CHAPTER
EIGHT
Treatment and disposal of leachates from landfills
A landfill is a site for the disposal of waste materials. It is a
designated site for the disposal of waste by
burying it in the ground.
Leachate is the liquid that percolates through landfill
waste, often carrying dissolved and suspended pollutants. It is
Water that has percolated through a solid and leeached out
some the constituents.
Landfill leachate is produced by residual water
and precipitation passing through degrading waste deposits
Landfill leachates may constitute
Treatment Options
Off-site
facility
On-site
facility
Partial
Complete
Disposal
• Effluents
• Sludges
etc.
Leachate Properties Affecting Treatment
Contaminant Concentration Fluctuation
 Some peak quickly and decline: e.g., BOD
 Some persist for long periods: e.g., NH3-N
 Daily and seasonal variations occur
Planning Treatment and Disposal
 Estimate leachate flow, Q
➹ Variations with site age
 Estimate leachate contaminant
conc., C
➹ Type
➹ Variations with age
 Identify treatment and disposal
options with discharge
standards and cost
 Select treatment and disposal
system
➹ Introduce uncertainty
➹ Maintain flexibility
Q
t
C
t
Constructed Wetland
7
Uses
 Polishing treatment
 Complete treatment
Advantages
 Relatively inexpensive to build/operate
 Associated with ‘green’ technologies
 Wetlands credits
Disadvantages
 Large land requirement
 Cold weather
 Mediocre results especially for complete
treatment systems
Reed Bed for Effluent
Polishing
88
Reed Bed
23
Leachate Treatment
24
 Off-Site
➹Removal by road tanker to sewage works
➹Removal via pipeline or sewer to disposal site
➹Most common
 On-Site
➹Biological
➹Physical/Chemical
➹Mixed
On-Site Treatment
25
 Physical/Chemical Processes
➹ Coagulation/flocculation/settlement
➹ pH control and aeration/air stripping
➹ Activated carbon adsorption
➹ Reverse osmosis
➹ Oxidation with hydrogen peroxide
➹ Oxidation with hypochlorite
➹ Degassing ➹ Evaporation
 Biological
➹ Aerobic: trickling filter, activated sludge, aerated
lagoon,
rotating biological contactor, sequencing batch reactor
(SBR)
➹ Anaerobic: submerged filter, upflow anaerobic sludge
blanket (UASB)
➹ Anoxic: denitrification
 Mixed
➹ Land treatment
➹ Vegetated ditch/root zone treatment
 Suspended growth system
 Completely mixed mode; batch mode with discontinuous
flow
Influent
2 3
1
Fill React Settle
Effluent
4
Draw Idle
5
Mixing
Sequencing Batch Reactor (SBR)
26
Aerated Lagoons
Surface
aerator
Raw
wastewater Effluent
Suspended growth system
Comletely mixed mode
Contact time limited to hydraulic
retention time due to no recycle of
sludge
Limited effluent quality
27
Rotating Biological Contactor (RBC)
Attached growth system
Design based on
specific surface
area
Aeration provided
by rotating disks
Better performance
than other fixed-
film systems due
to lower
organic
loading per mass of
biomass, longer
detention time,
and little short-
circuiting
28
Anaerobic Fixed Film Reactor
 Sludge age: > 100 days
VSS: > 20,000 mg/L
 Increased efficiency and
rapid elution of toxic sludge
 Not good for wastes containing a
large portion of particulates
and/or carbohydrates due to
clogging
 Possible to treat low strength
waste at nominal
temperatures economically
 Effluent recycle (sufficient
alkalinity) to raise pH to 7
 Possible buildup of
nonbiodegradable solids in
reactor
 Loading rate: 0.42~3.4 kg COD/m3·day at 25°C; 60~80% COD 29
Upflow Anaerobic Sludge
Blanket (UASB) Reactor
 High sludge age at high
loadings with separation
of gas from the sludge
solids
 VSS: 20,000 ~ 150,000
mg/L
 Sugar-beet waste: reactor size
800 m3, loading 10 kg
COD/m3·day, and HRT 4 hrs
 treatment efficiency 80%
 Difficult to maintain low effluent SS levels
and occasional unexplained biomass washout 30
On-Site Treatment
31
Anaerobic Biological Treatment
 Anaerobic Fixed Film Reactors
(AFFR) Films better than
digesters
➹ Biomass washout
reduced
➹ Higher loading possible
➹ Kinetically better
 Experience
➹ Field – limited
➹ Laboratory: support medium -
