOSAL CONSIDERATIONS
Do not discharge into drains or the environment, dispose to an authorized waste collection point
14. TRANSPORT INFORMATION
Description Not regulated
UN Number N/A
Material Safety Data Sheet
CMC
Revision date May 2005 Page 4/4
Packing group N/A
ADR/RID
Class ADR 2003 Label: --
ADR 2003 Classif. Code: --
Hazard Identification
IMDG
Class Subsidiary risk: -
Em S
IATA
Class
15. REGULATORY INFORMATION
EC Classification Not regulated
Hazard Symbol None
contains:
Risk Phrases
Safety Phrases S22: Do not breathe dust.
Do not add water to the product: the addition of water causes slippery
floor condition
16. OTHER INFORMATION
This material safety data sheet provides health and safety information. The product is to be used in applications consistent
with AVA technology. Individuals handling this product should be informed of the safety precautions and should have
access to this information.

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CMC.pdf

  • 1. Material Safety Data Sheet CMC Revision date May 2005 Page 1/4 1. IDENTIFICATION OF THE SUBSTANCES/PREPARATION AND THE COMPANY UNDERTAKING Product Name CMC HVT, HVS, HVP // CMC LVT, LVS, LVP Application Filtrate reducer for drilling fluids Supplier Ava S.p.A. via Salaria 1313/C 00138 ROMA Italy Emergency telephone number Off.: +39 06 885611324; +39 06 885611326; +39 06 885611373 Mob.: +39 3355897280; +39 3355234619; +39 3355710385 Telefax +39-06-8889363 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical description Carboxymethylcellulose High/Low viscosity. Technical/Semi pure/Pure grade Hazardous Impurities This product doesn't contain relevant concentrations of compounds classified as hazardous according to EC regulation EINECS-No. CAS-No. CMC, sodium salt: 9004-32-4 Sodium chloride: 7647-14-5 3. HAZARD IDENTIFICATION Inhalation Repeated or prolonged exposure may irritate the respiratory tract. Avoid generating dusts Skin contact May cause irritation with prolonged contact. Avoid contact with skin Eye contact May cause mild irritation Ingestion Do not take internally. Ingestion of product may cause the formation of a jelly-like mass which may result in a intestinal obstruction Human health hazards - Chronic No adverse effects expected Environmental hazards No adverse effects expected. Do not contaminate water courses Physical and chemical hazards Wet floor on which this powder is split may become very slippery. This powder, when dispersed in air, represents an explosion hazard 4. FIRST AID MEASURES Inhalation Remove to fresh air. Obtain medical attention Skin contact Remove contaminating clothing. Wash off affected area with plenty of water Eye contact Gently irrigate with water for at least 15’. Obtain medical attention Ingestion Rinse mouth immediately and repeatedly with water. Obtain medical attention
  • 2. Material Safety Data Sheet CMC Revision date May 2005 Page 2/4 Other information 5. FIRE FIGHTING MEASURES Extinguishing media In case of fire use water spray, foam, powder, carbon dioxide Unsuitable extinguishing media None Fire and explosion hazard Powder when dispersed in air represents an explosive hazard Protective equipment In case of fire wear a full face positive pressure self contained breathing apparatus and protective suit 6. ACCIDENTAL RELEASE MEASURES Personal precautions Do not breathe powders. Avoid the contact with eyes and skin Environmental precautions No adverse effects expected Methods for cleaning up Remove as much as possible with broom, scoop or vacuum, as the addition of water causes slippery floor conditions. System should be earthed to avoid risk of ignition by static electricity. The product makes the ground slippery when wet. 7. HANDLING AND STORAGE Handling Avoid dust formation, maintain good ventilation and a clean area Storage conditions Keep product dry. Store under cover 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures General ventilation is recommended Exposure limits (ACGIH 2004) Nuisance dust (inhalable fraction): TLV-TWA = 10 mg/m³ lung Personal protection equipment Respiratory protection Dust mask (when required by use conditions) Hand/skin protection Impervious gloves. Standard protective clothing Eye protection Safety glasses Hygiene measures Eye-wash fountain near-by 9. PHYSICAL AND CHEMICAL PROPERTIES Form Hygroscopic free flowing powder Colour Whitish - Yellowish Odour None Boiling point N/A Melting point N/A Flash point - (PMCC) None
  • 3. Material Safety Data Sheet CMC Revision date May 2005 Page 3/4 Auto ignition > 280 °C Explosion limits N/E Vapour pressure Negligible Relative density N/A Solubility in water Soluble pH (2 % sol.) 6.5 - 10.5 Viscosity @ 25 °C (2 % sol.) 5 - 15.000 mPa⋅s Bulk density 0.5 - 0.8 Freezing point N/A Pour point N/A Abbreviations: N/A = Not Applicable - N/E = Not Evaluated 10. STABILITY AND REACTIVITY Stability Stable under normal usage conditions Conditions to avoid Moisture Materials to avoid None know Hazardous decomposition products CO, CO2 (if involved in fire) 11. TOXICOLOGICAL INFORMATION Acute toxicity LD50 (oral rat) > 5g/kg Primary irritation skin/eye Can cause mild irritation Sensitization No adverse effects expected Chronic toxicity data No adverse effects expected 12. ECOLOGICAL INFORMATION Persistency and degradation Completely soluble Mobility and Bioaccumulation Solubility and mobility: high. Bioaccumulation: no adverse effects expected Ecotoxicological effects LC50 (Rainbow trout, 96h) > 100 ppm LC50 (Bluegill Sunfish, 96h) > 100 ppm 13. DISPOSAL CONSIDERATIONS Do not discharge into drains or the environment, dispose to an authorized waste collection point 14. TRANSPORT INFORMATION Description Not regulated UN Number N/A
  • 4. Material Safety Data Sheet CMC Revision date May 2005 Page 4/4 Packing group N/A ADR/RID Class ADR 2003 Label: -- ADR 2003 Classif. Code: -- Hazard Identification IMDG Class Subsidiary risk: - Em S IATA Class 15. REGULATORY INFORMATION EC Classification Not regulated Hazard Symbol None contains: Risk Phrases Safety Phrases S22: Do not breathe dust. Do not add water to the product: the addition of water causes slippery floor condition 16. OTHER INFORMATION This material safety data sheet provides health and safety information. The product is to be used in applications consistent with AVA technology. Individuals handling this product should be informed of the safety precautions and should have access to this information.