granular carbon, plastic film, sand,
On-Site Treatment
32
Physical/Chemical Processes
 Addition of simple chemicals followed by a
sequence of mixing, coagulation/flocculation, and
settlement
 Chemicals tested:
➹ Hydrated lime
➹ Quick lime
➹ Sodium hydroxide
➹ Magnesium hydroxide
➹ Alum
➹ Ferric chloride
➹ Ferric sulfate
➹ Polymeric coagulant aids
On-Site Treatment
Physical/Chemical Processes - Examples
Influent
Lime
Sludge
Backwash
Effluent
Carbon Adsorption
Granular
Filtration
Sedimentation
Chemical
Precipitation Precipitate
metals
Settle precipitates
Clarify influent
to
carbon adsorption
Carbon regeneration
Adsorb TOC and
solvents
Destroy TOC and
solvents
33
Proposed Leachate Treatment
Chemical
Sludge
wasting
Remove
ammonia
(optional)
Remove organics,
ammonia,
nitrite/nitrate, and
toxic compounds
Polish the effluent
Reed bed
Discharge
Leachate
Equalization
Tank
Chemical
Precipitation
Chemical
Equalize flow Remove heavy
metals and
solids
34
(optional)
Air
Stripping
SBR
Aerobic Landfill Bioreactor
35
Landfill as a Bioreactor
36
Measure of Success
 Faster landfill stabilization
 Increased air space
 Reduced leachate management costs
 Reduced gases and odors
 Reduced long-term care costs
 Possibly, mining to regenerate cover material -
a perpetual landfill?
Leachate Recirculation
37
 Can be used during the early stages when
leachate production quantities are low.
 Can be used in later stages to eliminate problems
of off-site transport during peak production
periods or during downtimes of the transport
devices.
Advantages
 Attenuation of leachate strength/quantity
 Increased rate of landfill stabilization
 Enhanced gas production rates
 Immobilization of metals from landfill material
 Improved landfill settling rates
 Increased compaction rates
Disadvantages
 Ponding/localized accumulation of leachate
 Severe localized subsidence/side slope
stability problems
 Other management requirement due to
excess leachate production
 Selective attenuation of contaminants
recirculation, thus further treatment required
 Mass/fluid transfer limitation
38
Leachate Recirculation
Methods of Recirculation
 Spray irrigation
 Surface application
 Gravity well/trench
 Injection well/trench
 Infiltration ponds
39
Leachate Recirculation (3)
Spray Irrigation
40
Advantages
 Good coverage
 Moderate weather restrictions
 Subject to evapotranspiration
 Easily adjusted for settlement
concerns
Disadvantages
 Subject to plugging
 Sophisticated design and construction
 Subject to freezing
 Surface water contamination potential
Injection Needles
33
Advantages
 Portable
 Good coverage
 Moderate design, construction
requirements
 Moderate weather restrictions
 Easily adjusted and maintained
Disadvantages
 Potential crushing of pipes
 Subject to freezing
 Surface water contamination potential
(thru pipe leaks), limited use after capping
Surface Application
42
Advantages
 Simple design
 Most evaporation potential
 Good coverage
 Low capital investment
 Least subject to plugging
 Easily accessed for maintenance
Disadvantages
 Odor
 Weather restrictions (wind, rain)
 Health risk
 Surface water contamination risk
Vertical Wells
43
Advantages
 Minimal weather restrictions
 No odor
 Simple design
 Easily combined with horizontal
distribution lines
Disadvantages
 Poor coverage w/o horizontal distribution
 Susceptible to differential settlement
damage
 Subject to plugging
 Subject to short circulating of leachate
 Difficult to maintain vertical levelness
Horizontal Wells/Trenches
44
Advantages
 Fair to good coverage
 Minimal weather restrictions
Disadvantages
 More sophisticated design and
construction required
 Susceptible to differential settlement
damage
 Virtually impossible repair or maintenance
Management of Leachate
 Collection(Drainage layers, Pipes and Storage
tanks)
 Treatment(Pre-Treatment, Biological
Treatment and Advanced Treatment)
 Disposal(Discharge to Municipal Sewers,
Recirculation, Evaporation and Off-site
Treatment)

WWQM CH-8 Treatment and disposal of leachates from landfills.pptx

  • 1.
    CHAPTER EIGHT Treatment and disposalof leachates from landfills A landfill is a site for the disposal of waste materials. It is a designated site for the disposal of waste by burying it in the ground. Leachate is the liquid that percolates through landfill waste, often carrying dissolved and suspended pollutants. It is Water that has percolated through a solid and leeached out some the constituents. Landfill leachate is produced by residual water and precipitation passing through degrading waste deposits
  • 8.
  • 17.
  • 19.
    Leachate Properties AffectingTreatment Contaminant Concentration Fluctuation  Some peak quickly and decline: e.g., BOD  Some persist for long periods: e.g., NH3-N  Daily and seasonal variations occur
  • 20.
    Planning Treatment andDisposal  Estimate leachate flow, Q ➹ Variations with site age  Estimate leachate contaminant conc., C ➹ Type ➹ Variations with age  Identify treatment and disposal options with discharge standards and cost  Select treatment and disposal system ➹ Introduce uncertainty ➹ Maintain flexibility Q t C t
  • 21.
    Constructed Wetland 7 Uses  Polishingtreatment  Complete treatment Advantages  Relatively inexpensive to build/operate  Associated with ‘green’ technologies  Wetlands credits Disadvantages  Large land requirement  Cold weather  Mediocre results especially for complete treatment systems
  • 22.
    Reed Bed forEffluent Polishing 88
  • 23.
  • 24.
    Leachate Treatment 24  Off-Site ➹Removalby road tanker to sewage works ➹Removal via pipeline or sewer to disposal site ➹Most common  On-Site ➹Biological ➹Physical/Chemical ➹Mixed
  • 25.
    On-Site Treatment 25  Physical/ChemicalProcesses ➹ Coagulation/flocculation/settlement ➹ pH control and aeration/air stripping ➹ Activated carbon adsorption ➹ Reverse osmosis ➹ Oxidation with hydrogen peroxide ➹ Oxidation with hypochlorite ➹ Degassing ➹ Evaporation  Biological ➹ Aerobic: trickling filter, activated sludge, aerated lagoon, rotating biological contactor, sequencing batch reactor (SBR) ➹ Anaerobic: submerged filter, upflow anaerobic sludge blanket (UASB) ➹ Anoxic: denitrification  Mixed ➹ Land treatment ➹ Vegetated ditch/root zone treatment
  • 26.
     Suspended growthsystem  Completely mixed mode; batch mode with discontinuous flow Influent 2 3 1 Fill React Settle Effluent 4 Draw Idle 5 Mixing Sequencing Batch Reactor (SBR) 26
  • 27.
    Aerated Lagoons Surface aerator Raw wastewater Effluent Suspendedgrowth system Comletely mixed mode Contact time limited to hydraulic retention time due to no recycle of sludge Limited effluent quality 27
  • 28.
    Rotating Biological Contactor(RBC) Attached growth system Design based on specific surface area Aeration provided by rotating disks Better performance than other fixed- film systems due to lower organic loading per mass of biomass, longer detention time, and little short- circuiting 28
  • 29.
    Anaerobic Fixed FilmReactor  Sludge age: > 100 days VSS: > 20,000 mg/L  Increased efficiency and rapid elution of toxic sludge  Not good for wastes containing a large portion of particulates and/or carbohydrates due to clogging  Possible to treat low strength waste at nominal temperatures economically  Effluent recycle (sufficient alkalinity) to raise pH to 7  Possible buildup of nonbiodegradable solids in reactor  Loading rate: 0.42~3.4 kg COD/m3·day at 25°C; 60~80% COD 29
  • 30.
    Upflow Anaerobic Sludge Blanket(UASB) Reactor  High sludge age at high loadings with separation of gas from the sludge solids  VSS: 20,000 ~ 150,000 mg/L  Sugar-beet waste: reactor size 800 m3, loading 10 kg COD/m3·day, and HRT 4 hrs  treatment efficiency 80%  Difficult to maintain low effluent SS levels and occasional unexplained biomass washout 30
  • 31.
    On-Site Treatment 31 Anaerobic BiologicalTreatment  Anaerobic Fixed Film Reactors (AFFR) Films better than digesters ➹ Biomass washout reduced ➹ Higher loading possible ➹ Kinetically better  Experience ➹ Field – limited ➹ Laboratory: support medium - granular carbon, plastic film, sand,
  • 32.
    On-Site Treatment 32 Physical/Chemical Processes Addition of simple chemicals followed by a sequence of mixing, coagulation/flocculation, and settlement  Chemicals tested: ➹ Hydrated lime ➹ Quick lime ➹ Sodium hydroxide ➹ Magnesium hydroxide ➹ Alum ➹ Ferric chloride ➹ Ferric sulfate ➹ Polymeric coagulant aids
  • 33.
    On-Site Treatment Physical/Chemical Processes- Examples Influent Lime Sludge Backwash Effluent Carbon Adsorption Granular Filtration Sedimentation Chemical Precipitation Precipitate metals Settle precipitates Clarify influent to carbon adsorption Carbon regeneration Adsorb TOC and solvents Destroy TOC and solvents 33
  • 34.
    Proposed Leachate Treatment Chemical Sludge wasting Remove ammonia (optional) Removeorganics, ammonia, nitrite/nitrate, and toxic compounds Polish the effluent Reed bed Discharge Leachate Equalization Tank Chemical Precipitation Chemical Equalize flow Remove heavy metals and solids 34 (optional) Air Stripping SBR
  • 35.
  • 36.
    Landfill as aBioreactor 36 Measure of Success  Faster landfill stabilization  Increased air space  Reduced leachate management costs  Reduced gases and odors  Reduced long-term care costs  Possibly, mining to regenerate cover material - a perpetual landfill?
  • 37.
    Leachate Recirculation 37  Canbe used during the early stages when leachate production quantities are low.  Can be used in later stages to eliminate problems of off-site transport during peak production periods or during downtimes of the transport devices. Advantages  Attenuation of leachate strength/quantity  Increased rate of landfill stabilization  Enhanced gas production rates  Immobilization of metals from landfill material  Improved landfill settling rates  Increased compaction rates
  • 38.
    Disadvantages  Ponding/localized accumulationof leachate  Severe localized subsidence/side slope stability problems  Other management requirement due to excess leachate production  Selective attenuation of contaminants recirculation, thus further treatment required  Mass/fluid transfer limitation 38 Leachate Recirculation
  • 39.
    Methods of Recirculation Spray irrigation  Surface application  Gravity well/trench  Injection well/trench  Infiltration ponds 39 Leachate Recirculation (3)
  • 40.
    Spray Irrigation 40 Advantages  Goodcoverage  Moderate weather restrictions  Subject to evapotranspiration  Easily adjusted for settlement concerns Disadvantages  Subject to plugging  Sophisticated design and construction  Subject to freezing  Surface water contamination potential
  • 41.
    Injection Needles 33 Advantages  Portable Good coverage  Moderate design, construction requirements  Moderate weather restrictions  Easily adjusted and maintained Disadvantages  Potential crushing of pipes  Subject to freezing  Surface water contamination potential (thru pipe leaks), limited use after capping
  • 42.
    Surface Application 42 Advantages  Simpledesign  Most evaporation potential  Good coverage  Low capital investment  Least subject to plugging  Easily accessed for maintenance Disadvantages  Odor  Weather restrictions (wind, rain)  Health risk  Surface water contamination risk
  • 43.
    Vertical Wells 43 Advantages  Minimalweather restrictions  No odor  Simple design  Easily combined with horizontal distribution lines Disadvantages  Poor coverage w/o horizontal distribution  Susceptible to differential settlement damage  Subject to plugging  Subject to short circulating of leachate  Difficult to maintain vertical levelness
  • 44.
    Horizontal Wells/Trenches 44 Advantages  Fairto good coverage  Minimal weather restrictions Disadvantages  More sophisticated design and construction required  Susceptible to differential settlement damage  Virtually impossible repair or maintenance
  • 45.
    Management of Leachate Collection(Drainage layers, Pipes and Storage tanks)  Treatment(Pre-Treatment, Biological Treatment and Advanced Treatment)  Disposal(Discharge to Municipal Sewers, Recirculation, Evaporation and Off-site Treatment)